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FR2712492A1 - Cosmetic compositions based on thermal waters and process for their preparation - Google Patents

Cosmetic compositions based on thermal waters and process for their preparation Download PDF

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Publication number
FR2712492A1
FR2712492A1 FR9313636A FR9313636A FR2712492A1 FR 2712492 A1 FR2712492 A1 FR 2712492A1 FR 9313636 A FR9313636 A FR 9313636A FR 9313636 A FR9313636 A FR 9313636A FR 2712492 A1 FR2712492 A1 FR 2712492A1
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weight
cosmetic composition
neutralizing agent
composition according
carboxypolymethylene
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Granted
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FR9313636A
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FR2712492B1 (en
Inventor
Dubois Jacques
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Pierre Fabre Dermo Cosmetique SA
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Pierre Fabre Dermo Cosmetique SA
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Priority to FR9313636A priority Critical patent/FR2712492B1/en
Priority to PCT/FR1994/001328 priority patent/WO1995013793A1/en
Publication of FR2712492A1 publication Critical patent/FR2712492A1/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0212Face masks
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/042Gels
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/965Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une composition cosmétique se présentant sous la forme d'un gel comprenant: - 99 % à 99,9 % en poids d'une eau thermale - 0,1 à 1 % en poids de carboxypolyméthylène - 0 à 1% en poids d'un agent neutralisant. Elle concerne également le procédé de préparation d'une composition cosmétique caractérisé en ce que l'on mélange intimement le carboxypolyméthylène et l'eau, éventuellement additionnée d'un agent neutralisant, puis on abandonne le mélange pendant une durée suffisante pour que la structure de gel se développe.The invention relates to a cosmetic composition in the form of a gel comprising: - 99% to 99.9% by weight of thermal water - 0.1 to 1% by weight of carboxypolymethylene - 0 to 1% in weight of a neutralizing agent. It also relates to the process for preparing a cosmetic composition, characterized in that the carboxypolymethylene and water are intimately mixed, optionally with the addition of a neutralizing agent, then the mixture is left for a period sufficient for the structure of frost develops.

Description

L'invention concerne une composition cosmétique à base d'eau thermale et son procédé de fabrication. The invention relates to a cosmetic composition based on thermal water and its manufacturing process.

Le domaine de l'invention concerne le thermalisme et l'ensemble des traitements externes à base d'eaux thermales et de produits dérivés. The field of the invention relates to hydrotherapy and all external treatments based on thermal waters and derived products.

Dans l'état de la technique antérieure, on sait que les soins réalisés en cure thermale doivent être effectués sur place, et utiliser exclusivement l'eau thermale, à la sortie du griffon. In the state of the prior art, it is known that spa treatments must be carried out on site, and use only thermal water at the exit of the griffon.

De ce fait, les applications d'eau thermale sont effectuées sous une grande variété de formes : bain, douche, jet filiforme, etc., selon le cas à traiter. Dans tous les cas, ces traitements sont réalisés sous un flux continu d'eau thermale. As a result, thermal water applications are carried out in a wide variety of forms: bath, shower, filiform jet, etc., depending on the case to be treated. In all cases, these treatments are carried out under a continuous flow of thermal water.

Il existe une technique particulière de soin, qui recourt à l'application de boues. Ce procédé consiste à recouvrir tout ou partie d'un membre ou du corps, d'un produit pâteux préparé à partir d'eau thermale. There is a particular technique of care, which resorts to the application of sludge. This method consists in covering all or part of a limb or body, a pasty product prepared from thermal water.

Divers additifs sont utilisés : argiles, algues et mucilages divers. Ce produit pâteux permet de maintenir l'eau thermale au contact de la peau, sans flux continu, pendant un temps prolongé. n peut en outre servir de véhicule à d'autres substances susceptibles d'ajouter leur effet propre à celui de l'eau thermale.Various additives are used: clays, algae and various mucilages. This pasty product makes it possible to keep the thermal water in contact with the skin, without continuous flow, for a prolonged time. It can also serve as a vehicle for other substances that may add their own effect to that of thermal water.

Bien que fréquemment utilisé, ce procédé de traitement par la boue peut susciter quelques critiques - il s'éloigne largement du concept de base lié à l'emploi exclusif d'eau thermale, car la proportion d'eau est éloignée du maximum de 100 %, en raison de sa dilution par les additifs à rôle technique, tels que l'argile. Although frequently used, this sludge treatment process can cause some criticism - it largely departs from the basic concept of the exclusive use of thermal water because the proportion of water is far from the maximum of 100% , because of its dilution by technical role additives, such as clay.

Cette dilution peut aller de 12-15 % à 50 % selon les cas.This dilution can range from 12-15% to 50% depending on the case.

- il soulève des problèmes d'hygiène liés à la contamination microbienne des additifs diluants; ce risque est d'autant plus grand que ces additifs sont d'origine naturelle.- it raises hygiene problems related to the microbial contamination of diluent additives; this risk is all the greater as these additives are of natural origin.

- il impose des caractéristiques désagréables, sur le plan cosmétique, aux produits utilisés sous cette forme, qui peuvent justifier une répugnance ou un rejet de la part de nombreux utilisateurs.- it imposes unpleasant cosmetic characteristics on products used in this form, which may justify repugnance or rejection on the part of many users.

C'est dans ces circonstances que s'est posée la question de savoir s'il était possible d'obtenir un produit permettant d'appliquer l'eau thermale sous une forme s'inspirant de la boue, mais en évitant les défauts de ce produit. It was in these circumstances that the question arose as to whether it was possible to obtain a product for applying thermal water in a form inspired by mud, but avoiding the defects of product.

Il est bien connu que l'on peut utiliser des gélifiants pour augmenter la viscosité de l'eau et permettre d'obtenir une pâte adhérant à la surface de la peau. It is well known that gelling agents can be used to increase the viscosity of the water and to obtain a paste adhering to the surface of the skin.

Tous les gélifiants ont été essayés, de toute nature et de toute origine: - minérale : argiles, bentonites - végétale : gomme, mucilage, alginate, pectines, amidons, glucomanoses, galactomanoses - synthétique : cellulose et dérivés, etc. All the gelling agents have been tried, of all kinds and from all origins: - mineral: clays, bentonites - vegetable: gum, mucilage, alginate, pectins, starches, glucomanoses, galactomanoses - synthetic: cellulose and derivatives, etc.

Tous posent des problèmes qui rendent leur utilisation inadéquate: - soit parce que la préparation de la pâte imposait des contraintes : durée, agitation, chauffage, - soit parce que le produit additif ne permettait pas d'obtenir une pâte aux qualités souhaitées : viscosité, plasticité, absence d'effet collant, et de séchage, - soit parce que la dose efficace de l'additif entrainait une dilution de l'eau thermale incompatible avec notre objectif dépassant toujours 1 ou 2 %. All pose problems that make their use inadequate: - either because the preparation of the dough imposed constraints: time, stirring, heating, - or because the additive product did not make it possible to obtain a dough with the desired qualities: viscosity, plasticity, lack of sticky effect, and drying, - or because the effective dose of the additive caused a dilution of the thermal water incompatible with our objective always exceeding 1 or 2%.

Toutefois, un produit a permis d'obtenir un résultat satisfaisant contre toute attente, car il satisfait toutes les contraintes - action viscosante à une concentration inférieure ou égale à 1 % - propriétés rhéologiques et plastiques parfaites - excellentes qualités cosmétiques : gel hyalin incolore, rigide, non collant, facile à éliminer par simple essuyage - propreté microbiologique parfaite - rapidité et simplicité d'utilisation et possibilité de réaliser la préparation sans recourir à un équipement spécialisé. However, a product has made it possible to obtain a satisfactory result against all expectations, because it satisfies all the constraints - viscosifying action at a concentration of less than or equal to 1% - perfect rheological and plastic properties - excellent cosmetic qualities: colorless hyaline gel, rigid , non-sticky, easy to remove by simple wiping - perfect microbiological cleanliness - speed and simplicity of use and ability to prepare without the need for specialized equipment.

