FR2453671A1 - Reforming and aromatising catalysts - contg. platinum-group metal, bismuth and chromium, molybdenum or manganese - Google Patents
Reforming and aromatising catalysts - contg. platinum-group metal, bismuth and chromium, molybdenum or manganeseInfo
- Publication number
- FR2453671A1 FR2453671A1 FR7909255A FR7909255A FR2453671A1 FR 2453671 A1 FR2453671 A1 FR 2453671A1 FR 7909255 A FR7909255 A FR 7909255A FR 7909255 A FR7909255 A FR 7909255A FR 2453671 A1 FR2453671 A1 FR 2453671A1
- Authority
- FR
- France
- Prior art keywords
- pref
- reforming
- pts
- catalysts
- group metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000002407 reforming Methods 0.000 title abstract 4
- 229910052804 chromium Inorganic materials 0.000 title abstract 3
- 229910052748 manganese Inorganic materials 0.000 title abstract 3
- 229910052751 metal Inorganic materials 0.000 title abstract 2
- 239000002184 metal Substances 0.000 title abstract 2
- 229910052750 molybdenum Inorganic materials 0.000 title abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 title 1
- 229910052797 bismuth Inorganic materials 0.000 title 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 title 1
- 239000011651 chromium Substances 0.000 title 1
- 239000011572 manganese Substances 0.000 title 1
- 239000011733 molybdenum Substances 0.000 title 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000011800 void material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
- C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
New catalysts comprise (a) 100 pts. wt. of an alumina support, (b) 0.05-0.6 (pref.0.1-0.5) pts. wt. of a Pt-group metal, (c) 0.005-5 (pref. 0.05-3) pts. wt. of Bi, (d) 0.005-5 (pref. 0.05-3) pts. wt. of Cr, Mo or Mn, and (e) 0.1-10 pts. wt. halogen. Component (b) is pref. Pt, Ir or Rh and component (d) is pref. Cr or Mn. Reforming and atomizing are pref. effected at 510-600 deg.C and 1-18 kg/square cm with a LHSV of 1-10 and an H2/feed molar ratio of 5-20. The process is pref. effected in a series of at least two mobile-bed reactors, with catalyst from the last reactor being regenerated, reduced and progressively recycled to the 1st reactor. The void vol. in each of the reactors is pref. 7% or less. The catalysts are esp. useful for continuous mobile-bed reforming and atomizing operations. They have high stability and selectivity under high-severity conditions (e.g. reforming to 102 RON clear).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7909255A FR2453671A1 (en) | 1979-04-10 | 1979-04-10 | Reforming and aromatising catalysts - contg. platinum-group metal, bismuth and chromium, molybdenum or manganese |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7909255A FR2453671A1 (en) | 1979-04-10 | 1979-04-10 | Reforming and aromatising catalysts - contg. platinum-group metal, bismuth and chromium, molybdenum or manganese |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2453671A1 true FR2453671A1 (en) | 1980-11-07 |
| FR2453671B1 FR2453671B1 (en) | 1983-11-10 |
Family
ID=9224246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7909255A Granted FR2453671A1 (en) | 1979-04-10 | 1979-04-10 | Reforming and aromatising catalysts - contg. platinum-group metal, bismuth and chromium, molybdenum or manganese |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2453671A1 (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2091114A5 (en) * | 1970-05-04 | 1972-01-14 | Shell Int Research | |
| FR2201338A1 (en) * | 1972-09-27 | 1974-04-26 | Inst Francais Du Petrole | |
| FR2260382A1 (en) * | 1974-02-13 | 1975-09-05 | Raffinage Cie Francaise | |
| US3980721A (en) * | 1971-11-19 | 1976-09-14 | Institut Francaise Du Petrole, Des Carburants Et Lubrifiants Et Entreprise De Recherches Et D'activites Petrolieres Elf | Catalyst particularly useful for dehydrogenating saturated hydrocarbons |
| US4036743A (en) * | 1976-09-20 | 1977-07-19 | Uop Inc. | Hydrocarbon conversion with an acidic multimetallic catalytic composite |
-
1979
- 1979-04-10 FR FR7909255A patent/FR2453671A1/en active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2091114A5 (en) * | 1970-05-04 | 1972-01-14 | Shell Int Research | |
| US3980721A (en) * | 1971-11-19 | 1976-09-14 | Institut Francaise Du Petrole, Des Carburants Et Lubrifiants Et Entreprise De Recherches Et D'activites Petrolieres Elf | Catalyst particularly useful for dehydrogenating saturated hydrocarbons |
| FR2201338A1 (en) * | 1972-09-27 | 1974-04-26 | Inst Francais Du Petrole | |
| FR2260382A1 (en) * | 1974-02-13 | 1975-09-05 | Raffinage Cie Francaise | |
| US4036743A (en) * | 1976-09-20 | 1977-07-19 | Uop Inc. | Hydrocarbon conversion with an acidic multimetallic catalytic composite |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2453671B1 (en) | 1983-11-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |