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FR2994510B1 - Procede pour la preparation de materiaux actifs proteges partiellement en surface pour des batteries au lithium - Google Patents

Procede pour la preparation de materiaux actifs proteges partiellement en surface pour des batteries au lithium

Info

Publication number
FR2994510B1
FR2994510B1 FR1257730A FR1257730A FR2994510B1 FR 2994510 B1 FR2994510 B1 FR 2994510B1 FR 1257730 A FR1257730 A FR 1257730A FR 1257730 A FR1257730 A FR 1257730A FR 2994510 B1 FR2994510 B1 FR 2994510B1
Authority
FR
France
Prior art keywords
preparation
active materials
lithium batteries
partially surface
protected active
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1257730A
Other languages
English (en)
Other versions
FR2994510A1 (fr
Inventor
Jean-Baptiste Ducros
Gregory Douglade
Jean-Frederic Martin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Renault SAS
Original Assignee
Renault SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1257730A priority Critical patent/FR2994510B1/fr
Application filed by Renault SAS filed Critical Renault SAS
Priority to JP2015525924A priority patent/JP2015530703A/ja
Priority to US14/420,459 priority patent/US20150295242A1/en
Priority to KR1020157005963A priority patent/KR20150041091A/ko
Priority to EP13756641.0A priority patent/EP2882688A2/fr
Priority to CN201380052894.2A priority patent/CN104703919B/zh
Priority to PCT/FR2013/051857 priority patent/WO2014023896A2/fr
Publication of FR2994510A1 publication Critical patent/FR2994510A1/fr
Application granted granted Critical
Publication of FR2994510B1 publication Critical patent/FR2994510B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/003—Titanates
    • C01G23/005—Alkali titanates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00—Compounds of zirconium
    • C01G25/02—Oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1228—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (MnO2)-, e.g. LiMnO2 or Li(MxMn1-x)O2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1242—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)-, e.g. LiMn2O4 or Li(MxMn2-x)O4
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Complex oxides containing cobalt and at least one other metal element
    • C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Complex oxides containing cobalt and at least one other metal element
    • C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C01G51/44—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese
    • C01G51/50—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese of the type (MnO2)n-, e.g. Li(CoxMn1-x)O2 or Li(MyCoxMn1-x-y)O2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Complex oxides containing cobalt and at least one other metal element
    • C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C01G51/44—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese
    • C01G51/54—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese of the type (Mn2O4)-, e.g. Li(CoxMn2-x)O4 or Li(MyCoxMn2-x-y)O4
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/54—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (Mn2O4)-, e.g. Li(NixMn2-x)O4 or Li(MyNixMn2-x-y)O4
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Composite Materials (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Battery Electrode And Active Subsutance (AREA)
FR1257730A 2012-08-09 2012-08-09 Procede pour la preparation de materiaux actifs proteges partiellement en surface pour des batteries au lithium Expired - Fee Related FR2994510B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1257730A FR2994510B1 (fr) 2012-08-09 2012-08-09 Procede pour la preparation de materiaux actifs proteges partiellement en surface pour des batteries au lithium
US14/420,459 US20150295242A1 (en) 2012-08-09 2013-07-31 Method for preparing partially surface-protected active materials for lithium batteries
KR1020157005963A KR20150041091A (ko) 2012-08-09 2013-07-31 부분적으로 표면-보호된 리튬 전지용 활물질의 제조 방법
EP13756641.0A EP2882688A2 (fr) 2012-08-09 2013-07-31 Procédé pour la préparation de matériaux actifs protégés partiellement en surface pour des batteries au lithium
JP2015525924A JP2015530703A (ja) 2012-08-09 2013-07-31 リチウムバッテリー用の部分的に表面保護された活性材料の調製のための方法
CN201380052894.2A CN104703919B (zh) 2012-08-09 2013-07-31 用于制备锂电池的部分受表面保护的活性材料的方法
PCT/FR2013/051857 WO2014023896A2 (fr) 2012-08-09 2013-07-31 Procédé pour la préparation de matériaux actifs protégés partiellement en surface pour des batteries au lithium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1257730A FR2994510B1 (fr) 2012-08-09 2012-08-09 Procede pour la preparation de materiaux actifs proteges partiellement en surface pour des batteries au lithium

