GB1005638A - Aliphatic amines suitable as ashless lubricant additives - Google Patents
Aliphatic amines suitable as ashless lubricant additivesInfo
- Publication number
- GB1005638A GB1005638A GB31385/64A GB3138564A GB1005638A GB 1005638 A GB1005638 A GB 1005638A GB 31385/64 A GB31385/64 A GB 31385/64A GB 3138564 A GB3138564 A GB 3138564A GB 1005638 A GB1005638 A GB 1005638A
- Authority
- GB
- United Kingdom
- Prior art keywords
- lubricant
- lubricating oil
- aliphatic
- added
- additive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003879 lubricant additive Substances 0.000 title abstract 4
- -1 Aliphatic amines Chemical class 0.000 title 1
- 229920000768 polyamine Polymers 0.000 abstract 4
- 239000000654 additive Substances 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 3
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 3
- 230000000996 additive effect Effects 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 abstract 2
- 239000000314 lubricant Substances 0.000 abstract 2
- 239000010687 lubricating oil Substances 0.000 abstract 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 abstract 1
- 239000003518 caustics Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000012141 concentrate Substances 0.000 abstract 1
- 239000003599 detergent Substances 0.000 abstract 1
- 239000010685 fatty oil Substances 0.000 abstract 1
- 150000008282 halocarbons Chemical class 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- 239000010688 mineral lubricating oil Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 239000010689 synthetic lubricating oil Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
- C10M133/54—Amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
- C10M2215/26—Amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/022—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amino group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
- C10N2040/253—Small diesel engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
- C10N2070/02—Concentrating of additives
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B3/00—Engines characterised by air compression and subsequent fuel addition
- F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Lubricants (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A lubricant additive comprises an aliphatic amine containing at least two aliphatic or cycloaliphatic polyamine groups, each linked to a hydrocarbon chain of at least 50 carbon atoms by one of its nitrogen atoms. The lubricant may be a mineral lubricating oil, a synthetic lubricating oil or a lubricating oil containing fatty oil. The additive may be added to the lubricant as such or as a concentrate obtained for instance by mixing the product with a small quantity of the oil. Conventional lubricant additives such as anti-oxidants, detergent additives, viscosity-index improvers, anti-corrosives, anti-foaming agents and agents to improve the lubricating effect may be added. In the example an additive obtained by heating a chlorinated ethylene-propylene copolymer with tetraethylene pentamine is added to a solvent-refined paraffinic lubricating oil distillate and then tested in diesel and gasoline engines. Specification 725,169 is referred to.ALSO:An aliphatic amine suitable for use as a lubricant additive contains at least two aliphatic or cycloaliphatic polyamine groups each linked to a hydrocarbon chain of at least 50 carbon atoms by one of its nitrogen atoms. It may be prepared by reacting a halogenated hydrocarbon having at least two halogen atoms as substituents and a hydrocarbon chain of at least 50 carbon atoms with a polyamine, preferably a polyalkylene-polyamine having 3 or more nitrogen atoms. In the example, an ethylene-propylene copolymer is chlorinated and the product is heated with tetraethylene-pentamine. Specification 725,169 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL296138 | 1963-08-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1005638A true GB1005638A (en) | 1965-09-22 |
Family
ID=19754925
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB31385/64A Expired GB1005638A (en) | 1963-08-02 | 1964-08-04 | Aliphatic amines suitable as ashless lubricant additives |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1520880C3 (en) |
| GB (1) | GB1005638A (en) |
| NL (2) | NL296138A (en) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3928504A (en) * | 1973-12-12 | 1975-12-23 | Shell Oil Co | Dyeable polypropylene compositions containing a polyamine adduct |
| GB2402942A (en) * | 2003-05-29 | 2004-12-22 | Nissan Motor | Cutting oil composition for machine tool |
| US7134381B2 (en) | 2003-08-21 | 2006-11-14 | Nissan Motor Co., Ltd. | Refrigerant compressor and friction control process therefor |
| US7146956B2 (en) | 2003-08-08 | 2006-12-12 | Nissan Motor Co., Ltd. | Valve train for internal combustion engine |
