GB1183298A - Rubbery Compositions - Google Patents
Rubbery CompositionsInfo
- Publication number
- GB1183298A GB1183298A GB34141/68A GB3414168A GB1183298A GB 1183298 A GB1183298 A GB 1183298A GB 34141/68 A GB34141/68 A GB 34141/68A GB 3414168 A GB3414168 A GB 3414168A GB 1183298 A GB1183298 A GB 1183298A
- Authority
- GB
- United Kingdom
- Prior art keywords
- nickel
- weight
- units
- bis
- cobalt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 8
- 150000001993 dienes Chemical class 0.000 abstract 5
- 229910052759 nickel Inorganic materials 0.000 abstract 4
- 229920002554 vinyl polymer Polymers 0.000 abstract 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- -1 Vinyl aromatic hydrocarbons Chemical class 0.000 abstract 3
- 229920001577 copolymer Polymers 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- 239000000945 filler Substances 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 150000002894 organic compounds Chemical class 0.000 abstract 2
- 150000002902 organometallic compounds Chemical class 0.000 abstract 2
- SHWZFQPXYGHRKT-FDGPNNRMSA-N (z)-4-hydroxypent-3-en-2-one;nickel Chemical compound [Ni].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O SHWZFQPXYGHRKT-FDGPNNRMSA-N 0.000 abstract 1
- YACTXGRTJNKUDC-UHFFFAOYSA-N 2-hydroxybenzaldehyde;nickel Chemical compound [Ni].OC1=CC=CC=C1C=O.OC1=CC=CC=C1C=O YACTXGRTJNKUDC-UHFFFAOYSA-N 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- OCQOQSPRQVBGTI-UHFFFAOYSA-N [Ni].C(C)(C)C1=C(C(C(=O)O)=CC(=C1)C(C)C)O.C(C)(C)C1=C(C(C(=O)O)=CC(=C1)C(C)C)O Chemical compound [Ni].C(C)(C)C1=C(C(C(=O)O)=CC(=C1)C(C)C)O.C(C)(C)C1=C(C(C(=O)O)=CC(=C1)C(C)C)O OCQOQSPRQVBGTI-UHFFFAOYSA-N 0.000 abstract 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 239000004568 cement Substances 0.000 abstract 1
- 239000004927 clay Substances 0.000 abstract 1
- HWVKIRQMNIWOLT-UHFFFAOYSA-L cobalt(2+);octanoate Chemical compound [Co+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O HWVKIRQMNIWOLT-UHFFFAOYSA-L 0.000 abstract 1
- JUPWRUDTZGBNEX-UHFFFAOYSA-N cobalt;pentane-2,4-dione Chemical compound [Co].CC(=O)CC(C)=O.CC(=O)CC(C)=O.CC(=O)CC(C)=O JUPWRUDTZGBNEX-UHFFFAOYSA-N 0.000 abstract 1
- OTBRDDMWXPLEPE-UHFFFAOYSA-N cobalt;quinolin-8-ol Chemical compound [Co].C1=CN=C2C(O)=CC=CC2=C1.C1=CN=C2C(O)=CC=CC2=C1.C1=CN=C2C(O)=CC=CC2=C1 OTBRDDMWXPLEPE-UHFFFAOYSA-N 0.000 abstract 1
- AILPTUURQRJHHF-UHFFFAOYSA-N diethyl(2-methylpropyl)alumane Chemical compound CC[Al](CC)CC(C)C AILPTUURQRJHHF-UHFFFAOYSA-N 0.000 abstract 1
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 abstract 1
- 230000009477 glass transition Effects 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000004679 hydroxides Chemical class 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 239000012280 lithium aluminium hydride Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- DLPASUVGCQPFFO-UHFFFAOYSA-N magnesium;ethane Chemical compound [Mg+2].[CH2-]C.[CH2-]C DLPASUVGCQPFFO-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- YVBZVWKQZRDLPA-UHFFFAOYSA-L nickel(2+);3-oxohexanoate Chemical compound [Ni+2].CCCC(=O)CC([O-])=O.CCCC(=O)CC([O-])=O YVBZVWKQZRDLPA-UHFFFAOYSA-L 0.000 abstract 1
- SZFRNDHFFWXKID-UHFFFAOYSA-N nickel;quinolin-8-ol Chemical compound [Ni].C1=CN=C2C(O)=CC=CC2=C1.C1=CN=C2C(O)=CC=CC2=C1 SZFRNDHFFWXKID-UHFFFAOYSA-N 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 239000012763 reinforcing filler Substances 0.000 abstract 1
- 150000004760 silicates Chemical class 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000012279 sodium borohydride Substances 0.000 abstract 1
- 229910000033 sodium borohydride Inorganic materials 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 abstract 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 abstract 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1,183,298. Hydrogenated diene polymers. BRIDGESTONE TIRE K.K. 17 July, 1968 [20 July, 1967], No. 34141/68. Heading C3P. A rubbery composition comprises (a) 100 parts by weight of a hydrogenated hydrocarbon copolymer having a glass transition temperature of above - 100‹ C. and having polymeric monomer units which consist of (1) vinyl aromatic hydrocarbon units of from 5 to 60% by weight; (2) conjugated diolefin units of less than 85% by .weight; and (3) hydrogenated conjugated diolefin units of not less than 10% by weight, wherein the vinyl aromatic hydrocarbon units are essentially randomly distributed in the polymeric monomer units; and (b) from 5 to 200 parts by weight of an inorganic reinforcing filler of which the number average particle diameter is smaller than 500 mÁ. Vinyl aromatic hydrocarbons: styrene and α-methyl styrene. Conjugated diolefines: 1,3-butadiene and isoprene. Fillers; carbon black, hydrous silica, hard clay and the carbonates, hydroxides, oxides, silicates or sulphates of aluminium, barium, calcium, magnesium, silicon, titanium and zinc. The rubbery composition may be prepared by copolymerizing 5-60 parts by weight of vinyl aromatic hydrocarbon and 95 - 40 parts by weight of conjugated diolefin either by solution polymerization (through the use of a catalyst) or by emulsion polymerization (radical type initiator), selectively hydrogenating the diolefin units of the resulting copolymer in a viscous toluene solution in the presence of a catalyst obtained by mixing an organic compound of nickel, cobalt or iron with an organometallic compound of a metal from Groups I, II and III of the Periodic Table (or other coinpounds specified below) and, optionally, olefirii cally or acetylenically unsaturated hydrocarbon, precipitating the hydrogenated copolymer by acetone or methanol acidified with hydrochloric acid and mixing it with the filler and, if desired, other conventional ingredients. Organic compounds of nickel &c.: nickel, cobalt or iron naphthenates, nickel or cobalt octanoate, bis (acetylacetone) nickel, tris (acetylacetone) cobalt, bis (ethyl acetoacetate) nickel, bis (salicylaldehyde) nickel, bis (8- hydroxyquinoline) nickel, tris (8-hydroxyquinoline) cobalt, bis (3,5-diisopropyl salicylic acid) nickel. Organometallic compounds: n-butyllithium, diethyl magnesium, triethylaluminium, triisobutylaluminium, triamylaluminium and diethylisobutylaluminium. Lithium aluminium hydride and sodium borohydride may be used instead. The rubbery compositions exhibit high-tensile strength in the unvulcanized state and can be used in the manufacture of many articles, including cements and paints.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4630467 | 1967-07-20 | ||
| US24519872A | 1972-04-18 | 1972-04-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1183298A true GB1183298A (en) | 1970-03-04 |
Family
ID=26386417
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB34141/68A Expired GB1183298A (en) | 1967-07-20 | 1968-07-17 | Rubbery Compositions |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE718324A (en) |
| FR (1) | FR1576702A (en) |
| GB (1) | GB1183298A (en) |
| NL (1) | NL6810320A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0775725A4 (en) * | 1994-08-08 | 1997-11-26 | Asahi Chemical Ind | HYDRATED RUBBER COMPOSITION |
| CN113845706A (en) * | 2020-06-26 | 2021-12-28 | 旭化成株式会社 | Rubber composition, method for producing rubber composition, rubber composition for crosslinking, molded article, and tread for tire |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5017660A (en) * | 1987-08-04 | 1991-05-21 | Asahi Kasei Kogyo Kabushiki Kaisha | Selectively, partially hydrogenated polymer and rubber composition and impact resistant styrenic resin containing the same |
-
1968
- 1968-07-17 GB GB34141/68A patent/GB1183298A/en not_active Expired
- 1968-07-19 BE BE718324D patent/BE718324A/xx unknown
- 1968-07-19 NL NL6810320A patent/NL6810320A/xx unknown
- 1968-07-22 FR FR1576702D patent/FR1576702A/fr not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0775725A4 (en) * | 1994-08-08 | 1997-11-26 | Asahi Chemical Ind | HYDRATED RUBBER COMPOSITION |
| CN113845706A (en) * | 2020-06-26 | 2021-12-28 | 旭化成株式会社 | Rubber composition, method for producing rubber composition, rubber composition for crosslinking, molded article, and tread for tire |
Also Published As
| Publication number | Publication date |
|---|---|
| NL6810320A (en) | 1969-01-22 |
| BE718324A (en) | 1968-12-31 |
| FR1576702A (en) | 1969-08-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |