FR2891743A1 - METHOD OF MAKE-UP OF SKIN AND LASHES - Google Patents

Abstract

The present invention relates to a cosmetic process for making up the skin or the eyelashes, comprising applying to the skin or the eyelashes, via at least one composition, an electrophilic monomer and a plasticizing oil contained in a fatty phase. liquid, said plasticizing oil being selected from oils having a molar mass of less than 800 g / mol, and having particular Hansen solubility parameters. The invention also relates to a kit and a makeup composition for the skin or eyelashes comprising said electrophilic monomer and said plasticizing oil. This process makes it possible to obtain a make-up of the skin or of the eyelashes having good resistance and / or resistance to transfer and / or crumbling and / or rubbing

Description

The subject of the present invention is a process for making up the skin or

  eyelashes comprising applying to the skin or the eyelashes a composition comprising a particular electrophilic monomer. Cosmetic compositions, especially for making up the skin, such as foundations, body make-up products, concealer, eye shadow or powder, or eye makeup, in particular mascaras or eyeliners, generally comprise fatty substances such as oils and / or waxes, and a particulate phase generally composed of fillers and pigments. They may thus be in the form of an anhydrous gel, in the form of a stick or stick or in the form of a soft paste, in the form of a liquid, such as, for example, mascaras, certain foundations or eyeshadows. In the case of make-up of the skin, they may also be in the form of a powder, which may be free, compacted or pressed. The makeup compositions can also comprise water or a hydrophilic phase, and can then be in particular in the form of oil-in-water emulsion, wax-in-water, water-in-oil, water-in-wax, multiple emulsion , especially when it comes to a foundation, tinted cream, care cream or a solar product. These compositions, when applied to the skin or eyelashes, do not always have good performance. It has indeed been found that some compositions have a tendency to spread, within the fine lines and / or wrinkles of the skin, in the case of foundation, or in the folds of the eyelid, in the case of makeup eyelids. Similarly, over time, it happens that the original color turns. On the other hand, certain make-up products may have the disadvantage of transferring: the makeup applied to the skin may be deposited, at least in part, on certain supports with which it is brought into contact, such as, for example, a garment or skin. Mascaras or eyeliners are deposited on the eyelashes in the form of a more or less continuous film. When this film does not have good resistance to mechanical friction and secretions such as tears, sweat, sebum, it results in the formation of grains related to the partial erosion of the film, or the appearance of rings under eyes related to the degradation of the film in contact with sebum or sweat. All these phenomena generate an unsightly effect that we want to avoid.

  To improve the holding of these different makeups on keratin supports, it is known to use film-forming polymers. However, the presence of such polymers in the compositions, in particular foundation, mascaras or eyeliners, has the disadvantage of altering the application properties of the product which presents a brake on the application, and spreads less easily. This results in a makeup result that is not homogeneous and uncomfortable for the user. There is therefore still a need for products, in particular for making up the skin or the eyelashes, exhibiting improved resistance while having good properties of spreading on application and comfort over time.

  To improve the hold properties of the make-up, the document EP 1 303 246 proposes the application of two cosmetic compositions on the surface to be made up, the first composition comprising a pro-adhesive material and the second composition comprising a diffusing compound, for example an oil. Similarly, the document EP 1 518 354 proposes cosmetic products 20 also associating two compositions, one of the compositions containing an ethylenic block polymer. The present invention aims to provide an alternative method of makeup of the skin and eyelashes to obtain a makeup with the holding properties, spreading and comfort described above. In particular, the subject of the present invention is, according to a first aspect, a cosmetic process for making up the skin or the eyelashes, comprising applying to the skin or the eyelashes, via at least one composition, at least one an electrophilic monomer and at least one plasticizing oil contained in a liquid fatty phase, said plasticizing oil being chosen from oils having a molecular weight of less than 800 g / mol, and having Hansen solubility parameters such that the dispersive component dd is of 12 (J / cm3) 112 to 18 (J / cm) v2, and the da component is less than 7.5 (J / cm3) 1'2. According to a second aspect, the subject of the invention is a makeup composition for the skin and the eyelashes comprising at least: an electrophilic monomer and at least one plasticizing oil contained in a liquid fatty phase, said plasticizing oil being chosen from oils having a molar mass of less than 800 g / mol, and having Hansen solubility parameters such that the dispersive component dd ranges from 12 (J / cm 3) 112 to 18 (J / cm 3) 112, and the da component is less than 7.5 (J / cmr, said plasticizing oil being present in the composition in a content ranging from 0.1 to 50% by weight, relative to the total weight of the composition, preferably ranging from 0.5 to 30% by weight. % by weight, and more preferably from 1 to 20% by weight According to a third aspect, the invention relates to a make-up kit, in particular to the skin or the eyelashes, comprising at least two compositions, i) a first composition comprising at least one electropormer hile, ii) a second composition comprising a physiologically acceptable medium, at least one of said first and second compositions comprising at least one plasticizing oil contained in a liquid fatty phase, said plasticizing oil being selected from oils having a lower molecular weight at 800 g / mol, and having Hansen solubility parameters such that the dispersive component dd ranges from 12 (J / cm3) 112 to 18 (J / cm3) 112, and the da component is less than 7.5 (J). / cc) 1I2. According to a fourth aspect, the subject of the invention is the use of a kit or a composition as described above, for obtaining a make-up of the skin or of the lashes having good resistance and / or resistance to transfer and / or crumbling and / or rubbing. By physiologically acceptable medium is meant a medium compatible with keratin materials, especially the skin and the lips, and in particular a cosmetic medium.

Electrophilic Monomer

  One of the compositions according to the invention comprises at least one electrophilic monomer. By electrophilic monomer is meant a monomer capable of polymerizing by anionic polymerization in the presence of a nucleophilic agent. By anionic polymerization is meant the mechanism defined in the "Advanced 15 Organic Chemistry", Third Edition by Jerry March, pages 151 to 161. In the context of anionic polymerization, the nucleophilic agent (such as, for example, the OH-hydroxyl ions contained in the water) triggers the polymerization of the electrophilic monomer by the formation of a carbanion.

  "Carbanion" is understood to mean the chemical species defined in "Advanced Organic Chemistry, Third Edition", by Jerry March, page 141. According to a particular embodiment, the electrophilic monomer corresponds to formula (A): R 1 R 3> - (R2 R4 (A) wherein: • R1 and R2 denote, independently of one another, a little or no electro-attracting group (little or no inductive-attractor) such that: - an atom of hydrogen, a saturated or unsaturated hydrocarbon group, linear, branched or cyclic, preferably having 1 to 20, more preferably 1 to 10 carbon atoms, and optionally containing one or more nitrogen atoms, oxygen , of sulfur, and optionally substituted with one or more groups chosen from -OR, -COOR, -COR, -SH, -SR, -OH, and the halogen atoms, a polyorganosiloxane residue modified or not, a grouping polyoxyalkylene, R3 and R4 each independently of one another is an electron group attractor (or inductive-attractor) preferably chosen from the groups -N (R) 3+, -S (R) 2+, -SH 2+, -NH 3 +, -NO 2, -SO 2 R, -CN, -COOH, -COOR, -COSR, -CONH2, CONHR, -F, -Cl, -Br, -I, OR, -COR, -SH, -SR, -OH, the linear or branched alkenyl groups, the linear or branched alkynyl groups, the groups C 1 -C 4 mono- or polyfluoroalkyl, aryl groups such as phenyl, or aryloxy groups such as phenoxyloxy, R denotes a saturated or unsaturated hydrocarbon group, linear, branched or cyclic, preferably comprising from 1 to 20, more preferably from 1 to 10 carbon atoms, and optionally containing one or more nitrogen, oxygen, sulfur atoms, and optionally substituted with one or more groups selected from OROR ', - COOR', -COR ', -SH, - SR ', -OH, the halogen atoms, or a polymer residue obtainable by radical polymerization, polycondensation or ring opening, R' denoting an alkyl group, CI-Clo. By electro-attractor or inductive-attractor group (-I) is meant any group more electronegative than carbon. Reference can be made to PR Wells Prog. Phys. Org. Chem., Vol 6.11 (1968).

  By grouping little or no electro-attractor means any group whose electronegativity is less than or equal to that of carbon. The alkenyl or alkynyl groups preferably have 2 to 20 carbon atoms, more preferably 2 to 10 carbon atoms. As saturated or unsaturated hydrocarbon group, linear, branched or cyclic, preferably containing 1 to 20 carbon atoms, there may be mentioned linear or branched alkyl, alkenyl or alkynyl groups, such as methyl, ethyl, n-butyl, tert-butyl, iso-butyl, pentyl, hexyl, octyl, butenyl or butynyl; cycloalkyl or aromatic groups. As the substituted hydrocarbon group, there may be mentioned, for example, hydroxyalkyl or polyhaloalkyl groups.

  As examples of unmodified polyorganosiloxane, there may be mentioned polyalkylsiloxanes such as polydimethylsiloxanes, polyarylsiloxanes such as polyphenylsiloxanes, polyarylalkylsiloxanes such as polymethylphenylsiloxanes. Among the modified polyorganosiloxanes, there may be mentioned polydimethylsiloxanes containing polyoxyalkylene and / or siloxy and / or silanol and / or amine and / or imine and / or fluoroalkyl groups. Among the polyoxyalkylene groups, there may be mentioned polyoxyethylene groups and polyoxypropylene groups preferably having 1 to 200 oxyalkylene units. Among the mono- or polyfluoroalkyl groups, there may be mentioned groups such as - (CH2) n- (CF2) m-CF3 or - (CH2) n- (CF2) m-CHF2 with n = 1 to 20 and m = 1 to 20. The substituents R 1 to R 4 may optionally be substituted by a group having a cosmetic activity. The cosmetic activities which are particularly used are obtained from groups with dyeing functions, antioxidants, UV filters and conditioning agents. Examples of dye-functional groups that may be mentioned include azo, quinone, methine, cyanomethine and triarylmethane groups. By way of examples of an antioxidant-functional group, mention may especially be made of butylhydroxyanisole (BHA), butylhydroxytoluene (BHT) or vitamin E type groups. Examples of groups having a UV-screening function are, for example, benzophenone, cinnamate, benzoate, benzylidene camphor and dibenzoylmethane moieties.

