FR2952536A1 - Composition for perfuming human keratin materials, comprises perfuming substance, silicon derivative of benzotriazole compound and dye in medium, where the composition is devoid of e.g. alkyl beta,beta'-diphenylacrylate compound - Google Patents

Abstract

Colored perfuming composition (A) comprises, in a medium, (a) at least 2 wt.% of a perfuming substance; (b) at least one silicon derivative of benzotriazole compound (I); and (c) at least one dye soluble in the medium, where the composition does not contain alkyl beta ,beta '-diphenylacrylate compound or alkyl alpha -cyano-beta ,beta '-diphenylacrylate compound. Colored perfuming composition (A) comprises, in a medium, (a) at least 2 wt.% of a perfuming substance; (b) at least one silicon derivative of benzotriazole compound of formula (O (3-a)/2Si(R) a-G) (I); and (c) at least one dye soluble in the medium, where the composition does not contain alkyl beta ,beta '-diphenylacrylate compound or alkyl alpha -cyano-beta ,beta '-diphenylacrylate compound. R : 1-10C alkyl (optionally halogenated), phenyl or trimethylsilyloxy radical; a : 0-3; G : a monovalent radical directly attached to silicon atom, which has the structure of formula (2a); Y1 : 1-4C alkyl, halo or 1-4C alkoxy, provided that, in the latter case, two adjacent Y1 of the same aryl ring can together form an 1-12C alkylidene dioxy group; X : O or NH; Z : H or 1-4C; n : 0-3; m : 0 or 1; and p : 1-10. [Image].

Description

Colorless perfume composition without alkyl diphenylacrylate containing a benzotriazole silicone

The invention relates to a colored perfuming composition comprising, in a cosmetically acceptable medium: a) at least 2% by weight of a perfuming substance relative to the total weight of the composition; b) at least one benzotriazole silicone of formula (I) which will be defined later in detail; c) at least one dye soluble in said medium; said composition not containing alkyl 13,3'-diphenylacrylate compound or alkyl α-cyano-13,13'-diphenylacrylate compound.

We know that a perfume is the combination of different odorous substances that evaporate at different times. Each perfume has what is called a "top note" which is the odor that diffuses first when applying the perfume or when opening the container containing it, a "heart or body note" that corresponds to the complete perfume (emission for a few hours after the "top note") and a "bottom note" which is the most persistent odor (emission for several hours after the "heart note"). The persistence of the heart note and the base note corresponds to the persistence of the perfume.

The human being has always sought to perfume and perfume the objects that surround him or the places in which he is, and this, both to mask strong and / or unpleasant odors that to give a good smell .

It is common to incorporate perfume in a number of products or compositions, in particular cosmetic and dermatological such as fresh water, toilet water, perfume water, aftershave lotions, care waters. For aesthetic reasons and cost of manufacture, the juice of the perfumes is colored by adding an effective amount of soluble dye in the support of the formulation (usually alcoholic or hydroalcoholic) rather than dyeing or lacquering the bottle which is a more industrial operation. expensive. The color developed in these scented formulations must remain stable both in time and exposed to light. A filter system and / or an antioxidant system is generally added.

In the application EP1897592, colored perfuming compositions comprising, as stabilizing system, at least 0.2% by weight relative to the total weight of the composition of at least one alkyl 13,13'-diphenylacrylate or α-cyano compound have been proposed. -13,13'-diphenylacrylate alkyl such as octocrylene relative to the total weight of the composition and at least one organic filter UV-A soluble in said medium However the use of a compound 13,13'-diphenylacrylate Alkyl or an α-cyano-13,13'-diphenylacrylate alkyl compound such as octocrylene and a UVA filter tended, on the one hand, to produce unpredictable recrystallizations according to the perfume concentrate used. On the other hand, the Applicant has discovered in the course of his research that a compound 13,13'-diphenylacrylate alkyl or a compound α-cyano-R'-diphenylacrylate alkyl such as octocrylene inhibited the stabilization of the color especially in the field of yellow and purple.

The application WO2005 / 042828 has proposed colored perfuming compositions comprising, as stabilizer system, a piperidinol derivative (ie Tris (tetramethylhydroxypiperidinol) citrate-Tinoguard Q) combined with an organic UV filter chosen from dibenzoylmethane derivatives, cinnamates and derivatives. camphor and s-triazines. Example 6 describes in particular a eau de toilette comprising a perfume, a dye, 0.1% of a mixture of butylmethoxydibenzoylmethane and octocrylene, a stabilizer of the piperidinol type

However, these pipeidinol derivatives have the disadvantage of generating a yellowing toilet water and a parasitic odor.

It has also been advocated in WO00 / 25370 colored toilet water stabilized by a particular benzotriazole compound and / or a particular triazine such as Sodium Benzotriazolyl Butylphenol Sulfonate such as the product sold under the name "TINOGUARD HS" by the company CIBA - GEIGY; Benzotriazolyl dodecyl p-Cresol as the product sold under the name "TINOGUARD TL" by the company CIBA-GEIGY. as the product sold under the trade name "CIBAFAST H Liquid" by the company CIBA-GEIGY, Bumetrizole as the product sold under the name "TINOGUARD AS" by the company CIBA-GEIGY. In the applications WO09 / 059872 and FR2923386, it has been proposed the use of a particular benzotriazole compound, especially Bumetrizole (TINOGUARD AS) in combination with other particular filters such as a dibenzoylmethane derivative with a compound 13, 13 However, these benzotriazole compounds, in particular Bumetrizole (TINOGUARD AS), are difficult to dissolve in toilet water, have a tendency to recrystallize over time, as a result of their use. more to have a poor stabilizing power.

It has also been proposed in patent applications EP1994921, FR 2916347, FR 2916348 and FR 2916349 the use of a UV filter of the aminobenzophenone type such as n-hexyl 2- (4-diethylamino-2-hydroxybenzoyl) benzoate sold under the trade name "UVINUL A +" with other special filters to stabilize the color of the toilet water. However, aminobenzophenone filters such as Uvinul A + provide a yellow color which is undesirable for light-colored scented formulations other than yellow.

There remains the need for colored perfuming products that do not have the disadvantages of the products of the prior art, and in particular the need for colored perfuming products whose color remains stable over time and under the effects of light.

The Applicant has surprisingly discovered that this objective could be achieved by using a colored perfuming composition comprising in a cosmetically acceptable medium: a) at least 2% by weight of a perfuming substance relative to the total weight of the composition; b) at least one benzotriazole silicone of formula (I) which will be defined further in detail c) at least one dye soluble in said medium; said composition not containing a compound of the formula (alkyl 3'-diphenylacrylate) or alkyl α-cyano-β3-diphenylacrylate.

