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FR2738148A1 - Applying aq. cosmetic cpd. to skin - Google Patents

Applying aq. cosmetic cpd. to skin Download PDF

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Publication number
FR2738148A1
FR2738148A1 FR9510285A FR9510285A FR2738148A1 FR 2738148 A1 FR2738148 A1 FR 2738148A1 FR 9510285 A FR9510285 A FR 9510285A FR 9510285 A FR9510285 A FR 9510285A FR 2738148 A1 FR2738148 A1 FR 2738148A1
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Prior art keywords
skin
composition
cosmetic composition
reagents
acid
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Granted
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FR9510285A
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French (fr)
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FR2738148B1 (en
Inventor
Jean Gedouin
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Codif International SA
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Codif International SA
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Priority to FR9510285A priority Critical patent/FR2738148B1/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/046Aerosols; Foams
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/22Gas releasing
    • A61K2800/222Effervescent
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/88Two- or multipart kits

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

Process for cutaneous application of an aq. cosmetic compsn. comprises starting a reaction to release carbon dioxide gas at the time and place of application of the compsn. The reaction is pref. started by reacting two reagents (3,4) included respectively in first and second parts of the compsn. The reagents are pref. an acid and a sodium carbonate, with the acid present in excess. The two reagents are pref. separately stored inside a container (1) divided by a partition (2) into two chambers, and mix at the outlet from the container to give off CO2 gas.

Description

La présente invention concerne un procédé d'application cutanée d'une composition cosmétique aqueuse, ainsi qu'un procédé de conditionnement de ladite composition, prévue pour être appliquée conformément audit procédé d'application cutanée. Plus précisément, I'invention s'applique à la diffusion dans la peau des principes actifs contenus dans une composition cosmétique, par l'intermédiaire du gaz carbonique. The present invention relates to a method for applying the skin to an aqueous cosmetic composition, as well as to a method for conditioning the said composition, which is intended to be applied in accordance with the said method for applying the skin. More specifically, the invention applies to the diffusion in the skin of the active principles contained in a cosmetic composition, via carbon dioxide.

Les effets bénéfiques du gaz carbonique sur les tissus cutanés humains sont connus de longue date. Des études, notamment celle publiée dans la revue "American
Heart Journal" dans un article de I. Stein et I. Weinstein (New York, N. Y. ) portant sur des bains à dégagement de gaz carbonique, bains aqueux utilisant la réaction chimique entre un acide et un carbonate de sodium, ont mis en évidence l'action de ce gaz sur les vaisseaux sanguins cutanés. Le gaz carbonique active la micro-circulation sanguine à la surface de la peau en dilatant les parois des vaisseaux sanguins, par effet de diffusion centripète. L'activation de la micro-circulation sanguine observée permet d'améliorer l'efficacité de ces principes actifs. De plus, le gaz carbonique étant inerte à la pression atmosphérique, il ne provoque pas d'intolérance.
The beneficial effects of carbon dioxide on human skin tissue have been known for a long time. Studies, including one published in the journal "American
Heart Journal "in an article by I. Stein and I. Weinstein (New York, NY) on carbon dioxide baths, aqueous baths using the chemical reaction between an acid and a sodium carbonate, highlighted the action of this gas on the cutaneous blood vessels. Carbon dioxide activates the blood micro-circulation on the surface of the skin by dilating the walls of the blood vessels, by centripetal diffusion effect. The activation of the blood micro-circulation observed improves the effectiveness of these active ingredients, and since carbon dioxide is inert at atmospheric pressure, it does not cause intolerance.

On a cherché à utiliser les propriétés précitées du gaz carbonique pour améliorer le flux centripète des principes actifs présents dans des compositions cosmétiques. Or, il est apparu qu'une composition cosmétique dans laquelle on introduit du gaz carbonique n'est pas stable, ce qui rend son utilisation rédhibitoire. Attempts have been made to use the aforementioned properties of carbon dioxide to improve the centripetal flow of the active ingredients present in cosmetic compositions. However, it has appeared that a cosmetic composition into which carbon dioxide is introduced is not stable, which makes its use prohibitive.