Le produit gélifiant qui a permis d'obtenir ce résultat surprenant est le carboxypolyméthylène, déjà utilisé comme agent épaississant et dispersant, stabilisant d'émulsion, mais jamais employé comme gélifiant d'eau pour application topique dans le cadre d'un soin thermal. The gelling agent which made it possible to obtain this surprising result is carboxypolymethylene, already used as a thickening and dispersing agent, emulsion stabilizer, but never used as a water gelling agent for topical application in the context of a thermal treatment.

Ce produit donne, dans cette application, le résultat étonnant de transformer l'eau en structure réticulée rigide; il permet dans le cas précis de l'invention, d'appliquer l'eau thermale en couche épaisse, alors que sa concentration n'excède pas 1%. This product gives, in this application, the astonishing result of transforming the water into a rigid reticulated structure; it allows in the specific case of the invention, to apply the thermal water in a thick layer, while its concentration does not exceed 1%.

Ce résultat imprévisible ouvre la possibilité nouvelle de réaliser de véritables "masques" ou cataplasmes ou bien des enveloppements d'eau thermale avec un produit constitué de 99 % au moins d'eau thermale. This unpredictable result opens the new possibility of real "masks" or poultices or thermal water wraps with a product consisting of at least 99% thermal water.

Selon la présente invention, la composition cosmétique se présente sous la forme d'un gel comprenant: - 99 % à 99,9 % en poids d'une eau thermale - 0,1 à 1 % en poids de carboxypolyméthylène - 0 à 1% en poids d'un agent neutralisant. According to the present invention, the cosmetic composition is in the form of a gel comprising: - 99% to 99.9% by weight of a thermal water - 0.1 to 1% by weight of carboxypolymethylene - 0 to 1% by weight of a neutralizing agent.

Selon une autre caractéristique de la présente invention, ledit gel comprend: - 99,25 à 99,75 % en poids d'une eau thermale - 0,25 à 0,75 % en poids de carboxypolyméthylène - 0 à 1 % en poids d'un agent neutralisant. According to another characteristic of the present invention, said gel comprises: - 99.25 to 99.75% by weight of a thermal water - 0.25 to 0.75% by weight of carboxypolymethylene - 0 to 1% by weight of a neutralizing agent.

Selon un mode de réalisation particulier, la composition est additionnée de 0,1 à 1 % en poids d'un agent neutralisant permettant d'obtenir un gel ayant un pH compris entre 5 et 8. According to a particular embodiment, the composition is added with 0.1 to 1% by weight of a neutralizing agent making it possible to obtain a gel having a pH of between 5 and 8.

Ledit agent neutralisant est avantageusement du bicarbonate de sodium, et peut le cas échéant être apporté par l'eau thermale. Said neutralizing agent is advantageously sodium bicarbonate, and may optionally be provided by thermal water.

Le carboxypolyméthylène, encore dénommé carboxyvinylpolymère ou carbomère, est un polymère de l'acide acrylique présentant la structure générale

Figure img00030001
Carboxypolymethylene, also called carboxyvinylpolymer or carbomer, is a polymer of acrylic acid having the general structure
Figure img00030001

Le poids moléculaire approximatif des carboxypolyméthylènes utilisables dans le cadre de la présente invention sera avantageusement compris entre 450 000 et 4 000 000. Le carboxypolyméthylène sera de préférence choisi parmi le CarbopolS 910, le Carbopol 907, le Carbopol 3; 934, le CarbopolS 934P, le CarbopolS 940, ainsi que leurs mélanges. The approximate molecular weight of the carboxypolymethylenes which can be used in the context of the present invention will advantageously be between 450,000 and 4,000,000. The carboxypolymethylene will preferably be chosen from CarbopolS 910, Carbopol 907 and Carbopol 3; 934, CarbopolS 934P, CarbopolS 940, and mixtures thereof.

