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FR3008981B1 - NOVEL POWDER POLYMER, PROCESS FOR PREPARING THE SAME, AND USE AS THICKENING - Google Patents

NOVEL POWDER POLYMER, PROCESS FOR PREPARING THE SAME, AND USE AS THICKENING

Info

Publication number
FR3008981B1
FR3008981B1 FR1357280A FR1357280A FR3008981B1 FR 3008981 B1 FR3008981 B1 FR 3008981B1 FR 1357280 A FR1357280 A FR 1357280A FR 1357280 A FR1357280 A FR 1357280A FR 3008981 B1 FR3008981 B1 FR 3008981B1
Authority
FR
France
Prior art keywords
molar
equal
less
monomeric units
monomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1357280A
Other languages
French (fr)
Other versions
FR3008981A1 (en
Inventor
Olivier Braun
Paul Mallo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe dExploitation de Produits pour les Industries Chimiques SEPPIC SA
Original Assignee
Societe dExploitation de Produits pour les Industries Chimiques SEPPIC SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1357280A priority Critical patent/FR3008981B1/en
Application filed by Societe dExploitation de Produits pour les Industries Chimiques SEPPIC SA filed Critical Societe dExploitation de Produits pour les Industries Chimiques SEPPIC SA
Priority to JP2016528581A priority patent/JP6370378B2/en
Priority to CN201480041310.6A priority patent/CN105392811B/en
Priority to EP14748247.5A priority patent/EP3024859B1/en
Priority to PCT/FR2014/051851 priority patent/WO2015011380A1/en
Priority to US14/907,965 priority patent/US10035143B2/en
Priority to KR1020167001607A priority patent/KR102196342B1/en
Publication of FR3008981A1 publication Critical patent/FR3008981A1/en
Application granted granted Critical
Publication of FR3008981B1 publication Critical patent/FR3008981B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/16Organic material
    • B01J39/18Macromolecular compounds
    • B01J39/20Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52Amides or imides
    • C08F220/54Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/58Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine
    • C08F220/585Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine and containing other heteroatoms, e.g. 2-acrylamido-2-methylpropane sulfonic acid [AMPS]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/10General cosmetic use
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/48Thickener, Thickening system
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/52Stabilizers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54Polymers characterized by specific structures/properties
    • A61K2800/542Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5424Polymers characterized by specific structures/properties characterized by the charge anionic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1812C12-(meth)acrylate, e.g. lauryl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1818C13or longer chain (meth)acrylate, e.g. stearyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/20Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10Esters
    • C08F222/1006Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/103Esters of polyhydric alcohols or polyhydric phenols of trialcohols, e.g. trimethylolpropane tri(meth)acrylate

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Medicinal Preparation (AREA)
  • Detergent Compositions (AREA)

Abstract

Polyélectrolyte anionique réticulé issu de la polymérisation pour 100% molaire : (i) - D'une proportion supérieure ou égale à 30% molaire et inférieure à 99,5% molaire d'unités monomériques issues d'un monomère possédant une fonction acide fort, partiellement salifiée ou totalement salifiée ; (ii) - D'une proportion supérieure ou égale à 0,5% molaire et inférieure ou égale à 5% d'unités monomériques issues d'au moins un monomère de formule (I) : CH =CH(CH )-C(=O)-OR (I) dans laquelle représente un radical alkyle comportant de dix à dix-huit atomes de carbone ; (iii) - D'une proportion supérieure à 0% molaire et inférieure ou égale à 5% molaire d'unités monomériques issues d'au moins un monomère de réticulation diéthylénique ou polyéthylénique (iv) - Et optionnellement d'une proportion inférieure à 69,5% molaire d'unités monomériques issues d'un monomère neutre ; un procédé pour sa préparation et son utilisation comme épaississant dans les compositions topiques.Cross-linked anionic polyelectrolyte resulting from the polymerization for 100% molar: (i) - Of a proportion greater than or equal to 30% molar and less than 99.5% molar of monomeric units resulting from a monomer having a strong acid function, partially salified or totally salified; (ii) - Of a proportion greater than or equal to 0.5% molar and less than or equal to 5% of monomeric units derived from at least one monomer of formula (I): CH=CH(CH)-C( =O)-OR (I) in which represents an alkyl radical containing from ten to eighteen carbon atoms; (iii) - Of a proportion greater than 0% molar and less than or equal to 5% molar of monomeric units derived from at least one diethylenic or polyethylenic crosslinking monomer (iv) - And optionally of a proportion less than 69 .5 mol% of monomeric units derived from a neutral monomer; a process for its preparation and its use as a thickener in topical compositions.

FR1357280A 2013-07-24 2013-07-24 NOVEL POWDER POLYMER, PROCESS FOR PREPARING THE SAME, AND USE AS THICKENING Expired - Fee Related FR3008981B1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1357280A FR3008981B1 (en) 2013-07-24 2013-07-24 NOVEL POWDER POLYMER, PROCESS FOR PREPARING THE SAME, AND USE AS THICKENING
CN201480041310.6A CN105392811B (en) 2013-07-24 2014-07-18 Powdered polymer, process for its preparation and use as thickener
EP14748247.5A EP3024859B1 (en) 2013-07-24 2014-07-18 Novel powder polymer, method for the preparation thereof, and use as a thickener
PCT/FR2014/051851 WO2015011380A1 (en) 2013-07-24 2014-07-18 Novel powder polymer, method for the preparation thereof, and use as a thickener
JP2016528581A JP6370378B2 (en) 2013-07-24 2014-07-18 NOVEL POWDER POLYMER, METHOD FOR PRODUCING THE SAME AND USE THEREOF AS A THINKING AGENT
US14/907,965 US10035143B2 (en) 2013-07-24 2014-07-18 Powder polymer, method for the preparation thereof, and use as a thickener
KR1020167001607A KR102196342B1 (en) 2013-07-24 2014-07-18 Novel powder polymer, method for the preparation thereof, and use as a thickener

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1357280A FR3008981B1 (en) 2013-07-24 2013-07-24 NOVEL POWDER POLYMER, PROCESS FOR PREPARING THE SAME, AND USE AS THICKENING

Publications (2)

Publication Number Publication Date
FR3008981A1 FR3008981A1 (en) 2015-01-30
FR3008981B1 true FR3008981B1 (en) 2016-11-18

Family

ID=49322633

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1357280A Expired - Fee Related FR3008981B1 (en) 2013-07-24 2013-07-24 NOVEL POWDER POLYMER, PROCESS FOR PREPARING THE SAME, AND USE AS THICKENING

Country Status (7)

Country Link
US (1) US10035143B2 (en)
EP (1) EP3024859B1 (en)
JP (1) JP6370378B2 (en)
KR (1) KR102196342B1 (en)
CN (1) CN105392811B (en)
FR (1) FR3008981B1 (en)
WO (1) WO2015011380A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10159638B2 (en) * 2016-06-21 2018-12-25 Johnson & Johnson Consumer Inc. Personal care compositions containing complexing polyelectrolytes
CN109957062A (en) * 2017-12-22 2019-07-02 万华化学(宁波)有限公司 Highly cross-linked acrylate copolymer and its preparation method and use as thickener
FR3078708B1 (en) * 2018-03-06 2020-03-27 Societe D'exploitation De Produits Pour Les Industries Chimiques Seppic SELF-REVERSIBLE REVERSE LATEX, INCLUDING AS A REVERSE AGENT FOR SURFACTANT SPECIES OF THE POLYGLYCEROL ESTER FAMILY, ITS USE AS A THICKENING AGENT AND AQUEOUS LIQUID DETERGENT COMPOSITIONS FOR HOUSEHOLD OR INDUSTRIAL USE AS A CONTAINER
FR3078709B1 (en) * 2018-03-06 2020-02-28 Societe D'exploitation De Produits Pour Les Industries Chimiques Seppic SELF-REVERSIBLE SELF-REVERSIBLE REVERSE LATEX COMPRISING AS A REVERSE AGENT FOR SURFACTANT SPECIES OF THE POLYGLYCEROL ESTER FAMILY, AND COMPOSITIONS COMPRISING SAME
EP3610853A1 (en) 2018-08-15 2020-02-19 The Boots Company PLC Cosmetic compositions
FR3099368B1 (en) * 2019-07-31 2022-08-19 Soc Dexploitation De Produits Pour Les Industries Chimiques Seppic Cosmetic composition in the form of a compact, impact-resistant powder
US20220249347A1 (en) * 2021-02-10 2022-08-11 TRI-K Industries, Inc. Composition and Method Containing Pea and Quinoa Natural Peptides And Niacinamide to Enhance Skin Glow, Radiance And Even Skin Tone

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FR2950060B1 (en) * 2009-09-11 2011-10-28 Soc Dexploitation De Produits Pour Les Industries Chimiques Seppic NOVEL POWDER POLYMER, PROCESS FOR PREPARING THE SAME, AND USE AS THICKENING
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Also Published As

Publication number Publication date
KR102196342B1 (en) 2020-12-29
KR20160037891A (en) 2016-04-06
FR3008981A1 (en) 2015-01-30
WO2015011380A1 (en) 2015-01-29
EP3024859B1 (en) 2019-03-27
JP2016525606A (en) 2016-08-25
CN105392811B (en) 2019-03-08
US20160167040A1 (en) 2016-06-16
EP3024859A1 (en) 2016-06-01
JP6370378B2 (en) 2018-08-08
US10035143B2 (en) 2018-07-31
CN105392811A (en) 2016-03-09

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