GB1018341A - Olefin copolymers - Google Patents
Olefin copolymersInfo
- Publication number
- GB1018341A GB1018341A GB1033964A GB1033964A GB1018341A GB 1018341 A GB1018341 A GB 1018341A GB 1033964 A GB1033964 A GB 1033964A GB 1033964 A GB1033964 A GB 1033964A GB 1018341 A GB1018341 A GB 1018341A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mixture
- methanol
- cyclohexane
- butylidene
- trichloroethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000089 Cyclic olefin copolymer Polymers 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 9
- 239000000203 mixture Substances 0.000 abstract 5
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 abstract 4
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 3
- 229920001577 copolymer Polymers 0.000 abstract 3
- XDILCINHTMZTGG-UHFFFAOYSA-N 3-(3-dodecoxy-3-oxopropyl)sulfanylpropanoic acid Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(O)=O XDILCINHTMZTGG-UHFFFAOYSA-N 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- 239000004743 Polypropylene Substances 0.000 abstract 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 abstract 2
- ZPFKRQXYKULZKP-UHFFFAOYSA-N butylidene Chemical group [CH2+]CC[CH-] ZPFKRQXYKULZKP-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- -1 polypropylene Polymers 0.000 abstract 2
- 229920001155 polypropylene Polymers 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 abstract 2
- 235000012431 wafers Nutrition 0.000 abstract 2
- 239000004411 aluminium Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 238000007598 dipping method Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 abstract 1
- 125000002524 organometallic group Chemical group 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- 238000007789 sealing Methods 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Crystalline, high molecular weight propylene/butene-1 copolymers are made by polymerizing a mixture of the monomers with, as catalyst, a mixture of a halide of a transition metal, an organometallic derivative of aluminium or a halide of such a derivative, and an ester, amide or ester-amide of phosphoric acid. In the examples the monomers are polymerized in cyclohexane solution with a catalyst comprising titanium trichloride, ethyl aluminium dichloride and hexamethylphosphoramide. The product is purified by washing with methanol, cutting into fine wafers and heating these wafers under reflux with methanol or a methanol/hydrochloric acid mixture. The copolymer together with a mixture of 4,41-bis(6-tert-butyl-m -cresol)butylidene and lauryl thiodipropionate as stabilizer is dissolved in either cyclohexane or trichloroethylene and coated on to biaxially stretched polypropylene film.ALSO:Biaxially stretched polypropylene film is coated by dipping in a solution in either cyclohexane or trichloroethylene of a crystalline, high molecular weight propylene/butene-1 copolymer (see Division C3) together with, as antioxidant, a mixture of 4,41-bis(6-tert-butyl-m-cresol)butylidene and lauryl thiodipropionate. The thus applied coating has heat-sealing properties.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR927838A FR1359276A (en) | 1963-03-13 | 1963-03-13 | New crystalline polyolefin copolymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1018341A true GB1018341A (en) | 1966-01-26 |
Family
ID=8799133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1033964A Expired GB1018341A (en) | 1963-03-13 | 1964-03-11 | Olefin copolymers |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE645117A (en) |
| CH (1) | CH427293A (en) |
| DE (1) | DE1230224B (en) |
| FR (1) | FR1359276A (en) |
| GB (1) | GB1018341A (en) |
| NL (2) | NL6402585A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2460597A1 (en) * | 1974-03-29 | 1975-10-02 | Ici Ltd | MULTILAYER FILMS AND METHOD OF MANUFACTURING THE SAME |