  As examples of a group with a conditioning function, mention may be made in particular of cationic and fatty ester groups. Among the electrophilic monomers corresponding to formula (A), there may be mentioned for example:

  benzylidene malononitrile derivatives of the formula ## STR2 ## 2- (4-chloro-benzylidene) -malononitrile of the formula Cl - ethyl 2-cyano-3-phenyl acrylate, CN Ph ~ / CN described in Sayyah, J. Polymer Research, 2000, p 97, methylidenemalonate derivatives such as: Diethyl 2-methylene malonate described in the following references by Hopff, Makromoleculare Chemie, 1961, p95, De Keyser, J. Pharm. Sci, 1991, p67 and Klemarczyk, Polymer, 1998, p173 CO2Et CO2Et-, ethyl 2-cyano-3- (4-chloro-phenyl) acrylate, CN 2 -CH 2 Cl 5, and 2-ethoxycarbonylmethyleneoxycarbonyl acrylate. ethyl described in the following references by Breton, Biomaterials, 1998, p271 and Couvreur, Pharmaceutical Research, 1994, p1270. The itaconate derivatives such as dimethyl isaconate described in the following reference by Bachrach, European Polymer Journal, 1976, p563 CO2Me CO2Me; methyl α- (methylsulfonyl) acrylate derivatives (K); Ethyl (L) methyl (methylsulfonyl) acrylates, methyl (M) t- butyl (tert-butylsulfonyl) acrylates, tert-butyl (N) α- (tert-butylsulfonyl) acrylates, α- (methylsulfonyl) acrylates, butyl (0) by Gipstein, J.Org.Chem, 1980, p1486 and 1,1-bis (methylsulfonyl) ethylene (P), 1-acetyl-1-methylsulphonyl ethylene (Q) 20, a- Methyl (R), methylsulfonylacrylonitrile (S) methylsulfonyl (S) by Shearer, US patent US2748050: SO2Me SO2Me SO2Me SO2Me CO2Me 'CO2Et (K) (L) SO2Me SO2Me SO2t-Bu CO2Me (M) SO2Me SO3Me SO2Me SO2t-Bu CO2t-Bu CO2tBu (N) (0) CN S02Me The electrophilic monomer (s) present in the composition of the invention can be chosen (s) Among: - Methyl vinyl sulfone and phenyl vinyl sulfo especially described by Boor, J. Polymer Science, 1971, p249 SO2Me SO2Ph - phenyl vinyl sulfoxide, especially described by Kanga, Polymer preprints (ACS, Divison of Polymer Chemistry), 1987, p322 15 - 3-methyl-N - (phenylsulfonyl) -1-aza-1,3-butadiene, especially described by Bonner, Polymer Bulletin, 1992, p517 NSO2Ph - acrylamide monomers such as: n-propyl-n- (3-triisopropoxysilylpropyl) acrylamide and n-propyl-n- (3-triethoxysilylpropyl) acrylamide, in particular described by Kobayashi, Journal of Polymer Science, Part A: Polymer Chemistry, 2005, p2754. Pr OiPr

  ~ NSi 1OiPr OiPr o Pr ~ And ~ N1 ~ OEt o 25 - acrylate monomers such as: 2-hydroxyethyl acrylate and 2-hydroxyethyl methacrylate, n-butyl acrylate, acrylate tert-butyl 30 - the itaconimide monomers selected from: n-butyl itaconimide (F), n- (4-tolyl) itaconimide (G), n- (2-ethylphenyl) itaconimide (H), N- (2, 6-diethylphenyl) itaconimide (I) especially described in the following reference by Wanatabe, J.Polymer Science: Part A: Polymer chemistry, 1994, p2073 R = Bu (F), 4-ethyphenyl (H), 2,6-diethylkphenyl (I) According to a preferred embodiment, the electrophilic monomer is a monomer of the cyanoacrylate family and their derivatives of formula (B): ## STR2 ## where X denotes NH, S or O, R1 and R2 having the same meanings as above, preferably R1 and R2 representing a hydrogen atom, R'3 representing a hydrogen atom or R as defined in formula (A). Preferably, X denotes O. The compounds of formula (B) that may be mentioned include the monomers: a) belonging to the family of C 1 -C 20 polyfluoroalkyl 2-cyanoacrylates, such as: ester 2.2, 3,3-tetrafluoropropyl of 2-cyano-2-propenoic acid of formula: C = N CH 2 = C 30 COO-CH 2 -CF 2 -CH 2 or the 2,2,2-trifluoroethyl ester of acid 2 -cyano-2-propenoic acid of formula: b) C 1 -C 10 alkyl or C 1 -C 10 alkoxy-C 1 -C 10 alkoxy acrylates.

  Mention may be made more particularly of ethyl 2-cyanoacrylate, methyl 2-cyanoacrylate, n-propyl 2-cyanoacrylate, isopropyl 2-cyanoacrylate, tert-butyl 2-cyanoacrylate and 2-cyanoacrylate. of n-butyl, isobutyl 2-cyanoacrylate, 3-methoxybutyl cyanoacrylate, n-decyl cyanoacrylate, hexyl 2-cyanoacrylate, 2-ethoxyethyl 2-cyanoacrylate, 2-cyanoacrylate of 2 methoxyethyl, 2-octyl 2-cyanoacrylate, 2-propoxyethyl 2-cyanoacrylate, n-octyl 2-cyanoacrylate and iso-amyl cyanoacrylate, and (c) benzylidene malononitrile derivatives of the formula

  Ph 2 CN 2- (4-chloro-benzylidene) -malononitrile of the formula and mixtures thereof. In the context of the invention, it is preferred to use the monomers b).

  According to a preferred embodiment, the cyanoacrylate monomer or monomers are chosen from C 6 -C 10 alkyl cyanoacrylates. Particularly preferred monomers are octyl cyanoacrylates of formula F and their mixtures: C = N 1 CH 2 = C COO-R '3 in which: R' 3 is selected from = - (CH 2) 7 -CH 3, - CH (CH3) - (CH2) 5-CH3, -CH2-CH (C2H5) - (CH2) 3-CH3, - (CH2) 5-CH (CH3) -CH3, - (CH2) 4-CH (C2H5) The most preferred cyanoacrylate monomer according to the invention is octyl 2-cyanoacrylate, linear or branched, sold under the commercial reference RITELOK CDN 1064 by the company Chemence. The monomers used in accordance with the invention may be covalently attached to supports such as polymers, oligomers or dendrimers. The polymer or oligomer may be linear, branched, comb or block. The distribution of the monomers of the invention on the polymeric, oligomeric or dendritic structure may be statistical, in the terminal position or in block form. The cyanoacrylate monomers of formula (B) according to the present invention can be synthesized according to the known methods described in the art. In particular, the cyanoacrylate monomers can be synthesized according to the teachings of US Pat. Nos. 3,527,224, 3,515,767, 3,667,472, 3,995,641, 4,035,334 and 4, 650, 826. (F) electrophilic monomer, and in particular the cyanoacrylate monomer of formula (B), in particular octyl 2-cyanoacrylate may be present in a content ranging from 0.1% to 99% by weight, relative to the total weight of the composition comprising it, preferably ranging from 1 to 90% by weight, preferably from 1 to 70% by weight, preferably from 1 to 60% by weight, preferably from 1 to 50% by weight, preferably from 1 to 40% by weight, and more preferably from 1 to 30% by weight. Nucleophilic Agents The nucleophilic agents capable of triggering the anionic polymerization are systems known in themselves, capable of generating a carbanion in contact with an electrophilic monomer. The nucleophilic agents may in particular be constituted by the hydroxyl ions contained in the water.

  The nucleophilic agent can be a molecular compound, an oligomer, a dendrimer or a polymer having nucleophilic functions. In a nonlimiting manner, the following functions may be mentioned as nucleophilic functions: ## STR2 ## ## STR2 ## in which R 2, R 3, C, PhNH, pyridine, R 1, R 2, R 2, R 3, R 3, R 3, R 3, R 3 RCOO-, SCN-, ROH, RSH, NCO-, CN NO3-, C104, H2O, Ph being phenyl; Ar represents an aryl group and R represents a C1-C10 alkyl group.

  Particularly preferred nucleophilic agents are hydroxyl ions, especially those present in water.

  The water containing the nucleophilic hydroxyl ions may, in particular, be the residual water of the skin and / or the eyelashes, or the water supplied by an external source, for example a misting agent, natural or artificial tears, or else still water brought by a second composition.

  According to a preferred embodiment, the composition comprising the electrophilic monomer is free of nucleophilic agent. According to another preferred embodiment, the nucleophilic agent is provided by a second composition, applied on or under the deposit formed by the application of the composition comprising the electrophilic monomer. Laminating oils

  One of the compositions according to the invention comprises at least one plasticizing oil chosen from oils having a molar mass of less than or equal to 10 800 g / mol, especially ranging from 200 to 800 g / mol, and having solubility parameters of Hansen such that the dispersive component dd ranges from 12 (J / cm3) 1! 2 to 18 (J / cm) 112, and more particularly from 13 (J / cm3) 1'2 to 17 (J / cm3) 1'2. and the component da is less than 7.5 (J / cm3) 1i2 and more particularly less than 7 (JIcm3) 1r2. According to a preferred embodiment, the plasticizing oil according to the invention has a molar mass less than or equal to 700 g / mol, especially ranging from 200 to 700 g / mol, and more preferably ranging from 200 to 500 g / mol. . The definition of the solubility parameters according to HANSEN is well known to those skilled in the art, and in particular described in the article by C. M. HANSEN: "The three dimensional solubility parameters" J. Paint Technol. 39, 105 (1967). These parameters are also described in KAO JP-A-08-109121 and the document by D.W. Van KREVELEN "Properties of Polymers" (1990), p. 190. According to this HANSEN space: - Sd characterizes the LONDON dispersion forces resulting from the formation of dipoles induced during molecular shocks; 25 - op characterizes the DEBYE interaction forces between permanent dipoles; and - 0h characterizes the specific interaction forces (hydrogen bond, acid / base, donor / acceptor type, etc.). _ Sa = (5p2 + 8h2) 1/2 The parameters 5d, 5p, bh and ba are generally expressed in (JIcm3) 1 "2. They are determined at ambient temperature (25 C) and in particular according to the indicated calculation method. in the KAO document identified above.

  The plasticizing oils may especially be chosen from:

  volatile hydrocarbon oils chosen in particular from hydrocarbon-based oils containing from 8 to 16 carbon atoms, and in particular C8-C16 branched alkanes such as C8-C16 isoalkanes of petroleum origin (also known as isoparaffins), such as isododecane ( also called 2,2,4,4,6-pentamethylheptane), isohexadecane, and for example the oils sold under the trade names of Isopars or Permethyls, non-volatile hydrocarbon oils, chosen in particular from among isoeicosane, hydrogenated polyisobutene such as Parleam oil, squalane, synthetic esters such as oils of formula RICOOR 2 in which R 1 represents the residue of a linear or branched fatty acid containing from 1 to 40 carbon atoms and R 2 represents a hydrocarbon chain, especially a branched chain containing from 1 to 40 carbon atoms, provided that RI + R2 is 10, for example purcellin oil (cetostearyl octanoate), isop myristate ropyl, isopropyl palmitate, C12-C15 alcohols benzoates, hexyl laurate, isononyl isononanoate, isodecyl neopentanoate, 2-ethylhexyl palmitate, isostearyl isostearate, isostearyl, 2-hexyl-decyl laurate, 2-octyl-decyl palmitate, 2-octyl-dodecyl myristate, oleyl oleate; diesters such as propylene glycol diheptanoates, dioctanoates, didecanoates or ricinoleates, di-isostearyl malate, triesters such as glyceryl tri-heptanoate, tridecyl tri-melitate, phenyl silicones such as phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisiloxanes, and mixtures thereof. According to a preferred embodiment, the plasticizing oil is chosen from: C12-C15 alkyl benzoates, iso-eicosane, hydrogenated polyisobutylenes such as parleam oil, phenyltrimethicone, squalene, glyceryl tri-heptanoate, tridecyl trimellitate, oleyl oleate, isononyl isononanoate and mixtures thereof.

  The one or more plasticizing oil (s) may represent all or part of the liquid fatty phase of the composition comprising them. For example, the oil or the mixture of oil (s) plasticizer (s) may represent from 0.1 to 100% by weight of the liquid fatty phase of the composition comprising it, and in particular from 0.5 to 50% in weight. The oil or the mixture of plasticizing oil (s) may represent from 1 to 30%, by weight, relative to the total weight of the composition comprising it, preferably from 1 to 40% by weight, and more preferably from 3 to 15% by weight. Those skilled in the art will take care to adjust the contents of plasticizing oil according to the embodiments and galenics envisaged. Fatty phase The composition (s) according to the invention may comprise, in addition to the electrophilic monomer and / or the plasticizing oil, an additional liquid fatty phase and / or solid fatty substances such as waxes and / or pasty compounds.

  By liquid fatty phase is meant all the oils present in the compositions. The composition (s) according to the invention may comprise an additional oil, other than the plasticizing oil described above, chosen from volatile oils and non-volatile oils.

  For the purpose of the invention, the term "volatile oil" means any oil capable of evaporating on contact with the skin at ambient temperature and atmospheric pressure. The volatile oils of the invention are volatile cosmetic oils which are liquid at room temperature and have a non-zero vapor pressure at ambient temperature and atmospheric pressure, in particular from 0.13 Pa to 40,000 Pa (0.001 to 300 g). mm Hg) and preferably ranging from 1.3 to 1300 Pa (0.01 to 10 mmHg). The volatile oil may be chosen from volatile hydrocarbon oils, volatile silicone oils, volatile fluoro oils, and mixtures thereof.

  The term "hydrocarbon oil" means an oil containing mainly hydrogen and carbon atoms and optionally oxygen, nitrogen, sulfur and / or phosphorus atoms.

  Volatile silicones can also be used as volatile oils, for example volatile linear or cyclic silicone oils, in particular those having a viscosity of 5 centistokes (5 × 10 -6 m 2 / s), and especially having from 2 to 10 silicon atoms, preferably from 2 to 7 silicon atoms, these silicones optionally containing alkyl or alkoxy groups having from 1 to 10 carbon atoms. As the volatile silicone oil that may be used in the invention, mention may especially be made of octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane, hexamethyl disiloxane, octamethyltrisiloxane and the like. decamethyl tetrasiloxane, dodecamethyl pentasiloxane and mixtures thereof.

  As the fluorinated volatile oil, there may be mentioned nonafluoroethoxybutane, nonafluoromethoxybutane, decafluoropentane, tetradecafluorohexane, dodecafluoropentane, and mixtures thereof.

  The additional volatile oil (other than the plasticizing oil) may be present in a content ranging from 1 to 95% by weight, relative to the total weight of the composition comprising it, preferably ranging from 5% to 70% by weight. weight, preferably ranging from 10% to 60% by weight, and more preferably ranging from 15% to 60% by weight.

  The composition or compositions according to the invention may comprise at least one additional non-volatile oil.

  By "non-volatile oil" is meant an oil remaining on the skin at room temperature and atmospheric pressure for at least several hours and having in particular a vapor pressure of less than 0.13 Pa (0.01 mm Hg) at ambient temperature ( 25 C). These non-volatile oils may be hydrocarbon oils, in particular of animal or vegetable origin, silicone oils, or mixtures thereof. The term "hydrocarbon-based oil" means an oil containing mainly hydrogen and carbon atoms and optionally oxygen, nitrogen, sulfur and / or phosphorus atoms.

  The non-volatile oils may in particular be chosen from fluorinated hydrocarbon oils which may be fluorinated and / or non-volatile silicone oils.

  As non-volatile hydrocarbon oils, mention may be made in particular of: - hydrocarbon-based oils of animal origin, - hydrocarbon-based oils of vegetable origin, such as triglycerides consisting of esters of fatty acids and of glycerol, the fatty acids of which may have various chain lengths of C4 to C24, the latter being linear or branched, saturated or unsaturated; or even the oils of wheat germ, sunflower seed, grape seeds, maize, apricot, castor oil, shea butter, avocado, olive, soya, sweet almond, palm, rapeseed, cotton, hazelnut, macadamia, jojoba, alfalfa, poppy, pumpkin, sesame, squash, rapeseed, blackcurrant, evening primrose, millet, barley, quinoa, rye, safflower, bancoulier, passionflower, muscat rose; shea butter - synthetic ethers having from 10 to 40 carbon atoms; linear or branched hydrocarbons of mineral or synthetic origin, such as petroleum jelly, polydecenes, paraffin oils, and mixtures thereof, synthetic esters chosen from diisopropyl adipate and hydroxylated esters, such as lactate, isostearyl, 2-octyl-dodecyl lactate; polyol esters and pentaerythritol esters,

  at room temperature liquids with a branched and / or unsaturated carbon chain having from 12 to 26 carbon atoms, such as octyl dodecanol, isostearyl alcohol, oleic alcohol, 2-hexyldecanol or 2-butyloctanol, and 2-undecylpentadecanol,

  higher fatty acids such as oleic acid, linoleic acid, linolenic acid and mixtures thereof.

  The non-volatile silicone oils that may be used in the composition (s) according to the invention may be non-volatile polydimethylsiloxanes (PDMS), polydimethylsiloxanes comprising pendant alkyl or alkoxy groups and / or silicone chain ends, and each having from 2 to 24 carbon atoms.

  The non-volatile oil may be present in the composition or compositions according to the invention in a content ranging from 0.1% to 90% by weight, relative to the total weight of the composition comprising it, preferably ranging from 1% to 70% by weight, preferably ranging from 3% to 50% by weight.

  The total liquid fatty phase of the composition (s) according to the invention may be present in a total content ranging from 10 to 70% by weight relative to the total weight of the composition, preferably ranging from 10% to 60% by weight, preferably ranging from 10% to 40% by weight, and more preferably ranging from 15% to 30% by weight.

  The composition or compositions according to the invention may also comprise fatty substances other than the oils mentioned above, such as waxes or pasty compounds.

  By wax is meant a solid fat body at room temperature.

  As waxes that can be used according to the invention, mention may be made of:

  animal waxes such as beeswax, spermaceti, lanolin wax and lanolin derivatives, vegetable waxes such as Carnauba wax, Candellila wax, Ouricury wax, Japan wax, butter wax of cocoa or waxes of cork fiber or sugar cane,

  mineral waxes, for example paraffin, petroleum jelly, lignite or microcrystalline waxes or ozokerites,

  synthetic waxes, among which are polyethylene waxes, polytetrafluoroethylene waxes and waxes obtained by Fisher-Tropsch synthesis,

  Silicone waxes, especially substituted linear polysiloxanes; mention may be made, for example, of polyether silicone waxes, alkyl or alkoxy dimethicones having from 16 to 45 carbon atoms, alkyl methicones such as C30-C45 alkylmethicone sold under the trade name "AMS C 30" by DOW CORNING,

  25 C-hydrogenated oils such as hydrogenated castor oil, hydrogenated jojoba oil, hydrogenated palm oil, hydrogenated tallow, hydrogenated coconut oil and concrete fatty esters at 25 ° C. as the C20-C40 alkyl stearate sold under the trade name "Kester WAX K82H" by Koster Keunen, and / or mixtures thereof.

  Preferably, use will be made of polyethylene waxes, microcrystalline waxes, carnauba waxes, hydrogenated jojoba oil, candellila waxes, beeswaxes and / or mixtures thereof. Preferably, the waxes are present in a content ranging from 0.05 to 45% by weight, relative to the total weight of the composition comprising them, more preferably from 1 to 30% by weight, and more preferably ranging from 5 to 25% by weight.

  The cosmetic composition (s) according to the present invention may also comprise at least one pasty compound.

  For the purposes of the present invention, the term "pasty" means a fatty compound with a reversible solid / liquid state change and comprising, at a temperature of 23 ° C., a liquid fraction and a solid fraction. Paste is also understood to mean vinyl polylaurate. The pasty compound within the meaning of the invention advantageously has a hardness at 20 C ranging from 0.001 to 0.5 MPa, preferably from 0.002 to 0.4 MPa. Among the pasty compounds which may be used in the composition (s) according to the invention, mention may be made of lanolines and lanolin derivatives, such as acetyl lanolines, oxypropylenated lanolins or isopropyl lanolate, and mixtures thereof. . It is also possible to use esters of fatty acids or of fatty alcohols, especially those having from 20 to 65 carbon atoms, for example triisotearyl citrate or cetyl citrate; arachidyl propionate; vinyl polylaurate; cholesterol esters such as triglycerides of plant origin such as hydrogenated vegetable oils, viscous polyesters and mixtures thereof. As vegetable triglycerides, hydrogenated castor oil derivatives, such as Rheox's "THIXINR", may be used. The pasty compounds may be present in a content ranging from 0.05 to 45% by weight, relative to the total weight of the composition comprising them, more preferably from 1 to 30% by weight, and more preferably ranging from at 25% by weight. Aqueous phase The composition (s) according to the invention may comprise an aqueous phase.

  The aqueous phase comprises water. The water may be a floral water such as cornflower water and / or mineral water such as VITTEL water, LUCAS water or LA ROCHE POSAY water and / or thermal water.

  The aqueous phase may also comprise water-miscible organic solvents (at room temperature - C) such as, for example, monoalcohols having from 2 to 6 carbon atoms, such as ethanol or isopropanol; Polyols having especially 2 to 20 carbon atoms, preferably having 2 to 10 carbon atoms, and preferably having 2 to 6 carbon atoms, such as glycerol, propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, dipropylene glycol, diethylene glycol; glycol ethers (having in particular from 3 to 16 carbon atoms) such as mono (di-or tripropylene glycol) (C1-C4) alkyl ethers, (C1-C4) alkyl mono, di or triethylene alkyl ethers; glycol, and mixtures thereof. The aqueous phase may further comprise stabilizing agents, for example sodium chloride, magnesium dichloride and magnesium sulfate. The aqueous phase may also comprise any water-soluble or water-dispersible compound compatible with an aqueous phase such as gelling agents, film-forming polymers, thickeners, surfactants and mixtures thereof. Preferably, the aqueous phase may be present in a content ranging from 0.1 to 100% by weight, relative to the total weight of the composition comprising it, preferably ranging from 1 to 95% by weight.

  Preferably, the water may be present in a content ranging from 0.1 to 100% by weight, relative to the total weight of the composition, comprising preferably from 1 to 95% by weight.

  According to a particular embodiment, the aqueous phase may be present in a composition intended to be applied on or under the deposition formed by a composition comprising the electrophilic monomer.

  According to another embodiment, the aqueous phase may be present in a third composition intended to form a third deposit, after application to the skin or the eyelashes, via at least one composition, of the electrophilic monomer and the plasticizing oil.

  The aqueous phase present in the composition (s) according to the invention makes it possible, by the presence of the nucleophilic hydroxyl ions, to polymerize the electrophilic monomer. Said aqueous phase may be provided by an external source such as a wet support or a fogger.

  According to a preferred embodiment, the composition comprising the electrophilic monomer is anhydrous. By anhydrous composition is meant a composition comprising less than 1% by weight of water, relative to the total weight of the composition, preferably less than 0.5% by weight of water. Even more preferably, the composition is free of water, the water not being added during the preparation of the composition but corresponding to the residual water provided by the mixed ingredients. Powder Phase The composition (s) according to the invention may comprise a pulverulent phase comprising pigments. By pigments, it is necessary to include particles, mineral or organic, insoluble in the liquid organic phase, intended to color and / or opacify the composition.

