FR2576749A1 - Product based on algae and aluminium chloride, application as fungicide or bactericide and process for treating plants using such a product - Google Patents
Product based on algae and aluminium chloride, application as fungicide or bactericide and process for treating plants using such a product Download PDFInfo
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- FR2576749A1 FR2576749A1 FR8501580A FR8501580A FR2576749A1 FR 2576749 A1 FR2576749 A1 FR 2576749A1 FR 8501580 A FR8501580 A FR 8501580A FR 8501580 A FR8501580 A FR 8501580A FR 2576749 A1 FR2576749 A1 FR 2576749A1
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- sep
- algae
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- fungicide
- cream
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- 241000195493 Cryptophyta Species 0.000 title claims abstract description 28
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 title claims abstract description 22
- 230000000855 fungicidal effect Effects 0.000 title claims description 16
- 239000000417 fungicide Substances 0.000 title claims description 16
- 238000000034 method Methods 0.000 title claims description 9
- 230000008569 process Effects 0.000 title claims description 5
- 230000000844 anti-bacterial effect Effects 0.000 title description 4
- 239000003899 bactericide agent Substances 0.000 title description 3
- 239000006071 cream Substances 0.000 claims abstract description 16
- 238000011282 treatment Methods 0.000 claims abstract description 6
- 208000035143 Bacterial infection Diseases 0.000 claims abstract description 4
- 241001474374 Blennius Species 0.000 claims description 6
- 201000010099 disease Diseases 0.000 claims description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 3
- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical group [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 claims description 3
- 229920000940 maneb Polymers 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims 1
- 208000031888 Mycoses Diseases 0.000 abstract description 3
- 230000001580 bacterial effect Effects 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 16
- 241000233679 Peronosporaceae Species 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 241000196252 Ulva Species 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical class C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 2
- 238000004445 quantitative analysis Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000000108 ultra-filtration Methods 0.000 description 2
- XERJKGMBORTKEO-VZUCSPMQSA-N (1e)-2-(ethylcarbamoylamino)-n-methoxy-2-oxoethanimidoyl cyanide Chemical compound CCNC(=O)NC(=O)C(\C#N)=N\OC XERJKGMBORTKEO-VZUCSPMQSA-N 0.000 description 1
- 241000199898 Alaria <Phaeophyceae> Species 0.000 description 1
- 241001156002 Anthonomus pomorum Species 0.000 description 1
- 235000016425 Arthrospira platensis Nutrition 0.000 description 1
- 240000002900 Arthrospira platensis Species 0.000 description 1
- 241000512260 Ascophyllum Species 0.000 description 1
- 241001260842 Bifurcaria Species 0.000 description 1
- 241001465180 Botrytis Species 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 241001428407 Ceramium Species 0.000 description 1
- 241000206576 Chondrus Species 0.000 description 1
- 241001478778 Cladophora Species 0.000 description 1
- 239000005756 Cymoxanil Substances 0.000 description 1
- 241001403302 Cystoclonium Species 0.000 description 1
- 241000199920 Ectocarpus Species 0.000 description 1
- 241000195480 Fucus Species 0.000 description 1
- 241001134786 Furcellaria Species 0.000 description 1
- 241000206672 Gelidium Species 0.000 description 1
- 241001467355 Gigartina Species 0.000 description 1
- 241000206581 Gracilaria Species 0.000 description 1
- 241001262084 Himanthalia Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001466453 Laminaria Species 0.000 description 1
- 241000422392 Laurencia Species 0.000 description 1
- 241001428728 Lomentaria Species 0.000 description 1
- 101100272974 Panax ginseng CYP716A47 gene Proteins 0.000 description 1
- 241001635237 Paonias Species 0.000 description 1
- 241000212297 Pelvetia Species 0.000 description 1
- 241000233626 Plasmopara Species 0.000 description 1
- 241000206616 Rhodymenia Species 0.000 description 1
- 241000159614 Ulothrix Species 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000009646 cryomilling Methods 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 230000013872 defecation Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000006260 ethylaminocarbonyl group Chemical group [H]N(C(*)=O)C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000816 ethylene group Chemical class [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- AWYFNIZYMPNGAI-UHFFFAOYSA-N ethylenebis(dithiocarbamic acid) Chemical class SC(=S)NCCNC(S)=S AWYFNIZYMPNGAI-UHFFFAOYSA-N 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- MSXHSNHNTORCAW-MPGIDXPLSA-M sodium;(3s,4s,5s,6r)-3,4,5,6-tetrahydroxyoxane-2-carboxylate Chemical compound [Na+].O[C@@H]1OC(C([O-])=O)[C@@H](O)[C@H](O)[C@@H]1O MSXHSNHNTORCAW-MPGIDXPLSA-M 0.000 description 1
- 229940082787 spirulina Drugs 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- CHNQZRKUZPNOOH-UHFFFAOYSA-J zinc;manganese(2+);n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[Zn+2].[S-]C(=S)NCCNC([S-])=S.[S-]C(=S)NCCNC([S-])=S CHNQZRKUZPNOOH-UHFFFAOYSA-J 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/03—Algae
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Biotechnology (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Produit à base d'algues. aDplication comme fongicide ou bactéricide et procédé de traitement de plantes utilisant un tel produit.Product based on algae. aDplication as a fungicide or bactericide and a method of treating plants using such a product.
La présente invention a pour objet un produit à base d'algues, l'application de celui-ci comme fongicide ou bactéricide et un procédé de traitement des plantes, notamment des vignes, contre les maladies en particulier cryptogamiques, comme le mildiou, ou bactériennes. The present invention relates to a product based on algae, the application thereof as a fungicide or bactericide and a method of treating plants, especially vines, against diseases, particularly fungal diseases, such as downy mildew, or bacterial .
Etat de la technique
Plusieurs produits sont déjà connus pour avoir une telle activité fongicide ou bactéricide sur les plantes. Brièvement, et de manière sans doutenon exhaustive, on peut citer tes documents suivants.State of the art
Several products are already known to have such fungicidal or bactericidal activity on plants. Briefly, and without any doubt, the following documents can be cited.
Le brevet français n 2 308 312 décrit une composition fongicide contenant comme matiere active au moins un composé choisi dans le groupe comprenant l'acide hypophosphoreux et ses sels minéraux. French Patent No. 2,308,312 describes a fungicidal composition containing as active ingredient at least one compound selected from the group comprising hypophosphorous acid and its inorganic salts.
Le brevet français n 2 377 155 décrit une composition fongicide utile notamment contre le mildiou de La vigne contenant comme matière active un monoester de l'acide phosphoreux et un fongicide de -contact choisi dans le groupe comprenant les composé à base de cuivre, les éthylenes-bis-dithiocarbamates métalliques et Les dérivés de la phtalimide. French Patent No. 2,377,155 describes a fungicidal composition that is particularly useful against vine downy mildew containing as active ingredient a phosphorous acid monoester and a contact fungicide selected from the group consisting of copper-based compounds, ethylenes, and the like. metallic bis-dithiocarbamates and phthalimide derivatives.
On connaît également le 2-cyano-N-(éthyLaminocarbonyL)- 2-(méthoxySmino)acétamide commercialisé par la firme americaine
Du Pont de Nemours sous le nom de marque CYMOXANIL#. Son activité curative contre le mildiou est toutefois limitée par sa breve persistance d'action dans la plante.2-cyano-N- (ethylaminocarbonyl) -2- (methoxySmino) acetamide sold by the American firm is also known.
Du Pont de Nemours under the brand name CYMOXANIL #. Its curative activity against mildew is however limited by its short persistence of action in the plant.
Les brevets français n 2 414 301 et n 2 438 425 appartenant au déposant décrivent des compositions utilisabLes pour la lutte contre des maladies des plantes contenant comme principe actif une quantité efficace d'aluminium sous la forme de cations
AI CFR. 2 414 301) éventuellement en combinaison avec des anions
Cl ou P04 et un carbamate.French Patent Nos. 2 414 301 and 2 438 425 belonging to the applicant describe compositions which are usable for the control of plant diseases containing as active ingredient an effective amount of aluminum in the form of cations.
