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FR2976934B1 - Nouveau solide hybride organique-inorganique im-22 et son utilisation dans la separation de paraffines multibranchees des paraffines lineaires et mono-branchees. - Google Patents

Nouveau solide hybride organique-inorganique im-22 et son utilisation dans la separation de paraffines multibranchees des paraffines lineaires et mono-branchees.

Info

Publication number
FR2976934B1
FR2976934B1 FR1101959A FR1101959A FR2976934B1 FR 2976934 B1 FR2976934 B1 FR 2976934B1 FR 1101959 A FR1101959 A FR 1101959A FR 1101959 A FR1101959 A FR 1101959A FR 2976934 B1 FR2976934 B1 FR 2976934B1
Authority
FR
France
Prior art keywords
paraffins
branched paraffins
linear
branched
mono
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1101959A
Other languages
English (en)
Other versions
FR2976934A1 (fr
Inventor
David Peralta
Karin Barthelet
Gerhard Pirngruber
Gerald Chaplais
Masseron Angelique Simon
Joel Patarin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
IFP Energies Nouvelles IFPEN
Universite de Haute Alsace
Original Assignee
Centre National de la Recherche Scientifique CNRS
IFP Energies Nouvelles IFPEN
Universite de Haute Alsace
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, IFP Energies Nouvelles IFPEN, Universite de Haute Alsace filed Critical Centre National de la Recherche Scientifique CNRS
Priority to FR1101959A priority Critical patent/FR2976934B1/fr
Priority to PCT/FR2012/000209 priority patent/WO2012175823A1/fr
Publication of FR2976934A1 publication Critical patent/FR2976934A1/fr
Application granted granted Critical
Publication of FR2976934B1 publication Critical patent/FR2976934B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28064—Surface area, e.g. B.E.T specific surface area being in the range 500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B01J20/28071—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B01D2257/7022—Aliphatic hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1081—Alkanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
FR1101959A 2011-06-24 2011-06-24 Nouveau solide hybride organique-inorganique im-22 et son utilisation dans la separation de paraffines multibranchees des paraffines lineaires et mono-branchees. Expired - Fee Related FR2976934B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR1101959A FR2976934B1 (fr) 2011-06-24 2011-06-24 Nouveau solide hybride organique-inorganique im-22 et son utilisation dans la separation de paraffines multibranchees des paraffines lineaires et mono-branchees.
PCT/FR2012/000209 WO2012175823A1 (fr) 2011-06-24 2012-05-24 Nouveau solide hybride organique-inorganique im-22 et son utilisation dans la separation de paraffines multibranchees des paraffines lineaires et mono-branchees

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1101959A FR2976934B1 (fr) 2011-06-24 2011-06-24 Nouveau solide hybride organique-inorganique im-22 et son utilisation dans la separation de paraffines multibranchees des paraffines lineaires et mono-branchees.

Publications (2)

Publication Number Publication Date
FR2976934A1 FR2976934A1 (fr) 2012-12-28
FR2976934B1 true FR2976934B1 (fr) 2013-06-14

Family

ID=46354392

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1101959A Expired - Fee Related FR2976934B1 (fr) 2011-06-24 2011-06-24 Nouveau solide hybride organique-inorganique im-22 et son utilisation dans la separation de paraffines multibranchees des paraffines lineaires et mono-branchees.

Country Status (2)

Country Link
FR (1) FR2976934B1 (fr)
WO (1) WO2012175823A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016048693A1 (fr) * 2014-09-11 2016-03-31 King Abdullah University Of Science And Technology Valorisation et reformage de carburant avec une structure métallo-organique
WO2017064648A1 (fr) 2015-10-13 2017-04-20 King Abdullah University Of Science And Technology Réseaux organométalliques de type zéolithe présentant une topologie ana
US10759724B2 (en) 2014-09-11 2020-09-01 King Abdullah University Of Science And Technology Zeolite-like metal-organic frameworks with ana topology
CN107469467A (zh) * 2017-09-21 2017-12-15 陕西科技大学 一种高效气体吸附型空气过滤材料的制备方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2985589A (en) 1957-05-22 1961-05-23 Universal Oil Prod Co Continuous sorption process employing fixed bed of sorbent and moving inlets and outlets
US4717784A (en) 1986-12-10 1988-01-05 Shell Oil Company Total isomerization process with mono-methyl-branched plus normal paraffin recycle stream
US4804802A (en) 1988-01-25 1989-02-14 Shell Oil Company Isomerization process with recycle of mono-methyl-branched paraffins and normal paraffins
US4855529A (en) 1988-04-25 1989-08-08 Shell Oil Company Isomerization process with preliminary normal paraffin and mono-methyl paraffin feed capture step
US4982052A (en) 1988-12-23 1991-01-01 Texaco Inc. Separation of a mixture of normal paraffins branched chain paraffins and cyclic paraffins
US4982048A (en) 1989-02-24 1991-01-01 Shell Oil Company Isomerization process with preliminary normal paraffin and mono-methyl paraffin feed capture step
EP1988996B1 (fr) 2006-02-28 2017-05-24 The Regents of the University of Michigan Préparation de structures zéolitiques fonctionnalisées
FR2910457B1 (fr) 2006-12-22 2009-03-06 Inst Francais Du Petrole Procede de purification par adsorption d'hydrogene avec cogeneration d'un flux de co2 en pression
WO2008140788A1 (fr) * 2007-05-11 2008-11-20 The Regents Of The University Of California Séparation de gaz d'adsorption de gaz multi-composants
EP2167511A4 (fr) * 2007-07-17 2010-12-22 Univ California Préparation de structures zéolithiques fonctionnalisées
US8071063B2 (en) * 2008-02-21 2011-12-06 Exxonmobile Research And Engineering Company Separation of hydrogen from hydrocarbons utilizing zeolitic imidazolate framework materials

Also Published As

Publication number Publication date
WO2012175823A1 (fr) 2012-12-27
FR2976934A1 (fr) 2012-12-28

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