  The pigments may be inorganic or organic pigments. As pigments, metal oxides such as iron oxides (especially those of yellow, red, brown, black color), carbon black, titanium dioxides, cerium oxide, zirconium oxide can be used. chromium oxide; manganese violet, blue ultramarine, prussian blue, ultramarine blue, ferric blue, bismuth oxychloride, mother-of-pearl, mica coated with titanium or bismuth oxychloride, pearlescent colored pigments such as than titanium mica with iron oxides, titanium mica with in particular ferric blue or chromium oxide, titanium mica with an organic pigment of the aforementioned type as well as pearlescent pigments based on bismuth oxychloride, and their mixtures. Iron oxide, titanium dioxide, and carbon black pigments are preferably used.

  The pigments can be surface treated with a hydrophobic agent to make them compatible with the organic phase of the composition. The hydrophobic treatment agent may be selected from silicones such as meticones, dimethicones, perfluoroalkylsilanes; fatty acids such as stearic acid; metallic soaps such as aluminum dimyristate, aluminum salt of hydrogenated tallow glutamate; perfluoroalkyl phosphates, perfluoroalkyl silanes, perfluoroalkyl silazanes, hexafluoropropylene polyoxides; polyorganosiloxanes comprising perfluoroalkyl perfluoropolyether groups, amino acids; the N-acyl amino acids or their salts; lecithin, isopropyl trisostearyl titanate, and mixtures thereof. The N-acylamino acids may comprise an acyl group having from 8 to 22 carbon atoms, for example a 2-ethylhexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl or cocoyl group. The salts of these compounds may be aluminum, magnesium, calcium, zirconium, zin, sodium or potassium salts. The amino acid can be for example lysine, glutamic acid, alanine

  The term alkyl mentioned in the compounds mentioned above denotes in particular an alkyl group having from 1 to 30 carbon atoms, preferably having from 5 to 16 carbon atoms. Hydrophobic-treated pigments are described in particular in application EP-A-1086683.

  The pigments may be present in the composition (s) according to the invention in a content ranging from 0.05 to 100% by weight, relative to the total weight of the composition comprising them, in particular ranging from From 5% to 50% by weight, preferably from 0.5% to 20% by weight.

  According to a preferred embodiment of the invention, the composition comprising the electrophilic monomer is free of surface-treated metal oxide pigments.

  According to a preferred embodiment of the invention, the composition comprising the electrophilic monomer is free of metal oxide pigments not surface-treated with a hydrophobic agent.

  According to another embodiment, the composition according to the invention comprising the electrophilic monomer may comprise pigments surface-treated with a silicone or a fluorinated hydrophobic agent. In addition to the pigments, the composition (s) according to the invention may comprise fillers, nacres and / or liposoluble dyes. By fillers, it is necessary to include particles of any form, colorless or white, mineral or synthetic, insoluble in the medium of the composition regardless of the temperature at which the composition is manufactured.

  The fillers may be inorganic or organic in any form, platelet-shaped, spherical or oblong, irrespective of the crystallographic form (for example sheetlet, cubic, hexagonal, orthorhombic, etc.). Mention may be made of talc, mica, silica, kaolin, polyamide (nylon) powders, poly-R-alanine powders, polyethylene powders, polymethylmethacrylates, polyurethane powders such as powder copolymer of hexamethylene diisocyanate and trimethylol hexyl lactone sold under the names PLASTIC POWDER D-400 by the company TOSHIKI, tetrafluoroethylene polymer powders (Teflon), lauroyl-lysine, starch, boron nitride polyvinylidene chloride / acrylonitrile copolymers, acrylic acid copolymers, silicone resin powders, in particular silsesquioxane powders (silicone resin powders, in particular described in patent EP 293795, Toshiba Tospearls, for example ), elastomeric polyorganosiloxane particles, precipitated calcium carbonate, magnesium carbonate and hydrocyanate, hydroxyapatite, hollow silica microspheres es, glass or ceramic microcapsules, metal soaps derived from organic carboxylic acids containing from 8 to 22 carbon atoms, preferably from 12 to 18 carbon atoms, for example zinc, magnesium or lithium stearate; zinc laurate, magnesium myristate; barium sulphate and their mixtures.

  The fillers may be present in the composition (s) according to the invention in a total content ranging from 0.05% to 100% by weight, relative to the total weight of the composition comprising them, preferably ranging from 0.1% to 80% by weight, and preferably 0.5% to 70% by weight.

  According to a preferred embodiment of the invention, the composition comprising the electrophilic monomer is free of metal oxide pigments and untreated surface charges, in particular by a hydrophobic agent.

  In addition to the pigments and fillers, the particulate phase of the composition (s) according to the invention may comprise nacres. By nacres, it is necessary to understand iridescent particles, in particular produced by certain shellfish in their shell or else synthesized, insoluble in the medium of the composition.

  The pearlescent agents may be chosen from white pearlescent pigments such as mica coated with titanium, or bismuth oxychloride, colored pearlescent pigments such as titanium mica with iron oxides, titanium mica with, for example, ferric blue or chromium oxide, titanium mica with an organic pigment of the aforementioned type as well as pearlescent pigments based on bismuth oxychloride. The composition or compositions according to the invention may also comprise hydro or liposoluble dyes. Fat-soluble dyes include generally organic compounds soluble in fats such as oils. Fat-soluble dyes are, for example, Sudan Red, D & C Red No. 17, D & C Green No. 6, [3-carotene, soybean oil, Sudan Brown, D & C Yellow No. 11, D & C Violet No. 2. , D & C Orange No. 5, yellow quinoline, annatto, bromoacids.

  The nacres and / or additional dyes may be present in the composition (s) according to the invention in a content ranging from 0.0001% to 50% by weight, relative to the total weight of the composition comprising them, preferably ranging from 0.01% to 30% by weight, and preferably ranging from 0.05% to 20% by weight.

Film-forming polymer

  The composition (s) according to the invention may comprise at least one film-forming polymer.

  The term "film-forming polymer" is intended to mean a polymer capable of forming, by itself or in the presence of an auxiliary film-forming agent, a macroscopically continuous and adherent film on the eyelashes, and preferably a cohesive film, and better still a film, the film of which is cohesion and the mechanical properties are such that said film can be isolatable and manipulable in isolation, for example when said film is made by casting on a non-stick surface such as a Teflon or silicone surface. Among the film-forming polymers that may be used in the composition of the present invention, mention may be made of synthetic polymers, of radical type or of polycondensate type, polymers of natural origin, and mixtures thereof. By radical-forming film-forming polymer is meant a polymer obtained by polymerization of unsaturated monomers, especially ethylenic monomers, each monomer being capable of homopolymerizing (unlike polycondensates). The radical-type film-forming polymers may in particular be vinyl polymers, or copolymers, especially acrylic polymers. The vinyl film-forming polymers may result from the polymerization of ethylenically unsaturated monomers having at least one acidic group and / or esters of these acidic monomers and / or amides of these acidic monomers. As the acid group-bearing monomer, α, β-ethylenic unsaturated carboxylic acids such as acrylic acid, methacrylic acid, crotonic acid, maleic acid, itaconic acid may be used. It is preferable to use (meth) acrylic acid and crotonic acid, and more preferably (meth) acrylic acid. The acidic monomer esters are advantageously chosen from (meth) acrylic acid esters (also called (meth) acrylates), in particular alkyl (meth) acrylates, in particular C 1 -C 30 alkyl, preferably C1-C20, (meth) acrylates of aryl, in particular of C6-C10 aryl, hydroxyalkyl (meth) acrylates, in particular of C2-C6 hydroxyalkyl. Among the alkyl (meth) acrylates, mention may be made of methyl methacrylate, ethyl methacrylate, butyl methacrylate, isobutyl methacrylate, 2-ethylhexyl methacrylate, lauryl methacrylate, cyclohexyl methacrylate. Among the hydroxyalkyl (meth) acrylates, mention may be made of hydroxyethyl acrylate, 2-hydroxypropyl acrylate, hydroxyethyl methacrylate and 2-hydroxypropyl methacrylate.

  Aryl (meth) acrylates include benzyl acrylate and phenyl acrylate. Particularly preferred (meth) acrylic acid esters are alkyl (meth) acrylates. According to the present invention, the alkyl group of the esters may be either fluorinated or perfluorinated, i.e. some or all of the hydrogen atoms of the alkyl group are substituted by fluorine atoms. Amides of the acidic monomers include, for example, (meth) acrylamides, and especially N-alkyl (meth) acrylamides, in particular C 2 -C 12 alkyl. Among the N-alkyl (meth) acrylamides, mention may be made of N-ethyl acrylamide, N-t-butyl acrylamide, N-t-octyl acrylamide and N-undecylacrylamide. The vinyl film-forming polymers can also result from the homopolymerization or copolymerization of monomers chosen from vinyl esters and styrene monomers. In particular, these monomers may be polymerized with acidic monomers and / or their esters and / or amides, such as those mentioned above. Examples of vinyl esters include vinyl acetate, vinyl neodecanoate, vinyl pivalate, vinyl benzoate and vinyl t-butyl benzoate. Styrene monomers include styrene and alpha-methyl styrene. Among the film-forming polycondensates, mention may be made of polyurethanes, polyesters, polyester amides, polyamides, and epoxy ester resins, polyureas. The polyurethanes may be chosen from anionic, cationic, nonionic or amphoteric polyurethanes, polyurethane-acrylics, polyurethane-polyvinylpyrrolidones, polyester-polyurethanes, polyether-polyurethanes, polyureas, polyurea-polyurethanes, and mixtures thereof. The polyesters can be obtained, in known manner, by polycondensation of dicarboxylic acids with polyols, especially diols. The dicarboxylic acid can be aliphatic, alicyclic or aromatic. Examples of such acids are: oxalic acid, malonic acid, dimethylmalonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, 2,2-acid. dimethylglutaric acid, azelaic acid, suberic acid, sebacic acid, fumaric acid, maleic acid, itaconic acid, phthalic acid, dodecanedioic acid, 1,3-acid, cyclohexanedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, isophthalic acid, terephthalic acid, 2,5-norbornane dicarboxylic acid, diglycolic acid, thiodipropionic acid, 2,5-naphthalenedicarboxylic acid, 2,6-naphthalenedicarboxylic acid. These dicarboxylic acid monomers may be used alone or in combination with at least two dicarboxylic acid monomers. Among these monomers, phthalic acid, isophthalic acid and terephthalic acid are preferably chosen. The diol may be chosen from aliphatic, alicyclic and aromatic diols. A diol chosen from among: ethylene glycol, diethylene glycol, triethylene glycol, 1,3-propanediol, cyclohexane dimethanol, 4-butanediol is preferably used. As other polyols, it is possible to use glycerol, pentaerythritol, sorbitol, trimethylolpropane. The polyester amides can be obtained in a similar manner to the polyesters by polycondensation of diacids with diamines or amino alcohols. As the diamine, ethylenediamine, hexamethylenediamine, meta- or para-phenylenediamine can be used. As aminoalcohol, monoethanolamine can be used. The polyester may further comprise at least one monomer carrying at least one -SO3M group, with M representing a hydrogen atom, an ammonium NH4 + ion or a metal ion, such as for example an Na +, Li +, K +, Mg2 +, Cal + ion. , Cul +, Fe2 +, Fe3 +. In particular, it is possible to use a bifunctional aromatic monomer comprising such a group -SO3M. The aromatic nucleus of the bifunctional aromatic monomer additionally carrying a group -SO 3 M as described above may be chosen for example from benzene, naphthalene, anthracene, diphenyl, oxydiphenyl, sulfonyldiphenyl and methylenediphenyl nuclei. An example of a bifunctional aromatic monomer also bearing an -SO 3 M group is sulfoisophthalic acid, sulphoterephthalic acid, sulphophthalic acid and 4-sulphonaphthalene-2,7-dicarboxylic acid. It is preferred to use copolymers based on isophthalatesulphthalate, and more particularly copolymers obtained by condensation of diethylene glycol, cyclohexane di-methanol, isophthalic acid, sulfoisophthalic acid. The polymers of natural origin, optionally modified, may be selected from shellac resin, sandarac gum, dammars, demis, copals, cellulosic polymers, and mixtures thereof. According to one embodiment, the film-forming polymer may be a water-soluble polymer and may be present in an aqueous phase of the composition (s) according to the invention; the polymer is solubilized in the aqueous phase of the composition (s).