La présente invention concerne également un procédé de préparation, caractérisé en ce que l'on mélange intimement le carboxypolyméthylène et l'eau, dans laquelle éventuellement l'agent neutralisant a été préalablement introduit, puis on abandonne le mélange pendant une durée suffisante pour que la structure du gel se développe. The present invention also relates to a preparation process, characterized in that the carboxypolymethylene is intimately mixed with water, in which optionally the neutralizing agent has been introduced beforehand, and then the mixture is left for a sufficient time so that the Gel structure develops.

Les exemples ci-après illustreront de façon non limitative l'objet de la présente invention.  The examples below will illustrate in a non-limiting way the object of the present invention.

* Exemple 1:
- CarbopolX 934 0,5 % g
- eau thermale (Avène(X9) 99,1 % g
- agent neutralisant CSP pH 7
(bicarbonate de sodium 0,4 % g)
On mélange et on laisse gonfler pendant environ 1 H.
* Example 1:
- CarbopolX 934 0.5% g
- thermal water (Avène (X9) 99.1% g
- neutralizing agent CSP pH 7
(sodium bicarbonate 0.4% g)
Mix and allow to swell for about 1 h.

* Exemple 2: - CarbopolS 940 0,40 % g - eau thermale (AvèneB) 99,35 % g - agent neutralisant CSP pH 6
(bicarbonate de sodium 0,25 % g)
On mélange et on laisse gonfler pendant environ 45 min.
* Example 2: - CarbopolS 940 0.40% g - thermal water (AvèneB) 99.35% g - neutralizing agent CSP pH 6
(sodium bicarbonate 0.25% g)
Mix and allow to swell for about 45 minutes.

Il faut noter que l'effet de gélification du CarbopolS à très faible dose est optimal pour des concentrations comprises entre 0,10 % et 1 % et plus particulièrement entre 0,25 % et 0,75 %. It should be noted that the gelling effect of CarbopolS at very low dose is optimal for concentrations of between 0.10% and 1% and more particularly between 0.25% and 0.75%.

Cet effet est révélé par addition d'un agent chimique alcalin dont la fonction est de neutraliser le CarbopolS acide, de façon à obtenir une pH adéquat qui peut être choisi entre 5 et 8. This effect is revealed by addition of an alkaline chemical agent whose function is to neutralize the acidic CarbopolS, so as to obtain a suitable pH which can be chosen between 5 and 8.

Selon un mode de réalisation particulier, on utilisera le bicarbonate de sodium, qui est bien connu pour son innocuité, sa parfaite tolérance. En outre, il peut également être un constituant naturel présent en quantité suffisante dans certaines eaux thermales. According to a particular embodiment, use sodium bicarbonate, which is well known for its safety, its perfect tolerance. In addition, it can also be a natural constituent present in sufficient quantity in certain thermal waters.

Les tests réalisés avec les compositions objet de la présente invention ont révélé une bonne tolérance locale, une application aisée et de bons résultats pharmaco-cliniques. The tests carried out with the compositions which are the subject of the present invention have revealed a good local tolerance, easy application and good pharmaco-clinical results.

Applications
Il convient en outre de relever que les compositions selon l'invention peuvent correspondre à une préparation extemporanée d'un produit d'application d'eau thermale, conservant les qualités de l'eau et appliqué sur le site sous forme d'illutation.
applications
It should further be noted that the compositions according to the invention may correspond to an extemporaneous preparation of a thermal water application product, retaining the qualities of water and applied to the site in the form of illutation.

Il peut aussi s'agir d'un produit destiné à l'application à domicile, sous forme ambulatoire d'eau thermale. Dans ce cas, le gel est préparé stérilement, ou est stérilisé par rayonnement après son conditionnement. It can also be a product intended for home application, in the form of outpatient thermal water. In this case, the gel is sterilized, or is sterilized by radiation after its conditioning.

n peut aussi être additionné d'un conservateur.n can also be added a preservative.

Pour la commodité de l'utilisateur, le produit peut être présenté cn conditionnement monodose, contenant la quantité à appliquer.  For the convenience of the user, the product may be presented as a single dose package containing the amount to be applied.

A titre d'exemples d'eaux thermales utilisables selon l'invention, on mentionnera: Avène, La Roche Posay, Molite les bains, Uriage, Amélie,
St Gervais, La Boulbenne, Cartera, Verduzan, Les Fumades, Neyrac,
Rochefort, St Christan, Tercis, St Paul les Dax, Barbotant, La Leclère,
Rogrère, Amélie Dax, Balaruc, Aix, EugénieX, Digne, Graux
As examples of thermal waters that may be used according to the invention, mention may be made of: Avène, La Roche Posay, Molite baths, Uriage, Amelie,
St Gervais, Boulbenne, Cartera, Verduzan, The Fumades, Neyrac,
Rochefort, St Christan, Tercis, St. Paul the Dax, Barbotant, La Leclere,
Rogrère, Amelie Dax, Balaruc, Aix, EugenieX, Digne, Graux

Claims (8)

REVENDICATIONS 1. Composition cosmétique se présentant sous la forme d'un gel comprenant: - 99 % à 99,9 % en poids d'une eau thermale - 0,1 à 1 % en poids de carboxypolyméthylène - 0 à 1% en poids d'un agent neutralisant. 1. Cosmetic composition in the form of a gel comprising: - 99% to 99.9% by weight of a thermal water - 0.1 to 1% by weight of carboxypolymethylene - 0 to 1% by weight of a neutralizing agent. 2. Composition cosmétique selon la revendication 1, caractérisée en ce que ledit gel comprend: - 99,25 à 99,75 % en poids d'une eau thermale - 0,25 à 0,75 % en poids de carboxypolyméthylène - 0 à 1 % en poids d'un agent neutralisant. 2. Cosmetic composition according to claim 1, characterized in that said gel comprises: - 99.25 to 99.75% by weight of a thermal water - 0.25 to 0.75% by weight of carboxypolymethylene - 0 to 1 % by weight of a neutralizing agent. 3. Composition cosmétique selon les revendications 1 et 2, caractérisée en ce qu'elle est additionnée de 0,1 à 1 % en poids d'un agent neutralisant permettant d'obtenir un gel ayant un pH compris entre 5 et 8. 3. Cosmetic composition according to claims 1 and 2, characterized in that it is added 0.1 to 1% by weight of a neutralizing agent for obtaining a gel having a pH of between 5 and 8. 4. Composition cosmétique selon la revendication 3, caractérisée en ce que ledit agent neutralisant est du bicarbonate de sodium. 4. Cosmetic composition according to claim 3, characterized in that said neutralizing agent is sodium bicarbonate. 5. Composition cosmétique selon les revendications 1 et 2, caractérisée en ce que l'agent neutralisant est apporté par l'eau thermale. 5. Cosmetic composition according to claims 1 and 2, characterized in that the neutralizing agent is provided by the thermal water. 6. Composition cosmétique selon les revendications 1 à 5, caractérisée en ce que le carboxypolyméthylène est choisi parmi le CarbopolS 910, le CarbopolB 907, le CarbopolS 934, le CarbopolS 934P, le CarbopoltD 940, ainsi que leurs mélanges. 6. Cosmetic composition according to claims 1 to 5, characterized in that the carboxypolymethylene is selected from CarbopolS 910, CarbopolB 907, CarbopolS 934, CarbopolS 934P, CarbopoltD 940, and mixtures thereof. 7. Composition cosmétique selon l'une des revendications 1 à 6, caractérisée en ce que l'eau thermale est choisie parmi les eaux thermales suivantes : Avène, La Roche PosayB, Molite les bains, Uriage, Amélie, St 7. Cosmetic composition according to one of claims 1 to 6, characterized in that the thermal water is selected from the following thermal waters: Avene, La Roche PosayB, Molite baths, Uriage, Amelie, St Gervais, La Boulbenne, Cartera, Verduzan, Les Fumades, Neyrac, Rochefort,Gervais, La Boulbenne, Cartera, Verduzan, The Fumades, Neyrac, Rochefort, St Christan, Tercis, St Paul les Dax, Barbotant, La Leclère, Rogrère, AmélieSt Christan, Tercis, St Paul the Dax, Barbotant, La Leclere, Rogrère, Amelie Dax, Balaruc, Aix, Eugénie, Digne, Graux Dax, Balaruc, Aix, Eugenie, Worthy, Graux 8. Procédé de préparation d'une composition cosmétique selon les revendications 1 à 6, caractérisé en ce que l'on mélange intimement le carboxypolyméthylène et l'eau, éventuellement additionnée d'un agent neutralisant, puis on abandonne le mélange pendant une durée suffisante pour que la structure de gel se développe.  8. Process for the preparation of a cosmetic composition according to claims 1 to 6, characterized in that the carboxypolymethylene is intimately mixed with water, optionally with a neutralizing agent, and then the mixture is left for a sufficient period of time. for the gel structure to develop.
FR9313636A 1993-11-16 1993-11-16 Cosmetic compositions based on thermal waters and their preparation process. Expired - Lifetime FR2712492B1 (en)

