GB1097950A - Self-extinguishing synthetic resins and a process for their production - Google Patents
Self-extinguishing synthetic resins and a process for their productionInfo
- Publication number
- GB1097950A GB1097950A GB1941965A GB1941965A GB1097950A GB 1097950 A GB1097950 A GB 1097950A GB 1941965 A GB1941965 A GB 1941965A GB 1941965 A GB1941965 A GB 1941965A GB 1097950 A GB1097950 A GB 1097950A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl chloride
- vinyl acetate
- methyl methacrylate
- phosphate
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920003002 synthetic resin Polymers 0.000 title abstract 2
- 239000000057 synthetic resin Substances 0.000 title abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 9
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 8
- HQUQLFOMPYWACS-UHFFFAOYSA-N tris(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCCl HQUQLFOMPYWACS-UHFFFAOYSA-N 0.000 abstract 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 6
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 abstract 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 4
- 229910052698 phosphorus Inorganic materials 0.000 abstract 3
- 239000011574 phosphorus Substances 0.000 abstract 3
- -1 phosphorus compound Chemical class 0.000 abstract 3
- WAEVHPCHEKMXFF-UHFFFAOYSA-N COP(OC)=O.C(C(=C)C)(=O)CC Chemical compound COP(OC)=O.C(C(=C)C)(=O)CC WAEVHPCHEKMXFF-UHFFFAOYSA-N 0.000 abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 2
- 239000003431 cross linking reagent Substances 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 150000002903 organophosphorus compounds Chemical class 0.000 abstract 2
- 235000011007 phosphoric acid Nutrition 0.000 abstract 2
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 abstract 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 abstract 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- GHHGVSCQWPVENX-UHFFFAOYSA-N 2-methylpent-1-en-3-one Chemical compound CCC(=O)C(C)=C GHHGVSCQWPVENX-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- LCXXNKZQVOXMEH-UHFFFAOYSA-N Tetrahydrofurfuryl methacrylate Chemical compound CC(=C)C(=O)OCC1CCCO1 LCXXNKZQVOXMEH-UHFFFAOYSA-N 0.000 abstract 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000010425 asbestos Substances 0.000 abstract 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 abstract 1
- 125000004386 diacrylate group Chemical group 0.000 abstract 1
- 239000012975 dibutyltin dilaurate Substances 0.000 abstract 1
- YLFBFPXKTIQSSY-UHFFFAOYSA-N dimethoxy(oxo)phosphanium Chemical compound CO[P+](=O)OC YLFBFPXKTIQSSY-UHFFFAOYSA-N 0.000 abstract 1
- LDCRTTXIJACKKU-ONEGZZNKSA-N dimethyl fumarate Chemical compound COC(=O)\C=C\C(=O)OC LDCRTTXIJACKKU-ONEGZZNKSA-N 0.000 abstract 1
- 229960004419 dimethyl fumarate Drugs 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 150000002334 glycols Chemical class 0.000 abstract 1
- 239000012760 heat stabilizer Substances 0.000 abstract 1
- 239000004611 light stabiliser Substances 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 239000011976 maleic acid Substances 0.000 abstract 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 150000003018 phosphorus compounds Chemical class 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 229920000151 polyglycol Polymers 0.000 abstract 1
- 239000010695 polyglycol Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 229910052895 riebeckite Inorganic materials 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000006188 syrup Substances 0.000 abstract 1
- 235000020357 syrup Nutrition 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
- 229940124543 ultraviolet light absorber Drugs 0.000 abstract 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
- C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Self-extinguishing synthetic resins are prepared by polymerizing a mixture comprising (A) at least 5 weight per cent of a vinyl chloride copolymer, (B) at least 1.2 weight per cent of phosphorus in the form of a phosphorus compound, (C) at least one monomeric polymerizable organic compound and optionally (D) up to 3 weight per cent of a cross-linking agent. (A) may be a copolymer of vinyl chloride with vinyl acetate, an ester of acrylic, methacrylic or maleic acid, or a phosphorus containing comonomer. Specified phosphorus compounds are orthophosphoric acid, trimethyl phosphate, trichlorethyl phosphate, bis-(chlorethyl)-propenyl-2-phosphonate and unsaturated compounds such as 1 - methacrylylethane - 1,1 - bis - (phosphonic acid dimethyl ester) and 1-methacrylylethane phosphonic acid dimethyl ester. The monomer (C) may be an acrylic or methacrylic ester, optionally in admixture with vinyl aromatic compounds, vinyl acetate or dicarboxylic acid anhydride or ester; and may be present as a monomer/polymer syrup or prepolymer. Specified cross-linking agents are diacrylates and dimethacrylates of glycols and polyglycols. Glass and asbestos fibres, fillers, pigments, heat and light stabilizers, and catalysts may also be present. Examples describe the polymerization of compositions comprising (1-4) methyl methacrylate monomer and prepolymer, vinyl chloride/vinyl acetate copolymer and trichlorethyl phosphate; methyl methacrylate monomer with and without prepolymer, vinyl chloride/vinyl acetate copolymer, dibutyl tin dilaurate, ultra-violet light absorber, and (6 and 7) a high molecular weight organic phosphorus compound, (8 and 9) a commercial organic phosphorus compound, (10 and 11) trimethyl phosphate, (12) bis-(chloropropyl) - propenyl - 2 - phosphonate and (14) trichlorethyl phosphate and triethylene glycol dimethacrylate; (13) methyl methacrylate, vinyl chloride/maleic ester copolymer, trichlorethyl phosphate and stabilizers; (18) methyl methacrylate, vinyl chloride/vinyl acetate copolymer, trichlorethyl phosphate together with (15) styrene, (16) butyl acrylate and triethylene glycol dimethacrylate, (20) triethylene glycol dimethacrylate, (26) maleic anhydride, and (27) dimethyl fumarate; methyl methacrylate, vinyl chloride/vinyl acetate copolymer and (17) 1-methacrylylethane phosphonic acid dimethyl ester, and (24 and 25) orthophosphoric acid, (19 and 21) methyl methacrylate monomer and prepolymer, vinyl chloride/vinyl acetate copolymer, trichlorethyl phosphate and triethylene glycol dimethacrylate; vinyl chloride/vinyl acetate copolymer trichlorethyl phosphate and (28) tetrahydrofurfuryl methacrylate and (29) cyclohexyl methacrylate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DED0045333 | 1964-09-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1097950A true GB1097950A (en) | 1968-01-03 |
Family
ID=7048931
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1941965A Expired GB1097950A (en) | 1964-09-02 | 1965-05-07 | Self-extinguishing synthetic resins and a process for their production |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1495544A1 (en) |
| FR (1) | FR1440823A (en) |
| GB (1) | GB1097950A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4585818A (en) * | 1983-03-31 | 1986-04-29 | Rohm Gmbh | Flame retardant polymethyl methacrylate molding compound |
-
1964
- 1964-09-02 DE DE19641495544 patent/DE1495544A1/en active Pending
-
1965
- 1965-04-22 FR FR14201A patent/FR1440823A/en not_active Expired
- 1965-05-07 GB GB1941965A patent/GB1097950A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4585818A (en) * | 1983-03-31 | 1986-04-29 | Rohm Gmbh | Flame retardant polymethyl methacrylate molding compound |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1440823A (en) | 1966-06-03 |
| DE1495544A1 (en) | 1969-02-13 |
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