  According to another embodiment, the film-forming polymer may be a polymer solubilized in a liquid fatty phase comprising organic oils or solvents such as those described above (it is said that the film-forming polymer is a liposoluble polymer). As an example of a fat-soluble polymer, mention may be made of vinyl ester copolymers (the vinyl group being directly connected to the oxygen atom of the ester group and the vinyl ester having a saturated hydrocarbon radical, linear or branched, from 1 to 19 carbon atoms, linked to the carbonyl ester group) and at least one other monomer which may be a vinyl ester (different from the vinyl ester already present), an α-olefin (having from 8 to 28 carbon atoms), an alkyl vinyl ether (whose alkyl group has 2 to 18 carbon atoms), or an allyl or methallyl ester (having a linear or branched, saturated hydrocarbon radical of 1 to 19 carbon atoms, linked to carbonyl ester group). These copolymers may be cross-linked with crosslinking agents which may be either of the vinyl type, or of the allylic or methallyl type, such as tetraallyloxyethane, divinylbenzene, divinyl octanoate, divinyl dodecanedioate, and octadecanedioate. of divinyl. Examples of these copolymers include copolymers: vinyl acetate / allyl stearate (such as Mexomere PQ from Chimex), vinyl acetate / vinyl laurate, vinyl acetate / vinyl stearate, vinyl acetate / octadecene, vinyl acetate / octadecylvinylether, vinyl propionate / allyl laurate, vinyl propionate / vinyl laurate, vinyl stearate / octadecene-1, vinyl acetate / dodecene-1, vinyl stearate / ethyl vinyl ether , vinyl propionate / cetyl vinyl ether, vinyl stearate / allyl acetate, 2,2-dimethyl-2 vinyl octanoate / vinyl laurate, 2,2-dimethyl-2-allyl pentanoate / vinyl laurate, vinyl dimethyl propionate / vinyl stearate, allyl dimethyl propionate / vinyl stearate, vinyl propionate / vinyl stearate, crosslinked with 0.2% divinyl benzene, vinyl dimethyl propionate / vinyl laurate, crosslinked with 0.2% divinyl benzene vinyl acetate / octadecyl v inyl ether crosslinked with 0.2% tetraallyloxyethane, vinyl acetate / aleate stearate, crosslinked with 0.2% divinyl benzene, vinyl acetate / octadecene-1 crosslinked with 0.2% divinyl benzene and propionate. allyl / allyl stearate crosslinked with 0.2% divinyl benzene. Liposoluble film-forming polymers that may also be mentioned include fat-soluble copolymers, and in particular those resulting from the copolymerization of vinyl esters having from 9 to 22 carbon atoms or of alkyl acrylates or methacrylates, the alkyl radicals having from 10 to 20 carbon atoms. Such liposoluble copolymers may be chosen from copolymers of vinyl polycrystearate, vinyl polystearate crosslinked with divinylbenzene, diallyl ether or diallyl phthalate, copolymers of stearyl poly (meth) acrylate, polyvinylpolate , poly (meth) acrylate lauryl, these poly (meth) acrylates can be crosslinked using dimethacrylate ethylene glycol or tetraethylene glycol. The liposoluble copolymers defined above are known and in particular described in application FR-A-2232303; they can have a weight average molecular weight of from 2,000 to 500,000 and preferably from 4,000 to 200,000. As liposoluble film-forming polymers that can be used in the invention, mention may also be made of polyalkylenes and especially copolymers of C2-C20 alkenes, such as polybutene, alkylcelluloses with a linear or branched, saturated or non-saturated C1 to C8 alkyl radical, for example Ethylcellulose and propylcellulose, copolymers of vinylpyrrolidone (PV) and in particular copolymers of vinylpyrrolidone and alkene C2 to C40 and better still C3 to C20. By way of example of a copolymer of VP which may be used in the invention, mention may be made of the copolymer of VP / vinyl acetate, VP / ethyl methacrylate, polyvinylpyrrolidone (PVP) butylated, VP / ethyl methacrylate / methacrylic acid, VP / eicosene, VP / hexadecene, VP / triacontene, VP / styrene, VP / acrylic acid / lauryl methacrylate.

  Mention may also be made of silicone resins, generally soluble or swellable in silicone oils, which are crosslinked polyorganosiloxane polymers. The nomenclature of the silicone resins is known under the name of "MDTQ", the resin being described according to the different siloxane monomeric units that it comprises, each of the letters "MDTQ" characterizing a type of unit.

  According to one particular embodiment, the film-forming polymer is a vinyl acetate / allyl stearate copolymer.

  As examples of commercially available polymethylsilsesquioxane resins, mention may be made of those sold by the company Wacker under the reference Resin MK such as Belsil PMS MK: by the company SHIN-ETSU under the references KR-220L. As siloxysilicate resins, mention may be made of trimethylsiloxysilicate (TMS) resins such as those sold under the reference SR1000 by the company General Electric or under the reference TMS 803 by the company Wacker. Mention may also be made of timethylsiloxysilicate resins sold in a solvent such as cyclomethicone, sold under the name "KF-7312J" by the company Shin-Etsu, "DC 749", "DC 593" by the company Dow Corning. Mention may also be made of silicone resin copolymers such as those mentioned above with polydimethylsiloxanes, such as the pressure-sensitive adhesive copolymers marketed by Dow Corning under the reference BIO-PSA and described in US Pat. No. 5,162. 410 or silicone copolymers derived from the reaction of a silicone resin, such as those described above, and a diorganosiloxane as described in WO 2004/073626.

  It is also possible to use silicone polyamides of the polyorganosiloxane type such as those described in documents US-A-5,874,069, US-A-5,919,441, US-A-6,051,216 and US-A-5,981,680. These silicone polymers may belong to the following two families: polyorganosiloxanes comprising at least two groups capable of establishing hydrogen interactions, these two groups being located in the polymer chain, and / or polyorganosiloxanes comprising at least two groups capable of establish hydrogen interactions, these two groups being located on grafts or branches. According to one embodiment of the invention, the film-forming polymer is a film-forming linear ethylenic block polymer, which preferably comprises at least a first sequence and at least a second sequence having different glass transition temperatures (Tg), said first and second sequences being interconnected by an intermediate sequence comprising at least one constituent monomer of the first block and at least one constituent monomer of the second block. Advantageously, the first and second sequences and the block polymer are incompatible with each other. Such polymers are described for example in EP 1411069 or W004 / 028488.

  The film-forming polymer may also be present in the composition (s) in the form of particles in dispersion in an aqueous phase or in a non-aqueous solvent phase, generally known under the name of latex or pseudolatex. The techniques for preparing these dispersions are well known to those skilled in the art. As the aqueous dispersion of film-forming polymer, it is possible to use the acrylic dispersions sold under the names Neocryl XK-90, Neocryl A-10700, Neocryl A-10900, Neocryl BT-62, Neocryl A-10790 and Neocryl A-5230 by the company Avecianeurores Dow Latex 432 by DOW CHEMICAL, Daitosol 5000 AD or Daitosol 5000 SJ by DAITO KASEY KOGYO; Syntran 5760 by the company Interpolymer, Allianz OPT by the company Rohm & Haas, aqueous dispersions of acrylic or styrene / acrylic polymers sold under the trade name JONCRYL by JOHNSON POLYMER or the aqueous polyurethane dispersions sold under the trade names Neorez R-9810 and Neorez R-974 by the company AVECIA-NEORESINS, the Avalure UR-405, Avalure UR-410, Avalure UR-425, Avalure UR-450, Sancure 875, Sancure 861, Sancure 878 and Sancure 2060 by the company GOODRICH, Impranil 85 by the company BAYER, Aquamere H-15110 by the company HYDROMER; the sulpopolyesters sold under the brand name Eastman AQ by Eastman Chemical Products, vinyl dispersions such as Mexomer PAM from Chimex and mixtures thereof.

  As examples of non-aqueous dispersions of film-forming polymer, mention may be made of acrylic dispersions in isododecane, such as Mexomere PAP from Chimex, particle dispersions of a grafted ethylenic polymer, preferably acrylic polymer, in a liquid fatty phase, the ethylenic polymer being advantageously dispersed in the absence of additional stabilizer at the surface of the particles as described in particular in WO 04/055081. The film-forming polymer may be present in the composition or compositions according to the invention in a dry matter content (or active material) ranging from 0.1% to 30% by weight, relative to the total weight of the composition comprising it, of preferably from 25% to 20% by weight, and more preferably from 1% to 15% by weight. Polymerization inhibitor

  It is also possible to introduce, in the composition (s) according to the invention comprising the electrophilic monomer, polymerization inhibitors, and more particularly anionic and / or radical polymerization inhibitors, in order to increase the stability of the polymer. composition in time. In a nonlimiting manner, mention may be made of the following polymerization inhibitors: sulfur dioxide, nitric oxide, organic acids such as a sulphonic acid or phosphoric acid, acetic acid, lactone, trifluoride and the like. boron, hydroquinone and its derivatives such as hydroquinone monethyl ether, tert-butylhydroquinone, benzoquinone and its derivatives such as duroquinone, catechol and its derivatives such as t-butyl catechol and methoxycatechol, anisole and its derivatives such as methoxyanisole or hydroxyanisole, pyrogallol and its derivatives, p-methoxyphenol, hydroxybutyl toluene, alkyl sulphates, alkyl sulphites, alkyl sulphones, alkyl sulphoxides, alkyl sulphides, mercaptans, and their mixtures. The alkyl groups preferably denote groups having 1 to 6 carbon atoms. The inhibitor concentration in the composition (s) according to the invention comprising the electrophilic monomer may be between 10 ppm and 10% by weight, relative to the total weight of the composition, and more preferably between 50 ppm and 5% by weight. weight.

additives

  The composition (s) according to the invention may comprise at least one other usual cosmetic ingredient which may be chosen in particular from hydrophilic or lipophilic gelling agents and / or thickeners, antioxidants, perfumes, preservatives, neutralizers, and sunscreens. , vitamins, self-tanning compounds, anti-wrinkle active agents, hydrophilic or lipophilic active agents, antipollution or anti-free radical agents, sequestering agents, surfactants, dermorelaxing active agents, soothing agents, agents stimulating the synthesis of macromolecules dermal or epidermal agents and / or preventing their degradation, anti-glycation agents, anti-irritant agents, desquamating agents, depigmenting, anti-pigmenting or pro-pigmenting agents, NO-synthase inhibitors, proliferation of fibroblasts or keranocytes and / or differentiation of keranocytes, the agents acting on the microcirculation ion, agents acting on the energetic metabolism of cells, healing agents, and their mixtures. Galenics The composition (s) according to the invention may especially be in the form of a suspension, a dispersion, a solution, an aqueous or anhydrous gel, an emulsion, in particular an oil-in-water emulsion (O / W). ) or water-in-oil (W / O), wax-in-water or water-in-wax, multiple (W / O / E or polyol / H / E or O / W / H), in cream form , foam, stick, dispersion of vesicles including ionic lipids or not, spray, powder, paste. The composition (s) may be anhydrous, for example it may be a stick or an anhydrous paste. The composition (s) may be a non-rinsed composition.

  The person skilled in the art may choose the appropriate dosage form, as well as its method of preparation, on the basis of his general knowledge, taking into account, on the one hand, the embodiment considered, on the other hand the nature of the constituents used. , in particular their solubility in the support, as well as the application envisaged for the composition.

  When the composition is a skin makeup composition, it is preferably in the form of an anhydrous composition comprising both the electrophilic monomer and the plasticizing oil. When this composition is applied to the skin, the water naturally present in the skin causes the polymerization of the electrophilic monomer by the presence of the nucleophilic hydroxyl ions it comprises.

  According to a first embodiment of the process according to the invention, said electrophilic monomer and said plasticizing oil are present in the same composition.

  According to a first variant of this first embodiment, the method comprises: i) extemporaneously mixing a first composition comprising the electrophilic monomer and the plasticizing oil, and a second composition comprising a physiologically acceptable medium; and ii) applying this mixture to the skin or eyelashes.

  To illustrate this first variant, it is possible for example to produce two compositions: a first composition comprising the electrophilic monomer and the plasticizing oil, a second composition comprising an aqueous phase and pigments.

  When the first and second compositions are mixed, the hydroxyl ions present in the water of the aqueous phase react with the electrophilic monomer, initiating its polymerization. This mixture is then applied to the skin or eyelashes.

  In the case where the second composition is anhydrous, the hydroxyl ions present in the residual water of the skin or eyelashes may allow the polymerization of the electrophilic monomer when the first composition is applied to the skin or the eyelashes.

  According to a second variant of this first embodiment, the method comprises: i) the formation of a first deposit by the application on said keratin materials of a first composition; ii) forming a second deposit by applying all or part of the first deposit, a second composition, one of the first or second compositions comprising the electrophilic monomer and the plasticizing oil, the other composition comprising a physiologically acceptable medium.

  To illustrate this second variant, it is possible for example to produce: a first composition comprising the electrophilic monomer and the plasticizing oil, a second composition comprising an aqueous phase and pigments.

  The first composition is applied to the skin or eyelashes. Then, on the deposit formed, the second composition comprising water and the pigments is applied. The hydroxyl ions present in the water of the aqueous phase react with the electrophilic monomer present in the first deposit, triggering its polymerization directly on the skin or the eyelashes.

  In the case where the second composition is anhydrous, the hydroxyl ions present in the residual water of the skin or eyelashes may allow the polymerization of the electrophilic monomer when the first composition is applied to the skin or the eyelashes. The second composition then brings the pigments.

  According to a second embodiment of the process according to the invention, said electrophilic monomer and said plasticizing oil are conveyed separately in at least two distinct compositions. According to a first variant of this second embodiment, the method comprises: i) extemporaneously mixing the composition comprising the electrophilic monomer and the composition comprising the plasticizing oil; and ii) applying this mixture to the skin or eyelashes. To illustrate this first variant, one can for example make two compositions: a first composition comprising the electrophilic monomer, a second composition comprising the plasticizing oil, pigments and water. These two compositions are mixed, the hydroxyl ions present in the water of the second composition initiating the polymerization of the electrophilic monomer. The mixture thus obtained is applied to the skin or eyelashes.

  In the case where the second composition is anhydrous, the hydroxyl ions present in the residual water of the skin or eyelashes can trigger the polymerization of the electrophilic monomer when the first composition is applied to the skin or eyelashes. variant of this second embodiment, the method comprises: i) the formation of a first deposit by application on said keratin materials of a first composition; ii) forming a second deposit by applying all or part of the first deposit of a second composition, one of the first or second compositions comprising the electrophilic monomer, the other composition comprising the plasticizing oil.

  To illustrate this second variant, it is possible for example to make: a first composition comprising the electrophilic monomer a second composition comprising the plasticizing oil, an aqueous phase and pigments. The first composition is applied to the skin or eyelashes. Then, on the deposit formed, the second composition is applied comprising water, plasticizing oil and pigments. The hydroxyl ions present in the water of the aqueous phase react with the electrophilic monomer present in the first deposit, triggering its polymerization directly on the skin or the eyelashes.

  In the case where the second composition is anhydrous, the hydroxyl ions present in the residual water of the skin or eyelashes (or tears) can trigger the polymerization of the electrophilic monomer when the first composition is applied to the skin or the eyelashes. The second composition then brings the pigments.

  According to a third variant of the second embodiment, the method according to the invention comprises: i) the formation of a first deposit by application on said keratin materials of a first composition; ii) forming a second deposit by applying all or part of the first deposit of a second composition; iii) forming a third deposit by applying all or part of the second deposit of a third composition; one of said first, second or third composition comprising the electrophilic monomer, another comprising the plasticizing oil and the latter comprising a physiologically acceptable medium.

  To illustrate this third variant of the second embodiment, it is possible, for example, to produce: a first composition comprising the electrophilic monomer, a second composition comprising the plasticizing oil, and pigments, and a third composition comprising water. The first composition is applied to the skin or eyelashes. Then, on the deposit formed, the second composition comprising the plasticizing oil and the pigments is applied. Finally, the third composition comprising water is applied, the hydroxyl ions present in the water initiating the polymerization of the electrophilic monomer directly on the skin or the eyelashes.

  The makeup kit described above may comprise several embodiments. According to a first embodiment of the kit, the plasticizing oil is present in the composition comprising the electrophilic monomer.

  According to a second embodiment of the kit, the plasticizing oil is present in the composition comprising the physiologically acceptable medium.

  According to a third embodiment, the kit comprises at least three compositions: i) the first composition comprising at least one electrophilic monomer ii) the second composition comprising at least one plasticizing oil contained in a liquid fatty phase, the said plasticizing oil being chosen among oils having a molecular weight of less than 800 g / mol, and having Hansen solubility parameters such that the dd dispersive component ranges from 12 (J / cm 3) 112 to 18 (J / cm 3) 12, and component da is less than 7.5 (J / cm3) v2, iii) the third composition comprises a physiologically acceptable medium.

  When the kit according to the invention is intended for making up the skin, it may comprise: a first anhydrous composition comprising the electrophilic monomer and the plasticizing oil, and a second composition in the form of a powder (free or compacted). Alternatively, two compositions may be included: a first anhydrous composition comprising the electrophilic monomer, and a second powdery composition (free or compacted) comprising the plasticizing oil. When the kit according to the invention is intended for the makeup of the eyelashes, it may comprise: a first anhydrous composition comprising the electrophilic monomer and the plasticizing oil, and a second composition in the form of a powder (free or compacted). Alternatively, two compositions may be included: a first anhydrous composition comprising the electrophilic monomer and the plasticizing oil, and a second composition comprising water or else comprising three compositions: a first anhydrous composition comprising the electrophilic monomer, A second composition in powder form (free or compacted) comprising the plasticizing oil, and a third composition comprising water. The present invention is illustrated in more detail in the examples hereinafter. First composition: - octyl cyanoacrylate sold under the name 50 RITELOK CDN 1064 by the company CHEMENCE 50 - Cyclopentasiloxane The two components are mixed with magnetic stirring at room temperature. Second Composition: Free Powder - Talc 64.7 - Iron Oxides 2.9 - Titanium Dioxide 7.1 - Nylon Powder - 12 sold under the name 10.0 ORGASOL 2002 EXD NAT COS 204 by the company 5.0 ARKEMA Polymethylsilsesquioxane resin powder sold under the name Tospearl 145 A by the company GE Toshiba 10.0 Silicones - isononyl isononanoate - preservative qs Procedure: The pulverulent components are mixed for 5 min and then the isononyl isononyl isononate is added. The mixture is passed to the Alpine set at 18000 rpm and then sieved manually at 250 μm.

  The first composition is applied to the skin. The residual water of the skin allows the polymerization of the cyanoacrylate monomer. Then the second composition comprising the plasticizing oil is applied to the first deposit. The makeup obtained has a good performance. Example 1: Makeup kit for the skin In the examples, the contents are expressed as a percentage by weight. EXAMPLE 2 First composition: Octyl cyanoacrylate sold under the name 90 RITELOK CDN 1064 by the company CHEMENCE 10 Isononyl isononanoate The cyanoacrylate monomer and the plasticizing oil are mixed with magnetic stirring at room temperature. Octyl cyanoacrylate sold under the name 100 RITELOK CDN 1064 by the company Chemence Second composition: Free powder - Talc 71.9 - Iron oxides 3.2 - Titanium dioxide 7.9 - Nylon-12 powder sold under the name denomination 11.1 ORGASOL 2002 EXD NAT COS 204 by the company ARKEMA - polymethylsilsesquioxane resin powder sold under the name 5.6 Tospearl 145 A by the company GE Toshiba Silicones - preservative qs First comparative composition (without plasticizing oil): 15 20 25 Procedure: The pulverulent components are mixed for 5 minutes. The mixture is passed to the Alpine set at 18,000 rpm and then sieved manually at 250 μm.

  In order to show the influence of the plasticizing oil on the good performance of the makeup, the first composition is spread on a glass plate and the first comparative composition on another plate. These two plates are allowed to stand in an oven at 36 ° C. for 6 hours. Then free powder (second composition) is applied to both plates. In the context of the kit according to the invention, the powder adheres well on the film: the kit thus has good makeup performance.

  When the second composition is applied to the comparative composition, the powder adheres little and slides on the glass plate. EXAMPLE 3 Eyelash Makeup Kit First Unstained Composition Beeswax 9.9 Carnauba Wax 4.52 Paraffin Wax 2.18 Modified Eldearyl Dimethyl Ammonium 5.32 (Bentone 38 V Elementis) 1.74 - Propylene carbonate - octyl cyanoacrylate sold under the name 10.0 RITELOK CDN 1064 by the company CHEMENCE 5.0 - Isononyl sononanoate - 0.75 vinyl polylaurate (Mexomer PP from Chimex) 0.84 - talc - preservatives qs - Isododecane gsp100% Procedure The waxes are heated, the isononyl isononanoate at about 95 ° C., with Rayneri stirring for about 20 minutes. Next, bentone gel, octyl cyanoacrylate and vinyl polylaurate are added. The mixture is brought back to 40 ° C. with mechanical stirring, then the remaining isododecane is added. Second colored compositions: Composition A: Black iron oxide (in the form of powder) 100% Composition B: A colored aqueous gel having the following composition: - Black iron oxide 5 - Hydroxyethyl cellulose 3.1 - preservatives qs - water qs 100% The first composition comprising the cyanoacrylate monomer and the plasticizing oil is applied to the eyelashes. Then one of the second compositions (A or B) is applied to the first deposit. When applying the composition A comprising no water, the polymerization of the cyanoacrylate monomer is obtained by the presence of residual water in the eyelashes. When applying composition B, the water provided by this second composition 20 allows a faster polymerization of the electrophilic monomer. The makeup obtained has good properties of resistance to mechanical crumbling (limits the formation of grains), water (sweat) and fat (limits the formation of rings under the eyes.) Using oxide of pure iron, the good adhesion of the powder makes it possible to obtain a make-up which loads the eyelashes well.

