GB1110091A - Process for the rapid tanning of medium weight and heavy leather - Google Patents
Process for the rapid tanning of medium weight and heavy leatherInfo
- Publication number
- GB1110091A GB1110091A GB76/66A GB7666A GB1110091A GB 1110091 A GB1110091 A GB 1110091A GB 76/66 A GB76/66 A GB 76/66A GB 7666 A GB7666 A GB 7666A GB 1110091 A GB1110091 A GB 1110091A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tannin
- leather
- tanning
- sulphonic acid
- liquor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010985 leather Substances 0.000 title abstract 9
- 238000000034 method Methods 0.000 title abstract 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 7
- 229920001864 tannin Polymers 0.000 abstract 6
- 235000018553 tannin Nutrition 0.000 abstract 6
- 239000001648 tannin Substances 0.000 abstract 6
- 239000003795 chemical substances by application Substances 0.000 abstract 4
- 239000007859 condensation product Substances 0.000 abstract 4
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 abstract 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 3
- 229910052804 chromium Inorganic materials 0.000 abstract 3
- 239000011651 chromium Substances 0.000 abstract 3
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 abstract 3
- 239000002699 waste material Substances 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 235000015217 chromium(III) sulphate Nutrition 0.000 abstract 2
- 239000011696 chromium(III) sulphate Substances 0.000 abstract 2
- 230000007935 neutral effect Effects 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 abstract 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 241001070941 Castanea Species 0.000 abstract 1
- 235000014036 Castanea Nutrition 0.000 abstract 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 abstract 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 1
- 235000017343 Quebracho blanco Nutrition 0.000 abstract 1
- 241000065615 Schinopsis balansae Species 0.000 abstract 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 abstract 1
- 235000011941 Tilia x europaea Nutrition 0.000 abstract 1
- 239000001887 acacia decurrens willd. var. dealbata absolute Substances 0.000 abstract 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 150000003841 chloride salts Chemical class 0.000 abstract 1
- 229920002705 flavono-ellagitannin Polymers 0.000 abstract 1
- 239000004571 lime Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 abstract 1
- 239000004289 sodium hydrogen sulphite Substances 0.000 abstract 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
- 235000013311 vegetables Nutrition 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/28—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/04—Mineral tanning
- C14C3/06—Mineral tanning using chromium compounds
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/08—Chemical tanning by organic agents
- C14C3/10—Vegetable tanning
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/08—Chemical tanning by organic agents
- C14C3/10—Vegetable tanning
- C14C3/12—Vegetable tanning using purified or modified vegetable tanning agents
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/08—Chemical tanning by organic agents
- C14C3/18—Chemical tanning by organic agents using polycondensation products or precursors thereof
- C14C3/20—Chemical tanning by organic agents using polycondensation products or precursors thereof sulfonated
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
A process for the rapid tanning of medium weight and heavy leather comprises pre-tanning with a chromium tannin, or a mixture of a chromium tannin and (a) a naphthalene sulphonic acid and/or (b) a condensation product of a naphthalene sulphonic acid and formaldehyde and/or (c) a synthetic tannin other than those mentioned in (a) and (b) and/or (d) sulphite waste liquor, in a liquor or without a liquor, treating the pre-tanned leather with a precursory agent comprising a condensation product of a naphthalene sulphonic acid and formaldehyde and/or sulphite waste liquor acid and optionally containing 5-20% by weight of a water soluble inorganic neutral salt, and finally tanning with a powdered synthetic and/or vegetable tannin without a liquor. The neutral salts specified include the chlorides and sulphates of sodium potassium and ammonium. The precursory agent has its acid number adjusted to at least 30 before or during its treatment of the pre-tanned leather, by means of formic, glutaric, adipic, oxalic or naphthalene sulphonic acid, sodium bisulphite or ammonia. In the Examples cow hides are treated in the lime house and pickled before being pretanned. The pre-tanning agents specified are a chromium complex tannin as in Example (1) of French Specification 1,329,231, a mixture of a condensation product of Example (1) of German Specification 1,053,517, sulphite waste liquor and chromic sulphate, chromic sulphate tannin, and a mixture of chromium sulphate and b -naphthalene sulphonic acid-formaldehyde condensation product. The final tanning agents specified are mimosa extract, chestnut extract, sulphited quebracho extract and synthetic exchange tannin. The tanning may be done in a drum. The process is suitable for the production of sole leather, sole leather splits, inside sole leather welting leather and upper leather.