GB1187362A - Process for the Preparation of Polyurethane Polyureas - Google Patents
Process for the Preparation of Polyurethane PolyureasInfo
- Publication number
- GB1187362A GB1187362A GB677268A GB677268A GB1187362A GB 1187362 A GB1187362 A GB 1187362A GB 677268 A GB677268 A GB 677268A GB 677268 A GB677268 A GB 677268A GB 1187362 A GB1187362 A GB 1187362A
- Authority
- GB
- United Kingdom
- Prior art keywords
- water
- soluble
- watersoluble
- polyureas
- feb
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920002396 Polyurea Polymers 0.000 title abstract 4
- 229920002635 polyurethane Polymers 0.000 title abstract 3
- 239000004814 polyurethane Substances 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 5
- 150000001412 amines Chemical class 0.000 abstract 3
- 125000003277 amino group Chemical group 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- -1 diisocyanate compound Chemical class 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 abstract 1
- KNIUHBNRWZGIQQ-UHFFFAOYSA-N 7-diethoxyphosphinothioyloxy-4-methylchromen-2-one Chemical compound CC1=CC(=O)OC2=CC(OP(=S)(OCC)OCC)=CC=C21 KNIUHBNRWZGIQQ-UHFFFAOYSA-N 0.000 abstract 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 abstract 1
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Chemical group 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 229940043276 diisopropanolamine Drugs 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 125000000524 functional group Chemical group 0.000 abstract 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 abstract 1
- KMBPCQSCMCEPMU-UHFFFAOYSA-N n'-(3-aminopropyl)-n'-methylpropane-1,3-diamine Chemical compound NCCCN(C)CCCN KMBPCQSCMCEPMU-UHFFFAOYSA-N 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 229960001124 trientine Drugs 0.000 abstract 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
- C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
- C08G18/4252—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids derived from polyols containing polyether groups and polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
1,187,362. Polyurethanes - polyureas. FARBENFABRIKEN BAYER A.G. 12 Feb., 1968 [10 Feb., 1967], No. 6772/68. Heading C3R. Polyurethane-polyureas which are watersoluble are prepared by reacting a watersoluble reaction product of a water-soluble polyhydroxyl compound which contains at least two reactive hydrogen atoms and an excess of a diisocyanate compound, with an aqueous solution containing from 0À1 to 10% by weight of one or more polyfunctional amines containing aliphatically linked amine groups, the amount of the poly-functional amine being such as to provide a polyurethane polyurea having free amino groups. The water-soluble polyhydroxy compounds are suitably of the formula wherein R is an alkylene radical having 2 to 4 carbon atoms, Y is oxygen, sulphur, tertiary nitrogen or the radical of an at least difunctional hydroxy-alkylatable compound obtained by removal of H atoms from the functional groups, x is an integer of at least 1 and z is an integer of at least 2. Exemplified polyhydroxyl compounds are polyethylene glycol ethers, methyldiethanolamine and a polyaddition product derived from methyl diisopropanolamine and triethylene glycol. The water-soluble polyhydroxyl compounds are reacted with conventional diisooyanate optionally in the presence of a solvent which is preferably soluble with water or miscible in water. Exemplified amines which are reacted with the watersoluble reaction product are diethylene triamine, triethylene tetramine, bis-(3-aminopropyl) methylamine and N-2-hydroxyethyl ethylene diamine.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF0051481 | 1967-02-10 | ||
| DEE0051481 | 1967-02-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1187362A true GB1187362A (en) | 1970-04-08 |
Family
ID=25973649
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB677268A Expired GB1187362A (en) | 1967-02-10 | 1968-02-12 | Process for the Preparation of Polyurethane Polyureas |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE710580A (en) |
| CH (1) | CH510074A (en) |
| DE (1) | DE1720617A1 (en) |
| FR (1) | FR1560629A (en) |
| GB (1) | GB1187362A (en) |
| NL (1) | NL6801363A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2062603A1 (en) * | 2007-11-15 | 2009-05-27 | Tyco Healthcare Group LP | Speeding cure rate of bioadhesives |
| US7858078B2 (en) | 2005-12-06 | 2010-12-28 | Tyco Healthcare Group Lp | Bioabsorbable surgical composition |
| US7858835B2 (en) | 2007-06-27 | 2010-12-28 | Tyco Healthcare Group Lp | Foam control for synthetic adhesive/sealant |
| US7947263B2 (en) | 2005-12-06 | 2011-05-24 | Tyco Healthcare Group Lp | Biocompatible surgical compositions |
| US8263704B2 (en) | 2008-04-23 | 2012-09-11 | Tyco Healthcare Group Lp | Bioabsorbable surgical composition |
| US8288477B2 (en) | 2005-12-06 | 2012-10-16 | Tyco Healthcare Group Lp | Bioabsorbable compounds and compositions containing them |
| US8449714B2 (en) | 2005-12-08 | 2013-05-28 | Covidien Lp | Biocompatible surgical compositions |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1069367B (en) * | 1959-11-19 | Bergheim/Sieg Michael Emmerich | Sash frame for windows made of a plastic-coated hollow metal profile with a rectangular cross-section | |
| DE1157758B (en) * | 1958-04-17 | 1963-11-21 | Georg Heinrich Kins | Window frames made of plastic profiles |
| US4143014A (en) * | 1977-11-09 | 1979-03-06 | The Upjohn Company | Novel compositions |
| EP0581159B1 (en) * | 1992-07-31 | 1997-05-28 | Bayer Ag | Anionically modified polyureas having reduced tack for leather coating |
-
1967
- 1967-02-10 DE DE19671720617 patent/DE1720617A1/en active Pending
-
1968
- 1968-01-12 CH CH44368A patent/CH510074A/en not_active IP Right Cessation
- 1968-01-30 NL NL6801363A patent/NL6801363A/xx unknown
- 1968-02-09 FR FR1560629D patent/FR1560629A/fr not_active Expired
- 1968-02-09 BE BE710580D patent/BE710580A/xx unknown
- 1968-02-12 GB GB677268A patent/GB1187362A/en not_active Expired
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7858078B2 (en) | 2005-12-06 | 2010-12-28 | Tyco Healthcare Group Lp | Bioabsorbable surgical composition |
| US7947263B2 (en) | 2005-12-06 | 2011-05-24 | Tyco Healthcare Group Lp | Biocompatible surgical compositions |
| US8288477B2 (en) | 2005-12-06 | 2012-10-16 | Tyco Healthcare Group Lp | Bioabsorbable compounds and compositions containing them |
| US8357361B2 (en) | 2005-12-06 | 2013-01-22 | Covidien Lp | Bioabsorbable surgical composition |
| US8449714B2 (en) | 2005-12-08 | 2013-05-28 | Covidien Lp | Biocompatible surgical compositions |
| US8790488B2 (en) | 2005-12-08 | 2014-07-29 | Covidien Lp | Biocompatible surgical compositions |
| US7858835B2 (en) | 2007-06-27 | 2010-12-28 | Tyco Healthcare Group Lp | Foam control for synthetic adhesive/sealant |
| EP2062603A1 (en) * | 2007-11-15 | 2009-05-27 | Tyco Healthcare Group LP | Speeding cure rate of bioadhesives |
| US8500947B2 (en) | 2007-11-15 | 2013-08-06 | Covidien Lp | Speeding cure rate of bioadhesives |
| AU2008243205B2 (en) * | 2007-11-15 | 2014-05-15 | Covidien Lp | Speeding cure rate of bioadhesives |
| US8263704B2 (en) | 2008-04-23 | 2012-09-11 | Tyco Healthcare Group Lp | Bioabsorbable surgical composition |
Also Published As
| Publication number | Publication date |
|---|---|
| BE710580A (en) | 1968-06-17 |
| CH510074A (en) | 1971-07-15 |
| NL6801363A (en) | 1968-08-12 |
| FR1560629A (en) | 1969-03-21 |
| DE1720617A1 (en) | 1971-07-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1187362A (en) | Process for the Preparation of Polyurethane Polyureas | |
| ES461680A1 (en) | Preparation of polyurethane ureas using as hardeners mixtures of water, amines, aldimines and ketimines | |
| GB1258545A (en) | ||
| FI107389B (en) | Polyurethane, its use and water-soluble paint in which polyurethane acts as a thickener | |
| GB924111A (en) | Process for the manufacture of foamed polyurethanes | |
| GB1288688A (en) | ||
| GB1457053A (en) | Process for preparation of anionic polyurethane emulsions | |
| GB1323313A (en) | Process for the production of polymers which contain polyamide urea and or urethane groups | |
| GB914579A (en) | Improvements in and relating to polyurethane foams | |
| US3743667A (en) | Alicyclic nitriles | |
| GB1310754A (en) | Process for the production of polyurethane-based one-compo nent systems which are stable on storage and which dry quickly in contact with atmospheric moisture | |
| GB1115788A (en) | Polyurethanes | |
| ES432353A1 (en) | Process for preparing non-ionic polyurethane emulsions | |
| GB1305136A (en) | ||
| GB942426A (en) | Cellular plastic material with rapid high strength | |
| GB1380680A (en) | Process for the production of polyurethane urea solutions | |
| GB912491A (en) | New polyurethanes and their production | |
| GB1455695A (en) | Delayed action catalysts | |
| ES8402323A1 (en) | Process for the production of possibly cellular moulded articles from polyurea elastomers. | |
| KR880006320A (en) | α, W-alkylene glycols and blends of polyether polyols and preparation methods thereof | |
| GB1370599A (en) | Agents for wet fastness properties | |
| GB1072196A (en) | Silylureas | |
| GB1340533A (en) | Polymer compositions | |
| ES8301252A1 (en) | Process for the preparation of a polymer of the cross-linked polyurethane type having a tridimensional structure, product obtained by this process and its use as a swelling agent, especially therapeutically. | |
| GB1429210A (en) | Polyurethane textile adhesive |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |