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FR3061036B1 - Solide porteur d'oxygene macroporeux a matrice ceramique d'oxydes, son procede de preparation et son utilisation pour un procede d'oxydo-reduction en boucle chimique - Google Patents

Solide porteur d'oxygene macroporeux a matrice ceramique d'oxydes, son procede de preparation et son utilisation pour un procede d'oxydo-reduction en boucle chimique Download PDF

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Publication number
FR3061036B1
FR3061036B1 FR1663301A FR1663301A FR3061036B1 FR 3061036 B1 FR3061036 B1 FR 3061036B1 FR 1663301 A FR1663301 A FR 1663301A FR 1663301 A FR1663301 A FR 1663301A FR 3061036 B1 FR3061036 B1 FR 3061036B1
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France
Prior art keywords
chemical loop
solid
oxido
reduction process
oxygen carrier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1663301A
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English (en)
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FR3061036A1 (fr
Inventor
Arnold Lambert
Mathieu Michau
Delphine MARTI
Elodie Comte
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
TotalEnergies Onetech SAS
Original Assignee
IFP Energies Nouvelles IFPEN
Total Raffinage Chimie SAS
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Priority to FR1663301A priority Critical patent/FR3061036B1/fr
Application filed by IFP Energies Nouvelles IFPEN, Total Raffinage Chimie SAS filed Critical IFP Energies Nouvelles IFPEN
Priority to BR112019011679A priority patent/BR112019011679A2/pt
Priority to AU2017383045A priority patent/AU2017383045A1/en
Priority to CA3045420A priority patent/CA3045420A1/fr
Priority to EP17822300.4A priority patent/EP3558515A1/fr
Priority to CN201780079798.5A priority patent/CN110225795B/zh
Priority to PCT/EP2017/084208 priority patent/WO2018115344A1/fr
Priority to US16/471,499 priority patent/US11717811B2/en
Publication of FR3061036A1 publication Critical patent/FR3061036A1/fr
Application granted granted Critical
Publication of FR3061036B1 publication Critical patent/FR3061036B1/fr
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/009—Preparation by separation, e.g. by filtration, decantation, screening
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2206/00—Fluidised bed combustion
    • F23C2206/10—Circulating fluidised bed
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Nanotechnology (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

- L'invention porte sur un solide porteur d'oxygène, sa préparation et son utilisation dans un procédé d'oxydo-réduction en boucle chimique sur masse active tel que la combustion en boucle chimique (CLC). Le solide sous forme de particules comporte une masse active d'oxydo-réduction formée d'oxyde(s) métallique(s) dispersée dans une matrice en céramique comportant au moins un oxyde ayant une température de fusion supérieure à 1500°C, tel que l'alumine, et présente une texture initiale macroporeuse spécifique. Le solide porteur d'oxygène est préparé à partir d'une suspension aqueuse comportant des grains d'oxydes précurseurs de la matrice céramique de taille spécifique, par une technique de séchage par atomisation.
FR1663301A 2016-12-23 2016-12-23 Solide porteur d'oxygene macroporeux a matrice ceramique d'oxydes, son procede de preparation et son utilisation pour un procede d'oxydo-reduction en boucle chimique Active FR3061036B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR1663301A FR3061036B1 (fr) 2016-12-23 2016-12-23 Solide porteur d'oxygene macroporeux a matrice ceramique d'oxydes, son procede de preparation et son utilisation pour un procede d'oxydo-reduction en boucle chimique
AU2017383045A AU2017383045A1 (en) 2016-12-23 2017-12-21 Macroporous oxygen carrier solid with a refractory matrix, method for the preparation thereof, and use thereof in a chemical-looping oxidation-reduction method
CA3045420A CA3045420A1 (fr) 2016-12-23 2017-12-21 Solide porteur d'oxygene macroporeux a matrice ceramique d'oxides, son procede de preparation et son utilisation pour un procede d'oxydo-reduction en boucle chimique
EP17822300.4A EP3558515A1 (fr) 2016-12-23 2017-12-21 Solide porteur d'oxygène macroporeux à matrice réfractaire, son procédé de préparation, son utilisation dans un procédé d'oxydo-réduction en boucle chimique
BR112019011679A BR112019011679A2 (pt) 2016-12-23 2017-12-21 sólido portador de oxigênio macroporoso com matriz de cerâmica de óxidos, processo de preparação do mesmo e utilização do mesmo para um processo de óxido-redução em circuito químico
CN201780079798.5A CN110225795B (zh) 2016-12-23 2017-12-21 具有难熔基质的大孔氧载体固体，其制备方法及其在化学链氧化还原方法中的用途
PCT/EP2017/084208 WO2018115344A1 (fr) 2016-12-23 2017-12-21 Solide porteur d'oxygène macroporeux à matrice réfractaire, son procédé de préparation, son utilisation dans un procédé d'oxydo-réduction en boucle chimique
US16/471,499 US11717811B2 (en) 2016-12-23 2017-12-21 Macroporous oxygen carrier solid with an oxide ceramic matrix, method for the preparation thereof, and use thereof for a chemical-looping oxidation-reduction method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1663301 2016-12-23
FR1663301A FR3061036B1 (fr) 2016-12-23 2016-12-23 Solide porteur d'oxygene macroporeux a matrice ceramique d'oxydes, son procede de preparation et son utilisation pour un procede d'oxydo-reduction en boucle chimique