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF44869A DE1288233B (en) | 1965-01-02 | 1965-01-02 | Process for the rapid tanning of medium or heavy skins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1110091A true GB1110091A (en) | 1968-04-18 |
Family
ID=7100240
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB76/66A Expired GB1110091A (en) | 1965-01-02 | 1966-01-03 | Process for the rapid tanning of medium weight and heavy leather |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3519378A (en) |
| BE (1) | BE674586A (en) |
| CH (1) | CH465125A (en) |
| DE (1) | DE1288233B (en) |
| FR (1) | FR1464309A (en) |
| GB (1) | GB1110091A (en) |
| NL (1) | NL6517270A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0533011A1 (en) * | 1991-09-19 | 1993-03-24 | Bayer Ag | Process for producing chrome-tanned leather |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3888625A (en) * | 1973-01-29 | 1975-06-10 | Chemtan Company | Method of chrome-retanning leather |
| IT1121190B (en) * | 1979-07-24 | 1986-03-26 | Torrini Ottavio | PROCESSING OF LEATHER WITH TRIVALENT GROMINE SALTS WITHIN ROTATING BARRELS WITHOUT RESIDUAL BATH FOR REASONS OF ECOLOGICAL ORDER |
| US4314802A (en) * | 1979-08-24 | 1982-02-09 | Rohm And Haas Company | Process for producing leather |
| CA1146302A (en) * | 1979-08-24 | 1983-05-17 | William C. Beier | Process for producing leather |
| BR9904027A (en) * | 1999-09-30 | 2001-06-05 | Seta S A Extrativa Tanino De A | Permeable packaging for gradual supply of tanning material and leather tanning process |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1327105A (en) * | 1915-04-23 | 1920-01-06 | Landmark Hans Brun | Process of the production of tanning extract from waste sulfite lye |
| US1430477A (en) * | 1920-03-25 | 1922-09-26 | Fulcra Tan Company | Tanning preparation |
| GB739312A (en) * | 1952-11-08 | 1955-10-26 | Toten Cellulosefab As | Process for reducing the salt content and adjusting ph in tanning solutions |
| DE941681C (en) * | 1953-01-29 | 1956-04-19 | Bayer Ag | Tanning agents in solid or powder form |
| US2955904A (en) * | 1956-09-11 | 1960-10-11 | Schnoller Desiderio | Rapid process for tanning hides |
| US2997364A (en) * | 1956-12-11 | 1961-08-22 | Bayer Ag | Chrome-tanning mixtures and preparation of leather therewith |
| US3065039A (en) * | 1957-02-02 | 1962-11-20 | Bayer Ag | Sulfo-methylated phenol-formaldehyde tanning agents |
| DE1137005B (en) * | 1961-03-10 | 1962-09-27 | Basf Ag | Process for the preparation of condensation products from naphthalenesulfonic acids and aldehydes |
| DE1244332B (en) * | 1961-07-19 | 1967-07-13 | Bayer Ag | Process for the rapid tanning of medium or heavy leathers |
| DE1273119B (en) * | 1961-08-03 | 1968-07-18 | Bayer Ag | Process for the rapid tanning of medium or heavy skin |
| FR1329231A (en) * | 1962-07-18 | 1963-06-07 | Bayer Ag | Process for the rapid tanning of medium and heavy leathers |
| FR1330451A (en) * | 1962-08-02 | 1963-06-21 | Bayer Ag | Process for the rapid tanning of medium and heavy leathers |
-
1965
- 1965-01-02 DE DEF44869A patent/DE1288233B/en active Pending
- 1965-12-13 CH CH1711965A patent/CH465125A/en unknown
- 1965-12-20 US US515236A patent/US3519378A/en not_active Expired - Lifetime
- 1965-12-31 BE BE674586D patent/BE674586A/xx unknown
- 1965-12-31 NL NL6517270A patent/NL6517270A/xx unknown
-
1966
- 1966-01-03 GB GB76/66A patent/GB1110091A/en not_active Expired
- 1966-01-03 FR FR44664A patent/FR1464309A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0533011A1 (en) * | 1991-09-19 | 1993-03-24 | Bayer Ag | Process for producing chrome-tanned leather |
| US5340365A (en) * | 1991-09-19 | 1994-08-23 | Bayer Aktiengesellschaft | Process for producing chrome leather |
Also Published As
| Publication number | Publication date |
|---|---|
| NL6517270A (en) | 1966-07-04 |
| US3519378A (en) | 1970-07-07 |
| FR1464309A (en) | 1966-12-30 |
| DE1288233B (en) | 1969-01-30 |
| CH465125A (en) | 1968-11-15 |
| BE674586A (en) | 1966-04-15 |
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