| US7228786B2 (en) | 2003-06-06 | 2007-06-12 | Nissan Motor Co., Ltd. | Engine piston-pin sliding structure |
| US7255083B2 (en) | 2002-10-16 | 2007-08-14 | Nissan Motor Co., Ltd. | Sliding structure for automotive engine |
| US7273655B2 (en) | 1999-04-09 | 2007-09-25 | Shojiro Miyake | Slidably movable member and method of producing same |
| US7284525B2 (en) | 2003-08-13 | 2007-10-23 | Nissan Motor Co., Ltd. | Structure for connecting piston to crankshaft |
| US7318514B2 (en) | 2003-08-22 | 2008-01-15 | Nissan Motor Co., Ltd. | Low-friction sliding member in transmission, and transmission oil therefor |
| US7322749B2 (en) | 2002-11-06 | 2008-01-29 | Nissan Motor Co., Ltd. | Low-friction sliding mechanism |
| US7406940B2 (en) | 2003-05-23 | 2008-08-05 | Nissan Motor Co., Ltd. | Piston for internal combustion engine |
| US7458585B2 (en) | 2003-08-08 | 2008-12-02 | Nissan Motor Co., Ltd. | Sliding member and production process thereof |
| US7500472B2 (en) | 2003-04-15 | 2009-03-10 | Nissan Motor Co., Ltd. | Fuel injection valve |
| US7572200B2 (en) | 2003-08-13 | 2009-08-11 | Nissan Motor Co., Ltd. | Chain drive system |
| US7771821B2 (en) | 2003-08-21 | 2010-08-10 | Nissan Motor Co., Ltd. | Low-friction sliding member and low-friction sliding mechanism using same |
| US8096205B2 (en) | 2003-07-31 | 2012-01-17 | Nissan Motor Co., Ltd. | Gear |
| US8206035B2 (en) | 2003-08-06 | 2012-06-26 | Nissan Motor Co., Ltd. | Low-friction sliding mechanism, low-friction agent composition and method of friction reduction |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3671511A (en) * | 1970-04-23 | 1972-06-20 | Lewis R Honnen | Process for preparing polyolefin-substituted amines |
| NL169595C (en) * | 1970-05-21 | 1982-08-02 | Shell Int Research | PROCESS FOR PREPARING AMINS AND LUBRICATING OILS AND LIQUID ENGINE FUELS CONTAINING THESE. |
-
0
- NL NL137370D patent/NL137370C/xx active
- NL NL296138D patent/NL296138A/xx unknown
-
1964
- 1964-07-31 DE DE1520880A patent/DE1520880C3/en not_active Expired
- 1964-08-04 GB GB31385/64A patent/GB1005638A/en not_active Expired
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3928504A (en) * | 1973-12-12 | 1975-12-23 | Shell Oil Co | Dyeable polypropylene compositions containing a polyamine adduct |
| US7273655B2 (en) | 1999-04-09 | 2007-09-25 | Shojiro Miyake | Slidably movable member and method of producing same |
| US7255083B2 (en) | 2002-10-16 | 2007-08-14 | Nissan Motor Co., Ltd. | Sliding structure for automotive engine |
| US7322749B2 (en) | 2002-11-06 | 2008-01-29 | Nissan Motor Co., Ltd. | Low-friction sliding mechanism |
| US8152377B2 (en) | 2002-11-06 | 2012-04-10 | Nissan Motor Co., Ltd. | Low-friction sliding mechanism |
| US7500472B2 (en) | 2003-04-15 | 2009-03-10 | Nissan Motor Co., Ltd. | Fuel injection valve |
| US7406940B2 (en) | 2003-05-23 | 2008-08-05 | Nissan Motor Co., Ltd. | Piston for internal combustion engine |
| GB2402942A (en) * | 2003-05-29 | 2004-12-22 | Nissan Motor | Cutting oil composition for machine tool |
| GB2402942B (en) * | 2003-05-29 | 2006-05-24 | Nissan Motor | Hard-carbon coated machine tool and cutting oil composition therefor |
| US7228786B2 (en) | 2003-06-06 | 2007-06-12 | Nissan Motor Co., Ltd. | Engine piston-pin sliding structure |
| US8096205B2 (en) | 2003-07-31 | 2012-01-17 | Nissan Motor Co., Ltd. | Gear |
| US8206035B2 (en) | 2003-08-06 | 2012-06-26 | Nissan Motor Co., Ltd. | Low-friction sliding mechanism, low-friction agent composition and method of friction reduction |
| US7458585B2 (en) | 2003-08-08 | 2008-12-02 | Nissan Motor Co., Ltd. | Sliding member and production process thereof |
| US7146956B2 (en) | 2003-08-08 | 2006-12-12 | Nissan Motor Co., Ltd. | Valve train for internal combustion engine |
| US8575076B2 (en) | 2003-08-08 | 2013-11-05 | Nissan Motor Co., Ltd. | Sliding member and production process thereof |
| US7284525B2 (en) | 2003-08-13 | 2007-10-23 | Nissan Motor Co., Ltd. | Structure for connecting piston to crankshaft |
| US7572200B2 (en) | 2003-08-13 | 2009-08-11 | Nissan Motor Co., Ltd. | Chain drive system |
| US7771821B2 (en) | 2003-08-21 | 2010-08-10 | Nissan Motor Co., Ltd. | Low-friction sliding member and low-friction sliding mechanism using same |
| US7134381B2 (en) | 2003-08-21 | 2006-11-14 | Nissan Motor Co., Ltd. | Refrigerant compressor and friction control process therefor |
| US7318514B2 (en) | 2003-08-22 | 2008-01-15 | Nissan Motor Co., Ltd. | Low-friction sliding member in transmission, and transmission oil therefor |
| US7650976B2 (en) | 2003-08-22 | 2010-01-26 | Nissan Motor Co., Ltd. | Low-friction sliding member in transmission, and transmission oil therefor |
Also Published As
| Publication number | Publication date |
|---|---|
| NL296138A (en) | |
| DE1520880C3 (en) | 1979-07-12 |
| DE1520880A1 (en) | 1969-11-27 |
| NL137370C (en) | |
| DE1520880B2 (en) | 1978-11-09 |
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