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FR3061036B1 true FR3061036B1 (fr) 2021-07-02

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EP (1) EP3558515A1 (fr)
CN (1) CN110225795B (fr)
AU (1) AU2017383045A1 (fr)
BR (1) BR112019011679A2 (fr)
CA (1) CA3045420A1 (fr)
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WO (1) WO2018115344A1 (fr)

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US12122967B1 (en) * 2017-04-04 2024-10-22 U.S. Department Of Energy Process for production of H2 rich synthesis gas from coal/steam with Cu—Fe-alumina based catalysts
US20210284540A1 (en) * 2018-07-18 2021-09-16 University Of Florida Research Foundation, Inc. Facile co2 sequestration and fuel production from a hydrocarbon
EP3721992A1 (fr) 2019-04-09 2020-10-14 Vito NV Procédé de préparation rédox d'un transporteur d'oxygène pour un processus en boucle chimique
US11433385B1 (en) * 2019-09-13 2022-09-06 Energy, United States Department Of Encapsulation method for preparation of pellets with high attrition resistance
CN111704949A (zh) * 2020-07-06 2020-09-25 山西恒投环保节能科技有限公司 一种载氧体组合物及其制备方法
FR3112970B1 (fr) 2020-07-31 2022-07-29 Ifp Energies Now Solide porteur d’oxygene a spinelle sous-stoechimetrique pour un procede d’oxydo-reduction en boucle chimique
CN113042753B (zh) * 2021-06-02 2021-08-13 天津大学 减少slm成形镍基高温合金裂纹及提升力学性能的方法
FR3125441B1 (fr) 2021-07-23 2023-07-14 Ifp Energies Now Procédé et installation CLC avec récupération d’oxygène gazeux produit par un porteur d’oxygène
US20250065318A1 (en) * 2021-12-21 2025-02-27 Basf Corporation Catalytic porous metal oxide particles
FR3132093A1 (fr) 2022-01-24 2023-07-28 IFP Energies Nouvelles Solide porteur d’oxygene a base de fer et de spinelle sous-stoechiometrique pour un procede d’oxydo-reduction en boucle chimique
EP4342582A1 (fr) * 2022-09-23 2024-03-27 Technische Universität Graz Produit porteur structuré d'oxygène et son procédé de préparation

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JP3315719B2 (ja) 1992-06-03 2002-08-19 東京電力株式会社 化学ループ燃焼方式発電プラントシステム
DE10061553A1 (de) * 2000-12-11 2002-06-13 Basf Ag Poröser Katalysator für die Hydrierung von Maleinsäureanhydrid zu Tetrahydrofuran
EP1723844A1 (fr) 2005-05-18 2006-11-22 Nederlandse Organisatie voor toegepast-natuurwetenschappelijk Onderzoek TNO Procédé pour la régulation de la chaleur et de la concentration de CO2 de l'air dans un endroit fermé
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EP2707583B1 (fr) 2011-05-11 2019-07-10 Ohio State Innovation Foundation Matériaux vecteurs d'oxygène
FR2985517B1 (fr) * 2012-01-11 2018-05-18 Ifp Energies Now Procede integre de gazeification et combustion indirecte de charges hydrocarbonees solides en boucle chimique
EP2826557A1 (fr) * 2013-07-18 2015-01-21 VITO NV (Vlaamse Instelling voor Technologisch Onderzoek NV) Processus en boucle chimique avec transporteur d'oxygène à base de métal supporté
FR3022161B1 (fr) * 2014-06-13 2021-05-07 Ifp Energies Now Catalyseur a phase active de nickel comalaxee mesoporeux et macroporeux ayant un diametre median macroporeux superieur a 300 nm et son utilisation en hydrogenation
FR3022160B1 (fr) 2014-06-13 2021-05-07 Ifp Energies Now Catalyseur a phase active de nickel comalaxee mesoporeux et macroporeux ayant un diametre median macroporeux compris entre 50 et 300 nm et son utilisation en hydrogenation
FR3061037B1 (fr) * 2016-12-23 2021-07-02 Ifp Energies Now Solide porteur d'oxygene a base de tectosilicates, son procede de preparation et son utilisation pour un procede d'oxydo-reduction en boucle chimique

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FR3061036A1 (fr) 2018-06-29
EP3558515A1 (fr) 2019-10-30
CN110225795A (zh) 2019-09-10
AU2017383045A1 (en) 2019-07-25
US11717811B2 (en) 2023-08-08
WO2018115344A1 (fr) 2018-06-28
CN110225795B (zh) 2022-12-16
CA3045420A1 (fr) 2018-06-28
US20190388874A1 (en) 2019-12-26
BR112019011679A2 (pt) 2019-10-15

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