FR2984341B1 - PROCESS FOR THE PRODUCTION OF ARTICLES BY ROTATION MOLDING OF A VINYL CHLORIDE POLYMER COMPOSITION - Google Patents
PROCESS FOR THE PRODUCTION OF ARTICLES BY ROTATION MOLDING OF A VINYL CHLORIDE POLYMER COMPOSITIONInfo
- Publication number
- FR2984341B1 FR2984341B1 FR1161865A FR1161865A FR2984341B1 FR 2984341 B1 FR2984341 B1 FR 2984341B1 FR 1161865 A FR1161865 A FR 1161865A FR 1161865 A FR1161865 A FR 1161865A FR 2984341 B1 FR2984341 B1 FR 2984341B1
- Authority
- FR
- France
- Prior art keywords
- vinyl chloride
- articles
- polymer
- production
- polymer composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000642 polymer Polymers 0.000 title abstract 7
- 239000000203 mixture Substances 0.000 title abstract 6
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000000465 moulding Methods 0.000 title 1
- 229920001577 copolymer Polymers 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 239000012760 heat stabilizer Substances 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000001175 rotational moulding Methods 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/003—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/04—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
- C08L91/08—Mineral waxes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
- B29K2027/06—PVC, i.e. polyvinylchloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Process for manufacturing articles, characterized in that it comprises a step of rotational moulding of a composition (C) comprising at least one vinyl chloride polymer (P) and at least one heat stabilizer (S), according to which - the said polymer (P) is a rigid polymer chosen from copolymers (P1) containing monomer units derived from vinyl chloride and monomer units derived from at least vinyl acetate and mixtures (M) comprising at least 30% by weight, relative to the total weight of polymers in the mixture (M), of at least one copolymer (P1) and at most 70% by weight, relative to the total weight of polymers in the mixture (M) of at least one vinyl chloride homopolymer (P2), the molecular mass of the polymer (P) being such that its K value, measured according to standard ISO 1628-2, is between 45 and 60, and - the stabilizer (S) is chosen from liquid organotins. Composition, use thereof and manufactured articles.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1161865A FR2984341B1 (en) | 2011-12-19 | 2011-12-19 | PROCESS FOR THE PRODUCTION OF ARTICLES BY ROTATION MOLDING OF A VINYL CHLORIDE POLYMER COMPOSITION |
| PCT/EP2012/075339 WO2013092363A1 (en) | 2011-12-19 | 2012-12-13 | Process for manufacturing articles by rotational moulding of a composition based on vinyl chloride polymer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1161865A FR2984341B1 (en) | 2011-12-19 | 2011-12-19 | PROCESS FOR THE PRODUCTION OF ARTICLES BY ROTATION MOLDING OF A VINYL CHLORIDE POLYMER COMPOSITION |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2984341A1 FR2984341A1 (en) | 2013-06-21 |
| FR2984341B1 true FR2984341B1 (en) | 2014-01-17 |
Family
ID=47351688
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR1161865A Expired - Fee Related FR2984341B1 (en) | 2011-12-19 | 2011-12-19 | PROCESS FOR THE PRODUCTION OF ARTICLES BY ROTATION MOLDING OF A VINYL CHLORIDE POLYMER COMPOSITION |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR2984341B1 (en) |
| WO (1) | WO2013092363A1 (en) |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3887519A (en) * | 1971-09-02 | 1975-06-03 | Cincinnati Milacron Chem | Dimethyltin ester stabilizers for vinyl-halide polymers |
| DE3135668A1 (en) * | 1981-09-09 | 1983-05-11 | Basf Ag, 6700 Ludwigshafen | Moulding composition |
| FR2703060B1 (en) * | 1993-03-26 | 1995-05-19 | Rhone Poulenc Chimie | Use as an additive for improving optical properties, of gamma-hydroxy-alkylated silicone oils in compositions based on chlorinated polymer. |
| GB9325849D0 (en) * | 1993-12-17 | 1994-02-23 | Akcros Chem | Stabilised vinyl chloride polymer composition |
| FR2909029B1 (en) | 2006-11-27 | 2011-10-21 | Solvay | METHOD FOR MANUFACTURING A COMPOSITE PLATE BASED ON PVC AND STRUCTURE INCLUDING SUCH A PLATE |
| PL388960A1 (en) * | 2009-09-03 | 2011-03-14 | Instytut Chemii Przemysłowej im. Prof. Ignacego Mościckiego | Method of suspension polymerization of vinyl chloride in the presence of nanofiller |
-
2011
- 2011-12-19 FR FR1161865A patent/FR2984341B1/en not_active Expired - Fee Related
-
2012
- 2012-12-13 WO PCT/EP2012/075339 patent/WO2013092363A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| FR2984341A1 (en) | 2013-06-21 |
| WO2013092363A1 (en) | 2013-06-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |
Effective date: 20150831 |