This discovery is the basis of the invention.

The invention also relates to a colored perfuming composition comprising in a cosmetically acceptable medium a) at least 2% by weight of a perfuming substance relative to the total weight of the composition b) at least one benzotriazole silicone of formula (I) which will be defined later in detail c) at least one dye soluble in said medium; said composition does not contain compound 3, (3'-diphenylacrylate alkyl or α-cyano-p, 3'-diphenylacrylate alkyl.

The invention also relates to a process for the perfuming of human keratinous materials and in particular the skin, the lips, the hair, the scalp, the eyelashes and eyebrows, the nails or a garment, comprising the application on the keratin materials or said garment of the composition as defined above.

The invention also relates to the use of at least one silicon derivative of benzotriazole of formula (1), as stabilizing agent for the organoleptic properties of a colored perfuming cosmetic composition with respect to external aggression, in particular of light or temperature differences, in particular the color and / or the odor of said composition; said composition not containing alkyl X3,3'-diphenylacrylate compound or alkyl α-cyano- (1,1'-diphenylacrylate) compound.

By perfume composition is meant any composition leaving after application on ketatinic materials a perfume. 40 "Perfuming substance" means any perfume or aroma likely to perfume the skin and human keratin materials in general including the skin, the hair, the scalp, the lips; nails.

45 "Human keratin materials" means skin (face, body, lips, inner eyelids), scalp, hair, eyelashes, eyebrows, nails, mucous membranes. The term "cosmetically acceptable medium" in the composition of the invention means a non-toxic medium that can be applied to human keratin materials including the skin, the lips, the nails, the hair, the scalp, the eyelashes, eyebrows. By not containing any compound I3,13'-diphenylacrylate alkyl or acyano-R, R'-diphenylacrylate alkyl as containing less than 0.2% by weight of compound I3,13'-diphenylacrylate alkyl or of alkyl α-cyano-R, R'-diphenylacrylate or even less than 0.1% by weight or even free of compound I3,13'-diphenylacrylate alkyl and α-cyano-compound R, R'- alkyl diphenylacrylate.

SILICICITY DERIVATIVES OF BENZOTRIAZOLE

The benzotriazole-functional silicon derivatives used in the present invention are preferably benzotriazole-functional silanes or siloxanes comprising at least one unit of the following formula (1): O (3-a) / 2 Si (R) a-G ( R 1 represents an optionally halogenated C 1 -C 10 alkyl radical or a phenyl radical or a trimethylsilyloxy radical; a is an integer selected from 0 to 3 inclusive; and the symbol G denotes a monovalent radical directly attached to a silicon atom, and which corresponds to the following formula (2): ## STR3 ## in which: Y, which are identical or different, are chosen from the following formulas: C1-C8 alkyl radicals, halogens and C1-C4 alkoxy radicals, it being understood that, in the latter case, two adjacent Y's of the same aromatic ring may together form an alkylidene dioxy group in which the alkylidene group contains 1 to 2 carbon atoms, X represents O or NH, 35 - Z represents hydrogen or a C1-C4 alkyl radical; n is an integer between 0 and 3 inclusive; mestoou1; p represents an integer between 1 and 10, inclusive.

These compounds are especially described in patent applications EP-A-0392883; EP-A-0660701; EP-A-0708108; EP-A-0711778; EP-A-711779.

Preferably, the silicon derivatives used in the context of the present invention belong to the general family of benzotriazole silicones which is described in particular in EP-A-0660701.

A family of benzotriazole silicones that are particularly suitable for carrying out the present invention is that comprising the compounds corresponding to the following formulas (5) or (6): ## STR5 ## in which: R7, which are identical or different, are chosen from C1-C10 alkyl, phenyl, 3,3,3-trifluoropropyl and trimethylsilyloxy radicals, at least 80% by number of the radicals R7 being methyl, -D, the same or different radicals are chosen from radicals R7 and radical G, - r is an integer between 0 and 50 inclusive, and s is an integer between 0 and 20 inclusive, and if s = 0, at least 1 one of the two symbols D denotes G, u is an integer between 1 and 6 inclusive, and t is an integer between 0 and 10 inclusive, provided that t + u is equal to or greater than 3, and the symbol G corresponds to formula (2) above.

As is apparent from formula (2) given above, the attachment of - (X) m- (CH 2) p -CH (Z) -CH 2 - to the benzotriazole unit, which thus ensures the connection of said unit benzotriazole at the silicon atom of the silicone chain may, according to the present invention, be in all the available positions offered by the two aromatic rings of benzotriazole: Preferably, this attachment is at the 3, 4, 5 position. (aromatic ring carrying the hydroxy function) or 4 '(adjacent benzene ring triazole ring), and even more preferably in position 3, 4 or 5. In a preferred embodiment of the invention, the attachment is in position 3.

Likewise, the attachment of the substituent unit (s) Y can take place in all the other positions available within benzotriazole. However, preferably, this attachment is in position 3, 4, 4 ', 5 and / or 6. In a preferred embodiment of the invention, the attachment of the Y pattern is in position 5.

In the formulas (5) and (6) above, the alkyl radicals may be linear or branched and chosen in particular from methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl and tert-butyl radicals. n-amyl, isoamyl, neopentyl, n-hexyl, n-heptyl, n-octyl, 2-ethylhexyl and tert-octyl. The preferred R7 alkyl radicals according to the invention are the methyl, ethyl, propyl, n-butyl, noctyle and 2-ethylhexyl radicals. Even more preferably, the radicals R7 are all methyl radicals.