AI CFR. 2,414,301) optionally in combination with anions
Cl or PO4 and a carbamate.
Il a maintenant été découvert de manière surprenante que l'association, nouvelle en soi, de chlorure d'aluminium (ALCL3) et d'une creme d'algues produisait un effet de synergie important dans la lutte contre les maladies bactériennes ou cryptogamiques des plantes, notamment le mildiou. Le produit peut éventuellement comporter d'autres cations métalliques, par exemple sous La forme de chlorure. Parmi ceux-ci, on peut citer les ions Fe++, Cu++, Ti et Zr+++
On appelle crème d'algues le filtrat obtenu selon le procédé décrit dans la demande de brevet français n 83 19142. Cette crème pourra être également obtenue par lyophilisation ou par simpLe homogénéisation,mais avec de moins bons résultats.La demande n 83 19142 n'étant pas publiée à cette date, on rappelle ci-après les principales caractéristiques de ce procédé. Les algues entières sont traitées par la combinaison des étapes suivantes
a > cryobroyage- (congélation des algues ou plantes coupées à -20/-500C, puis broyage à cette température dans un broyeur à couteaux ou à dents, puis dans un ou plusieurs broyeurs à la température ambiante) donnant une bouillie de dimension.de particules 100 à 50 ou 10 ; b) brovaae moléculaire:
c) décantation 9 erande vitesse;
d) ultrafiltration et récupération du filtrat liquide stérile ainsi obtenu.It has now surprisingly been discovered that the association, new in itself, of aluminum chloride (ALCL3) and an algae cream produced an important synergistic effect in the fight against plant bacterial or fungal diseases. , especially mildew. The product may optionally comprise other metal cations, for example in the form of chloride. Among these, we can mention Fe ++, Cu ++, Ti and Zr +++ ions.
The filtrate obtained according to the process described in French Patent Application No. 83 19142 is called algae cream. This cream may also be obtained by lyophilization or by simple homogenization, but with less good results. Application No. 83 19142 being not published at this date, we recall below the main characteristics of this process. Whole algae are treated by the combination of the following steps
a> freeze-crushing (freezing of algae or cut plants at -20 / -500C, then grinding at this temperature in a knife mill or tooth mill, then in one or more mills at room temperature) giving a slurry of dimension.de particles 100 to 50 or 10; b) molecular brovae:
(c) decantation at high speed;
d) ultrafiltration and recovery of the sterile liquid filtrate thus obtained.
On peut également utiliser le jus de décantation de l'étape c) appelé "protoexoplasma" comme produit à base d'algues. It is also possible to use the settling juice of step c) called "protoexoplasma" as a product based on algae.
Parmi les aLgues convenant pour la présente invention, on peut citer : Ulva, Enteromorpha, Laminaria, Cladophora,
Rhodymenia, Chodium, Chondrus, Lomentaria, Fucus, Gastrocelonium,
Spirulina, Ceramium, Bracchiomonas, Ectocarpus, Platymonia, Paonia,
ULothrix, Coradophylum, Alaria, Pelvetia, HimanthaLia, Bifurcaria,
Cystosera, Gelidium, Dilcea, Furcellaria, Cystoclonium, Gigartina,
Callibepharis, Gracilaria, Paliara, Laurencia, Ascophyllum, Nodosum.Among the compounds suitable for the present invention, mention may be made of: Ulva, Enteromorpha, Laminaria, Cladophora,
Rhodymenia, Chodium, Chondrus, Lomentaria, Fucus, Gastrocelonium,
Spirulina, Ceramium, Bracchiomonas, Ectocarpus, Platymonia, Paonia,
ULothrix, Coradophylum, Alaria, Pelvetia, HimanthaLia, Bifurcaria,
Cystosera, Gelidium, Dilcea, Furcellaria, Cystoclonium, Gigartina,
Callibepharis, Gracilaria, Paliara, Laurencia, Ascophyllum, Nodosum.
