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FR2814737B1 - Compose anhydre a base d'un halogenure de terre rare ou de gallium, son procede de preparation et son utilisation comme catalyseur - Google Patents

Compose anhydre a base d'un halogenure de terre rare ou de gallium, son procede de preparation et son utilisation comme catalyseur

Info

Publication number
FR2814737B1
FR2814737B1 FR0012582A FR0012582A FR2814737B1 FR 2814737 B1 FR2814737 B1 FR 2814737B1 FR 0012582 A FR0012582 A FR 0012582A FR 0012582 A FR0012582 A FR 0012582A FR 2814737 B1 FR2814737 B1 FR 2814737B1
Authority
FR
France
Prior art keywords
catalyst
preparation
rare earth
compound based
anhydrous compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0012582A
Other languages
English (en)
Other versions
FR2814737A1 (fr
Inventor
Thomas Mathivet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Terres Rares SA
Original Assignee
Rhodia Terres Rares SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0012582A priority Critical patent/FR2814737B1/fr
Application filed by Rhodia Terres Rares SA filed Critical Rhodia Terres Rares SA
Priority to JP2002532166A priority patent/JP2004510725A/ja
Priority to PCT/FR2001/003017 priority patent/WO2002028776A1/fr
Priority to EP01972229A priority patent/EP1373142A1/fr
Priority to CA002424925A priority patent/CA2424925A1/fr
Priority to US10/398,044 priority patent/US20040048735A1/en
Priority to CNB018179959A priority patent/CN100447088C/zh
Priority to AU2001292010A priority patent/AU2001292010A1/en
Priority to KR1020037004763A priority patent/KR100550178B1/ko
Publication of FR2814737A1 publication Critical patent/FR2814737A1/fr
Application granted granted Critical
Publication of FR2814737B1 publication Critical patent/FR2814737B1/fr
Priority to US11/818,642 priority patent/US20070259772A1/en
Priority to JP2008127400A priority patent/JP2008297302A/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/128—Mixtures of organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F17/00—Compounds of rare earth metals
    • C01F17/20—Compounds containing only rare earth metals as the metal element
    • C01F17/253—Halides
    • C01F17/271—Chlorides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/003—Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/37—Lanthanum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/38—Lanthanides other than lanthanum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
FR0012582A 2000-10-03 2000-10-03 Compose anhydre a base d'un halogenure de terre rare ou de gallium, son procede de preparation et son utilisation comme catalyseur Expired - Fee Related FR2814737B1 (fr)

Priority Applications (11)

Application Number Priority Date Filing Date Title
FR0012582A FR2814737B1 (fr) 2000-10-03 2000-10-03 Compose anhydre a base d'un halogenure de terre rare ou de gallium, son procede de preparation et son utilisation comme catalyseur
KR1020037004763A KR100550178B1 (ko) 2000-10-03 2001-09-28 희토류 또는 갈륨 부가 조성물, 그의 제조 방법 및 그의 촉매로서의 용도
EP01972229A EP1373142A1 (fr) 2000-10-03 2001-09-28 Composes d'addition de terre rare ou de gallium, procedes pour leur preparation et leur utilisation comme catalyseur
CA002424925A CA2424925A1 (fr) 2000-10-03 2001-09-28 Composes d'addition de terre rare ou de gallium, procedes pour leur preparation et leur utilisation comme catalyseur
US10/398,044 US20040048735A1 (en) 2000-10-03 2001-09-28 Rare earth or gallium additive composition, methods for preparing the same and use thereof as catalyst
CNB018179959A CN100447088C (zh) 2000-10-03 2001-09-28 稀土或镓的加成组合物、其制备方法和作为催化剂的用途
JP2002532166A JP2004510725A (ja) 2000-10-03 2001-09-28 カルボン酸とハロゲン化又はハロゲノカルボン酸希土類元素又はガリウムとの付加化合物、ハロゲン化希土類元素又はガリウムと窒素又は酸素供与体との無水付加化合物、それらの製造方法及び触媒としての使用
PCT/FR2001/003017 WO2002028776A1 (fr) 2000-10-03 2001-09-28 Composes d'addition de terre rare ou de gallium, procedes pour leur preparation et leur utilisation comme catalyseur
AU2001292010A AU2001292010A1 (en) 2000-10-03 2001-09-28 Rare earth or gallium additive composition, methods for preparing same and use thereof as catalyst
US11/818,642 US20070259772A1 (en) 2000-10-03 2007-06-15 Addition compound of a carboxylic acid and a rare earth or gallium halide or halogenocarboxylate, an anhydrous addition compound of a rare earth or gallium halide and a nitrogen or oxygen donor, preparation processes, and use as a catalyst
JP2008127400A JP2008297302A (ja) 2000-10-03 2008-05-14 カルボン酸とハロゲン化又はハロゲノカルボン酸希土類元素又はガリウムとの付加化合物、ハロゲン化希土類元素又はガリウムと窒素又は酸素供与体との無水付加化合物、それらの製造方法及び触媒としての使用

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0012582A FR2814737B1 (fr) 2000-10-03 2000-10-03 Compose anhydre a base d'un halogenure de terre rare ou de gallium, son procede de preparation et son utilisation comme catalyseur

Publications (2)

Publication Number Publication Date
FR2814737A1 FR2814737A1 (fr) 2002-04-05
FR2814737B1 true FR2814737B1 (fr) 2003-08-29

Family

ID=8854924

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0012582A Expired - Fee Related FR2814737B1 (fr) 2000-10-03 2000-10-03 Compose anhydre a base d'un halogenure de terre rare ou de gallium, son procede de preparation et son utilisation comme catalyseur

Country Status (2)

Country Link
US (1) US20040048735A1 (fr)
FR (1) FR2814737B1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10724120B2 (en) * 2017-08-31 2020-07-28 National Technology & Engineering Solutions Of Sandia, Llc Rapid synthesis of gallium alloys

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2830080A1 (de) * 1978-07-08 1980-01-17 Bayer Ag Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien
GB2061918B (en) * 1979-08-31 1984-05-31 Asahi Dow Ltd Organic rare-earth salt phosphors
CA1223396A (fr) * 1981-06-29 1987-06-23 Tooru Shibata Preparation de polymere dienique conjugue
US4599201A (en) * 1982-04-12 1986-07-08 Rhone-Poulenc, Inc. Process for preparing ceric carboxylates
US4507245A (en) * 1982-06-06 1985-03-26 Hokko Chemical Industry Co., Ltd. Process for the production of a rare earth metal alkoxide
GB8830007D0 (en) * 1988-12-22 1989-02-15 Enichem Elastomers Polymerization of butadiene
US5286694A (en) * 1991-12-11 1994-02-15 Phillips Petroleum Company Lanthanide halide catalyst, method of producing the catalyst, and polymerization process employing the catalyst
DE69310007T2 (de) * 1992-02-28 1997-12-18 Sentrachem Ltd Herstellung eines organischen Salzes des seltenen Erdmetalls
US5362459A (en) * 1993-05-17 1994-11-08 Pure-Etch Co. Neodymium recovery process
GB9319945D0 (en) * 1993-09-28 1993-11-17 Solvay Interox Ltd Oxidation of alkylaromatic compounds
DE4334045A1 (de) * 1993-10-06 1995-04-13 Bayer Ag Katalysator, dessen Herstellung und Verwendung zur Gasphasenpolymerisation von konjugierten Dienen
DE19512127A1 (de) * 1995-04-04 1996-10-10 Bayer Ag Neuer Katalysator für die Gasphasenpolymerisation von konjugierten Dienen
US5783676C1 (en) * 1996-03-29 2002-03-12 Rhodia Rare Earths Inc Synthesis of solid powdery rare earth carboxylates by a precipitation method
US6054563A (en) * 1997-03-05 2000-04-25 Rhodia Chimie Preparation of solid, powdery rare earth carboxylates by evaporation method
IT1296572B1 (it) * 1997-11-27 1999-07-14 Enichem Spa Complessi catalitici a base di lantanidi per la (co)polimerizzazione di dieni coniugati
US6111082A (en) * 1998-04-17 2000-08-29 Rhodia Rare Earths Inc. Stable concentrated rare earth carboxylate liquids
US6090926A (en) * 1998-06-05 2000-07-18 Rhodia Rare Earths Inc. Powdery, solid rare earth carboxylates with improved solubility in aliphatic solvents which are highly active catalysts in Ziegler-Natta systems
KR100290437B1 (ko) * 1998-10-07 2001-09-22 박찬구 연속식 1,3-부타디엔 중합에 적합한 니오디뮴할로겐 착화합물의제조방법
FR2799394A1 (fr) * 1999-10-11 2001-04-13 Michelin Soc Tech Catalyseur solide supporte utilisable pour la polymerisation de dienes conjugues, son procede de preparation et procede de polymerisation de dienes conjugues utilisant ce catalyseur
KR100352764B1 (ko) * 2000-03-16 2002-09-16 금호석유화학 주식회사 신규한 단분자 니오디뮴 카르복실레이트 화합물 및 이를포함하는 디엔 중합용 촉매

Also Published As

Publication number Publication date
FR2814737A1 (fr) 2002-04-05
US20040048735A1 (en) 2004-03-11

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Effective date: 20100630