Claims (84)

  1. A cosmetic process for making up the skin or the eyelashes, comprising the application to the skin or the eyelashes, via at least one composition, of at least one electrophilic monomer and at least one plasticizing oil contained in a liquid fatty phase, said plasticizer oil being selected from oils having a molecular weight of less than 800 glmole, and having Hansen solubility parameters such that the dispersant component dd ranges from 12 (J / cm3) 112 to 18 (J / cm3) 1'2, and the da component is less than 7.5 (J / cm) -1.   2. Cosmetic process according to the preceding claim, characterized in that the electrophilic monomer corresponds to the formula (A): R 1 R 3> '(R 2 R 4 (A) in which: R 1 and R 2 each independently denote one of the other, a little or no electro-attractor group, and R3 and R4 each independently of one another is an electron-withdrawing group.   3. Cosmetic makeup method according to any one of the preceding claims, characterized in that said electrophilic monomer and said plasticizing oil are present in the same composition. 25   4. Method according to the preceding claim, characterized in that it comprises: i) extemporaneously mixing a first composition comprising at least the electrophilic monomer and the plasticizing oil and a second composition comprising a physiologically acceptable medium; and ii) applying said mixture to the skin or eyelashes. 20   5. Cosmetic make-up method according to claim 3, characterized in that it comprises: i) the formation of a first deposit by application on said keratin materials of a first composition; ii) forming a second deposit by applying, on all or part of the first deposit, a second composition, one of the first or second composition comprising the electrophilic monomer and the plasticizing oil, the other composition comprising a physiologically acceptable medium.   6. Cosmetic make-up method according to claim 1 or 2, characterized in that said electrophilic monomer and said plasticizing oil are conveyed separately in two separate compositions.   7. Method according to the preceding claim, comprising: i) extemporaneously mixing a first composition comprising the monomer and a second composition comprising the plasticizing oil; and ii) applying said mixture to the skin or eyelashes.   The method of claim 6 comprising: i) forming a first deposit by applying to said keratin materials a first composition; ii) forming a second deposit by applying all or part of the first deposit, a second composition, one of the first and second compositions comprising the electrophilic monomer, the other comprising the plasticizing oil.   9. Process according to any one of claims 2 to 8, characterized in that the monomers of formula (A) are such that RI and R2, independently represents a hydrogen atom; a saturated or unsaturated hydrocarbon group, linear, branched or cyclic, preferably containing from 1 to 20, and optionally containing one or more nitrogen, oxygen and sulfur atoms, and optionally substituted by one or more groups chosen from -OR - COOR, -COR, -SH, -SR, -OH, and the halogen atoms; a modified or unsubstituted polyorganosiloxane residue; a polyoxyalkylene group, R denoting a saturated or unsaturated hydrocarbon group, linear, branched or cyclic, containing from 1 to 20, and optionally containing one or more nitrogen, oxygen and sulfur atoms, and optionally substituted with one or more groups selected from OR ', -COOR', -COR ', -SH, -SR', -OH, the halogen atoms, or a polymer residue, R 'denoting a C1-C10 alkyl group;   10. Process according to the preceding claim, characterized in that the monomers of formula (A) are such that R3 and R4, independently, are chosen from the groups -N (R) 3+, -S (R) 2+, -SH2 + , -NH3 +, -NO2, -SO2R, -C = N, -OOOH, -COOR, -COSR, -CONHR, -CONH2, -F, -CI, -Br, -I, OR, -COR, -SH, -SR, -OH, linear or branched alkenyl groups, linear or branched alkynyl groups, C 1 -C 4 mono- or polyfluoroalkyl groups, aryl groups or aryloxy groups, R denoting a linear or saturated saturated hydrocarbon group, branched or cyclic, having from 1 to 20, and optionally containing one or more nitrogen, oxygen, sulfur atoms, and optionally substituted with one or more groups selected from OROR ', - COOR', -COR ', - SH, -SR ', -OH,, the halogen atoms, or a polymer residue, R' being a C1-C10 alkyl radical.   11. Process according to any one of claims 9 and 10, characterized in that the monomers of formula (A) are cyanoacrylate monomers of formula: RI Cr - N 1 C = C (B) 1 R2 COXR'3 X denotes NH, S or O, R'3 being selected from hydrogen or R, R, R1 and R2 being as defined in claim 9.   12. A process according to claim 10, wherein the cyanoacrylate monomers correspond to the formula ## STR1 ## C10 or (C1-C4) alkoxy (C1-C10) alkyl and R1 and R2 are as defined in claim 11.   13. Process according to the preceding claim, characterized in that R '3 is an alkyl radical comprising from 6 to 10 carbon atoms.   14. Method according to any one of claims 2 to 13, characterized in that the electrophilic monomer is such that R1 and R2 represent a hydrogen atom.   15. Process according to any one of the preceding claims, characterized in that the electrophilic monomer is an alkyl cyanoacrylate of formula Ca - N 20 CH 2 = C COO - R '3 in which: R' 3 is chosen from - (CH 2) 7-CH 3, -CH (CH 3) - (CH 2) 5 -CH 3, -CH 2 -CH (C 2 H 5) - (CH 2) 3 -CH 3, - (CH 2) 5 -CH (CH 3) -CH 3, - ( CH2) 4-CH (C2H5) CH3. 25   16. Process according to the preceding claim, characterized in that the cyanoacrylate monomer is octyl 2-cyanoacrylate.   17. Method according to any one of the preceding claims, characterized in that the electrophilic monomer is present in a content ranging from 0.1 to 99% by weight of the total weight of the composition comprising it, preferably from 1 to 90% by weight, more preferably ranging from 3 to 30% by weight. 15 (F)   18. Process according to any one of the preceding claims, characterized in that the plasticizing oil is chosen from oils having Hansen solubility parameters such that the dispersive component dd ranges from 13 (J / cm 3) v 2 to 17 (J). / cm) 1I2   19. Process according to any one of the preceding claims, characterized in that the plasticizing oil is chosen from oils having Hansen solubility parameters such that the da component is less than or equal to 7 (J / cm 3).   20. Process according to any one of the preceding claims, characterized in that the plasticizing oil is chosen from those having a molar mass ranging from 200 to 800 g / mol, preferably from 200 to 700 g / mol, and preferably still, ranging from 200 to 500 g / mol.   21. Process according to any one of the preceding claims, characterized in that the plasticizing oil represents 0.1 to 100% by weight, relative to the total weight of the liquid fatty phase containing it, in particular from 0.5 to 50% by weight. % in weight. 20   22. Process according to any one of the preceding claims, characterized in that the composition or compositions comprise at least one additional oil different from the plasticizing oil.   23. Process according to the preceding claim, characterized in that the additional oil is chosen from volatile oils.   24. Method according to any one of the preceding claims, characterized in that, in addition, on the skin or the eyelashes, a fatty substance chosen from waxes and pasty compounds is applied.   25. Method according to any one of the preceding claims, characterized in that pigments are applied to the skin or to the eyelashes.   26. Method according to the preceding claim, characterized in that the pigments 35 are surface-treated pigments, in particular by a hydrophobic agent. 15 30   27. Method according to the preceding claim, characterized in that the surface-treated pigments are chosen from pigments of iron oxides or titanium dioxide with a silicone or a fluorinated hydrophobic agent.   28. Process according to any one of the preceding claims, characterized in that the electrophilic monomer (s) are conveyed in a composition free of surface-treated metal oxide pigments.   29. Process according to any one of the preceding claims, characterized in that the electrophilic monomer (s) are (are) carried in an anhydrous composition.   30. Method according to any one of the preceding claims, characterized in that at least one film-forming polymer is applied to the skin or the eyelashes.   31. Makeup composition for the skin and the eyelashes comprising at least one electrophilic monomer and at least one plasticizing oil contained in a liquid fatty phase, said plasticizing oil being chosen from oils having a molecular weight of less than 800 g / mol, and having Hansen solubility parameters such that the dispersive component dd is from 12 (J / cm3) 112 to 18 (J / cm3) 112, and the da component is less than 7.5 (JIcm3) h / 2, said oil plasticizer being present in the composition in a content ranging from 0.1 to 50% by weight, relative to the total weight of the composition, preferably ranging from 1 to 20% by weight.   32. Composition according to the preceding claim, characterized in that the electrophilic monomer corresponds to the formula (A): R 1 R 3 R 2 R 4 (A) in which: R 1 and R 2 each independently of one another a group with little or no electro-attractor, and • R3 and R4 each independently denote an electron-withdrawing group.   33. A composition according to claim 31 or 32, characterized in that the monomers of formula (A) are such that R1 and R2 independently represents a hydrogen atom; a saturated or unsaturated hydrocarbon group, linear, branched or cyclic, preferably containing from 1 to 20, and optionally containing one or more nitrogen, oxygen and sulfur atoms, and optionally substituted by one or more groups selected from - OR, -COOR, -COR, -SH, -SR, -OH, and halogen atoms; a modified or unsubstituted polyorganosiloxane residue; a polyoxyalkylene group, R denoting a saturated or unsaturated hydrocarbon group, linear, branched or cyclic, containing from 1 to 20, and optionally containing one or more nitrogen, oxygen and sulfur atoms, and optionally substituted with one or more groups selected from ùOR ', - COOR', -COR ', -SH, -SR', -OH, the halogen atoms, or a polymer residue, R 'denoting a C1-C10 alkyl group.   34. Composition according to the preceding claim, characterized in that the monomers of formula (A) are such that R3 and R4, independently, are chosen from the groups -N (R) 3+, -S (R) 2+, -SH2 + , -NH3 +, -NO2, -SO2R, -CN, -COOH, -COOR, -COSR, -CONHR, -CONH2, -F, -Cl, -Br, -I, OR, -COR, -SH, -RS , -OH, linear or branched alkenyl groups, linear or branched alkynyl groups, C 1 -C 4 mono- or polylloalkyl groups, aryl groups or aryloxy groups, R denoting a linear or branched, saturated or unsaturated hydrocarbon-based group, cyclic, comprising from 1 to 20, and optionally containing one or more nitrogen, oxygen, sulfur atoms, and optionally substituted by one or more groups chosen from ùOR ', -COOR', -COR ', -SH, -SR ', -OH,, the halogen atoms, or a polymer residue, R' being a C1-C10 alkyl radical.   35. Composition according to any one of claims 32 to 34, characterized in that the monomers of formula (A) are cyanoacrylate monomers of formula: ## STR2 ## X denoting NH, S or O, (B) R ' 3 being selected from hydrogen or R, R, R1 and R2 being as defined in claim 33.   36. Composition according to the preceding claim, characterized in that the 5 cyanoacrylate monomers correspond to the formula R 1 C = NC = C (C) R 2 COOR '3 in which R' 3 represents a C 1 -C 10 alkyl or alkoxy radical ( C1-C4) alkyl (C1-C10) and R1 and R2 are as defined in claim 35.   