GB1018661A - Process for the hydrogenation of hydroperoxides - Google Patents
Process for the hydrogenation of hydroperoxidesInfo
- Publication number
- GB1018661A GB1018661A GB508762A GB508762A GB1018661A GB 1018661 A GB1018661 A GB 1018661A GB 508762 A GB508762 A GB 508762A GB 508762 A GB508762 A GB 508762A GB 1018661 A GB1018661 A GB 1018661A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydroperoxides
- hydrogenation
- methylpentene
- compound
- examples
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 3
- 150000002432 hydroperoxides Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 2
- CPDFKYYJROYOQC-UHFFFAOYSA-N CCCC=CC.OO Chemical class CCCC=CC.OO CPDFKYYJROYOQC-UHFFFAOYSA-N 0.000 abstract 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052787 antimony Inorganic materials 0.000 abstract 2
- 229910052785 arsenic Inorganic materials 0.000 abstract 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 abstract 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract 2
- 229910052797 bismuth Inorganic materials 0.000 abstract 2
- 229910052793 cadmium Inorganic materials 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 229910052745 lead Inorganic materials 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052709 silver Inorganic materials 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- QEEPPWQOVJWUBC-UHFFFAOYSA-N 1-hydroperoxycyclohexene Chemical compound OOC1=CCCCC1 QEEPPWQOVJWUBC-UHFFFAOYSA-N 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical compound CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 abstract 1
- 239000004113 Sepiolite Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001260 acyclic compounds Chemical class 0.000 abstract 1
- 125000002015 acyclic group Chemical group 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 235000010216 calcium carbonate Nutrition 0.000 abstract 1
- ONIOAEVPMYCHKX-UHFFFAOYSA-N carbonic acid;zinc Chemical compound [Zn].OC(O)=O ONIOAEVPMYCHKX-UHFFFAOYSA-N 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- RYPKRALMXUUNKS-UHFFFAOYSA-N hex-2-ene Chemical class CCCC=CC RYPKRALMXUUNKS-UHFFFAOYSA-N 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 235000019260 propionic acid Nutrition 0.000 abstract 1
- 229910052624 sepiolite Inorganic materials 0.000 abstract 1
- 235000019355 sepiolite Nutrition 0.000 abstract 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052716 thallium Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000011667 zinc carbonate Substances 0.000 abstract 1
- 229910000010 zinc carbonate Inorganic materials 0.000 abstract 1
- 235000004416 zinc carbonate Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C33/02—Acyclic alcohols with carbon-to-carbon double bonds
- C07C33/025—Acyclic alcohols with carbon-to-carbon double bonds with only one double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Organic hydroperoxides are hydrogenated in the presence of a platinum group metal modified by a compound of Ag, Cu, Zn, Cd, Hg, Sn, Pb, As, Sb, Bi or Tl. The hydroperoxides are preferably acyclic or unsaturated acyclic compounds, e.g. cyclohexenyl hydroperoxide. The catalyst is selective for hydrogenation of methylpentene hydroperoxides in the presence of methyl pentenes. Examples 1 and 2 describe selective reduction of tertiary-butyl hydroperoxide. Example 3 the reduction of methylpentene hydroperoxides and Example 4 a combination.ALSO:Hydrogenation catalysts comprise platinum group metal, preferably palladium, modified by a compound of a metal selected from Ag, Cu, Zn, Cd, Hg, Sn, Pb, As, Sb, Bi and T1. Catalyst supports mentioned are C, CaCO3, BaCO3, ZnCO3, MgO, BaSO4, Al2O3 or sepiolite. Acids mentioned are HNO3, CH3COOH and C2H5COOH. Examples are given.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB508762A GB1018661A (en) | 1962-02-09 | 1962-02-09 | Process for the hydrogenation of hydroperoxides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB508762A GB1018661A (en) | 1962-02-09 | 1962-02-09 | Process for the hydrogenation of hydroperoxides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1018661A true GB1018661A (en) | 1966-01-26 |
Family
ID=9789526
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB508762A Expired GB1018661A (en) | 1962-02-09 | 1962-02-09 | Process for the hydrogenation of hydroperoxides |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1018661A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4209651A (en) | 1979-02-21 | 1980-06-24 | E. I. Du Pont De Nemours And Company | Hydrogenation of butadienepolyperoxide to unsaturated diols |
| US4255338A (en) | 1979-02-21 | 1981-03-10 | E. I. Du Pont De Nemours And Company | Process for the preparation of 2,5-dihydrofuran |
| US5354917A (en) * | 1993-11-12 | 1994-10-11 | Texaco Chemical Company | Use of supported rhodium catalysts in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide |
| WO1998037966A1 (en) * | 1997-02-27 | 1998-09-03 | Phillips Petroleum Company | Hydrogenation catalysts for unsaturated hydrocarbons |
-
1962
- 1962-02-09 GB GB508762A patent/GB1018661A/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4209651A (en) | 1979-02-21 | 1980-06-24 | E. I. Du Pont De Nemours And Company | Hydrogenation of butadienepolyperoxide to unsaturated diols |
| US4255338A (en) | 1979-02-21 | 1981-03-10 | E. I. Du Pont De Nemours And Company | Process for the preparation of 2,5-dihydrofuran |
| US5354917A (en) * | 1993-11-12 | 1994-10-11 | Texaco Chemical Company | Use of supported rhodium catalysts in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide |
| WO1998037966A1 (en) * | 1997-02-27 | 1998-09-03 | Phillips Petroleum Company | Hydrogenation catalysts for unsaturated hydrocarbons |
| US6127310A (en) * | 1997-02-27 | 2000-10-03 | Phillips Petroleum Company | Palladium containing hydrogenation catalysts |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| FR1434062A (en) | Process for the selective hydrogenation of unsaturated organic compounds | |
| GB1018661A (en) | Process for the hydrogenation of hydroperoxides | |
| GB1028475A (en) | Improvements in or relating to clay catalysts | |
| ES8100263A1 (en) | PROCEDURE TO PREPARE A 1-BENZL-1,2,5,6-TETRAHYDROPYRIDINE-3-CARBOXYL ACID DERIVATIVE | |
| FR2256134B1 (en) | ||
| OA00530A (en) | A process for the preparation of an alkylaryl compound suitable for the preparation of biologically degradable detergents. | |
| DE3571968D1 (en) | Process for the preparation of olefinic unsaturated compounds, especially alkenols | |
| FR1337516A (en) | Organosilicon compounds substituted by alpha, beta-unsaturated carboxylic ester groups | |
| CH388274A (en) | Process for preparing a catalyst for the selective hydrogenation of an acetylenically unsaturated compound to the corresponding ethylenically unsaturated compound | |
| FR1367793A (en) | Process for the preparation of unsaturated carbonyl compounds | |
| FR1431116A (en) | Process for the preparation of ethylenically unsaturated alpha, beta carbonyl compounds | |
| GB886477A (en) | Selective hydrogenation of fatty oils | |
| MX9202938A (en) | COMPOSITION FOR PROPHYLAXIS OR TREATMENT OF PIG LIVESTOCK DISENTERIA AND TO INCREASE ITS PRODUCTIVITY. | |
| FR1338285A (en) | Double collar, preferably for tubular scaffolding | |
| CH416261A (en) | Automatic control mechanism for turret lathes | |
| AU6664160A (en) | Method of improving the feed efficiency of feed compositions for meat-producing animals | |
| AR217743A1 (en) | WATER TREATMENT APPLIANCE SERVED BY THE ACTIVATED SLUDGE PROCESS | |
| FR1244730A (en) | Process for the selective hydrogenation of unsaturated compounds in c4 fractions | |
| FR1310875A (en) | Process for preparing copolymers of alpha, beta ethylenically unsaturated aldehydes | |
| AU254298B2 (en) | A process forthe stabilization ofa polymer ofan unsaturated aldehyde or its derivative anda novel composition comprising such polymer, or its derivative together withan epoxide | |
| FR1410438A (en) | Process for the preparation of organic, alpha, beta-unsaturated compounds | |
| ES309189A1 (en) | Procedure for the fight against the cryptogamic diseases of vegetables. (Machine-translation by Google Translate, not legally binding) | |
| CA818597A (en) | Process for the selective hydrogenation of unsaturated organic compounds | |
| GB1392840A (en) | Polycyclic compounds | |
| GB993759A (en) | 2,3,-di-o-acyl derivatives of 6-azauridine and a method for their preparation |