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FR3114690B1 - Procédé de recyclage d’une électrode pour batterie lithium-ion, mélange précurseur et composition d’électrode pour cette batterie. - Google Patents

Procédé de recyclage d’une électrode pour batterie lithium-ion, mélange précurseur et composition d’électrode pour cette batterie. Download PDF

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Publication number
FR3114690B1
FR3114690B1 FR2009896A FR2009896A FR3114690B1 FR 3114690 B1 FR3114690 B1 FR 3114690B1 FR 2009896 A FR2009896 A FR 2009896A FR 2009896 A FR2009896 A FR 2009896A FR 3114690 B1 FR3114690 B1 FR 3114690B1
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FR
France
Prior art keywords
electrode
recycling
precursor mixture
battery
coating
Prior art date
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Active
Application number
FR2009896A
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English (en)
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FR3114690A1 (fr
Inventor
Bruno Dufour
Ksenia Astafyeva
Capucine Dousset
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Hutchinson SA
Original Assignee
Hutchinson SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR2009896A priority Critical patent/FR3114690B1/fr
Application filed by Hutchinson SA filed Critical Hutchinson SA
Priority to PCT/FR2021/051689 priority patent/WO2022069838A1/fr
Priority to CA3197314A priority patent/CA3197314A1/fr
Priority to EP21798745.2A priority patent/EP4222794A1/fr
Priority to US18/028,588 priority patent/US20230361371A1/en
Priority to KR1020237014282A priority patent/KR20230079141A/ko
Priority to CN202180079652.7A priority patent/CN116583967A/zh
Publication of FR3114690A1 publication Critical patent/FR3114690A1/fr
Application granted granted Critical
Publication of FR3114690B1 publication Critical patent/FR3114690B1/fr
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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/54—Reclaiming serviceable parts of waste accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H01M4/623—Binders being polymers fluorinated polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • H01M2300/0028—Organic electrolyte characterised by the solvent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/84—Recycling of batteries or fuel cells

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)

Abstract

L’invention concerne notamment un procédé de recyclage d’une première électrode pour batterie lithium-ion, un mélange précurseur d’une composition d’électrode obtenue par ce recyclage, et la composition en résultant. La première électrode comporte un premier collecteur et un premier revêtement qui comprend des premiers ingrédients, et le procédé comprend :a) une séparation du premier revêtement d’avec le premier collecteur,b) un mélangeage par voie fondue et sans solvant du premier revêtement récupéré avec des seconds ingrédients neufs comprenant une seconde matière active, un second liant comprenant un liant permanent et un liant sacrificiel, et un second additif conducteur électrique, pour obtenir le mélange précurseur, puisc) une élimination du liant sacrificiel, pour obtenir la composition formant un second revêtement d’électrode. Fig. 4
FR2009896A 2020-09-29 2020-09-29 Procédé de recyclage d’une électrode pour batterie lithium-ion, mélange précurseur et composition d’électrode pour cette batterie. Active FR3114690B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR2009896A FR3114690B1 (fr) 2020-09-29 2020-09-29 Procédé de recyclage d’une électrode pour batterie lithium-ion, mélange précurseur et composition d’électrode pour cette batterie.
CA3197314A CA3197314A1 (fr) 2020-09-29 2021-09-29 Procede de recyclage d'une electrode pour batterie lithium-ion, melange precurseur et composition d'electrode pour cette batterie
EP21798745.2A EP4222794A1 (fr) 2020-09-29 2021-09-29 Procédé de recyclage d'une électrode pour batterie lithium-ion, mélange précurseur et composition d'électrode pour cette batterie
US18/028,588 US20230361371A1 (en) 2020-09-29 2021-09-29 Method for recycling a lithium ion battery electrode, precursor mixture and electrode composition for said battery
PCT/FR2021/051689 WO2022069838A1 (fr) 2020-09-29 2021-09-29 Procédé de recyclage d'une électrode pour batterie lithium-ion, mélange précurseur et composition d'électrode pour cette batterie.
KR1020237014282A KR20230079141A (ko) 2020-09-29 2021-09-29 리튬 이온 배터리 전극, 전구체 혼합물 및 이의 배터리 전극 조성물을 재활용하는 방법
CN202180079652.7A CN116583967A (zh) 2020-09-29 2021-09-29 用于回收锂离子电池电极的方法，用于该电池的前体混合物和电极组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2009896 2020-09-29
FR2009896A FR3114690B1 (fr) 2020-09-29 2020-09-29 Procédé de recyclage d’une électrode pour batterie lithium-ion, mélange précurseur et composition d’électrode pour cette batterie.

Publications (2)

Publication Number Publication Date
FR3114690A1 FR3114690A1 (fr) 2022-04-01
FR3114690B1 true FR3114690B1 (fr) 2024-02-09

Family

ID=74347201

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2009896A Active FR3114690B1 (fr) 2020-09-29 2020-09-29 Procédé de recyclage d’une électrode pour batterie lithium-ion, mélange précurseur et composition d’électrode pour cette batterie.

Country Status (7)

Country Link
US (1) US20230361371A1 (fr)
EP (1) EP4222794A1 (fr)
KR (1) KR20230079141A (fr)
CN (1) CN116583967A (fr)
CA (1) CA3197314A1 (fr)
FR (1) FR3114690B1 (fr)
WO (1) WO2022069838A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2025000169A1 (fr) * 2023-06-26 2025-01-02 广东邦普循环科技有限公司 Électrode pour extraire du lithium d'un lac salé et son procédé de préparation
KR102860082B1 (ko) * 2024-02-29 2025-09-16 주식회사 에이비알 공정 폐기물로 발생된 음극재 재활용 방법
FR3160270A1 (fr) * 2024-03-18 2025-09-19 Saft Procédé de désassemblage de composants ou d’éléments électrochimiques

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20010033973A1 (en) * 2000-01-13 2001-10-25 Krause Larry J. Electrode compositions having improved cycling behavior
JP4629290B2 (ja) 2000-12-26 2011-02-09 トータル ワイヤレス ソリューショオンズ リミテッド リチウムイオンポリマー二次電池
JP5533700B2 (ja) * 2011-01-27 2014-06-25 住友金属鉱山株式会社 有価金属の浸出方法及びこの浸出方法を用いた有価金属の回収方法
US11127992B2 (en) * 2012-04-04 2021-09-21 Worcester Polytechnic Institute Charge material for recycled lithium-ion batteries
KR101497921B1 (ko) * 2013-06-28 2015-03-03 한국생산기술연구원 폐리튬이온전지로부터 ncm계 양극활물질의 재생방법과 이 방법에 의해 제조된 ncm계 양극활물질
CA2937663C (fr) * 2014-02-19 2020-09-01 Hutchinson Procede de preparation d'une composition d'electrode ou a proprietes magnetiques, melange et composition obtenus par ce procede et cette electrode.
US9614261B2 (en) 2014-08-13 2017-04-04 Farasis Energy, Inc. Process for recycling electrode materials from lithium-ion batteries
DE102015207843B4 (de) 2015-04-28 2018-06-07 Duesenfeld Gmbh Verfahren zum Behandeln gebrauchter Batterien und Batterie-Verarbeitungsanlage
WO2018169830A1 (fr) 2017-03-13 2018-09-20 The Regents Of The Universtiy Of California Procédé de production de graphite pré-lithié à partir de batteries li-ion recyclées
KR102227311B1 (ko) * 2018-05-11 2021-03-15 주식회사 엘지화학 양극재의 재활용 방법
US10777843B2 (en) * 2018-10-31 2020-09-15 Nissan North America, Inc. Regenerated lithium-ion cathode materials having modified surfaces

Also Published As

Publication number Publication date
US20230361371A1 (en) 2023-11-09
CA3197314A1 (fr) 2022-04-07
CN116583967A (zh) 2023-08-11
KR20230079141A (ko) 2023-06-05
WO2022069838A1 (fr) 2022-04-07
EP4222794A1 (fr) 2023-08-09
FR3114690A1 (fr) 2022-04-01

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