GB1254349A - Polymerisation process - Google Patents
Polymerisation processInfo
- Publication number
- GB1254349A GB1254349A GB2277669A GB2277669A GB1254349A GB 1254349 A GB1254349 A GB 1254349A GB 2277669 A GB2277669 A GB 2277669A GB 2277669 A GB2277669 A GB 2277669A GB 1254349 A GB1254349 A GB 1254349A
- Authority
- GB
- United Kingdom
- Prior art keywords
- haloformate
- polymerized
- acid
- polymerisation process
- dipersebacic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000007900 aqueous suspension Substances 0.000 abstract 1
- RIFGWPKJUGCATF-UHFFFAOYSA-N ethyl chloroformate Chemical compound CCOC(Cl)=O RIFGWPKJUGCATF-UHFFFAOYSA-N 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 150000004965 peroxy acids Chemical class 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1,254,349. Polymerization process. BP CHEMICALS Ltd. 4 May, 1970 [5 May, 1969], No. 22776/69. Heading C3P. Ethylenically unsaturated monomers are polymerized in aqueous suspension in the presence of an acylperoxycarbonate initiator formed in situ from a peracid R(CO.O.OH) n and a haloformate R<SP>1</SP>OCOX where R and R<SP>1</SP> are organic radicals, X is halogen and n is an integer. In the examples vinyl chloride is polymerized using as the acid percaprylic, dipersebacic or peracetic acid and as the haloformate ethyl chloroformate, which is added with the monomer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2277669A GB1254349A (en) | 1969-05-05 | 1969-05-05 | Polymerisation process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2277669A GB1254349A (en) | 1969-05-05 | 1969-05-05 | Polymerisation process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1254349A true GB1254349A (en) | 1971-11-17 |
Family
ID=10184897
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2277669A Expired GB1254349A (en) | 1969-05-05 | 1969-05-05 | Polymerisation process |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1254349A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2355004A1 (en) * | 1976-06-16 | 1978-01-13 | Argus Chem | THERMALLY STABLE ACYLPEROXYCARBONIC ESTERS OF HIGH MOLECULAR MASSES AND THEIR USE AS POLYMERIZATION INITIATING AGENTS |
-
1969
- 1969-05-05 GB GB2277669A patent/GB1254349A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2355004A1 (en) * | 1976-06-16 | 1978-01-13 | Argus Chem | THERMALLY STABLE ACYLPEROXYCARBONIC ESTERS OF HIGH MOLECULAR MASSES AND THEIR USE AS POLYMERIZATION INITIATING AGENTS |
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