FR2457304A1 - Procede pour la polymerisation en suspension du chlorure de vinyle - Google Patents
Procede pour la polymerisation en suspension du chlorure de vinyleInfo
- Publication number
- FR2457304A1 FR2457304A1 FR8011632A FR8011632A FR2457304A1 FR 2457304 A1 FR2457304 A1 FR 2457304A1 FR 8011632 A FR8011632 A FR 8011632A FR 8011632 A FR8011632 A FR 8011632A FR 2457304 A1 FR2457304 A1 FR 2457304A1
- Authority
- FR
- France
- Prior art keywords
- polymerization
- monomer
- vinyl chloride
- cooling zone
- suspension polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000010557 suspension polymerization reaction Methods 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 abstract 5
- 239000000178 monomer Substances 0.000 abstract 4
- 238000001816 cooling Methods 0.000 abstract 2
- 239000002270 dispersing agent Substances 0.000 abstract 2
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000003505 polymerization initiator Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2455—Stationary reactors without moving elements inside provoking a loop type movement of the reactants
- B01J19/2465—Stationary reactors without moving elements inside provoking a loop type movement of the reactants externally, i.e. the mixture leaving the vessel and subsequently re-entering it
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
PROCEDE POUR LA POLYMERISATION EN SUSPENSION EN DISCONTINU DE CHLORURE DE VINYLE EVENTUELLEMENT CONJOINTEMENT AVEC UN AUTRE MONOMERE ETHYLENIQUEMENT INSATURE COPOLYMERISABLE AVEC CE DERNIER. SELON L'INVENTION, LA POLYMERISATION EST EXECUTEE EN MILIEU AQUEUX EN PRESENCE D'UN AGENT DISPERSANT ET D'UN INITIATEUR DE POLYMERISATION OLEOSOLUBLE DANS UN REACTEUR DE POLYMERISATION 1 RELIE PAR L'INTERMEDIAIRE D'UNE CONDUITE DE CIRCULATION 6 A UNE ZONE DE REFROIDISSEMENT EXTERNE 2, DANS LEQUEL LE RAPPORT EN VOLUME DE LA CHARGE TOTALE DE MONOMERE A LA QUANTITE D'EAU EST MAINTENU A UNE VALEUR SUPERIEURE A 0,8 ET LA QUANTITE D'AGENTS DISPERSANTS A UTILISER EST DE 0,03 A 0,1 EN POIDS SUR LA BASE DE LA CHARGE TOTALE DE MONOMERE, LA CIRCULATION DU MELANGE DE REACTION DE POLYMERISATION DANS LA ZONE DE REFROIDISSEMENT EXTERNE COMMENCANT APRES QUE LA CONVERSION DU MONOMERE DANS LE REACTEUR DE POLYMERISATION A ATTEINT AU MOINS 20 EN POIDS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6465079A JPS55157607A (en) | 1979-05-25 | 1979-05-25 | Suspension polymerization of vinyl chloride |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2457304A1 true FR2457304A1 (fr) | 1980-12-19 |
| FR2457304B1 FR2457304B1 (fr) | 1985-05-10 |
Family
ID=13264322
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8011632A Expired FR2457304B1 (fr) | 1979-05-25 | 1980-05-23 | Procede pour la polymerisation en suspension du chlorure de vinyle |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4464517A (fr) |
| JP (1) | JPS55157607A (fr) |
| DE (1) | DE3019584A1 (fr) |
| ES (1) | ES8105013A1 (fr) |
| FR (1) | FR2457304B1 (fr) |
| GB (1) | GB2052531B (fr) |
| IT (1) | IT1147740B (fr) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0526741A3 (fr) * | 1991-07-05 | 1993-02-24 | Shin-Etsu Chemical Co., Ltd. | Système de réacteur pour la polymérisation en suspension au chlorure de vinyle |
| EP0608567A1 (fr) * | 1992-12-28 | 1994-08-03 | Shin-Etsu Chemical Co., Ltd. | Procédé pour préparer un polymère à base de chlorure de vinyle |