Un but de l'invention est de proposer un procédé d'application cutanée d'une composition cosmétique aqueuse, ainsi qu'un procédé de conditionnement de ladite composition, prévue pour être appliquée conformément audit procédé d'application cutanée, qui permettent de tirer parti des effets centripètes du gaz carbonique pour augmenter l'efficacité des principes actifs contenus dans ladite composition. An object of the invention is to provide a method for applying the skin to an aqueous cosmetic composition, as well as a method for conditioning the said composition, intended to be applied in accordance with the said method for applying the skin, which make it possible to take advantage of centripetal effects of carbon dioxide to increase the effectiveness of the active ingredients contained in said composition.

A cet effet, un procédé d'application cutanée d'une composition cosmétique aqueuse selon l'invention est tel qu'il consiste à déclencher une réaction de dégagement de gaz carbonique au moment et au lieu de l'application de ladite composition. To this end, a process for the cutaneous application of an aqueous cosmetic composition according to the invention is such that it consists in triggering a carbon dioxide release reaction at the time and at the place of application of said composition.

Ce procédé permet d'améliorer la pénétration et la diffusion dans la peau des principes actifs contenus dans ladite composition, par l'intermédiaire du gaz carbonique produit lors du mélange desdits réactifs.  This process makes it possible to improve the penetration and the diffusion in the skin of the active principles contained in said composition, by means of carbon dioxide produced during the mixing of said reagents.

Préférentiellement, pour déclencher ladite réaction, on fait réagir deux réactifs inclus respectivement dans une première et une seconde parties de ladite composition. Preferably, to trigger said reaction, two reactants are reacted, included respectively in a first and a second part of said composition.

Préférentiellement, lesdits réactifs sont respectivement un acide et un carbonate de sodium. Preferably, said reagents are respectively an acid and a sodium carbonate.

Avantageusement, ledit acide est présent en excès dans ladite composition. Advantageously, said acid is present in excess in said composition.

Selon une autre caractéristique de l'invention, un procédé de conditionnement d'une composition cosmétique, prévue pour être appliquée conformément au procédé précité, est tel qu'il consiste à loger lesdites première et seconde parties de la composition dans deux compartiments prévus à l'intérieur d'un récipient. According to another characteristic of the invention, a method of packaging a cosmetic composition, intended to be applied in accordance with the aforementioned method, is such that it consists in accommodating said first and second parts of the composition in two compartments provided for inside a container.

Dans ce cas, la réaction de dégagement de gaz carbonique n'a lieu que lorsque les réactifs inclus dans lesdites première et seconde parties de ladite composition sont appliqués simultanément sur la peau. In this case, the carbon dioxide evolution reaction takes place only when the reagents included in said first and second parts of said composition are applied simultaneously to the skin.

Préférentiellement, les sorties desdits compartiments se trouvent au niveau de la sortie dudit récipient. Preferably, the outlets of said compartments are located at the outlet of said container.

Avantageusement, ledit procédé de conditionnement consiste à loger lesdites première et seconde parties de ladite composition à l'intérieur de récipients distincts. Advantageously, said packaging method consists in housing said first and second parts of said composition inside separate containers.

Dans ce cas, la réaction de dégagement de gaz carbonique n'a lieu que lorsque les réactifs sont appliqués successivement sur la peau. In this case, the carbon dioxide evolution reaction only takes place when the reagents are applied successively to the skin.

Les caractéristiques de l'invention mentionnée ci-dessus, ainsi que d'autres, apparaîtront plus clairement à la lecture de la description suivante d'un exemple de réalisation, ladite description étant faite en relation avec le dessin joint, dans lequel:
la Fig. unique est une vue schématique en coupe longitudinale d'un récipient permettant la mise en oeuvre des procédés selon l'invention.
The characteristics of the invention mentioned above, as well as others, will appear more clearly on reading the following description of an exemplary embodiment, said description being made in relation to the attached drawing, in which:
Fig. a single is a schematic view in longitudinal section of a container allowing the methods according to the invention to be implemented.

Le récipient 1 représenté à la Fig. unique contient une composition cosmétique aqueuse. ll comporte une cloison étanche longitudinale 2 destinée à isoler deux parties 3 et 4 de ladite composition, incluant respectivement deux réactifs prévus pour dégager du gaz carbonique lorsqu'ils interagissent en milieu aqueux. Ces réactifs sont constitués respectivement d'un acide, de préférence un acide faible, et d'un carbonate de sodium. Ledit récipient 1 est fermé par un bouchon ou couvercle 5. The container 1 shown in FIG. unique contains an aqueous cosmetic composition. It comprises a longitudinal watertight partition 2 intended to isolate two parts 3 and 4 of said composition, respectively including two reagents provided for releasing carbon dioxide when they interact in an aqueous medium. These reagents consist respectively of an acid, preferably a weak acid, and of a sodium carbonate. Said container 1 is closed by a plug or cover 5.

Selon un exemple préféré de réalisation, I'acide faible choisi est un hydroxyacide présent en excès dans ladite composition, tel que l'acide hydroxy -2 propanoique ou acide lactique, I'acide tartrique, I'acide citrique ou encore l'acide malique. Le carbonate de sodium utilisé peut être du bicarbonate, par exemple. According to a preferred embodiment, the weak acid chosen is a hydroxy acid present in excess in said composition, such as hydroxy -2 propanoic acid or lactic acid, tartaric acid, citric acid or even malic acid. . The sodium carbonate used can be bicarbonate, for example.

Du fait de la présence de la cloison 2 isolant l'acide du carbonate dans le récipient 1, la migration des ions de chaque réactif en particulier du proton issu de l'acide et de l'anion hydrogénocarbonate issu du carbonate, est rendue impossible. Due to the presence of the partition 2 isolating the acid from the carbonate in the container 1, the migration of the ions of each reagent, in particular of the proton from the acid and from the hydrogen carbonate anion from the carbonate, is made impossible.

Par contre, lorsque la composition cosmétique aqueuse est extraite du récipient 1 pour être appliquée sur la peau du patient, lesdites parties 3 et 4 se mélangent et les réactifs qu'elles contiennent respectivement réagissent selon la réaction chimique suivante:

Figure img00030001
On the other hand, when the aqueous cosmetic composition is extracted from the container 1 to be applied to the patient's skin, said parts 3 and 4 mix and the reagents which they contain respectively react according to the following chemical reaction:
Figure img00030001

On peut constater qu'elle s'accompagne d'un dégagement de gaz carbonique en milieu aqueux, produit de la réaction entre les ions contenus dans l'acide et le carbonate.It can be seen that it is accompanied by the release of carbon dioxide in an aqueous medium, the product of the reaction between the ions contained in the acid and the carbonate.

Le procédé d'application cutanée d'une composition aqueuse selon l'invention est tel que le gaz carbonique, produit seulement au contact de la peau, diffuse intégralement à travers les couches épidermiques, dermiques et hypodermiques par micro-circulation, entraînant avec lui les principes actifs présents dans ladite composition. Le flux centripète de ces principes actifs est donc augmenté. De plus,
I'eau produite par la réaction chimique permet d'hydrater la surface de la peau.
The skin application process of an aqueous composition according to the invention is such that carbon dioxide, produced only in contact with the skin, diffuses integrally through the epidermal, dermal and hypodermic layers by micro-circulation, bringing with it the active ingredients present in said composition. The centripetal flow of these active ingredients is therefore increased. Furthermore,
The water produced by the chemical reaction hydrates the surface of the skin.

Le procédé de conditionnement d'une composition cosmétique prévue pour être appliquée conformément au procédé d'application cutanée selon l'invention présente l'avantage d'empêcher tout dégagement de ce gaz lors de la première ouverture du récipient 1 contenant la composition cosmétique, et après la première application cutanée. De plus, un tel récipient 1 est d'une structure simple. The method of packaging a cosmetic composition intended to be applied in accordance with the skin application method according to the invention has the advantage of preventing any release of this gas when the container 1 containing the cosmetic composition is opened for the first time, and after the first skin application. In addition, such a container 1 is of a simple structure.

n est entendu que le procédé de conditionnement selon l'invention s'étend à d'autres modes d'isolation des deux parties 3 et 4 de la composition cosmétique, de telle sorte que la réaction chimique précitée n'a lieu que lors de leur application cutanée. En particulier, un tel procédé pourrait consister à loger chaque partie 3, 4 de ladite composition contenant respectivement lesdits réactifs dans deux récipients ou tubes distincts, de manière que le gaz carbonique ne soit produit que lors de l'application successive desdites parties 3 et 4 au contact de la peau. It is understood that the packaging method according to the invention extends to other modes of isolation of the two parts 3 and 4 of the cosmetic composition, so that the abovementioned chemical reaction only takes place during their skin application. In particular, such a process could consist in housing each part 3, 4 of said composition containing said reagents respectively in two separate containers or tubes, so that carbon dioxide is produced only during the successive application of said parts 3 and 4 on contact with the skin.

On comprendra que le procédé d'application cutanée d'une composition cosmétique aqueuse selon l'invention consiste, d'une manière générale, à prévoir tout moyen permettant de déclencher ladite réaction au moment et au lieu de l'application de ladite composition. En particulier, on pourrait prévoir à cet effet deux récipients distincts contenant respectivement une première composition non aqueuse constituée desdits réactifs, et une seconde composition aqueuse quelconque.  It will be understood that the skin application process of an aqueous cosmetic composition according to the invention consists, in general, of providing any means making it possible to trigger said reaction at the time and at the place of application of said composition. In particular, two separate containers could be provided for this purpose, respectively containing a first non-aqueous composition consisting of said reagents, and any second aqueous composition.

Claims (7)

REVENDICATIONS 1) Procédé d'application cutanée d'une composition cosmétique aqueuse, caractérisé en ce qu'il consiste à déclencher une réaction de dégagement de gaz carbonique au moment et au lieu de l'application de ladite composition. 1) A method of skin application of an aqueous cosmetic composition, characterized in that it consists in triggering a carbon dioxide release reaction at the time and at the place of application of said composition. 2) Procédé d'application cutanée d'une composition cosmétique aqueuse selon la revendication 1, caractérisé en ce que pour déclencher ladite réaction, on fait réagir deux réactifs inclus respectivement dans une première et une seconde parties (3 et 4) de ladite composition. 2) A method of skin application of an aqueous cosmetic composition according to claim 1, characterized in that to trigger said reaction, two reagents are reacted included respectively in a first and a second part (3 and 4) of said composition. 3) Procédé d'application cutanée d'une composition cosmétique aqueuse selon la revendication 2, caractérisé en ce que lesdits réactifs sont respectivement un acide et un carbonate de sodium. 3) A method of skin application of an aqueous cosmetic composition according to claim 2, characterized in that said reagents are respectively an acid and a sodium carbonate. 4) Procédé d'application cutanée d'une composition cosmétique aqueuse selon la revendication 3, caractérisé en ce que ledit acide est présent en excès dans ladite composition. 4) A method of skin application of an aqueous cosmetic composition according to claim 3, characterized in that said acid is present in excess in said composition. 5) Procédé de conditionnement d'une composition cosmétique prévue pour être appliquée conformément au procédé selon l'une des revendications 2 à 4, caractérisé en ce qu'il consiste à loger lesdites première et seconde parties (3 et 4) dans deux compartiments prévus à l'intérieur d'un récipient (1). 5) A method of packaging a cosmetic composition intended to be applied in accordance with the method according to one of claims 2 to 4, characterized in that it consists in housing said first and second parts (3 and 4) in two compartments provided inside a container (1). 6) Procédé de conditionnement d'une composition cosmétique selon la revendication 5, caractérisé en ce que les sorties desdits compartiments se trouvent au niveau de la sortie dudit récipient (1). 6) A method of packaging a cosmetic composition according to claim 5, characterized in that the outlets of said compartments are located at the outlet of said container (1). 7) Procédé de conditionnement d'une composition cosmétique prévue pour être appliquée conformément au procédé selon l'une des revendications 2 à 4, caractérisé en ce qu'il consiste à loger lesdites première et seconde parties (2, 3) de ladite composition à l'intérieur de récipients distincts.  7) A method of packaging a cosmetic composition intended to be applied in accordance with the method according to one of claims 2 to 4, characterized in that it consists in housing said first and second parts (2, 3) of said composition to inside separate containers.
FR9510285A 1995-08-28 1995-08-28 METHOD FOR SKIN APPLICATION OF AN AQUEOUS COSMETIC COMPOSITION AND METHOD FOR CONDITIONING SAID COMPOSITION, PROVIDED FOR APPLICATION IN ACCORDANCE WITH SAID SKIN APPLICATION METHOD Expired - Fee Related FR2738148B1 (en)

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FR9510285A FR2738148B1 (en) 1995-08-28 1995-08-28 METHOD FOR SKIN APPLICATION OF AN AQUEOUS COSMETIC COMPOSITION AND METHOD FOR CONDITIONING SAID COMPOSITION, PROVIDED FOR APPLICATION IN ACCORDANCE WITH SAID SKIN APPLICATION METHOD

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FR9510285A FR2738148B1 (en) 1995-08-28 1995-08-28 METHOD FOR SKIN APPLICATION OF AN AQUEOUS COSMETIC COMPOSITION AND METHOD FOR CONDITIONING SAID COMPOSITION, PROVIDED FOR APPLICATION IN ACCORDANCE WITH SAID SKIN APPLICATION METHOD