De préférence la crème d'aLgues doit etre telle que l'anaLyse quantitative soit relativement proche de celle donnée à L'exemple 1 c-aprés. Preferably the cream of algae should be such that the quantitative analysis is relatively close to that given in Example 1 below.
SeLon l'utilisation du produit il est possibLe de faire varier les proportions relatives de crème d'algues et de chlorure d'aluminium à l'intérieur d'une fourchette très Large. Depending on the use of the product it is possible to vary the relative proportions of algae cream and aluminum chloride within a very wide range.
Toutefois, avantageusement, on préférera les proportions suivantes (en pourcentage en poids)
90 à 10% de crème d'algues
10 à 90% d'aluminium et de préférence 30 à 70 de crème d'algues et 70 à 30 de chlorure d'aluminium.However, advantageously, the following proportions (in percentage by weight) will be preferred.
90 to 10% seaweed cream
10 to 90% of aluminum and preferably 30 to 70 of seaweed cream and 70 to 30 of aluminum chloride.
Le produit peut également contenir un fongicide, de préférence de contact. Parmi ceux-ci on peut citer 4 les composés a base de cuivre, les éthylènes-bis-dithiocarbamates métaLliques comme L'éthyléne-bis-dithiocarbamate de zinc et de manganèse ou "mancozebe". Le manèbe s'est révélé particulièrement intéressant. Les dérivés de la phtalimide peuvent également être utilisés dans le cadre de l'invention. On pourra trouver une Liste détaittée de ces fongicides de contact dans le brevet français n 2 377 155. The product may also contain a fungicide, preferably a fungicide. Among these are copper-based compounds, metal ethylene-bis-dithiocarbamates such as zinc-manganese ethylene-bis-dithiocarbamate or "mancozebe". Maneb has proved particularly interesting. The phthalimide derivatives can also be used in the context of the invention. A list of these contact fungicides can be found in French Patent No. 2,377,155.
De préférence Le fongicide est utilisé avec le produit à base d'algues dans une proportion comprise entre 10% et 90% en poids par rapport au poids total crème d'algues et chlorure d'aluminium et de préférence entre 30 et 70x. Preferably the fungicide is used with the algae product in a proportion of between 10% and 90% by weight relative to the total weight of algae cream and aluminum chloride and preferably between 30 and 70x.
Les produits décrits ci-dessus se sont révélés d'excellents fongicides, notamment pour traiter le mildiou ou Le botrytis des vignes ainsi que pour traiter l'excoriose, le black-rot ou le brenner. L'invention a également pour objet un procédé de traitement des plantes, notamment des vignes, contre les maladies, particulier cryptogamiques et bactériennes, caractérisé en ce que l'on associe à ces plantes l'un des produits cités ci-dessus. The products described above have proven to be excellent fungicides, especially for treating late blight or botrytis in vines as well as for treating excoriosis, black rot or brenner. The subject of the invention is also a method for treating plants, especially vines, against diseases, particularly cryptogamic and bacterial diseases, characterized in that one associates with these plants one of the products mentioned above.
Le déport peut être effectuée manière diverse, mais on proférera la pulvérisation d'une solution, de préférence aqueuse. The offset can be carried out in a variety of ways, but the spraying of a solution, preferably an aqueous one, will be carried out.
Avantageusement, on utilisera 0,2 à 20 kg de produit à base d'algues par hectare de vigne et avantageusement entre 2 et 20 kg et mieux 6 et 12 kg. Advantageously, use will be made of 0.2 to 20 kg of algae product per hectare of vine and advantageously between 2 and 20 kg and better 6 and 12 kg.
L'exemple ci-dessous illustre l'invention. The example below illustrates the invention.
Une crème d'algues préparée par cryobroyage, broyage moléculaire, décantation à grande vitesse et ultrafiltration répond à l'analyse quantitative suivante : - Sodium (Na) mg/kg i 210 - Potassium (K) " 690 - Calcium (Ca) " 450 - Magnésium (Mg) " 20 000 - Strontium (Sr) " 7 - Plomb (Pb) " 8 - Cadmium (Ca) " 0,85 - Cuivre (Cu) " 550 - Zinc (Zh) " 22 000 - Fer (Fe) " 880 - Manganèse (Mn) " 1 700 - Etain (Sn) " # 4 - Arsenic (As) " 1,0 - Soufre (S04) " 142 000 - Bore (B) @ " 58 - Chlore (Ci) " 11 300 - Iode (I) i' 18 - Fluore (F) " - Azote (N) " 30 500 - Phosphore (P) " 27 - Brome (Br) " < 2
On mélange cette crème avec du chlorure d'atu- minium de manière que L'on ait 300 g de crème d'algues, 293 g de AlCl3 par titre.A seaweed cream prepared by cryomilling, molecular grinding, high-speed settling and ultrafiltration meets the following quantitative analysis: Sodium (Na) mg / kg i 210 - Potassium (K) "690 - Calcium (Ca)" 450 - Magnesium (Mg) "20,000 - Strontium (Sr)" 7 - Lead (Pb) "8 - Cadmium (Ca)" 0.85 - Copper (Cu) "550 - Zinc (Zh)" 22,000 - Iron (Fe) ) "880 - Manganese (Mn)" 1700 - Tin (Sn) "# 4 - Arsenic (As)" 1.0 - Sulfur (SO4) "142,000 - Boron (B) @" 58 - Chlorine (Ci) " 11 300 - Iodine (I) 18 - Fluorine (F) "- Nitrogen (N)" 500 - Phosphorus (P) "27 - Bromine (Br)"<2
This cream is mixed with atu- mium chloride so that one has 300 g of seaweed cream, 293 g of AlCl 3 per title.
Le liquide est mélangé,la piupart du temps lors de l'utilisation, avec 35 g de manèbe pour de liquide. Ce produit est dilué dans l'eau à raison de 0,850 g/hl. The liquid is mixed, most of the time during use, with 35 g of maneb for liquid. This product is diluted in water at a rate of 0.850 g / hl.
La solution est pulvérisée sur des vignes de type
Sémillon contaminées par le parasite Plasmopora viticola. La contanina- tion est effectuée avec des souches résistantes aux fongicides anitides :
a) sur Les feuilles, au jour J (10 juin)
b) sur les grappes,au jour J + 33
Le traitement est effectué par pulvérisation à pression à jet projeté à raison de 1 000 l/ha, appareil à dos, tous
Les 14 jours de J-16 à J+55 environ. (La défeuiLlaison intervient à
J+135).The solution is sprayed on vines of type
Sémillon contaminated with the parasite Plasmopora viticola. Contamination is carried out with strains resistant to fungicides anitides:
a) on the leaves, on the day (June 10)
b) on the bunches, on day D + 33
The treatment is carried out by spray jet spray at a rate of 1000 l / ha, backpack, all
14 days from D-16 to D + 55 approximately. (The defeuiLlaison intervenes at
J + 135).
On note ensuite
- Le pourcentage du nombre de grappes malades
- le pourcentage de dégäts moyens par grappe
- le pourcentage de dégâts sur le feuillage
La notation se fait selon La méthode statistique A-F-V.We then note
- The percentage of the number of sick bunches
- the percentage of average defects per cluster
- the percentage of damage on the foliage
The rating is according to the statistical method AFV.
Les résultats sont réunis dans le tableau ci-après : TABLEAU
Mildiou <SEP> grappes <SEP> J+75 <SEP> Mildiou <SEP> feuilles <SEP> J+83 <SEP> Mildiou <SEP> feuilles <SEP> J+103
<tb> Défeuillaison
<tb> Traitements <SEP> Nbre <SEP> grappes <SEP> Dégâts <SEP> Bas <SEP> Haut <SEP> Bas <SEP> Haut
<tb> (doses <SEP> kg <SEP> ou <SEP> 1/ha) <SEP> malades
<tb> "Bliss <SEP> p.cent <SEP> Note <SEP> p.cent <SEP> Note <SEP> p.cent <SEP> Note <SEP> p.cent <SEP> Note <SEP> p.cent <SEP> Note <SEP> p.cent <SEP> Note <SEP> p.cent
<tb> TENOIN <SEP> NON <SEP> TRAITE <SEP> 90 <SEP> 100 <SEP> 7,03 <SEP> 85,30 <SEP> 7,83 <SEP> 93 <SEP> 9 <SEP> 97,5 <SEP> 7,92 <SEP> 94,40 <SEP> 9,25 <SEP> 98,12 <SEP> 7,67 <SEP> 92
<tb> Mancozebe <SEP> 0,350 <SEP> 66,52 <SEP> 84,10 <SEP> 1,83 <SEP> 4,65 <SEP> 2,16 <SEP> 7 <SEP> 5,83 <SEP> 66 <SEP> 2,92 <SEP> 14,20 <SEP> 8,08 <SEP> 95,25 <SEP> 2,67 <SEP> 12
<tb> Produit <SEP> à <SEP> base <SEP> 0,500
<tb> #d'algues <SEP> 0,175# <SEP> 75,10 <SEP> 93,40 <SEP> 1,94 <SEP> 4,85 <SEP> 2 <SEP> 5 <SEP> 4,83 <SEP> 46 <SEP> 1,67 <SEP> 4,17 <SEP> 5,17 <SEP> 53,40 <SEP> 2,67 <SEP> 12
<tb> Manébe
<tb> F. <SEP> calculé <SEP> 8,92 <SEP> 54,92 <SEP> 97,64 <SEP> 17,18 <SEP> 112,70 <SEP> 32,30 <SEP> 21,60
<tb> F.tables <SEP> 3,38 <SEP> 3,38 <SEP> 3,38 <SEP> 3,38 <SEP> 3,38 <SEP> 3,38 <SEP> 3,38
<tb> P <SEP> P <SEP> D <SEP> S <SEP> P <SEP> = <SEP> 0,01 <SEP> 17,97 <SEP> 0,99 <SEP> 0,80 <SEP> 1,18 <SEP> 0,73 <SEP> 0,90 <SEP> 7,25
<tb> PPDS : Plus petite différence significative
Le mildiou a envahi très gravement l'essai à la suite des contaminations artificielles à J et J+33.Downy mildew <SEP> bunches <SEP> D + 75 <SEP> Downy mildew <SEP> leaves <SEP> D + 83 <SEP> Downy mildew <SEP> leaves <SEP> D + 103
<tb> Defecation
<tb> Treatments <SEP> Number <SEP> Clusters <SEP> Damage <SEP> Low <SEP> High <SEP> Low <SEP> Top
<tb> (doses <SEP> kg <SEP> or <SEP> 1 / ha) <SEP> Sick
<tb>"Bliss<SEP> p.cent <SEP> Note <SEP> p.cent <SEP> Note <SEP> p.cent <SEP> Note <SEP> p.cent <SEP> Note <SEP> p. cent <SEP> Note <SEP> p.cent <SEP> Note <SEP> p.cent
<tb> TENOIN <SEP> NO <SEP> TREATED <SEP> 90 <SEP> 100 <SEP> 7.03 <SEP> 85.30 <SEP> 7.83 <SE> 93 <SEP> 9 <SEP> 97 , 5 <SEP> 7.92 <SEP> 94.40 <SEP> 9.25 <SEP> 98.12 <SEP> 7.67 <SE> 92
<tb> Mancozebe <SEP> 0.350 <SEP> 66.52 <SEP> 84.10 <SEP> 1.83 <SEP> 4.65 <SEP> 2.16 <SEP> 7 <SEP> 5.83 <SEP > 66 <SEP> 2.92 <SEP> 14.20 <SEP> 8.08 <SEP> 95.25 <SEP> 2.67 <SEP> 12
<tb> Product <SEP> to <SEP> base <SEP> 0.500
<tb># Algae <SEP> 0.175 # <SEP> 75.10 <SEP> 93.40 <SEP> 1.94 <SEP> 4.85 <SEP> 2 <SEP> 5 <SEP> 4.83 <SEP> 46 <SEP> 1.67 <SEP> 4.17 <SEP> 5.17 <SEP> 53.40 <SEP> 2.67 <SEP> 12
<tb> Manebe
<tb> F. <SEP> calculated <SEP> 8.92 <SEP> 54.92 <SEP> 97.64 <SEP> 17.18 <SEP> 112.70 <SEP> 32.30 <SEP> 21, 60
<tb> F.tables <SEP> 3.38 <SEP> 3.38 <SE> 3.38 <SE> 3.38 <SE> 3.38 <SE> 3.38 <SE> 3.38
<tb> P <SEP> P <SEP> D <SEP> S <SEP> P <SEP> = <SEP> 0.01 <SEP> 17.97 <SEP> 0.99 <SEP> 0.80 <SEP > 1.18 <SEP> 0.73 <SEP> 0.90 <SEP> 7.25
<tb> PPDS: Smallest significant difference
Mildew invaded the test very severely following artificial contaminations on D and D + 33.
A J+83, les parcelles non traitées présentaient 100% de grappes malades et préside 85% de dégâts. Le feuillage était également fortement atteint. A la fin d'août, il était pratiquement détruit. At D + 83, the untreated plots had 100% diseased bunches and 85% of the damage. The foliage was also strongly affected. By the end of August, it was practically destroyed.
Dans ces conditions très sévères, le mancozebe, produit de référence, assure une protection suffisante des grappes avec cependant un nombre de grappes malades relativement élevé dû à l'intervalle de 14 jours entre les traitements. Under these very severe conditions, the reference product, mancozebe, provides sufficient protection for clusters with, however, a relatively high number of diseased clusters due to the 14-day interval between treatments.
Le mélange produit à base d'algues + manèbe se comporte à peu près comme la référence pour la protection des grappes et des feuilles, mais il apparaît très nettement à l'examen des feuilles de l'extrémité des rameaux que Le produit agit également à distance, peut-être par systémie. En effet, à J+83 et plus nettement encore à J+103, on observe une très bonne tenue du feuiLlage de l'extrémité des rameaux, avec une attaque de mildiou fortement réduite par rapport à celle des parcelles traitées avec le produit de référence. The seaweed + manbebe mixture behaves much like the reference for the protection of bunches and leaves, but it is very obvious when the leaves of the tips of the twigs are examined that distance, perhaps by system. Indeed, at D + 83 and even more clearly at D + 103, we observe a very good resistance of the foliage of the end of the branches, with an attack of mildew strongly reduced compared to that of the plots treated with the product of reference .
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8501580A FR2576749B1 (en) | 1985-02-05 | 1985-02-05 | PRODUCT BASED ON ALGAE AND ALUMINUM CHLORIDE, APPLICATION AS FUNGICIDE OR BACTERICIDE AND METHOD FOR TREATING PLANTS USING SUCH A PRODUCT |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8501580A FR2576749B1 (en) | 1985-02-05 | 1985-02-05 | PRODUCT BASED ON ALGAE AND ALUMINUM CHLORIDE, APPLICATION AS FUNGICIDE OR BACTERICIDE AND METHOD FOR TREATING PLANTS USING SUCH A PRODUCT |
| EP86401596A EP0253035A1 (en) | 1986-07-17 | 1986-07-17 | Algae-based product, its use as a fungicide or bactericide and process for treating plants using such a product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2576749A1 true FR2576749A1 (en) | 1986-08-08 |
| FR2576749B1 FR2576749B1 (en) | 1987-04-30 |
Family
ID=26105870
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8501580A Expired FR2576749B1 (en) | 1985-02-05 | 1985-02-05 | PRODUCT BASED ON ALGAE AND ALUMINUM CHLORIDE, APPLICATION AS FUNGICIDE OR BACTERICIDE AND METHOD FOR TREATING PLANTS USING SUCH A PRODUCT |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2576749B1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0253035A1 (en) * | 1986-07-17 | 1988-01-20 | Goemar S.A. | Algae-based product, its use as a fungicide or bactericide and process for treating plants using such a product |
| FR2741238A1 (en) * | 1995-11-17 | 1997-05-23 | Goemar Lab Sa | USE OF ALUMINUM CHLORIDE AS AN ELICITOR OF RESVERATROL SYNTHESIS |