Among the compounds of formulas (5) or (6) above, it is preferred to use those corresponding to formula (5), that is to say short-chain linear diorganosiloxanes. Among the compounds of formulas (5) above, it is preferred to use those for which the radicals D are both radicals R7

Of the linear diorganosiloxanes falling within the scope of the present invention, more preferred are the random or well-defined block derivatives having at least one, and even more preferably all, of the following characteristics: D is a radical R7 - R7 is alkyl and even more preferably methyl, r is 0 to 15 inclusive; s is between 1 and 10 inclusive, n is non-zero, and preferably 1, and Y is then selected from methyl, tert-butyl or C 1 -C 4 alkoxy, Z is hydrogen or methyl, m = 0, or [m = 1 and X = O] - 1.25 pestgal A family of benzotriazole silicones particularly suitable for the invention is that defined by the following general formula (7): CH 3 CH 3 -SiO 3 ## STR5 ## where E represents the divalent radical: ## STR2 ## In a particularly preferred embodiment of the invention, ## STR2 ## benzotriazole silicone is the compound Drometzole Trisiloxane (CTFA name) corresponding to the following formula: CH3 CH3 CH3 CH3-Si-O-Si-O Si-CH3 CH3 CH3 Processes suitable for the preparation of the products of formula (1), ( 5), (6) and (7) above are described in particular in US Pat. Nos. 3,220,972, 3,697,473, 4,340,709, 4,316,033, 4,328,346 and in US Pat. Patent applications EP-A-0392883 and EP-A-0742003. The benzotriazole-functional silicon derivative may be present in the compositions according to the invention at levels ranging from 0.1 to 10%, preferably from 0 to 1 to 1%, by weight, always with respect to the total weight of the composition. FRAGRANCES Fragrances are compositions containing, in particular, the raw materials described in S. Arctander, Perfume and Flavor Chemicals (Montclair, NJ, 1969), (7) in S. Arctander, Perfume and Flavor Materials of Natural Origin (Elizabeth , NJ, 1960) and in "Flavor and Fragrance Materials - 1991", Allured Publishing Co. Wheaton, III.

It can be natural products (essential oils, absolutes, resinoids, resins, concretes) and / or synthetic (terpene or sesquiterpenic hydrocarbons, alcohols, phenols, aldehydes, ketones, ethers, acids, esters, nitriles, peroxides, saturated or unsaturated, aliphatic or cyclic).

According to the definition given in International Standard ISO 9235 and adopted by the European Pharmacopoeia Commission, an essential oil is a fragrant product generally of complex composition, obtained from a botanically defined plant raw material, either by steam distillation of water, either by dry distillation or by a suitable mechanical process without heating (cold expression). The essential oil is most often separated from the aqueous phase by a physical process that does not entail a significant change in the composition.

Modes of obtaining essential oils The choice of the technique depends mainly on the raw material: its original state and its characteristics, its nature proper. The yield "essential oil / vegetable raw material" can be extremely variable according to the plants: 15 ppm to more than 20%. This choice conditions the characteristics of the essential oil, in particular viscosity, color, solubility, volatility, enrichment or depletion in certain constituents.

Steam Training Steam training corresponds to the vaporization in the presence of water vapor of a substance that is not very miscible with water. The raw material is brought into the presence of boiling water or water vapor in a still. The water vapor causes the essential oil vapor which is condensed in the refrigerant to be recovered in liquid phase in a florentine (or essencier) vase where the essential oil is separated from the water by decantation. The aqueous distillate which remains in steam distillation after the separation of the essential oil is called "aromatic water or" hydrosol "or" floral distilled water ".

Dry distillation

The essential oil is obtained by distillation of wood, bark or roots, without the addition of water or water vapor in a closed chamber designed for the liquid to be recovered in its lower part. Cade oil is the best-known example of this method of production.

Cold expression

This method of production only applies to citrus fruits (Citrus spp.) By mechanical processes at room temperature. The principle of the method is as follows: the zests are dilacerated and the contents of the secretory sacs that have been ruptured are recovered by a physical process. The conventional method consists in exerting under a stream of water an abrasive action on the entire surface of the fruit. After removal of solid waste, the essential oil is separated from the aqueous phase by centrifugation. Most industrial plants actually allow the simultaneous or sequential recovery of fruit juice and essential oil.

Physico-chemical characters.

Essential oils are usually volatile and liquid at room temperature, which differentiates them from so-called fixed oils. They are more or less colored and their density is generally lower than that of water. They have a high refractive index and most deflect polarized light. They are liposoluble and soluble in the usual organic solvents, entrainable with water vapor, very little soluble in water.

Among the essential oils that can be used according to the invention, mention may be made of those obtained from plants belonging to the following botanical families: Abietaceous or Pinaceae: conifers Amaryllidaceae Anacardiaceae Anonaceae: ylang ylang Apiaceae (for example umbelliferae): dill, angelic, coriander, sea fennel, carrot, parsley Araceae Aristolochiaceae Asteraceae: achiliate, mugwort, chamomile, helichryse Betulaceae Brassicaceae Burseraceae: incense Caryophyllaceae Canellaceae Césalpiniaceae: copaïfera (copahu) Chenopodaceae Cistaceae: rockrose Cyperaceae Dipérocarpacées Ericaceae: wintergreen Euphorbiaceae Fabaceae Geraniaceae: geranium Guttifères Hamamélidacées Hernandiacées Hypericaceae: St. John's Wort Iridaceae Juglandaceae Lamiaceae: thyme, oregano, shrimps, savory, basil, marjoram, mint, patchouli, lavender, sage, catnip, rosemary, hyssop, lemon balm, rosemary Lauraceae: ravensara, laurie r, rosewood, cinnamon, bedsea Liliaceae: garlic Magnoliaceae: magnolia 5 Malvaceae Meliaceae Moniiaceae Moraceae: hemp, hops Myricaceae 10 Mysiristicaceae: nutmeg Myrtaceae: eucalyptus, tea tree, niaouli, cajeput, backousia, clove, myrtle Oléacées Piperaceae: pepper Pittosporaceae 15 Poaceae: lemongrass, lemongrass, vetiver Polygonaceae Rucunculaceae Rosaceae: roses Rubiaceae 20 Rutaceae: all citrus Salicaceae Santalaceae: sandalwood Saxifragaceae Schisandraceae 25 Styracaceae: benzoin Thymelaceae: agarwoods Valiaceraceae: Valerian, vine Verbenaceae: lantana, verbena 30 Violaceae Zingiberaceae : galangal, turmeric, cardamom, ginger Zygophyllaceae

There may also be mentioned essential oils extracted from flowers (lily, lavender, rose, jasmine, yilang-ylang, neroli), stems and leaves (patchouli, geranium, petit-grain), fruits (coriander, anise, caraway , juniper), fruit peel (bergamot, lemon, orange), roots (angelica, celery, cardamom, iris, acore, ginger), wood (pine wood, sandalwood, guaiac, rose cedar, camphor), herbs and grasses (tarragon, rosemary, basil, lemongrass, sage, thyme), needles and 40 branches (spruce, fir, pine, pine), resins and balms (galbanum, elemi, benzoin , myrrh, oliban, opopanax).