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FR9313636A FR2712492B1 (en) 1993-11-16 1993-11-16 Cosmetic compositions based on thermal waters and their preparation process.
PCT/FR1994/001328 WO1995013793A1 (en) 1993-11-16 1994-11-15 Spa water based cosmetic compositions and method for preparing same

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US6649176B1 (en) 2000-06-29 2003-11-18 Johnson & Johnson Consumer Companies, Inc. Compositions containing mineral water
US6630175B1 (en) 2000-06-29 2003-10-07 Johnson & Johnson Consumer Companies, Inc. Method of reducing eye irritation
US6372791B1 (en) 2000-06-29 2002-04-16 Johnson & Johnson Consumer Companies, Inc. Method of promoting skin cell metabolism
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US6432424B1 (en) 2000-06-29 2002-08-13 Johnson & Johnson Consumer Companies, Inc. Cosmetic compositions containing creatine, carnitine, and/or pyruvic acid
AT507845B1 (en) 2009-02-12 2012-05-15 Lengheim Hubert COSMETIC PREPARATION FOR SKIN CARE
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RO65077A2 (en) * 1975-06-27 1979-02-15 Miraj Cosmetice MASK OF BEAUTY FOR FAT AND NATURAL TEINT
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Publication number Priority date Publication date Assignee Title
RO65077A2 (en) * 1975-06-27 1979-02-15 Miraj Cosmetice MASK OF BEAUTY FOR FAT AND NATURAL TEINT
WO1992006666A1 (en) * 1990-10-17 1992-04-30 Pierre Fabre Cosmetique Dna gel stabilized thermal water liposomes

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* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 93, no. 18, November 1980, Columbus, Ohio, US; abstract no. 173616, SPETEANU ET AL.: "BEAUTY MASK FOR THE CARE OF OILY AND NORMAL COMPLEXIONS" *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013088063A1 (en) * 2011-12-16 2013-06-20 Laboratoires M&L Cosmetic composition containing thyme honey and neyrac mineral water
FR2984151A1 (en) * 2011-12-16 2013-06-21 Melvita Production COSMETIC COMPOSITION COMPRISING THYME HONEY AND WHICH MAY INCLUDE NEYRAC THERMAL WATER

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FR2712492B1 (en) 1996-02-09

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