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FR2738148B1 FR2738148B1 (en) 1997-10-17

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000027356A1 (en) * 1998-11-10 2000-05-18 Color Access, Inc. Self-foaming cleansing systems
EP1059076A3 (en) * 1999-06-09 2003-04-16 Wella Aktiengesellschaft Preparation of an instant gel and the use of gaseous solid particles for cosmetic treatments
GB2386603A (en) * 2002-03-18 2003-09-24 Pz Cussons Personal cleaning composition
GB2386604A (en) * 2002-03-18 2003-09-24 Pz Cussons Personal cleansing composition
WO2004078185A1 (en) * 2003-03-04 2004-09-16 Neochemir Inc. Method of transdermal and transmucosal absorption of carbon dioxide and cosmetic method and therapeutic method
DE10327432A1 (en) * 2003-06-18 2005-01-05 Beiersdorf Ag Reactive foaming of a skin-care preparation or cosmetic and/or dermatological preparation uses spatially separated product strips, one containing (bi)carbonate and another an acid
WO2008041045A1 (en) * 2006-10-06 2008-04-10 Piller Istvan A multi chamber container for the production and dispensing of carbon dioxide foam, process for production and use of said foam
US9516877B2 (en) 2012-03-30 2016-12-13 Gojo Industries, Inc. Antimicrobial alcohol foam compositions and methods of preparation

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2477414A1 (en) * 1980-03-04 1981-09-11 Oreal Cleaning skin by applying gas foamed aq. suspension - e.g. from aerosol container, produces sensation of tightening as it dries on the skin
FR2518960A1 (en) * 1981-12-28 1983-07-01 Colgate Palmolive Co EFFERVESCENT TOOTHPASTE DISPENSER
WO1992004007A1 (en) * 1990-09-11 1992-03-19 Beecham, Incorporated Color change mouthrinse

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2477414A1 (en) * 1980-03-04 1981-09-11 Oreal Cleaning skin by applying gas foamed aq. suspension - e.g. from aerosol container, produces sensation of tightening as it dries on the skin
FR2518960A1 (en) * 1981-12-28 1983-07-01 Colgate Palmolive Co EFFERVESCENT TOOTHPASTE DISPENSER
WO1992004007A1 (en) * 1990-09-11 1992-03-19 Beecham, Incorporated Color change mouthrinse

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005325129A (en) * 1998-11-10 2005-11-24 Color Access Inc Self-foaming cleansing system
US6177092B1 (en) 1998-11-10 2001-01-23 Color Access, Inc. Self-foaming cleansing systems
EP1133983A3 (en) * 1998-11-10 2001-12-05 Color Access, Inc. Self-foaming cleansing systems
WO2000027356A1 (en) * 1998-11-10 2000-05-18 Color Access, Inc. Self-foaming cleansing systems
AU764366B2 (en) * 1998-11-10 2003-08-14 Color Access, Inc. Self-foaming cleansing systems
EP1059076A3 (en) * 1999-06-09 2003-04-16 Wella Aktiengesellschaft Preparation of an instant gel and the use of gaseous solid particles for cosmetic treatments
GB2386604A (en) * 2002-03-18 2003-09-24 Pz Cussons Personal cleansing composition
GB2386603A (en) * 2002-03-18 2003-09-24 Pz Cussons Personal cleaning composition
GB2386603B (en) * 2002-03-18 2006-09-20 Pz Cussons Personal cleaning composition
WO2004078185A1 (en) * 2003-03-04 2004-09-16 Neochemir Inc. Method of transdermal and transmucosal absorption of carbon dioxide and cosmetic method and therapeutic method
DE10327432A1 (en) * 2003-06-18 2005-01-05 Beiersdorf Ag Reactive foaming of a skin-care preparation or cosmetic and/or dermatological preparation uses spatially separated product strips, one containing (bi)carbonate and another an acid
WO2008041045A1 (en) * 2006-10-06 2008-04-10 Piller Istvan A multi chamber container for the production and dispensing of carbon dioxide foam, process for production and use of said foam
US9516877B2 (en) 2012-03-30 2016-12-13 Gojo Industries, Inc. Antimicrobial alcohol foam compositions and methods of preparation
US9943080B2 (en) 2012-03-30 2018-04-17 Gojo Industries, Inc. Antimicrobial alcohol foam compositions and methods of preparation

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