Examples of perfuming substances are in particular: geraniol, geranyl acetate, farnesol, borneol, bornyl acetate, linalool, linalyl acetate, linalyl propionate, linalyl butyrate, tetrahydrolinalol, citronellol, citronellyl acetate, citronellyl formate, citronellyl propionate, dihydromyrcenol, dihydromyrcenyl acetate, tetrahydromyrcenol, terpineol, terpinyl acetate, nopol, nopyl acetate , nerol, neryl acetate, 2-phenylethanol, 2-phenylethyl acetate, benzyl alcohol, benzyl acetate, benzyl salicylate, styrallyl acetate, benzyl benzoate amyl salicylate, dimethylbenzylcarbinol, trichloromethylphenylcarbinyl acetate, p-tert-butylcyclohexyl acetate, isononyl acetate, vettiveryl acetate, vetiferol, alpha-hexylcinnamaldehyde, 2-methyl-3- (p-tert-butylphenyl) prop Anal, 2-methyl-3- (p-isopropylphenyl) propanal, 3- (p-tert-butylphenyl) propanal, 2,4-dimethylcyclohex-3-enylcarboxaldehyde, tricyclodecenyl acetate, propionate tricyclodecenyl, 4- (4-hydroxy-4-methylpentyl) -3-cyclohexenecarboxaldehyde, 4- (4-methyl-3-pentenyl) -3-cyclohexenecarboxaldehyde, 4-acetoxy-3-pentyl-tetrahydropyran, 3 carboxymethyl-2-pentylcyclopentane, 2-n-4-heptylcyclopentanone, 3-methyl-2-pentyl-2-cyclopentenone, menthone, carvone, tagetone, geranyl acetone, n-decanal, n- dodecanal, 9-decenol-1, phenoxyethyl isobutyrate, phenylacetaldehyde dimethylacetal, phenylacetaldehyde diethylacetal, geranonitrile, citronellonitrile, cyroyl acetate, 3-isocamphylcyclohexanol, cedaryl methyl ether, isolongifolanone, aubepinonitrile, hawthorn, heliotropin, coumarin, eugenol, vanillin, diphenyl ether, citral, citronel lal, hydroxycitronellal, damascone, ionones, methylionones, isomethylionones, solanone, irones, cis-3-hexenol and its esters, musk-indanes, musk-tetralines, musks-isochromanes, macrocyclic ketones, musks-macrolactones, ethylene brassylate and mixtures thereof.

According to a preferred embodiment of the invention, a mixture of different perfuming substances is used which generate in common a pleasant note for the user.

The fragrant substances should preferably be chosen so that they produce notes (head, heart and base) in the following families: hesperides, aromatics, floral notes spicy, woody greedy chypre, ferns leather . The perfume compositions of the invention preferably contain from 2% to 40% by weight of perfuming substance, better still from 2% to 30% by weight, in particular from 2% to 25% by weight relative to the total weight.

The cosmetically acceptable medium according to the present invention preferably contains at least one volatile alcohol and / or a volatile silicone oil and / or a volatile hydrocarbon oil and optionally water. Preferably, the medium of the composition contains water in an amount ranging from 0.01% to 50% and more preferably from 0.5% to 25% by weight relative to the total weight of the composition. For the purposes of the invention, the term "volatile" is intended to mean any molecule capable of evaporating on contact with the skin or the keratin fiber in less than one hour, at ambient temperature and atmospheric pressure. The volatile compound (s) of the invention are liquid at ambient temperature, have a non-zero vapor pressure, at ambient temperature and atmospheric pressure, in particular ranging from 0.13 Pa to 40 000 Pa (10-3 to 300 mm). Hg), in particular ranging from 1.3 Pa to 13 000 Pa (0.01 to 100 mm Hg), and more particularly ranging from 1.3 Pa to 1300 Pa (0.01 to 10 mm Hg).

VOLATILE ALCOHOLS

"Volatile alcohol" means any compound having at least one hydroxyl group and in which more than 95% by weight of the compound is capable of being evaporated in less than one hour at ambient temperature (25 ° C.) and atmospheric pressure ( 760 mmHg) in contact with a keratin material such as skin or hair.

The volatile alcohols according to the present invention are preferably chosen from lower C 1 -C 5 monoalcohols may be chosen from methanol, ethanol, propanol, isopropanol, n-butanol, isobutanol, t-butanol and more particularly ethanol. Their viscosity at 20 ° C., measured with a HAAKE Rheostress 600 apparatus with a 60 mm diameter rotor, an angle of 2 ° at a shear rate of 200 sec -1 is preferably 0.3 to 3 mPa.s. .

The volatile alcohol (s) are preferably present in amounts ranging from 40 to 80% and more preferably in amounts ranging from 55 to 80% by weight relative to the total weight of the composition.

VOLATILE SILICONE OILS

As volatile silicone oils, mention may be made, for example, of volatile linear or cyclic silicone oils, in particular those having a viscosity of 6 centistokes (6.10-6 m 2 / s), and having in particular 2 to 10 silicon atoms, these silicones possibly comprising alkyl or alkoxy groups having from 1 to 22 carbon atoms. As volatile silicone oil that can be used in the invention, there may be mentioned in particular octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane, hexamethylisiloxane, octamethyltrisiloxane and decamethyl tetrasiloxane, dodecamethylpentasiloxane and mixtures thereof.

The volatile silicone oil or oils are present preferably from 10 to 80% relative to the total weight of the composition.

VOLATILE HYDROCARBON OILS

The volatile hydrocarbon oils may be chosen from hydrocarbon-based oils having 8 to 16 carbon atoms, and especially C8-C16 branched alkanes such as C8-C16 isoalkanes of petroleum origin (also known as isoparaffins), such as isododecane ( also called 2,2,4,4,6-pentamethylheptane), isodecane, isohexadecane, the oils sold under the trade names of Isopars or permetyls, branched C8-C16 esters, and isopecanone neopentanoate. hexyl, and mixtures thereof. Other volatile hydrocarbon oils such as petroleum distillates, in particular those sold under the name Shell or by Shell, can also be used. According to one embodiment, the volatile solvent is chosen from volatile hydrocarbon oils having 8 to 16 carbon atoms and mixtures thereof.

According to a particularly preferred embodiment of the invention, a volatile linear alkane will be used as hydrocarbon oil.

VOLATILE LINEAR ALKANES The composition according to the invention contains one or more volatile linear alkane (s). By "one or more volatile linear alkane (s)" is meant indifferently "one or more volatile linear alkane (s) oil (s)".

A volatile linear alkane suitable for the invention is liquid at room temperature (about 25 ° C) and at atmospheric pressure (760 mm Hg).