| DE2757863A1 (en) * | 1976-12-24 | 1978-06-29 | Mitsui Petrochemical Ind | STATISTICAL COPOLYMERIZATION OF PROPYLENE AND 1-BUTENE AND THE PROCESS FOR THE PRODUCTION THEREOF |
| DE2813334A1 (en) * | 1977-09-26 | 1979-03-29 | Mitsui Petrochemical Ind | THERMOPLASTIC OLEFINAL RESIN COMPOSITION AND LAMINATED FILMS OR PANELS MANUFACTURED THEREOF |
| US4360650A (en) | 1979-07-30 | 1982-11-23 | Naphtachimie Societe Anonyme | Process for the production of copolymers of propylene and but-1-ene, products resulting therefrom and uses thereof |
| US4663238A (en) * | 1979-01-17 | 1987-05-05 | Bp Chemicals Limited | Copolymers propylene and but-1-ene and uses thereof |
| EP1209165A2 (en) | 1993-06-07 | 2002-05-29 | Mitsui Chemicals, Inc. | Novel transition metal compound for use as a polymerisation caltalyst |
| CN114539456A (en) * | 2022-03-15 | 2022-05-27 | 山东京博石油化工有限公司 | Preparation method of poly-1-butene polymer, preparation method of master batch of poly-1-butene-based membrane material and poly-1-butene membrane |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1495776A (en) * | 1975-06-11 | 1977-12-21 | Ici Ltd | Film-forming olefin polymer compositions |
-
0
- NL NL128622D patent/NL128622C/xx active
-
1963
- 1963-03-13 FR FR927838A patent/FR1359276A/en not_active Expired
-
1964
- 1964-03-11 GB GB1033964A patent/GB1018341A/en not_active Expired
- 1964-03-12 BE BE645117A patent/BE645117A/xx unknown
- 1964-03-12 NL NL6402585A patent/NL6402585A/xx unknown
- 1964-03-13 DE DER37449A patent/DE1230224B/en active Pending
- 1964-03-13 CH CH328764A patent/CH427293A/en unknown
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2460597A1 (en) * | 1974-03-29 | 1975-10-02 | Ici Ltd | MULTILAYER FILMS AND METHOD OF MANUFACTURING THE SAME |
| US4252851A (en) | 1974-03-29 | 1981-02-24 | Imperial Chemical Industries Limited | Multiple-layer films |
| DK156549B (en) * | 1974-03-29 | 1989-09-11 | Ici Ltd | HEATABLE MULTILAYER FILM APPLICABLE FOR WRAPPING AND COMPREHENSIVE LAYER OF A COPOLYMER OF PROPYLENE AND LAYER OF AN ALFA OLEPHINE AND PROCEDURES FOR PRODUCING THEREOF |
| DE2757863A1 (en) * | 1976-12-24 | 1978-06-29 | Mitsui Petrochemical Ind | STATISTICAL COPOLYMERIZATION OF PROPYLENE AND 1-BUTENE AND THE PROCESS FOR THE PRODUCTION THEREOF |
| US4168361A (en) | 1976-12-24 | 1979-09-18 | Mitsui Petrochemical Industries, Ltd. | Random copolymer of propylene and 1-butene and process for its production |
| DE2813334A1 (en) * | 1977-09-26 | 1979-03-29 | Mitsui Petrochemical Ind | THERMOPLASTIC OLEFINAL RESIN COMPOSITION AND LAMINATED FILMS OR PANELS MANUFACTURED THEREOF |
| US4663238A (en) * | 1979-01-17 | 1987-05-05 | Bp Chemicals Limited | Copolymers propylene and but-1-ene and uses thereof |
| US4925902A (en) * | 1979-01-17 | 1990-05-15 | Bp Chemicals Limited | Copolymers of propylene and but-1-ene and uses thereof |
| US4360650A (en) | 1979-07-30 | 1982-11-23 | Naphtachimie Societe Anonyme | Process for the production of copolymers of propylene and but-1-ene, products resulting therefrom and uses thereof |
| EP1209165A2 (en) | 1993-06-07 | 2002-05-29 | Mitsui Chemicals, Inc. | Novel transition metal compound for use as a polymerisation caltalyst |
| CN114539456A (en) * | 2022-03-15 | 2022-05-27 | 山东京博石油化工有限公司 | Preparation method of poly-1-butene polymer, preparation method of master batch of poly-1-butene-based membrane material and poly-1-butene membrane |
| CN114539456B (en) * | 2022-03-15 | 2024-03-12 | 山东京博石油化工有限公司 | Preparation method of poly (1-butene) polymer, preparation method of poly (1-butene) base membrane material master batch and poly (1-butene) membrane |
Also Published As
| Publication number | Publication date |
|---|---|
| NL128622C (en) | |
| DE1230224B (en) | 1966-12-08 |
| FR1359276A (en) | 1964-04-24 |
| BE645117A (en) | 1964-09-14 |
| NL6402585A (en) | 1964-09-14 |
| CH427293A (en) | 1966-12-31 |
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