FR2483226A1 - Natural colourants prepd. by extn. of Rubiaceae plants - of specified variety used in cosmetics, esp. hair dyeing - Google Patents
Natural colourants prepd. by extn. of Rubiaceae plants - of specified variety used in cosmetics, esp. hair dyeing Download PDFInfo
- Publication number
- FR2483226A1 FR2483226A1 FR8011880A FR8011880A FR2483226A1 FR 2483226 A1 FR2483226 A1 FR 2483226A1 FR 8011880 A FR8011880 A FR 8011880A FR 8011880 A FR8011880 A FR 8011880A FR 2483226 A1 FR2483226 A1 FR 2483226A1
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- France
- Prior art keywords
- process according
- plants
- rubiaceae
- genus
- rubia
- Prior art date
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- Granted
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 10
- 241001107098 Rubiaceae Species 0.000 title claims description 5
- 238000004043 dyeing Methods 0.000 title description 4
- 238000004040 coloring Methods 0.000 claims abstract description 6
- 238000002360 preparation method Methods 0.000 claims abstract description 6
- 241001495496 Coprosma Species 0.000 claims abstract description 4
- 241000157491 Morinda Species 0.000 claims abstract description 3
- 235000017524 noni Nutrition 0.000 claims abstract description 3
- 241001149655 Rubia tinctorum Species 0.000 claims abstract 2
- 239000002904 solvent Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 241000196324 Embryophyta Species 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 6
- 229930182559 Natural dye Natural products 0.000 claims description 5
- 239000000978 natural dye Substances 0.000 claims description 5
- 241001103643 Rubia Species 0.000 claims description 4
- 239000000118 hair dye Substances 0.000 claims description 4
- 238000000605 extraction Methods 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 244000186140 Asperula odorata Species 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 150000002505 iron Chemical class 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 150000003077 polyols Chemical class 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 235000019737 Animal fat Nutrition 0.000 claims 1
- 244000132059 Carica parviflora Species 0.000 claims 1
- 241000349465 Coprosma areolata Species 0.000 claims 1
- 244000013539 Cuscuta australis Species 0.000 claims 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims 1
- 244000287680 Garcinia dulcis Species 0.000 claims 1
- 241001465754 Metazoa Species 0.000 claims 1
- 244000116430 Mirabilis longiflora Species 0.000 claims 1
- 244000100617 Morinda tinctoria Species 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 150000004056 anthraquinones Chemical class 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 229910052733 gallium Inorganic materials 0.000 claims 1
- 150000008282 halocarbons Chemical class 0.000 claims 1
- 235000019871 vegetable fat Nutrition 0.000 claims 1
- 239000003086 colorant Substances 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 241000123069 Ocyurus chrysurus Species 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- -1 Alkyl ether sodium sulfate Chemical class 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 239000002453 shampoo Substances 0.000 description 3
- LVDKZNITIUWNER-UHFFFAOYSA-N Bronopol Chemical compound OCC(Br)(CO)[N+]([O-])=O LVDKZNITIUWNER-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000011499 joint compound Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-M 4-hydroxybenzoate Chemical compound OC1=CC=C(C([O-])=O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-M 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 241001101998 Galium Species 0.000 description 1
- 235000008526 Galium odoratum Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 241000408521 Lucida Species 0.000 description 1
- 244000062730 Melissa officinalis Species 0.000 description 1
- 235000010654 Melissa officinalis Nutrition 0.000 description 1
- 241000415842 Morinda royoc Species 0.000 description 1
- AQLLBJAXUCIJSR-UHFFFAOYSA-N OC(=O)C[Na] Chemical compound OC(=O)C[Na] AQLLBJAXUCIJSR-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229920003123 carboxymethyl cellulose sodium Polymers 0.000 description 1
- 229940063834 carboxymethylcellulose sodium Drugs 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000003631 expected effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000000865 liniment Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004094 preconcentration Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B61/00—Dyes of natural origin prepared from natural sources, e.g. vegetable sources
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biotechnology (AREA)
- Botany (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Cosmetics (AREA)
Abstract
L'INVENTION CONCERNE UN COLORANT NATUREL DESTINE A UN USAGE CAPILLAIRE. CE COLORANT EST EXTRAIT DE PLANTES DE LA FAMILLE DES RUBIACEES, CHOISIES NOTAMMENT PARMI LE RUBIA TINCTORUM, LES COPROSMA, LES MORINDA. APPLICATION A LA PREPARATION DE PRODUITS COSMETIQUES.THE INVENTION RELATES TO A NATURAL COLORANT FOR HAIR USE. THIS COLORING IS EXTRACTED FROM PLANTS OF THE RUBIACEA FAMILY, CHOSEN IN PARTICULAR FROM RUBIA TINCTORUM, COPROSMA, MORINDA. APPLICATION TO THE PREPARATION OF COSMETIC PRODUCTS.