By "volatile linear alkane" suitable for the invention is meant a linear cosmetic alkane, capable of evaporating on contact with the skin in less than one hour, at ambient temperature (25 ° C.) and at atmospheric pressure (760 mm). Hg, ie 101,325 Pa), liquid at room temperature, having in particular an evaporation rate ranging from 0.01 to 15 mg / cm 2 / min, at ambient temperature (25 ° C.) and pressure. atmospheric (760 mmHg).

Preferably, the "volatile linear alkanes" that are suitable for the invention exhibit an evaporation rate ranging from 0.01 to 3.5 mg / cm 2 / min, at ambient temperature (25 ° C.) and atmospheric pressure (760.degree. mm Hg).

Preferably, the "volatile linear alkanes" that are suitable for the invention have an evaporation rate ranging from 0.01 to 1.5 mg / cm 2 / min, at ambient temperature (25 ° C.) and atmospheric pressure (760.degree. mm Hg).

More preferably, the "volatile linear alkanes" suitable for the invention have an evaporation rate ranging from 0.01 to 0.8 mg / cm 2 / min, at room temperature (25 ° C.) and at atmospheric pressure ( 760 mmHg).

Still more preferably, the "volatile linear alkanes" that are suitable for the invention have an evaporation rate ranging from 0.01 to 0.3 mg / cm 2 / min, at ambient temperature (25 ° C.) and atmospheric pressure (760.degree. mm Hg). More preferably, the "volatile linear alkanes" that are suitable for the invention have an evaporation rate ranging from 0.01 to 0.12 mg / cm 2 / min, at ambient temperature (25 ° C.) and atmospheric pressure (760.degree. mm Hg).

The rate of evaporation of a volatile alkane according to the invention (and more generally of a volatile solvent) can be evaluated in particular by means of the protocol described in WO 06/013413, and more particularly by means of the protocol described herein. -after.

A crystallizer (diameter: 7 cm) placed on a balance in a chamber of about 0.3 m 3 controlled by temperature (25 ° C.) and hygrometry (relative humidity 50%) is introduced into a crystallizer (15 g) of hydrocarbon solvent. volatile.

The liquid is allowed to evaporate freely without stirring, providing ventilation by a fan (PAPST-MOTOREN, reference 8550 N, rotating at 2700 rpm) disposed in a vertical position above the crystallizer containing the solvent. volatile hydrocarbon, the blades being directed to the crystallizer, at a distance of 20 cm from the bottom of the crystallizer.

The mass of volatile hydrocarbon solvent remaining in the crystallizer is measured at regular time intervals.

The evaporation profile of the solvent is then obtained by plotting the curve of the amount of product evaporated (in mg / cm 2) as a function of time (in min). Then the evaporation rate is calculated which corresponds to the tangent at the origin of the curve obtained. The evaporation rates are expressed in mg of volatile solvent evaporated per unit area (cm 2) and per unit of time (minute).

According to a preferred embodiment, the "volatile linear alkanes" that are suitable for the invention have a non-zero vapor pressure (also called saturated vapor pressure) at room temperature, in particular a vapor pressure of 0.3 Pa at 6000 Pa.

In a preferred manner, the "volatile linear alkanes" that are suitable for the invention have a vapor pressure ranging from 0.3 to 2000 Pa at room temperature (25 ° C.). Preferably, the "volatile linear alkanes" that are suitable for the invention have a vapor pressure ranging from 0.3 to 1000 Pa, at ambient temperature (25 ° C.). More preferably, "volatile linear alkanes" that are suitable according to the invention have a vapor pressure ranging from 0.4 to 600 Pa, at room temperature (25 ° C).

In a preferred manner, the "volatile linear alkanes" that are suitable for the invention have a vapor pressure ranging from 1 to 200 Pa at room temperature (25 ° C.).

More preferably, the "volatile linear alkanes" suitable for the invention have a vapor pressure ranging from 3 to 60 Pa, at room temperature (25 ° C).

According to one embodiment, a volatile linear alkane suitable for the invention may have a flash point in the range of from 30 to 120 ° C, and more particularly from 40 to 100 ° C. In particular, the flash point is measured according to ISO 3679.

According to one embodiment, an alkane that is suitable for the invention may be a volatile linear alkane comprising from 7 to 14 carbon atoms.

In a preferred manner, the "volatile linear alkanes" that are suitable for the invention comprise from 8 to 14 carbon atoms. In a preferred manner, the "volatile linear alkanes" that are suitable for the invention comprise from 9 to 14 carbon atoms.

In a preferred manner, the "volatile linear alkanes" that are suitable for the invention comprise from 10 to 14 carbon atoms.

In a preferred manner, the "volatile linear alkanes" that are suitable for the invention comprise from 11 to 14 carbon atoms.

According to an advantageous embodiment, the "volatile linear alkanes" that are suitable for the invention have an evaporation rate, as defined above, ranging from 0.01 to 3.5 mg / cm 2 / min, at room temperature. (25 ° C) and atmospheric pressure (760 mm Hg), and comprise from 8 to 14 carbon atoms. A volatile linear alkane suitable for the invention may advantageously be of plant origin.

Preferably, the volatile linear alkane or the mixture of volatile linear alkanes present in the composition according to the invention comprises at least one carbon isotope 14C (carbon 14), in particular the isotope 14C may be present in a ratio 14C / 12C greater than or equal to 1.10-16, preferably greater than or equal to 1.10-15, more preferably greater than or equal to 7.5.10-14, and better still greater than or equal to 1.5.10-13. Preferably, the ratio 14C / 12C is from 6.10-13 to 1.2.10-12. The amount of 14 C isotopes in the volatile linear alkane or the mixture of volatile linear alkanes can be determined by methods known to those skilled in the art such as the Libby counting method, liquid scintillation spectrometry or still Accelerator Mass Spectrometry.

Such an alkane can be obtained, directly or in several stages, from a vegetable raw material such as an oil, a butter, a wax, etc.

By way of example of alkanes which are suitable for the invention, mention may be made of the alkanes described in the patent applications of Cognis WO 2007/068371, or WO2008 / 155059 (distinct alkane mixtures and differing from at least a carbon). These alkanes are obtained from fatty alcohols, themselves obtained from coconut oil or palm oil.

By way of example of linear alkanes which are suitable for the invention, mention may be made of n-heptane (C7), n-octane (C8), n-nonane (C9) and n-decane (C1o), nundecane (C11), n-dodecane (C12), n-tridecane (C13), n-tetradecane (C14), and mixtures thereof. According to a particular embodiment, the volatile linear alkane is selected from n-nonane, n-undecane, n-dodecane, n-tridecane, ntetradecane, and mixtures thereof.

According to a preferred embodiment, mention may be made of the mixtures of n-undecane (C11) and n-tridecane (C13) obtained in Examples 1 and 2 of Application WO2008 / 155059 from Cognis.

Mention may also be made of n-dodecane (C12) and n-tetradecane (C14) sold by Sasol respectively under the references PARAFOL 12-97 and PARAFOL 14-97, as well as their mixtures. The volatile linear alkane alone can be used.

Alternatively, or alternatively, use may be made of a mixture of at least two distinct volatile linear alkanes, differing from each other by a number of carbon atoms of at least 1, in particular differing from each other by a carbon number of 1 or 2.

According to a first embodiment, a mixture of at least two different volatile linear alkanes having from 10 to 14 carbon atoms and differing from each other by a carbon number of at least 1 is used. mention may in particular be made of mixtures of linear volatile alkanes C10 / C11, C11 / C12 or C12 / C13.

According to another embodiment, a mixture of at least two distinct volatile linear alkanes having from 10 to 14 carbon atoms and differing from each other by a carbon number of at least 2 is used. mention may in particular be made of mixtures of linear volatile alkanes C10 / C12 or C12 / C14 for an even number of carbon and the C11 / C13 mixture for an odd number of carbon n. According to a preferred embodiment, a mixture of at least two volatile linear alkanes having from 10 to 14 distinct carbon atoms and differing from each other by a carbon number of at least 2, and in particular a mixture of carbon atoms, is used. Vol. C18 / C13 volatile linear alkanes or a mixture of C12 / C14 volatile linear alkanes.

Other mixtures comprising more than 2 volatile linear alkanes according to the invention, such as, for example, a mixture of at least 3 volatile linear alkanes having 7 to 14 distinct carbon atoms and differing from each other in a number of carbon atoms. at least 1, are also part of the invention, but the mixtures of 2 linear volatile alkanes according to the invention are preferred (binary mixtures), said 2 volatile linear alkanes preferably representing more than 95% and better still more than 99% by weight of the total content of volatile linear alkanes in the mixture. According to one particular embodiment of the invention, in a mixture of volatile linear alkanes, the volatile linear alkane having the smallest carbon number is predominant in the mixture.

According to another embodiment of the invention, a volatile linear alkane mixture is used in which the volatile linear alkane having the largest carbon number is predominant in the mixture.

By way of examples of mixtures which are suitable for the invention, mention may be made in particular of the following mixtures: from 50 to 90% by weight, preferably from 55 to 80% by weight, and still more preferably from 60 to 75% by weight, C n volatile linear alkane with n ranging from 7 to 14 - from 10 to 50% by weight, preferably from 20 to 45% by weight, preferably from 24 to 40% by weight, of C n volatile linear alkane + X with x greater than or equal to 1, preferably x = 1 or x = 2, with n + x between 10 and 14, relative to the total weight of the alkanes in said mixture. In particular, said mixture of alkanes according to the invention contains: less than 2% by weight, preferably less than 1% by weight of branched hydrocarbons, and / or less than 2% by weight, preferably less 1% by weight of aromatic hydrocarbons, and / or less than 2% by weight, preferably less than 1% by weight and preferably less than 0.1% by weight of unsaturated hydrocarbons in the mixture.

More particularly, a volatile linear alkane suitable for the invention may be used in the form of a n-undecane / n-tridecane mixture.

In particular, a mixture of volatile linear alkanes comprising: from 55 to 80% by weight, preferably from 60 to 75% by weight of volatile linear alkane, C 1 (n-undecane), from 20 to 45, % by weight, preferably 24 to 40% by weight of volatile linear C13 alkane (n-tridecane) relative to the total weight of the alkanes in said mixture.

According to one particular embodiment, the alkane mixture is a n-undecane / n-tridecane mixture. In particular such a mixture can be obtained according to Example 1 or Example 2 of WO 2008/155059.

According to another particular embodiment, the n-dodecane sold under the reference PARAFOL 12-97 is used by SASOL.

According to another particular embodiment, n-tetradecane sold under the reference PARAFOL 14-97 is used by SASOL.

According to yet another embodiment, a mixture of n-dodecane and n-tetradecane is used.

Additives

The composition of the invention may furthermore comprise any additive usually used in the field of perfumes chosen in particular from antioxidants, fatty substances such as oils (vegetable, mineral or synthetic oils such as esters, perfluoroethers), cosmetic or dermatological active agents such as emollients or softeners such as sweet almond oil, apricot kernel oils, moisturizing agents such as glycerine, soothing agents such as a-bisabolol, allantoin, aloes vera; vitamins and their derivatives, essential fatty acids, insect repellents, propellants, peptizers, fillers, co-solvents, UV filters other than those of formula (I), stabilizers or preservatives, 25 dyes, nacres, flakes and mixtures thereof. When they are present in the composition of the invention, these additives may be present in an amount ranging from 0.001 to 10% and better still from 0.01 to 5% by weight relative to the total weight of the composition.

Among the cosolvents that may be used according to the invention, mention may be made of octyldodecanol, tri-ethylcitrate, dicaprylylcarbonate, isononyl isononanoate, isopropyl myristate and palmitate and 2-ethylhexyl palmitate.

Among the additional UV filters, mention may be made of organic filters filtering UVA and / or UVB radiation, for instance dibenzoylmethane derivatives, such as Butyl Methoxydibenzoylmethane, sold in particular under the trade name Parsol 1789 by DSM Nutritional Products, derivatives thereof. of benzophenone such as Benzophenone-2 sold under the trade name "UVINUL D50" by BASF, Benzophenone-3 or Oxybenzone sold under the trade name "UVINUL M40" by BASF or Benzophenone-4 sold under the trade name "UVINUL MS40" By BASF, aminobenzophenone derivatives such as n-hexyl 2- (4-diethylamino-2-hydroxybenzoyl) benzoate sold under the trade name Uvinul 45 A + by BASF, benzylidene camphor derivatives, Terephthalylidene Dicamphor Sulfonic Acid manufactured under the name "MEXORYL SX" by CHIMEX, - salicylic acid derivatives such as Homosalate sold under the name "Eusolex HMS" by Rona / EM Industries and Ethylhexyl Sa licylate sold under the name 50 NEO HELIOPAN OS by SYMRISE. cinnamic acid derivatives, such as ethylhexyl methoxycinnamate sold in particular under the trade name PARSOL MCX by DSM Nutritional Products, the composition of the invention may further comprise soluble dyes in the support of said composition;

As soluble dyes in accordance with the invention, mention may be made of hydrosoluble or hydrophilic dyes such as: caramel, Yellow 5, Acid Blue 9 / Blue 1, Green 5, Green 3 / Fast Green FCF 3, Orange 4, Red 4 / Food Red 1, Yellow 6, Red Acid 33 / Food Red 12, Red 40, Cochineal Carmine (CI 15850, Cl 75470), Ext. Violet 2, Red 6-7, Ferric Ferrocyanide, Ultramarines, Yellow 3 / Yellow 10 Acid, Blue 3 Acid, Yellow 10.

The soluble dye (s) according to the invention are preferably present in amounts ranging from 10-5 to 1% of the total weight of the composition, preferably from 10-4 to 0.1% of the total weight of the composition. total weight of the composition.

Perfume color stabilizers include Tris (tetramethylhydroxypiperidinol) citrate such as product sold under the name "TINOGUARD Q" by CIBA-GEIGY, Sodium Benzotriazolyl Butylphenol Sulfonate as the product sold under the name "TINOGUARD HS" by CIBA-GEIGY; Benzotriazolyl dodecyl p-Cresol as the product sold under the name "TINOGUARD TL" by the company CIBA-GEIGY. as the product sold under the trade name "CIBAFAST H LIQUID" by the company CIBA-GEIGY. Bumetrizole as the product sold under the name "TINOGUARD AS" by the company CIBA-GEIGY.

According to one particular form of the invention, at least one additional anti-oxidant and / or at least one peptizing agent will be used in order to improve the clarity of the composition and / or to reduce or even eliminate the phenomena of cold precipitation which may be caused by certain perfumes and / or improve the stability of the composition on storage.

Among the antioxidants, mention may be made, for example, of BHA (tert-butyl-4-hydroxyanisole), BHT (2,6-di-tert-butyl-p-cresol), tocopherols such as vitamin E and its derivatives such as tocopheryl acetate. They are used at concentrations ranging from 0.01% to 1% relative to the total weight of the composition.

Among the peptizers which can be used according to the invention, use will more particularly be made of hydrogenated castor oil which is oxyethylenated with 60 moles of ethylene oxide: INCI name: PEG-60 HYDROGENATED CASTOR OIL as the products sold under the trade names CREMOPHOR RH60 or CREMOPHOR C040. by BASF. They are used at concentrations ranging from 0.1% to 2 times the concentration of perfume concentrate relative to the total weight of the composition

Of course, those skilled in the art will take care to choose the possible additional additives and / or their quantity in such a way that the advantageous properties of the composition according to the invention are not or not substantially impaired by the addition envisaged.

GALENIC FORMS

The invention applies not only to perfuming products but also to care products, skin treatment, including scalp, and lips, containing an odoriferous substance. The composition according to the invention may thus constitute a composition for perfuming, caring for and treating keratin materials, and in particular be in the form of fresh water, eau de toilette, eau de parfum, lotion afterwards. shaving, care water, silicone or hydrosilicone care oil. It can also be in the form of a scented bi-phasic lotion (eau de toilette phase / hydrocarbon oil phase and / or silicone oil).

The composition according to the invention can be manufactured by known methods, generally used in the field of perfume formulations.

The compositions according to the invention may be packaged in the form of flasks.

The perfuming composition of the invention can be diffused according to different systems such as sprays, aerosols, piezoelectric devices.

They can also be applied in the form of fine particles by means of mechanical or propellant pressurizing devices. The devices according to the invention are well known to those skilled in the art and include pump-bottles or "sprays", aerosol containers comprising a propellant as well as aerosol pumps using compressed air as a propellant. These are described in US Pat. Nos. 4,077,441 and 4,850,517.

The aerosol-conditioned compositions according to the invention generally contain conventional propellants such as, for example, dimethyl ether, isobutane, n-butane and propane.

The perfume compositions are preferably transparent. Their transparency is measured by a turbidity ranging from 1 to 200 NTU and preferably from 10 to 90 NTU turbidity measured at 24 hours to the portable turbidimeter HACH - Model 2100 P.

The compositions according to the invention are, according to a particular form of the invention, lotions and preferably have a viscosity ranging from 10 to 120 UD and more preferably from 30 to 120 UD, still more preferably from 40 to 80 UD; the viscosity being measured at Rheomat TVe-05, at 25 ° C, rotational speed 200 rpm, mobile 1, 10 min. These low viscosities make it possible to condition the compositions of the invention by means of mechanical or propellant pressurizing devices so as to be applied in the form of fine particles (vaporization).

The invention will now be described with reference to the following examples given for illustrative and non-limiting. In these examples, unless otherwise indicated, the amounts are expressed as percentages by weight. The following scented formulations were made; the quantities are indicated in percentages by weight:

Examples The tests were carried out according to the measurement protocol described on EP1897592 A1, but on different colors, in order to prove the protection power of the benzotriazole silicone filter of formula (1): Drometrizole Trisiloxane on two very different types of colors: YELLOW 5 / Cl 19140 EXT. VIOLET 2 / Cl 60730

Principle The principle of these tests consists in exposing the products to be tested to a radiating light source whose spectral distribution is perfectly defined and the emitted energy perfectly quantified. The commonly used light sources are xenon lamps emitting through: - a platinum quartz filter which diverts infrared radiation and eliminates it towards the top of the apparatus - and a glass filter, which absorbs the radiation ultra violet short allows to simulate the radiation received behind an exhibition window.

Equipment 25 A CPS Sun -test device is used: - The illumination provided by a xenon lamp between 300 and 800nm is fixed at 765W / m2 (value set by the manufacturer) - Optical filtration is provided by a quartz filter with IR coating and a special glass pane)

The color of each vial is then observed before and after exposure to light, the naked eye and using a MINOLTA CM3600-d spectrophotometer. The color obtained is quantified. The averaged results are expressed in the system (L *, a *, b *) where L * is the luminance, a * is the red-green axis (-a * = green, + a * = red) and b * represents the yellow-blue axis (-b * = blue, + b * = yellow). Thus, a * and b * express the color of the composition. The color variation of the toilet water after 16 hours of suntest is evaluated by the eye, but also by the spectrophotometer by the AE, which corresponds to the root of the squared squares of the L * a * b * values of the spectrocolorimeter. . The higher the value of the AE, then the color degradation is important.

The following formulations are prepared and tested: Ingredients Ex 1 Ex 2 Ex 3 Ex 4 (Excluding (excluding (invention) invention) Invention Flanker OTB perfume 10.00 10.00 10.00 10.00 XXXX dye Octocrylene (Uvinul N539) - 0,20 0,20 - Butylmethoxydibenzoylmethane - 0,20 - - (Parsol 1789) Drometrizole Trisiloxane - - 0,20 0,40 (Mexoryl XL) Ethanol 75.00 75.00 75.00 75.00 Water qs 100 qs qs 100 qs qs qs 100 The dyes are used in the following X amounts:

YELLOW 5 / CI 19140 5.25 ppm EXT. PURPLE 2 / Cl 60730 1.75 ppm

The results obtained are as follows: Colorant Ex 1 Ex 2 Ex 3 EX 4 (outside (outside (outside (invention) invention) invention)) Yellow dye AE = 16.6 AE = 10.2 AE = 12.4 AE = 9, 4 (discolored) (Yellow) (discolored) (Yellow) Violet dye AE = 5.2 AE = 2.3 AE = 1.8 AE = 0.5 (discolored) (discolored) (discolored) (Purple) the composition according to the invention comprising the benzotriazole silicone filter of formula (I) (ie Drometrizole Trisiloxane) without the compound R, R 'diphenylacrylate alkyl or alkyl-α-cyano-R'-diphenylacrylate (ie octocrylene) has a color more stable in time than 15 - composition 1 without filter - composition 2 associating octocrylene with another UVA filter - composition 3 associating octocrylene with silicone benzotriazole of formula (I): Drometrizone Trisiloxane

It is deduced that the presence of octocrylene tends to inhibit the photoprotective effect on the color of the benzotriazole silicone of formula (I) on the color of the perfume.

Claims (12)

REVENDICATIONS1. A colored perfuming composition comprising, in a cosmetically acceptable medium: a) at least 2% by weight of a perfuming substance relative to the total weight of the composition; b) at least one silicon derivative of benzotriazole of formula (1) O (3-a) / 2 Si (R) a-G (1) in which: R represents an optionally halogenated C1-C10 alkyl radical or a radical; phenyl or a trimethylsilyloxy radical, - a is an integer chosen from 0 to 3 inclusive, and the symbol G denotes a monovalent radical directly attached to a silicon atom, and which corresponds to the following formula (2): (Y) n (X) m- (CH 2) p CH -CH 2 Z (2) in which: Y, which may be identical or different, are chosen from C 1 -C 4 alkyl radicals, halogens and C 1 -C 4 alkoxy radicals, it being understood that in the latter case, two adjacent Y's of the same aromatic ring may together form an alkylidene dioxy group in which the alkylidene group contains from 1 to 2 carbon atoms, - X represents O or NH, - Z represents hydrogen or a C1-C4 alkyl radical, n is an integer between 0 and 3 inclusive, 30 - m is 0 or 1, - p represents an integer between 1 and 10, inclusive. c) at least one dye soluble in said medium; said composition not containing alkyl 13,13'-diphenylacrylate compound or alkyl α-cyano-R, R'-diphenylacrylate compound. 35 5 2. Composition according to claim 1, wherein the silicon derivative of benzotriazole of formula (I) is chosen from the compounds corresponding to the following formulas (5) or (6): R7 s R7 (5) r or 10 _ R7 G tu (6) in which: R7, which are identical or different, are chosen from C1-C10 alkyl, phenyl, 3,3,3-trifluoropropyl and trimethylsilyloxy radicals, at least 80% by number of the radicals R7 being methyl, D, which are identical or different, are chosen from the radicals R7 and the radical G; - r is an integer between 0 and 50 inclusive, and s is an integer between 0 and 20 inclusive, and if s = 0, at minus one of the two symbols D denotes G, - u is an integer between 1 and 6 inclusive, and t is an integer from 0 to 10 inclusive, with the proviso that t + u is equal to or greater than 3 and the symbol G corresponds to formula (2) above. 3. The composition according to claim 2, wherein the benzotriazole silicon derivative of formula (I) is selected from compounds of formula (5). 4. Composition according to claim 3, wherein the silicon derivative of benzotriazole of formula (I) is chosen from the compounds corresponding to formula (5) for which the radicals D are both radicals R7. 30 5. Composition according to any one of claims 2 to 4, wherein the silicon derivative of benzotriazole of formula (5) having at least one, and even more preferably all, of the following characteristics: D is an R7 radical R 7 is alkyl and even more preferentially is methyl; r is between 0 and 15 inclusive; s is between 1 and 10 inclusive, - n is non-zero, and preferably equal to 1, and Y is then chosen from methyl, tert-butyl or C 1 -C 4 alkoxy, - Z is hydrogen or methyl, - m = 0, or [m = 1 and X = O] - pestal to 1. 6. Composition according to any one of claims 1 to 5, wherein the compound of formula (I) is chosen from the compounds corresponding to the following formula (7): CH 3 CH 3 Si -O CH 3 CH 3 Si-O CH 3 CH 3 Si ## STR2 ## where E represents the divalent radical: ## STR2 ## The composition according to claim 3, wherein the compound of formula (7) is the compound Drometzole Trisiloxane having the following formula: CH3 CH3 CH3 CH3-Si-O-Si-O Si-CH3 CH3 (7) CH3 8. Composition according to any one of claims 1 to 7, further comprising at least one additive chosen from antioxidants, fatty substances such as oils (vegetable, mineral or synthetic oils such as esters, perfluoroethers), cosmetic active ingredients or dermatological agents such as emollients or softeners such as sweet almond oil, apricot kernel oil, moisturizing agents such as glycerine, soothing agents such as a-bisabolol, allantoin, aloes vera; vitamins and their derivatives, essential fatty acids, insect repellents, propellants, peptizers, fillers, co-solvents, UV filters other than those of formula (1), stabilizers or preservatives, dyes, nacres, glitter and mixtures thereof. 9. Composition according to any one of claims 1 to 8, in the form of fresh water, eau de toilette, eau de parfum, aftershave, care water, oil silicone or hydrosilicone skincare; scented biphasic lotion. 10. Composition according to any one of claims 1 to 9, packaged in the form of a bottle; packaged in a pressurized form in a spray, an aerosol, a piezoelectric device. 11. A process for perfuming human keratin materials or a garment, comprising applying to said keratin materials or said garment the composition as defined in claims 1 to 10. 12. Use of at least one silicon derivative of benzotriazole of formula (1), as stabilizing agent for the organoleptic properties of a colored perfuming cosmetic composition with respect to external aggression, in particular of light or temperature differences. particularly the color and / or odor of said composition; said composition does not contain alkyl compound 3 ', 3'-diphenylacrylate or alkyl α-cyano-3α-diphenylacrylate compound. 35