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FR3030585B1 - Procede d'impregnation d'un substrat fibreux avec un melange (meth)acrylique, composition dudit melange, et materiau composite obtenu apres polymerisation dudit melange. - Google Patents

Procede d'impregnation d'un substrat fibreux avec un melange (meth)acrylique, composition dudit melange, et materiau composite obtenu apres polymerisation dudit melange.

Info

Publication number
FR3030585B1
FR3030585B1 FR1463058A FR1463058A FR3030585B1 FR 3030585 B1 FR3030585 B1 FR 3030585B1 FR 1463058 A FR1463058 A FR 1463058A FR 1463058 A FR1463058 A FR 1463058A FR 3030585 B1 FR3030585 B1 FR 3030585B1
Authority
FR
France
Prior art keywords
mixture
impregnating
meth
polymerization
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1463058A
Other languages
English (en)
Other versions
FR3030585A1 (fr
Inventor
Pierre Gerard
Gilles Francois
Sebastien Taillemite
Melanie Lafarge
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1463058A priority Critical patent/FR3030585B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to CA2971543A priority patent/CA2971543A1/fr
Priority to BR112017013517A priority patent/BR112017013517A2/pt
Priority to PCT/FR2015/053711 priority patent/WO2016102884A1/fr
Priority to US15/538,440 priority patent/US20180002503A1/en
Priority to MX2017008226A priority patent/MX2017008226A/es
Priority to CN201580076635.2A priority patent/CN107531977A/zh
Priority to EP15828360.6A priority patent/EP3237505A1/fr
Priority to JP2017533432A priority patent/JP2017538844A/ja
Priority to KR1020177020558A priority patent/KR20170101264A/ko
Publication of FR3030585A1 publication Critical patent/FR3030585A1/fr
Application granted granted Critical
Publication of FR3030585B1 publication Critical patent/FR3030585B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/043Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10Coating
    • C03C25/24Coatings containing organic materials
    • C03C25/26Macromolecular compounds or prepolymers
    • C03C25/28Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/285Acrylic resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/44Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/14Methyl esters, e.g. methyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/28Oxygen or compounds releasing free oxygen
    • C08F4/32Organic compounds
    • C08F4/34Per-compounds with one peroxy-radical
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/244Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/14Peroxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12Homopolymers or copolymers of methyl methacrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/14Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/42Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • B29C70/48Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating the reinforcements in the closed mould, e.g. resin transfer moulding [RTM], e.g. by vacuum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2033/00Use of polymers of unsaturated acids or derivatives thereof as moulding material
    • B29K2033/04Polymers of esters
    • B29K2033/12Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0005Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/10Homopolymers or copolymers of methacrylic acid esters
    • C08J2333/12Homopolymers or copolymers of methyl methacrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Polymerisation Methods In General (AREA)
  • Reinforced Plastic Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Graft Or Block Polymers (AREA)
FR1463058A 2014-12-22 2014-12-22 Procede d'impregnation d'un substrat fibreux avec un melange (meth)acrylique, composition dudit melange, et materiau composite obtenu apres polymerisation dudit melange. Expired - Fee Related FR3030585B1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
FR1463058A FR3030585B1 (fr) 2014-12-22 2014-12-22 Procede d'impregnation d'un substrat fibreux avec un melange (meth)acrylique, composition dudit melange, et materiau composite obtenu apres polymerisation dudit melange.
JP2017533432A JP2017538844A (ja) 2014-12-22 2015-12-22 繊維基材に(メタ)アクリル混合物を含浸させるための方法、前記(メタ)アクリル混合物の成分、及び前記(メタ)アクリル混合物の重合後に生成される複合材料
PCT/FR2015/053711 WO2016102884A1 (fr) 2014-12-22 2015-12-22 Procede d'impregnation d'un substrat fibreux avec un melange (meth)acrylique, composition dudit melange (meth)acrylique, et materiau composite obtenu apres polymerisation dudit melange (meth)acrylique
US15/538,440 US20180002503A1 (en) 2014-12-22 2015-12-22 Method for impregnating a fibrous substrate with a (meth)acrylic mixture, composition of said (meth)acrylic mixture, and composite material produced after polymerisation of said (meth)acrylic mixture
MX2017008226A MX2017008226A (es) 2014-12-22 2015-12-22 Proceso de impregnacion de un sustrato fibroso con una mezcla (met)acrilica, composicion de la mezcla (met)acrilica, y material compuesto obtenido despues de la polimerizacion de la mezcla (met)acrilica.
CN201580076635.2A CN107531977A (zh) 2014-12-22 2015-12-22 用(甲基)丙烯酸系混合物浸渍纤维基材的方法、所述(甲基)丙烯酸系混合物的组合物和聚合所述(甲基)丙烯酸系混合物后制得的复合材料
CA2971543A CA2971543A1 (fr) 2014-12-22 2015-12-22 Procede d'impregnation d'un substrat fibreux avec un melange (meth)acrylique, composition dudit melange (meth)acrylique, et materiau composite obtenu apres polymerisation dudit melange (meth)acrylique
BR112017013517A BR112017013517A2 (pt) 2014-12-22 2015-12-22 processo de impregnação de um substrato fibroso com uma mistura (met)acrílica, composição da referida mistura (met)acrílica, e material compósito obtido após polimerização da referida mistura (met)acrílica
KR1020177020558A KR20170101264A (ko) 2014-12-22 2015-12-22 (메트)아크릴 혼합물로 섬유질 기재를 함침시키는 방법, 상기 (메트)아크릴 혼합물의 조성물, 및 상기 (메트)아크릴 혼합물의 중합 후에 생성된 복합 물질
EP15828360.6A EP3237505A1 (fr) 2014-12-22 2015-12-22 Procede d'impregnation d'un substrat fibreux avec un melange (meth)acrylique, composition dudit melange (meth)acrylique, et materiau composite obtenu apres polymerisation dudit melange (meth)acrylique

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1463058A FR3030585B1 (fr) 2014-12-22 2014-12-22 Procede d'impregnation d'un substrat fibreux avec un melange (meth)acrylique, composition dudit melange, et materiau composite obtenu apres polymerisation dudit melange.

Publications (2)

Publication Number Publication Date
FR3030585A1 FR3030585A1 (fr) 2016-06-24
FR3030585B1 true FR3030585B1 (fr) 2017-02-03

Family

ID=53398137

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1463058A Expired - Fee Related FR3030585B1 (fr) 2014-12-22 2014-12-22 Procede d'impregnation d'un substrat fibreux avec un melange (meth)acrylique, composition dudit melange, et materiau composite obtenu apres polymerisation dudit melange.

Country Status (10)

Country Link
US (1) US20180002503A1 (fr)
EP (1) EP3237505A1 (fr)
JP (1) JP2017538844A (fr)
KR (1) KR20170101264A (fr)
CN (1) CN107531977A (fr)
BR (1) BR112017013517A2 (fr)
CA (1) CA2971543A1 (fr)
FR (1) FR3030585B1 (fr)
MX (1) MX2017008226A (fr)
WO (1) WO2016102884A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3053350B1 (fr) 2016-06-29 2020-03-27 Arkema France Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci
FR3087203B1 (fr) * 2018-10-15 2022-01-21 Arkema France Compositions polymeres (meth)acryliques pour composite, leur procede de preparation et leur utilisation

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5162280A (en) 1988-01-27 1992-11-10 Witco Corporation Aqueous dispersions of aromatic diacyl peroxides
US5300600A (en) 1989-10-12 1994-04-05 Witco Corporation Aqueous dispersions of peroxides
DE69917106T2 (de) * 1998-03-06 2005-05-19 Nippon Shokubai Co. Ltd. (Meth)acrylsäurepolymer und Verfahren zu seiner Herstellung
TWI506078B (zh) * 2008-08-14 2015-11-01 Lucite Int Uk Ltd 可硬化雙組份丙烯酸組合物
SA110310245B1 (ar) * 2009-04-03 2014-11-12 اكزو نوبل كيميكا معلق بيروكسيد ثنائي آسيل صلب مائي
WO2012170866A1 (fr) * 2011-06-10 2012-12-13 Norac Pharma Procédé pour microparticules de peroxyde de benzoyle
FR2981652B1 (fr) * 2011-10-21 2015-03-27 Arkema France Composites via la polymerisation in-situ de resines thermoplastiques methacryliques
FR2993581B1 (fr) 2012-07-18 2016-01-22 Arkema France Procede d'impregnation pour un substrat fibreux, sirop (meth)acrylique liquide pour le procede d'impregnation, son procede de polymerisation et produit structure obtenu a partir de celui-ci
FR3002941B1 (fr) * 2013-03-08 2015-04-10 Arkema France Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne

Also Published As

Publication number Publication date
KR20170101264A (ko) 2017-09-05
US20180002503A1 (en) 2018-01-04
JP2017538844A (ja) 2017-12-28
WO2016102884A1 (fr) 2016-06-30
EP3237505A1 (fr) 2017-11-01
MX2017008226A (es) 2017-10-06
BR112017013517A2 (pt) 2018-03-06
CN107531977A (zh) 2018-01-02
CA2971543A1 (fr) 2016-06-30
FR3030585A1 (fr) 2016-06-24

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