| FR2748631A1 (en) * | 1996-05-15 | 1997-11-21 | Agrocean | Algae composition increasing cellular permeability of plants |
| WO1999053761A1 (en) * | 1998-04-16 | 1999-10-28 | Aventis Cropscience S.A. | Novel use of antifungal and/or antibacterial and/or antiviral compounds |
| ES2237318A1 (en) * | 2003-11-19 | 2005-07-16 | Servalesa, S.L. | PROCEDURE FOR OBTAINING AN ORGANIC ALUMINUM-BASED PRODUCT FOR THE SELF-DEFENSE OF PLANTS AGAINST PATHOGENS FOR ECOLOGICAL TRADITIONAL AGRICULTURE. |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3891756A (en) * | 1973-05-21 | 1975-06-24 | Mitsubishi Chem Ind | Agricultural pesticide composition |
| FR2414301A1 (en) * | 1978-01-16 | 1979-08-10 | Temz Mor Algues | Trivalent aluminium cation compsns. - for protection of plants against microorganism esp. Botrytis |
| FR2438425A2 (en) * | 1978-10-10 | 1980-05-09 | Temz Mor Algues | Aluminium carbamate and chloride or phosphate compsn. - used to control plant fungal diseases |
| EP0060121A1 (en) * | 1981-03-09 | 1982-09-15 | University Of Hawaii | Cyclic peptide and its use as a fungicide |
-
1985
- 1985-02-05 FR FR8501580A patent/FR2576749B1/en not_active Expired
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3891756A (en) * | 1973-05-21 | 1975-06-24 | Mitsubishi Chem Ind | Agricultural pesticide composition |
| FR2414301A1 (en) * | 1978-01-16 | 1979-08-10 | Temz Mor Algues | Trivalent aluminium cation compsns. - for protection of plants against microorganism esp. Botrytis |
| FR2438425A2 (en) * | 1978-10-10 | 1980-05-09 | Temz Mor Algues | Aluminium carbamate and chloride or phosphate compsn. - used to control plant fungal diseases |
| EP0060121A1 (en) * | 1981-03-09 | 1982-09-15 | University Of Hawaii | Cyclic peptide and its use as a fungicide |
Non-Patent Citations (1)
| Title |
|---|
| CHEMICAL ABSTRACTS, vol. 95, 1981, réf. no. 147021c, page 336, Columbus, Ohio, US; K. BENDERLIEV et al.: "Coagulation of Chlorella vulgaris var. vulgaris Beijer with iron(III) chloride and aluminum chloride" & KHIDROBIOLOGIYA 1981, 13, 27-32 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0253035A1 (en) * | 1986-07-17 | 1988-01-20 | Goemar S.A. | Algae-based product, its use as a fungicide or bactericide and process for treating plants using such a product |
| FR2741238A1 (en) * | 1995-11-17 | 1997-05-23 | Goemar Lab Sa | USE OF ALUMINUM CHLORIDE AS AN ELICITOR OF RESVERATROL SYNTHESIS |
| WO1997018715A1 (en) * | 1995-11-17 | 1997-05-29 | Laboratoires Goemar S.A. | Use of aluminium chloride as a resveratrol synthesis elicitor |
| FR2748631A1 (en) * | 1996-05-15 | 1997-11-21 | Agrocean | Algae composition increasing cellular permeability of plants |
| WO1999053761A1 (en) * | 1998-04-16 | 1999-10-28 | Aventis Cropscience S.A. | Novel use of antifungal and/or antibacterial and/or antiviral compounds |
| US6770303B1 (en) | 1998-04-16 | 2004-08-03 | Bayer Cropscience S.A. | Use of antifungal and/or antibacterial and/or antiviral compounds |
| ES2237318A1 (en) * | 2003-11-19 | 2005-07-16 | Servalesa, S.L. | PROCEDURE FOR OBTAINING AN ORGANIC ALUMINUM-BASED PRODUCT FOR THE SELF-DEFENSE OF PLANTS AGAINST PATHOGENS FOR ECOLOGICAL TRADITIONAL AGRICULTURE. |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2576749B1 (en) | 1987-04-30 |
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