Publications (2)

Publication Number Publication Date
FR2994510A1 FR2994510A1 (fr) 2014-02-14
FR2994510B1 true FR2994510B1 (fr) 2014-08-08

Family

ID=47257867

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1257730A Expired - Fee Related FR2994510B1 (fr) 2012-08-09 2012-08-09 Procede pour la preparation de materiaux actifs proteges partiellement en surface pour des batteries au lithium

Country Status (7)

Country Link
US (1) US20150295242A1 (fr)
EP (1) EP2882688A2 (fr)
JP (1) JP2015530703A (fr)
KR (1) KR20150041091A (fr)
CN (1) CN104703919B (fr)
FR (1) FR2994510B1 (fr)
WO (1) WO2014023896A2 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10186706B2 (en) * 2013-05-17 2019-01-22 Mitsui Mining & Smelting Co., Ltd. Positive electrode active material for lithium secondary battery
WO2016011412A1 (fr) 2014-07-17 2016-01-21 Ada Technologies, Inc. Batteries à longévité extrême et haute densité d'énergie et leur procédé de fabrication et d'utilisation
JP6466145B2 (ja) * 2014-11-14 2019-02-06 マクセルホールディングス株式会社 非水二次電池用正極材料及びその製造方法、並びにその非水二次電池用正極材料を用いた非水二次電池用正極及びそれを用いた非水二次電池
US11996564B2 (en) * 2015-06-01 2024-05-28 Forge Nano Inc. Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings
CN106450270B (zh) * 2015-08-13 2020-08-11 中国科学院物理研究所 锂离子二次电池的正极活性材料及其制备方法和应用
JP6624631B2 (ja) * 2015-08-24 2019-12-25 新日本電工株式会社 リチウム遷移金属複合酸化物及びその製造方法
US9964589B1 (en) * 2016-11-08 2018-05-08 Globalfoundries Singapore Pte. Ltd. System for detection of a photon emission generated by a device and methods for detecting the same
CN108461716A (zh) * 2017-02-17 2018-08-28 宝山钢铁股份有限公司 钛酸锂复合材料及其制备方法和用途
US11024846B2 (en) * 2017-03-23 2021-06-01 Ada Technologies, Inc. High energy/power density, long cycle life, safe lithium-ion battery capable of long-term deep discharge/storage near zero volt and method of making and using the same

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4588576A (en) * 1984-11-01 1986-05-13 Celanese Corporation Production of microcrystalline zirconia
DE19962130A1 (de) * 1999-12-21 2001-07-05 Basell Polypropylen Gmbh Teilkristalline Propylenpolymerisat-Zusammensetzungen mit guter Eignung zur Herstellung von biaxial orientierten Folien
DE10014884A1 (de) * 2000-03-24 2001-09-27 Merck Patent Gmbh Beschichtete Lithium-Mischoxid-Partikel und ein Verfahren zu deren Herstellung
US7393648B2 (en) * 2001-12-03 2008-07-01 Alexion Pharmaceuticals, Inc. Hybrid antibodies
US9023525B2 (en) * 2002-03-22 2015-05-05 Lg Chem, Ltd. Cathode active material for lithium secondary battery
US20040191633A1 (en) * 2003-02-26 2004-09-30 The University Of Chicago Electrodes for lithium batteries
CA2651235C (fr) * 2006-05-04 2014-12-09 Lg Chem, Ltd. Materiau d'electrode actif a haute stabilite et dispositif electrochimique l'utilisant
US8187746B2 (en) * 2008-05-16 2012-05-29 Uchicago Argonne, Llc Surface modification agents for lithium batteries
CN102376980A (zh) * 2010-08-07 2012-03-14 孙美红 一种使用无碳磷酸铁锂作为正极的电池及其制造方法

Also Published As

Publication number Publication date
US20150295242A1 (en) 2015-10-15
CN104703919A (zh) 2015-06-10
JP2015530703A (ja) 2015-10-15
WO2014023896A3 (fr) 2014-04-03
WO2014023896A2 (fr) 2014-02-13
FR2994510A1 (fr) 2014-02-14
CN104703919B (zh) 2017-07-28
EP2882688A2 (fr) 2015-06-17
KR20150041091A (ko) 2015-04-15

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