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FR2451364A1 - ORGANIC-SOLUBLE COMPLEXES WITH HIGH IRON CONTENT FOR USE AS COMBUSTION ADJUVANTS IN LIQUID FUELS - Google Patents

ORGANIC-SOLUBLE COMPLEXES WITH HIGH IRON CONTENT FOR USE AS COMBUSTION ADJUVANTS IN LIQUID FUELS

Info

Publication number
FR2451364A1
FR2451364A1 FR7906783A FR7906783A FR2451364A1 FR 2451364 A1 FR2451364 A1 FR 2451364A1 FR 7906783 A FR7906783 A FR 7906783A FR 7906783 A FR7906783 A FR 7906783A FR 2451364 A1 FR2451364 A1 FR 2451364A1
Authority
FR
France
Prior art keywords
iron
sulphonic acid
liquid fuels
organo
soluble
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7906783A
Other languages
French (fr)
Other versions
FR2451364B1 (en
Inventor
Maurice Born
Lucienne Briquet
Gabriel De Gaudemaris
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7906783A priority Critical patent/FR2451364A1/en
Priority to BE1/9745A priority patent/BE882154A/en
Priority to DE19803009657 priority patent/DE3009657A1/en
Priority to NLAANVRAGE8001538,A priority patent/NL187628C/en
Priority to US06/130,307 priority patent/US4347062A/en
Priority to IT20642/80A priority patent/IT1130963B/en
Priority to GB8008907A priority patent/GB2046744B/en
Publication of FR2451364A1 publication Critical patent/FR2451364A1/en
Application granted granted Critical
Publication of FR2451364B1 publication Critical patent/FR2451364B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/29—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings
    • C07C309/30—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings of six-membered aromatic rings substituted by alkyl groups
    • C07C309/31—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings of six-membered aromatic rings substituted by alkyl groups by alkyl groups containing at least three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
    • C10L1/2437—Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

ON DECRIT DES COMPLEXES ORGANO-SOLUBLES DU FER, UTILISABLES COMME ADJUVANTS POUR LA COMBUSTION DES COMBUSTIBLES LIQUIDES. CES COMPLEXES ORGANO-SOLUBLES, FORMES ESSENTIELLEMENT ENTRE UN ACIDE SULFONIQUE ET DU FER, PRESENTENT UN RAPPORT R ENTRE LE NOMBRE D'EQUIVALENTS-GRAMME D'ACIDE SULFONIQUE ET LE NOMBRE D'ATOMES-GRAMME DE FER ENGAGE D'ENVIRON 16 A 110, OU ENCORE PLUS FAIBLE (PAR EXEMPLE JUSQU'A ENVIRON 112). ILS SONT PREPARES PAR UN PROCEDE DANS LEQUEL ON MET EN CONTACT UN ACIDE SULFONIQUE, TEL QU'UN ACIDE ALKYLBENZENE SULFONIQUE, AVEC DE L'HYDROXYDE FERRIQUE AU SEIN D'UN SYSTEME SOLVANT CONSTITUE: A.D'UN LIQUIDE ORGANIQUE CHOISI PARMI LES HYDROCARBURES AROMATIQUES LEGERS ET LES HYDROCARBURES ALIPHATIQUES HALOGENES LEGERS, ET B.D'UN MONOALCOOL ALIPHATIQUE SATURE INFERIEUR. ON OBTIENT LES TENEURS EN FER LES PLUS ELEVEES, EN AJOUTANT EN OUTRE AU MILIEU REACTIONNEL UN ACIDE CARBOXYLIQUE INFERIEUR. DANS LEUR UTILISATION COMME ADJUVANTS DE COMBUSTION POUR LES COMBUSTIBLES LIQUIDES LES COMPLEXES ORGANO-SOLUBLES DE FER CONSIDERES PRESENTENT UNE EXCELLENTE EFFICACITE, NOTAMMENT POUR REDUIRE LES EMISSIONS DE FUMEES.ORGANO-SOLUBLE IRON COMPLEXES ARE DESCRIBED FOR USE AS ADDITIVES FOR THE COMBUSTION OF LIQUID FUELS. THESE ORGANO-SOLUBLE COMPLEXES, ESSENTIALLY FORMED BETWEEN SULPHONIC ACID AND IRON, SHOW A RATIO BETWEEN THE NUMBER OF EQUIVALENT GRAMS OF SULPHONIC ACID AND THE NUMBER OF GRAMS OF IRON ENGAGED OF APPROXIMATELY 16 TO 110, OR EVEN LOWER (FOR EXAMPLE UP TO ABOUT 112). THEY ARE PREPARED BY A PROCESS IN WHICH SULPHONIC ACID, SUCH AS AN ALKYLBENZENE SULPHONIC ACID, IS IN CONTACT WITH FERRIC HYDROXIDE WITHIN A SOLVENT SYSTEM CONSTITUTES: A. OF AN ORGANIC LIQUID CHOSEN FROM HYDROCARBURES LIGHT AROMATICS AND LIGHT ALIPHATIC HALOGENOUS HYDROCARBONS, AND B. LOWER SATURATED ALIPHATIC MONOALCOOL. THE HIGHEST IRON CONTENTS ARE OBTAINED BY ADDING IN ADDITION TO THE REACTIONAL MEDIUM A LOWER CARBOXYLIC ACID. IN THEIR USE AS COMBUSTION ADDITIVES FOR LIQUID FUELS, THE ORGANO-SOLUBLE IRON COMPLEXES UNDER CONSIDERED PRESENT EXCELLENT EFFICIENCY, IN PARTICULAR IN REDUCING SMOKE EMISSIONS.

FR7906783A 1979-03-16 1979-03-16 ORGANIC-SOLUBLE COMPLEXES WITH HIGH IRON CONTENT FOR USE AS COMBUSTION ADJUVANTS IN LIQUID FUELS Granted FR2451364A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR7906783A FR2451364A1 (en) 1979-03-16 1979-03-16 ORGANIC-SOLUBLE COMPLEXES WITH HIGH IRON CONTENT FOR USE AS COMBUSTION ADJUVANTS IN LIQUID FUELS
BE1/9745A BE882154A (en) 1979-03-16 1980-03-10 ORGANIC-SOLUBLE COMPLEXES WITH HIGH IRON CONTENT FOR USE AS COMBUSTION ADJUVANTS IN LIQUID FUELS
DE19803009657 DE3009657A1 (en) 1979-03-16 1980-03-13 ORGANICALLY SOLUBLE HIGH-IRON COMPLEXES USED AS COMBUSTION ADJUVANTS IN FLAMMABLE LIQUIDS
NLAANVRAGE8001538,A NL187628C (en) 1979-03-16 1980-03-14 COMPLEX SOLUBLE IN ORGANIC LIQUIDS OF AT LEAST A SULFONIC ACID AND IRON, METHOD FOR THE PREPARATION THEREOF, AND LIQUID FUELS CONTAINING SUCH A COMPLEX AS A COMBUSTION DEVICE.
US06/130,307 US4347062A (en) 1979-03-16 1980-03-14 Complexes of high iron content soluble in organic media and usable as combustion additives in liquid fuels
IT20642/80A IT1130963B (en) 1979-03-16 1980-03-14 OTHER IRON CONTENT SOLUBLE ORGAN COMPLEX USABLE AS COMBUSTION ADJUVANTS IN LIQUID FUELS
GB8008907A GB2046744B (en) 1979-03-16 1980-03-17 Clomplexes of high iron content soluble in organic media and usable as combustion additives in liquid fuels

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7906783A FR2451364A1 (en) 1979-03-16 1979-03-16 ORGANIC-SOLUBLE COMPLEXES WITH HIGH IRON CONTENT FOR USE AS COMBUSTION ADJUVANTS IN LIQUID FUELS

Publications (2)

Publication Number Publication Date
FR2451364A1 true FR2451364A1 (en) 1980-10-10
FR2451364B1 FR2451364B1 (en) 1983-04-15

Family

ID=9223225

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7906783A Granted FR2451364A1 (en) 1979-03-16 1979-03-16 ORGANIC-SOLUBLE COMPLEXES WITH HIGH IRON CONTENT FOR USE AS COMBUSTION ADJUVANTS IN LIQUID FUELS

Country Status (7)

Country Link
US (1) US4347062A (en)
BE (1) BE882154A (en)
DE (1) DE3009657A1 (en)
FR (1) FR2451364A1 (en)
GB (1) GB2046744B (en)
IT (1) IT1130963B (en)
NL (1) NL187628C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2715401A1 (en) * 1994-01-26 1995-07-28 Inst Francais Du Petrole New sulfonated compounds of bismuth, their preparation and their use especially for the preparation of overbased colloidal products, themselves usable as additives for lubricants.
FR2715403A1 (en) * 1994-01-26 1995-07-28 Inst Francais Du Petrole Novel bismuth alkyl-benzenesulphonates

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2537593B1 (en) * 1982-12-10 1986-04-11 Raffinage Cie Francaise COMBINED ORGANOMETALLIC COMPOSITIONS COMPRISING ELEMENTS OF THE IRON AND LANTHANIDE GROUPS, PROCESS FOR THE PREPARATION AND APPLICATION OF THE SAME COMPOSITIONS AS ADDITIVES FOR FUELS OR FUELS
US4732574A (en) * 1986-03-06 1988-03-22 Celanese Corporation Luminosity enhancement of trioxane fuels
US5288393A (en) * 1990-12-13 1994-02-22 Union Oil Company Of California Gasoline fuel
TW230781B (en) 1991-05-13 1994-09-21 Lubysu Co
IL100669A0 (en) * 1991-05-13 1992-09-06 Lubrizol Corp Low-sulfur diesel fuel containing organometallic complexes
US5376154A (en) * 1991-05-13 1994-12-27 The Lubrizol Corporation Low-sulfur diesel fuels containing organometallic complexes
US5360459A (en) * 1991-05-13 1994-11-01 The Lubrizol Corporation Copper-containing organometallic complexes and concentrates and diesel fuels containing same
US5344467A (en) * 1991-05-13 1994-09-06 The Lubrizol Corporation Organometallic complex-antioxidant combinations, and concentrates and diesel fuels containing same
USH1305H (en) 1992-07-09 1994-05-03 Townsend Daniel J Reformulated gasolines and methods of producing reformulated gasolines
DE19643832A1 (en) * 1996-10-30 1998-05-07 Clariant Gmbh Heavy oils with improved properties and an additive for them
CA2376700A1 (en) * 2002-03-13 2003-09-13 Irving Oil Limited Unleaded gasoline compositions
US8177864B1 (en) 2008-05-22 2012-05-15 Environmental Bio-Fuels, Inc. Fuel and fuel additive

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2172797A1 (en) * 1972-02-22 1973-10-05 Gamlen Naintre Sa Oil-sol ferric salts of org acids - for use as paint and varnish siccatives and fuel additives

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2279086A (en) * 1940-09-23 1942-04-07 Shell Dev Compounded lubricating oil
US3085866A (en) * 1958-02-26 1963-04-16 Exxon Research Engineering Co Fuel oil compositions of improved combustion characteristics
US3891401A (en) * 1971-03-01 1975-06-24 Standard Oil Co Reducing deposits and smoke from jet fuels
US3897470A (en) * 1971-05-14 1975-07-29 Continental Oil Co Process for producing oil-soluble metal sulfonates

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2172797A1 (en) * 1972-02-22 1973-10-05 Gamlen Naintre Sa Oil-sol ferric salts of org acids - for use as paint and varnish siccatives and fuel additives

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2715401A1 (en) * 1994-01-26 1995-07-28 Inst Francais Du Petrole New sulfonated compounds of bismuth, their preparation and their use especially for the preparation of overbased colloidal products, themselves usable as additives for lubricants.
FR2715403A1 (en) * 1994-01-26 1995-07-28 Inst Francais Du Petrole Novel bismuth alkyl-benzenesulphonates
EP0665217A1 (en) * 1994-01-26 1995-08-02 Institut Francais Du Petrole Sulphonated bismuth compounds, their preparation and their use notably for the preparation of overbased colloidal products, themselves suitable for use as additives for lubricants

Also Published As

Publication number Publication date
NL187628B (en) 1991-07-01
NL187628C (en) 1991-12-02
NL8001538A (en) 1980-09-18
FR2451364B1 (en) 1983-04-15
IT8020642A0 (en) 1980-03-14
GB2046744A (en) 1980-11-19
US4347062A (en) 1982-08-31
BE882154A (en) 1980-09-10
IT1130963B (en) 1986-06-18
DE3009657A1 (en) 1980-09-25
GB2046744B (en) 1983-10-12

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