37. Composition according to the preceding claim, characterized in that R '3 is an alkyl radical comprising from 6 to 10 carbon atoms.   38. Composition according to any one of claims 31 to 37, characterized in that the electrophilic monomer is such that R1 and R2 represent a hydrogen atom.   39. Composition according to any one of claims 31 to 38, characterized in that the electrophilic monomer is an alkyl cyanoacrylate of formula CN 1 CH 2 = C (F) COO-R '3 in which: R' 3 is chosen from - (CH 2) 7 -CH 3, -CH (CH 3) - (CH 2) 5 -CH 3, -CH 2 -CH (C 2 H 5) - (CH 2) 3 -CH 3, - (CH 2) 5 -CH (CH 3) -CH 3, - {CH2) 4-CH (C2H5) CH3. 30   40. Composition according to the preceding claim, characterized in that the cyanoacrylate monomer is octyl 2-cyanoacrylate. 20,255   41. Composition according to any one of Claims 31 to 40, characterized in that the electrophilic monomer is present in a content ranging from 0.1% and 99% by weight, of the total weight of the composition, preferably ranging from 3% to 30% by weight.   42. Composition according to any one of claims 31 to 41, characterized in that the plasticizing oil is chosen from oils having Hansen solubility parameters such that the dispersive component dd ranges from 13 (J / cm) -2. at 17 (J / cm3) 112 10   43. Composition according to any one of claims 31 to 42, characterized in that the plasticizing oil is chosen from oils having Hansen solubility parameters such that the da component is less than or equal to 7 (J / cm3) 1r2.   44. Composition according to any one of claims 31 to 43, characterized in that the plasticizing oil is chosen from those having a molar mass ranging from 200 to 800 g / mol, preferably from 200 to 700 g / mol, and more preferably, ranging from 200 to 500 g / mol. 20   45. Composition according to any one of claims 31 to 44, characterized in that the plasticizing oil represents 0.1 to 100% by weight, relative to the total weight of the liquid fatty phase containing it, in particular 0.5 at 50% by weight. 25   46. Composition according to any one of claims 31 to 45, characterized in that it comprises at least one additional oil different from the plasticizing oil.   47. Composition according to the preceding claim, characterized in that the additional oil is chosen from volatile oils.   48. Composition according to any one of claims 31 to 47, characterized in that it comprises a fatty substance chosen from waxes and pasty compounds. 35   49. Composition according to any one of claims 31 to 48, characterized in that it comprises pigments. 15   50. Composition according to the preceding claim, characterized in that it comprises surface-treated pigments, in particular by a hydrophobic agent.   51. Composition according to the preceding claim, characterized in that the surface-treated pigments are chosen from pigments of iron oxides or titanium dioxide surface-treated with a silicone or fluorinated agent.   52. Composition according to any one of claims 31 to 48, characterized in that it is free of surface-treated metal oxide pigments.   53. Composition according to any one of claims 31 to 52, characterized in that it is anhydrous.   54. Composition according to any one of claims 31 to 53, characterized in that it comprises at least one film-forming polymer.   55. Makeup kit, in particular of the skin or eyelashes, comprising at least two compositions, i) a first composition comprising at least one electrophilic monomer, ii) a second composition comprising a physiologically acceptable medium, at least one of said first and second compositions containing at least one plasticizing oil contained in a liquid fatty phase, said plasticizing oil being chosen from oils having a molar mass of less than 800 g / mol, and having Hansen solubility parameters such that the dispersive component dd is of 12 (J / cm 3) 12 to 18 (J / cm 2), and the component da is less than 7.5 (J / cm 2).   56. Make-up kit according to the preceding claim, characterized in that the electrophilic monomer corresponds to the formula (A): R 2 R 4 (A) in which: R 1 and R 2 each independently of one another a group with little or no electro-attractor, and • R3 and R4 each independently denote an electron-withdrawing group.   57. Kit according to any one of claims 55 and 56, characterized in that said plasticizing oil is conveyed in the first composition.   58. Kit according to any one of claims 55 and 56, characterized in that said plasticizing oil is conveyed in the second composition.   59. Kit according to any one of claims 55, 56 and 60, characterized in that it comprises 3 compositions: i) a first composition comprising at least one electrophilic monomer ii) a second composition comprising at least one plasticizing oil contained in a liquid fatty phase, said plasticizing oil being chosen from oils having a molar mass of less than 800 g / mol, and having Hansen solubility parameters such that the dispersive component dd is 12 (J / cm 3) -1 at 18 (J / cm) -2, and the da component is less than 7.5 (J / cm); iii) a third composition comprising a physiologically acceptable medium. 25   60. Kit according to the preceding claim, characterized in that the electrophilic monomer corresponds to the formula (A): R 1 R 3> (R 2 R 4 (A)) in which: R 1 and R 2 each independently denote one of the other, a little or no electro-attractor group, and R3 and R4 each independently of one another is an electron-withdrawing group.   61. Kit according to any one of claims 56 to 60, characterized in that the monomers of formula (A) are such that R1 and R2, independently represents a hydrogen atom; a saturated or unsaturated hydrocarbon group, linear, branched or cyclic, preferably containing from 1 to 20, and optionally containing one or more nitrogen, oxygen and sulfur atoms, and optionally substituted by one or more groups selected from - OR, -COOR, -COR, -SH, -SR, -OH, and halogen atoms; a modified or unsubstituted polyorganosiloxane residue; a polyoxyalkylene group, R denoting a saturated or unsaturated hydrocarbon group, linear, branched or cyclic, containing from 1 to 20, and optionally containing one or more nitrogen, oxygen and sulfur atoms, and optionally substituted with one or more groups selected from ùOR ', - COOR', -COR ', -SH, -SR', -OH, the halogen atoms, or a polymer residue, R 'denoting a C1-C10 alkyl group.   62. Kit according to the preceding claim, characterized in that the monomers of formula (A) are such that R3 and R4, independently are selected from the groups -N (R) 3+, -S (R) 2+, -SH2 + , -NH3 +, -NO2, -SO2R, -CN, -COOH, -COOR, -COSR, -CONHR, -CONH2, -F, -CI, -Br, -I, ùOR, -COR, -SH, -SR , -OH, linear or branched alkenyl groups, linear or branched alkynyl groups, C 1 -C 4 mono- or polyfluoroalkyl groups, aryl groups or aryloxy groups, R denoting a linear or branched, saturated or unsaturated hydrocarbon-based group; cyclic, having 1 to 20, and optionally containing one or more nitrogen, oxygen, sulfur atoms, and optionally substituted with one or more groups selected from ùOR ', - COOR', -COR ', -SH, -SR ', -OH,, the halogen atoms, or a polymer residue, R' being a C1-C10 alkyl radical.   63. Kit according to any one of claims 56 to 62, characterized in that the monomers of formula (A) are cyanoacrylate monomers of formula: ## STR2 ## X denoting NH, S or O, R'3 being selected from hydrogen or R, R, R1 and R2 being as defined in claim 61.   64. Kit according to the preceding claim, characterized in that the cyanoacrylate monomers correspond to the formula R 1 CN 1 C = C (C) 1 R 2 COOR'3 in which R '3 represents a C 1 -C 10 alkyl or alkoxy radical ( C1-C4) alkyl (C1-C10) and R1 and R2 are as defined in claim 63.   65. Kit according to the preceding claim, characterized in that R'3 is an alkyl radical comprising from 6 to 10 carbon atoms.   66. Kit according to any one of claims 56 to 65, characterized in that the electrophilic monomer is such that R1 and R2 represent a hydrogen atom.   67. Kit according to any one of claims 56 to 66, characterized in that the electrophilic monomer is an alkyl cyanoacrylate of formula CN CH2 = C (F) COO-R'3 25 30 355in which: R'3 is selected from - (CH 2) 7 -CH 3, -CH (CH 3) - (CH 2) 5 -CH 3, -CH 2 -CH (C 2 H 5) - (CH 2) 3 -CH 3, - (CH 2) 5 -CH (CH 3) -CH 3 - (CH2) 4-CH (C2H5) -CH3.   68. Kit according to the preceding claim, characterized in that the cyanoacrylate monomer is octyl 2-cyanoacrylate.   69. Kit according to any one of claims 55 to 68, characterized in that the electrophilic monomer is present in a content ranging from 0.1 and 99% by weight of the total weight of the composition comprising it, preferably from 3 to at 30% by weight. 10   70. Kit according to any one of claims 55 to 69, characterized in that the plasticizing oil is chosen from oils having Hansen solubility parameters such that the dispersive component dd ranges from 13 to 17 (J / cm 3). ~ 2 15   71. Kit according to any one of claims 55 to 70, characterized in that the plasticizing oil is selected from oils having Hansen solubility parameters such that the component da is less than or equal to 7 (J / cm3) 1h '2   72. Kit according to any one of claims 55 to 71, characterized in that the plasticizing oil is chosen from those having a molar mass ranging from 200 to 800 g / mol, preferably from 200 to 700 g / mol, and more preferably, from 200 to 500 g / mol.   73. Kit according to any one of claims 55 to 72, characterized in that the plasticizing oil represents 0.1 to 100% by weight, relative to the total weight of the liquid fatty phase containing it, in particular of 0, 5 to 50% by weight.   74. Kit according to any one of claims 55 to 73, characterized in that at least one of the first, second and, if appropriate, third compositions comprises at least one additional oil different from the plasticizing oil.   75. Kit according to the preceding claim, characterized in that the additional oil is chosen from volatile oils.   76. Kit according to any one of claims 55 to 75, characterized in that at least one of the first, second and, if appropriate, third compositions comprises a fatty substance chosen from waxes and pasty compounds.   77. Kit according to any one of claims 55 to 76, characterized in that the composition or compositions comprise pigments.   78. Kit according to the preceding claim, characterized in that the pigment is a surface-treated pigment, in particular by a hydrophobic agent.   79. Kit according to the preceding claim, characterized in that the surface-treated pigment is selected from pigments of iron oxides or titanium dioxide surface-treated with a silicone or a fluorinated agent.   80. Kit according to any one of claims 55 to 79, characterized in that the composition comprising the electrophilic monomer is free of surface-treated metal oxide pigments.   81. Kit according to any one of claims 55 to 80, characterized in that the composition comprising the electrophilic monomer is anhydrous. 25   82. Kit according to any one of claims 55 to 81, characterized in that at least one of the first, second and, where appropriate, third compositions comprises at least one film-forming polymer.   83. Use of a kit according to any one of claims 55 to 82, for obtaining a make-up of the skin or eyelashes having good resistance and / or resistance to transfer and / or crumbling and / or friction.   84. Use of a composition according to any one of claims 31 to 54, for obtaining a makeup of the skin or eyelashes having good resistance and / or resistance to transfer and / or crumbling and / or friction. 10