GB1091474A - Improvements in writing inks - Google Patents
Improvements in writing inksInfo
- Publication number
- GB1091474A GB1091474A GB2842466A GB2842466A GB1091474A GB 1091474 A GB1091474 A GB 1091474A GB 2842466 A GB2842466 A GB 2842466A GB 2842466 A GB2842466 A GB 2842466A GB 1091474 A GB1091474 A GB 1091474A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fast
- pontamine
- direct
- black
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000976 ink Substances 0.000 title abstract 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 abstract 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 4
- 229920002873 Polyethylenimine Polymers 0.000 abstract 4
- 239000000975 dye Substances 0.000 abstract 4
- SZKZLHLJJLRYKJ-UHFFFAOYSA-N sodium 4-amino-3-[[4-[4-[(2,4-diaminophenyl)diazenyl]phenyl]phenyl]diazenyl]-5-hydroxy-6-phenyldiazenylnaphthalene-2,7-disulfonic acid Chemical compound C1=CC=C(C=C1)N=NC2=C(C3=C(C(=C(C=C3C=C2S(=O)(=O)O)S(=O)(=O)O)N=NC4=CC=C(C=C4)C5=CC=C(C=C5)N=NC6=C(C=C(C=C6)N)N)N)O.[Na+] SZKZLHLJJLRYKJ-UHFFFAOYSA-N 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 abstract 2
- STOOUUMSJPLRNI-UHFFFAOYSA-N 5-amino-4-hydroxy-3-[[4-[4-[(4-hydroxyphenyl)diazenyl]phenyl]phenyl]diazenyl]-6-[(4-nitrophenyl)diazenyl]naphthalene-2,7-disulfonic acid Chemical compound OS(=O)(=O)C1=CC2=CC(S(O)(=O)=O)=C(N=NC=3C=CC(=CC=3)C=3C=CC(=CC=3)N=NC=3C=CC(O)=CC=3)C(O)=C2C(N)=C1N=NC1=CC=C([N+]([O-])=O)C=C1 STOOUUMSJPLRNI-UHFFFAOYSA-N 0.000 abstract 2
- ZKGSVVHFMZASJS-UHFFFAOYSA-N 6-methyl-1h-indole-2-carboxylic acid Chemical compound CC1=CC=C2C=C(C(O)=O)NC2=C1 ZKGSVVHFMZASJS-UHFFFAOYSA-N 0.000 abstract 2
- 101100507451 Drosophila melanogaster sip3 gene Proteins 0.000 abstract 2
- LUWJPTVQOMUZLW-UHFFFAOYSA-N Luxol fast blue MBS Chemical compound [Cu++].Cc1ccccc1N\C(N)=N\c1ccccc1C.Cc1ccccc1N\C(N)=N\c1ccccc1C.OS(=O)(=O)c1cccc2c3nc(nc4nc([n-]c5[n-]c(nc6nc(n3)c3ccccc63)c3c(cccc53)S(O)(=O)=O)c3ccccc43)c12 LUWJPTVQOMUZLW-UHFFFAOYSA-N 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 2
- 229920001665 Poly-4-vinylphenol Polymers 0.000 abstract 2
- 241000083869 Polyommatus dorylas Species 0.000 abstract 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 abstract 2
- MRQIXHXHHPWVIL-ISLYRVAYSA-N Sudan I Chemical compound OC1=CC=C2C=CC=CC2=C1\N=N\C1=CC=CC=C1 MRQIXHXHHPWVIL-ISLYRVAYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 239000000654 additive Substances 0.000 abstract 2
- 239000012670 alkaline solution Substances 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 2
- IRPXADUBAQAOKL-UHFFFAOYSA-N chembl1408927 Chemical compound C1=CC=C2C(N=NC3=C4C=CC(=CC4=CC(=C3O)S(O)(=O)=O)S(O)(=O)=O)=CC=C(S(O)(=O)=O)C2=C1 IRPXADUBAQAOKL-UHFFFAOYSA-N 0.000 abstract 2
- UFUQRRYHIHJMPB-UHFFFAOYSA-L chembl3182005 Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(NC(=O)C=3C=CC=CC=3)=CC=C2C(O)=C1N=NC(C=C1)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UFUQRRYHIHJMPB-UHFFFAOYSA-L 0.000 abstract 2
- HZBTZQVWJPRVDN-UHFFFAOYSA-J copper;disodium;5-[[4-[4-[[2,6-dioxido-3-[(2-oxido-5-sulfonatophenyl)diazenyl]phenyl]diazenyl]phenyl]phenyl]diazenyl]-2-oxidobenzoate;hydron Chemical compound [H+].[H+].[Na+].[Na+].[Cu+2].C1=C([O-])C(C(=O)[O-])=CC(N=NC=2C=CC(=CC=2)C=2C=CC(=CC=2)N=NC=2C(=C(N=NC=3C(=CC=C(C=3)S([O-])(=O)=O)[O-])C=CC=2[O-])[O-])=C1 HZBTZQVWJPRVDN-UHFFFAOYSA-J 0.000 abstract 2
- 150000002170 ethers Chemical class 0.000 abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- 235000011187 glycerol Nutrition 0.000 abstract 2
- -1 glycol ethers Chemical class 0.000 abstract 2
- 150000002334 glycols Chemical class 0.000 abstract 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 150000007524 organic acids Chemical class 0.000 abstract 2
- 239000003960 organic solvent Substances 0.000 abstract 2
- GVKCHTBDSMQENH-UHFFFAOYSA-L phloxine B Chemical compound [Na+].[Na+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 GVKCHTBDSMQENH-UHFFFAOYSA-L 0.000 abstract 2
- 150000008442 polyphenolic compounds Polymers 0.000 abstract 2
- 235000013824 polyphenols Nutrition 0.000 abstract 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 abstract 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 abstract 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 150000005846 sugar alcohols Polymers 0.000 abstract 2
- YXZRCLVVNRLPTP-UHFFFAOYSA-J turquoise blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Cu+2].NC1=NC(Cl)=NC(NC=2C=C(NS(=O)(=O)C3=CC=4C(=C5NC=4NC=4[N-]C(=C6C=CC(=CC6=4)S([O-])(=O)=O)NC=4NC(=C6C=C(C=CC6=4)S([O-])(=O)=O)NC=4[N-]C(=C6C=CC(=CC6=4)S([O-])(=O)=O)N5)C=C3)C(=CC=2)S([O-])(=O)=O)=N1 YXZRCLVVNRLPTP-UHFFFAOYSA-J 0.000 abstract 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/46—Post-polymerisation treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D179/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
- C09D179/02—Polyamines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
A writing ink comprises an alkaline solution of a polyethyleneimine and an acid or direct dyestuff. The latter includes Chlorantine Fast Red 5B, Syno Direct Fast Red 8 BLNW, Phloxine BP, Pontamine Fast Orange EGL, Chlorantine Fast Yellow 5GLL, Chinoline Yellow SSF, Direct Brilliant Green CBM, Fastusol Turquoise Blue LGP, Luxol Fast Blue MBSN, Pontamine Fast Violet 4BL, Calcodur Violet 4BL, Pontamine Fast Brown NP, Direct Black E, Calcomine Black BHD and Pontamine Black ULR. Water which should preferably be distilled or deionized may be used as a solvent for the ink and suitable organic solvents, which may be used instead of or in addition to water are polyhydric alcohols and their ethers and especially suitable are glycerine, the glycols and the glycol ethers. The ink contains 0.05 to 12% by weight of dyestuff and 0.05 to 10% by weight of polyethyleneimine. Other additives include polyvinyl pyrrolidone, phenol or one of the substituted or poly phenols. A pH range from 10.5 to 12.5 is preferred and may be controlled by the addition of inorganic basic material, e.g. ammonia, or a water-soluble organic amine such as an ethanolamine, or an organic acid such as acetic acid. Uses.-Fountain pen or ball pen inks, for felt tip marking pens and stamp pads.ALSO:A writing ink comprises an alkaline solution of a polyethyleneimine and a dyestuff. Suitable dyestuffs are acid and direct dyestuffs and include Chlorantine Fast Red 5B, Syno Direct Fast Red 8BLNW, Phloxine BP, Pontamine Fast Orange EGL, Chlorantine Fast Yellow 5GLL, Chinoline Yellow SSF, Direct Brilliant Green CBM, Fastusol Turquoise Blue LGP, Luxol Fast Blue MBSN, Pontamine Fast Violet 4BL, Calcodur Violet 4BL, Pontamine Fast Brown NP, Direct Black E, Calcomine Black BHD, and Pontamine Black ULR. Water which should preferably be distilled or deionized may be used as a solvent for the ink and suitable organic solvents, which may be used instead of or in addition to water, are polyhydric alcohols and their ethers and especially suitable are glycerine, the glycols and the glycol ethers. The ink contains 0.05 to 12% by weight of dyestuff and 0.05 to 10% by weight of polyethyleneimine. Other additives include polyvinyl pyrrolidone, phenol or one of the substituted or poly phenols. A pH range from 10.5 to 12.5 is preferred and may be controlled by the addition of inorganic basic material, e.g. ammonia, or a water-soluble organic amine such as an ethanolamine, or an organic acid such as acetic acid.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US53177666A | 1966-03-04 | 1966-03-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1091474A true GB1091474A (en) | 1967-11-15 |
Family
ID=24118998
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2842466A Expired GB1091474A (en) | 1966-03-04 | 1966-06-24 | Improvements in writing inks |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE681754A (en) |
| ES (1) | ES327063A1 (en) |
| GB (1) | GB1091474A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005071024A1 (en) * | 2004-01-14 | 2005-08-04 | Sanford, L.P. | Writing instruments with eradicable inks and eradicating fluids |
| US7163575B2 (en) | 2004-07-15 | 2007-01-16 | Sanford, L.P. | Water-based, resin-free and solvent-free eradicable ball-pen inks |
| DE102013015315A1 (en) * | 2013-09-16 | 2015-04-02 | Stabilo International Gmbh | Paste preparation for writing instruments |
-
1966
- 1966-05-23 ES ES0327063A patent/ES327063A1/en not_active Expired
- 1966-05-27 BE BE681754D patent/BE681754A/xx unknown
- 1966-06-24 GB GB2842466A patent/GB1091474A/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005071024A1 (en) * | 2004-01-14 | 2005-08-04 | Sanford, L.P. | Writing instruments with eradicable inks and eradicating fluids |
| US7229487B2 (en) | 2004-01-14 | 2007-06-12 | Sanford, L.P. | Writing instruments with eradicable inks and eradicating fluids |
| US7163575B2 (en) | 2004-07-15 | 2007-01-16 | Sanford, L.P. | Water-based, resin-free and solvent-free eradicable ball-pen inks |
| DE102013015315A1 (en) * | 2013-09-16 | 2015-04-02 | Stabilo International Gmbh | Paste preparation for writing instruments |
| DE102013015315B4 (en) * | 2013-09-16 | 2017-07-27 | Stabilo International Gmbh | ballpoint pen paste |
Also Published As
| Publication number | Publication date |
|---|---|
| ES327063A1 (en) | 1967-08-01 |
| BE681754A (en) | 1966-11-28 |
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