Description
ta présente invention réalisée au Centre de Recherches Pierre Fabre est relative à un colorant capillaire entièrement naturel constitue, par un extrait de Rubia tinctorum.your present invention made at the Pierre Fabre Research Center relates to an all-natural hair dye consisting of an extract of Rubia tinctorum.
Rubia tinctorum, de la famille des Rubiacées, est une plante herbacée dont la racine ligneuse était autrefois utilisée pour la teinture textile. De nos jours cette teinture naturelle, concurrencée par les produits de synthèse, n'est plus utilisée pour la coloration des fibres textiles.Rubia tinctorum, from the Rubiaceae family, is a herbaceous plant whose woody root was once used for textile dyeing. Nowadays this natural dye, competing with synthetic products, is no longer used for dyeing textile fibers.
La présente invention se rapporte à l'utilisation d'un extrait colorant naturel atoxique, et antibactérien, particulièrement approprié à la réalisation de préparations cosmétiques diverses telles que shampooings, lotions, sprays, bains de boue, crèmes et baumes.The present invention relates to the use of an atoxic natural dye extract, and antibacterial, particularly suitable for the production of various cosmetic preparations such as shampoos, lotions, sprays, mud baths, creams and balms.
D'autres plantes de la même famille des Rubiacées, sont également adaptées à la préparation du colorant capillaire objet de l'invention, particulièrement les Coprosma (Australis-, lucida, parviflora, areolata...) les Morinda (tinctoria, longiflora...) Asperula odorata Galium dasypodum et Rubia iberica.Other plants of the same family of Rubiaceae, are also suitable for the preparation of the hair dye object of the invention, particularly the Coprosma (Australis-, lucida, parviflora, areolata ...) the Morinda (tinctoria, longiflora .. .) Asperula odorata Galium dasypodum and Rubia iberica.
Conformément à la présente invention les teintures capillaires à base de
Rubia tinctorum sont obtenues à partir des organes souterrains de préférence par épuisement avec un solvant suffisamment polaire et volatil tel que les alcools, de préférence méthylique, éthylique ou isopropylique éventuellement acidifiés par l'acide phosphorique ou l'acide sulfurique, les cétones de préférence diméthylcétone ou des solvants chlorés tels que le chlorure de méthylène ou le trichloro 1-1-1 éthane.In accordance with the present invention, hair dyes based on
Rubia tinctorum are obtained from underground organs preferably by exhaustion with a sufficiently polar and volatile solvent such as alcohols, preferably methyl, ethyl or isopropyl optionally acidified with phosphoric acid or sulfuric acid, ketones preferably dimethyl ketone or chlorinated solvents such as methylene chloride or trichloro 1-1-1 ethane.
Après une préconcentration du solvant et addition d'un polyol estérifié ou non, l'évaporation est menée jusqu'à élimination complète du solvant d'extraction.After a preconcentration of the solvent and addition of an esterified polyol or not, the evaporation is carried out until complete elimination of the extraction solvent.
Suivant le même processus, les substances actives de Rubia tinctorum peuvent également être solubilisées par des huiles ou des graisses ou des tensio-actifs compatibles avec une utilisation cosmétologique.According to the same process, the active substances of Rubia tinctorum can also be dissolved by oils or fats or surfactants compatible with cosmetic use.
Un dosage intermédiaire des substances actives, avant reprise par le solvant porteur permet la dilution de l'extrait à un titre standard, convenablement choisi en fonction des effets attendus.An intermediate dosage of the active substances, before taking up in the carrier solvent allows the dilution of the extract to a standard titre, suitably chosen according to the expected effects.
Les colorants selon la présente invention sont plus particulièrement destinés à la préparation de compositions cosmétiques de teinture capillaire, en particulier shampooing, lotion, spray, bain de boue. tes supports cosmétiques utilisables sont bien entendu tous les supports connus dans ce domaine.The dyes according to the present invention are more particularly intended for the preparation of cosmetic compositions for hair dyeing, in particular shampoo, lotion, spray, mud bath. your usable cosmetic supports are of course all the supports known in this field.
Selon une variante de ce procédé la couleur initiale beige peut etre nuancée par addition de faibles quantités de sels métalliques en particulier de sel d'aluminium et de sel de fer.According to a variant of this process, the initial beige color can be nuanced by adding small amounts of metal salts, in particular aluminum salt and iron salt.
Les exemples suivants sont donnés à titre indicatif,non limitatif. The following examples are given as a non-limiting indication.
Exemple 1 1 Kg de racines de Rubia tinctorum broyées est extrait successivement par 6 1 et 4 1 de méthanol à 0,5 7. phosphorique à reflux pendant 1 h. Après filtration et essorage du marc, les jus méthyliques sont préconcentrés à 2 1 puis évaporés sur 2 1 environ de propanediol jusqu'à élimination totale du méthanol.Example 1 1 kg of crushed Rubia tinctorum roots is extracted successively with 6 1 and 4 1 of methanol at 0.5 7. phosphoric acid at reflux for 1 h. After filtration and draining of the marc, the methyl juices are preconcentrated to 2 1 and then evaporated on approximately 2 1 of propanediol until complete elimination of the methanol.
L'extrait est alors clarifié, dosé en principe actif et standardisé à 1 % en principe colorant pour utilisation dans les spécialités cosmétiques.The extract is then clarified, dosed in active principle and standardized to 1% in coloring principle for use in cosmetic specialties.
Exemple 2 100 g d'écorces broyées de Coprosma Australis sont extraits par 800 ml d'acétone à reflux. Après filtration et lavage du marc par 200 ml de solvant, les filtrats groupés sont concentrés à 200 ml, dilués par 400 ml d'eau et acidifiés à pH 1 à laide d'acide phosphorique.Example 2 100 g of ground bark of Coprosma Australis are extracted with 800 ml of acetone at reflux. After filtration and washing of the marc with 200 ml of solvent, the grouped filtrates are concentrated to 200 ml, diluted with 400 ml of water and acidified to pH 1 with phosphoric acid.
Le principe colorant est extrait en liquide-liquide à l'aide de 2 x 300 ml de trichloréthylène. Après lavage à l'eau et séchage sur sulfate de sodium, le solvant évaporé à sec fournit une poudre brun rougeatre qui est dissoute à raison de 1 % dans une solution aqueuse à 30 % de lauryl sulfate de sodium.The coloring principle is extracted in liquid-liquid using 2 x 300 ml of trichlorethylene. After washing with water and drying over sodium sulfate, the solvent evaporated to dryness provides a reddish brown powder which is dissolved at a rate of 1% in a 30% aqueous solution of sodium lauryl sulfate.
Exemple 3 100 g de racines et tiges broyées de Morinda umbellata sont extraits par 600 ml de soude 0,5 N à température ambiante. Après filtration et lavage du marc par 200 ml d'eau, les filtrats groupés sont acidifiés à pH voisin de 1 à laide diacide phosphorique dilué.Example 3 100 g of crushed roots and stems of Morinda umbellata are extracted with 600 ml of 0.5 N sodium hydroxide solution at room temperature. After filtration and washing of the marc with 200 ml of water, the grouped filtrates are acidified to a pH close to 1 with dilute phosphoric acid.
Le principe colorant est extrait en liquide-liquide à l'aide de 3 x 200 ml de méthyl-éthyl-cétone. Après lavage à l'eau, le solvant est concentré à 200 ml et évaporé sur 200 ml propanediol.The coloring principle is extracted in liquid-liquid using 3 x 200 ml of methyl ethyl ketone. After washing with water, the solvent is concentrated to 200 ml and evaporated on 200 ml propanediol.
Après clarification, l'extrait est dosé en principe actif et standardisé à 0,5 Z0 en principe colorant pour utilisation dans les spécialités cosmétiques.After clarification, the extract is dosed in active principle and standardized to 0.5 Z0 in coloring principle for use in cosmetic specialties.
A titre d'exemples non limitatifs de préparations cosmétologiques selon l'invention on mentionnera ci-après 3 exemples de formulation de shampooing
Exemple A
Alkyl éther sulfate de sodium * 10 7
Carboxy méthyl cellulose sodique e 2 7.By way of nonlimiting examples of cosmetic preparations according to the invention, 3 examples of shampoo formulation will be mentioned below.
Example A
Alkyl ether sodium sulfate * 10 7
Carboxy methyl sodium cellulose e 2 7.
2-bromo-2-nitro-propane-1,3-diol............ 0,25 %
Parfum...................................... 0,25 %
Extrait de Rubia standardisé à 0,5 % .............................. 2 %
Eau distillée............................. Q.S.P.100 ml
Exemple B
Alkyl éther sulfate de sodium et magnésium ............. 10 %
Alkyl sorbate éthoxylé ............................ 5 %
Bentone..................................... 0,5 %
Parahydroxy benzoate........................ 0,15 %
Parfum...................................... 0,25 %
Extrait de Rubia standardisé à 0,5 % .................. 2 %
Eau....................................... 100 %
Exemple C
Alkyl éther sulfate de sodium............... 10 %
Carboxy méthyl cellulose sodique............ 2 % 2-Bromo-2-nitro-propane-1,3-diol............ 0,05 %
Parfum ............................................... 0,25 %
Extrait de Rubia standardisé à 0,5 % .......................... 2 %
Chlorure ferrique......................... 0,1 %
Eau distillée . . .. .. . .. ... .. .. . . Q. S.P. QoSPo 100 ml 2-bromo-2-nitro-propane-1,3-diol ............ 0.25%
Perfume ...................................... 0.25%
Rubia extract standardized to 0.5% .............................. 2%
Distilled water ............................. QSP100 ml
Example B
Alkyl ether sodium and magnesium sulfate ............. 10%
Alkyl ethoxylated sorbate ............................ 5%
Bentone ..................................... 0.5%
Parahydroxy benzoate ........................ 0.15%
Perfume ...................................... 0.25%
Rubia extract standardized to 0.5% .................. 2%
Water ....................................... 100%
Example C
Alkyl ether sodium sulfate ............... 10%
Carboxy methyl cellulose sodium ............ 2% 2-Bromo-2-nitro-propane-1,3-diol ............ 0.05%
Perfume ............................................... 0, 25%
Rubia extract standardized to 0.5% .......................... 2%
Ferric chloride ......................... 0.1%
Distilled water . . .. ... .. ... .. ... . QSP QoSPo 100 ml
Claims (12)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8011880A FR2483226A1 (en) | 1980-05-28 | 1980-05-28 | Natural colourants prepd. by extn. of Rubiaceae plants - of specified variety used in cosmetics, esp. hair dyeing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8011880A FR2483226A1 (en) | 1980-05-28 | 1980-05-28 | Natural colourants prepd. by extn. of Rubiaceae plants - of specified variety used in cosmetics, esp. hair dyeing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2483226A1 true FR2483226A1 (en) | 1981-12-04 |
| FR2483226B1 FR2483226B1 (en) | 1983-06-10 |
Family
ID=9242438
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8011880A Granted FR2483226A1 (en) | 1980-05-28 | 1980-05-28 | Natural colourants prepd. by extn. of Rubiaceae plants - of specified variety used in cosmetics, esp. hair dyeing |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2483226A1 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2549721A1 (en) * | 1983-07-28 | 1985-02-01 | Secta Labo Cosmetologie Y Roch | Method and compositions for colouring superficial body growths |
| EP0133129A3 (en) * | 1983-07-28 | 1985-07-10 | Secta-Laboratoires De Cosmetologie Yves Rocher | Process and compositions for dyeing the annexes of the epidermis |
| FR2567400A2 (en) * | 1984-07-12 | 1986-01-17 | Secta Lab Cosmetologie Y Roche | Process and compositions for dyeing exoskeletons. |
| EP0440494A3 (en) * | 1990-02-02 | 1992-06-10 | Tokiwa Kanpo Pharmaceutical Co., Ltd. | Hair dyeing |
| EP1191070A1 (en) * | 2000-09-26 | 2002-03-27 | Coöperatie Rubia | Method for the production of a dye preparation based on madder root |
| WO2004105718A1 (en) * | 2003-06-03 | 2004-12-09 | Unilever Plc | Skin lightening composition comprising an extract of plants from the families of symplocos or rubia |
| WO2011045150A3 (en) * | 2009-10-12 | 2011-11-03 | Unilever Nv | A personal care composition |
-
1980
- 1980-05-28 FR FR8011880A patent/FR2483226A1/en active Granted
Non-Patent Citations (1)
| Title |
|---|
| EXBK/52 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2549721A1 (en) * | 1983-07-28 | 1985-02-01 | Secta Labo Cosmetologie Y Roch | Method and compositions for colouring superficial body growths |
| EP0133129A3 (en) * | 1983-07-28 | 1985-07-10 | Secta-Laboratoires De Cosmetologie Yves Rocher | Process and compositions for dyeing the annexes of the epidermis |
| AU570706B2 (en) * | 1983-07-28 | 1988-03-24 | Secta-Laboratoires De Cosmetologie Yves Rocher | Process and composition for colouration of phanera |
| FR2567400A2 (en) * | 1984-07-12 | 1986-01-17 | Secta Lab Cosmetologie Y Roche | Process and compositions for dyeing exoskeletons. |
| EP0440494A3 (en) * | 1990-02-02 | 1992-06-10 | Tokiwa Kanpo Pharmaceutical Co., Ltd. | Hair dyeing |
| EP1191070A1 (en) * | 2000-09-26 | 2002-03-27 | Coöperatie Rubia | Method for the production of a dye preparation based on madder root |
| US6596036B2 (en) | 2000-09-26 | 2003-07-22 | Coöperatie Rubia U.A. | Method for the production of a dye preparation based on madder root |
| WO2004105718A1 (en) * | 2003-06-03 | 2004-12-09 | Unilever Plc | Skin lightening composition comprising an extract of plants from the families of symplocos or rubia |
| WO2011045150A3 (en) * | 2009-10-12 | 2011-11-03 | Unilever Nv | A personal care composition |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2483226B1 (en) | 1983-06-10 |
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