| EP0853975A1 (fr) * | 1997-01-20 | 1998-07-22 | CP TECH S.r.l. | Appareil pour la production de polymères d'addition à partir d'oxydes d'alkylène avec un réacteur combinant un disperseur liquide dans gaz et gaz dans liquide |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60158206A (ja) * | 1984-01-27 | 1985-08-19 | Toyo Soda Mfg Co Ltd | 塩化ビニルの懸濁重合法 |
| KR100191378B1 (ko) | 1989-09-18 | 1999-06-15 | 후루타 다케시 | 비닐 클로라이드 수지를 제조하기위한 미세현탁중합법 |
| JPH0678388B2 (ja) * | 1990-08-31 | 1994-10-05 | 信越化学工業株式会社 | 塩化ビニル系重合体の製造方法 |
| US5449723A (en) * | 1991-07-05 | 1995-09-12 | Shin-Etsu Chemical Co., Ltd. | Method for the preparation of a vinyl chloride-based polymer |
| JPH05255409A (ja) * | 1992-01-14 | 1993-10-05 | Shin Etsu Chem Co Ltd | 重合装置 |
| JP3252616B2 (ja) * | 1994-09-12 | 2002-02-04 | 信越化学工業株式会社 | 塩化ビニル系重合体の製造方法 |
| KR101009797B1 (ko) * | 2003-11-20 | 2011-01-19 | 솔베이(소시에떼아노님) | 유기 화합물의 제조 방법 |
| KR20080037613A (ko) | 2005-05-20 | 2008-04-30 | 솔베이(소시에떼아노님) | 폴리히드록실화 지방족 탄화수소의 클로로히드린으로의전환 방법 |
| EA200702553A1 (ru) * | 2005-05-20 | 2008-06-30 | Солвей (Сосьете Аноним) | Способ получения хлоргидрина |
| US8124814B2 (en) * | 2006-06-14 | 2012-02-28 | Solvay (Societe Anonyme) | Crude glycerol-based product, process for its purification and its use in the manufacture of dichloropropanol |
| US20100032617A1 (en) * | 2007-02-20 | 2010-02-11 | Solvay (Societe Anonyme) | Process for manufacturing epichlorohydrin |
| FR2913421B1 (fr) * | 2007-03-07 | 2009-05-15 | Solvay | Procede de fabrication de dichloropropanol. |
| FR2913684B1 (fr) * | 2007-03-14 | 2012-09-14 | Solvay | Procede de fabrication de dichloropropanol |
| TW200911740A (en) | 2007-06-01 | 2009-03-16 | Solvay | Process for manufacturing a chlorohydrin |
| TW200911773A (en) | 2007-06-12 | 2009-03-16 | Solvay | Epichlorohydrin, manufacturing process and use |
| TW200911693A (en) * | 2007-06-12 | 2009-03-16 | Solvay | Aqueous composition containing a salt, manufacturing process and use |
| WO2009043796A1 (fr) * | 2007-10-02 | 2009-04-09 | Solvay (Société Anonyme) | Utilisation de compositions contenant du silicium pour améliorer la résistance à la corrosion de récipients |
| FR2925045B1 (fr) | 2007-12-17 | 2012-02-24 | Solvay | Produit a base de glycerol, procede pour son obtention et son utilisation dans la fabrication de dichloropropanol |
| TWI478875B (zh) * | 2008-01-31 | 2015-04-01 | Solvay | 使水性組成物中之有機物質降解之方法 |
| WO2009121853A1 (fr) | 2008-04-03 | 2009-10-08 | Solvay (Société Anonyme) | Composition comprenant du glycérol, son procédé d'obtention et son utilisation dans la fabrication de dichloropropanol |
| FR2935968B1 (fr) | 2008-09-12 | 2010-09-10 | Solvay | Procede pour la purification de chlorure d'hydrogene |
| FR2939434B1 (fr) * | 2008-12-08 | 2012-05-18 | Solvay | Procede de traitement de glycerol. |
| CN107759771A (zh) | 2010-09-30 | 2018-03-06 | 索尔维公司 | 天然来源的环氧氯丙烷的衍生物 |
| KR102024141B1 (ko) * | 2016-06-21 | 2019-09-23 | 주식회사 엘지화학 | 염화비닐계 중합체의 제조방법 |
| KR102159221B1 (ko) * | 2016-09-26 | 2020-09-23 | 주식회사 엘지화학 | 염화비닐계 중합체의 제조방법 |
| EP3809872A1 (fr) * | 2018-06-19 | 2021-04-28 | Société des Produits Nestlé S.A. | Réacteur discontinu à boucle d'écoulement de recirculation à échangeur de chaleur externe |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2089551A5 (fr) * | 1970-04-13 | 1972-01-07 | Shinetsu Chemical Co | |
| GB2001659A (en) * | 1977-07-27 | 1979-02-07 | Anic Spa | Process for, and apparatus suitable for use in, the polymerization in suspension of vinyl chloride |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2754289A (en) * | 1952-02-29 | 1956-07-10 | Shell Dev | Process for polymerizing unsaturated compounds by conducting droplets through an aqueous medium with control of pressure fluctuations |
| GB1053572A (fr) * | 1963-05-14 | |||
| JPS5338311A (en) * | 1976-09-21 | 1978-04-08 | Oki Electric Ind Co Ltd | Reading system |
| US4089365A (en) * | 1976-09-30 | 1978-05-16 | The Badger Company | Method of pump-around cooling reaction mass during polymerization of olefins |
| JPS5426890A (en) * | 1977-08-02 | 1979-02-28 | Nippon Zeon Co Ltd | Preparation of vinyl chloride resin |
| JPS6043846B2 (ja) * | 1977-09-01 | 1985-09-30 | 日本ゼオン株式会社 | 還流凝縮器を使用する塩化ビニル系樹脂の製造方法 |
-
1979
- 1979-05-25 JP JP6465079A patent/JPS55157607A/ja active Granted
-
1980
- 1980-05-22 DE DE19803019584 patent/DE3019584A1/de not_active Withdrawn
- 1980-05-23 GB GB8017071A patent/GB2052531B/en not_active Expired
- 1980-05-23 FR FR8011632A patent/FR2457304B1/fr not_active Expired
- 1980-05-23 ES ES491790A patent/ES8105013A1/es not_active Expired
- 1980-05-26 IT IT67824/80A patent/IT1147740B/it active
-
1981
- 1981-10-31 US US06/316,568 patent/US4464517A/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2089551A5 (fr) * | 1970-04-13 | 1972-01-07 | Shinetsu Chemical Co | |
| GB2001659A (en) * | 1977-07-27 | 1979-02-07 | Anic Spa | Process for, and apparatus suitable for use in, the polymerization in suspension of vinyl chloride |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0526741A3 (fr) * | 1991-07-05 | 1993-02-24 | Shin-Etsu Chemical Co., Ltd. | Système de réacteur pour la polymérisation en suspension au chlorure de vinyle |
| EP0608567A1 (fr) * | 1992-12-28 | 1994-08-03 | Shin-Etsu Chemical Co., Ltd. | Procédé pour préparer un polymère à base de chlorure de vinyle |
| US5420215A (en) * | 1992-12-28 | 1995-05-30 | Shin-Etsu Chemical Co., Ltd. | Process for producing vinyl chloride-based polymer |
| EP0853975A1 (fr) * | 1997-01-20 | 1998-07-22 | CP TECH S.r.l. | Appareil pour la production de polymères d'addition à partir d'oxydes d'alkylène avec un réacteur combinant un disperseur liquide dans gaz et gaz dans liquide |
| WO1998031459A1 (fr) * | 1997-01-20 | 1998-07-23 | Linde Ag | Dispositif servant a preparer des produit de polyaddition d'oxydes d'alkylene au moyen d'un reacteur combine de dispersion de liquide dans du gaz ou de gaz dans du liquide |
| US6180728B1 (en) | 1997-01-20 | 2001-01-30 | Linde Aktiengesellschaft | Apparatus for the production of polyadducts of alkylene oxides with a combined liquid-in-gas and gas-in-liquid dispersion reactor |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3019584A1 (de) | 1980-12-04 |
| JPS6411642B2 (fr) | 1989-02-27 |
| US4464517A (en) | 1984-08-07 |
| IT8067824A0 (it) | 1980-05-26 |
| ES491790A0 (es) | 1981-05-16 |
| IT1147740B (it) | 1986-11-26 |
| ES8105013A1 (es) | 1981-05-16 |
| JPS55157607A (en) | 1980-12-08 |
| GB2052531B (en) | 1983-04-07 |
| FR2457304B1 (fr) | 1985-05-10 |
| GB2052531A (en) | 1981-01-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |