FR2449728A2 - Uranium recovery from iron-contg. phosphate soln. - using conc. pyrophosphoric acid di:ester extractant phase - Google Patents
Uranium recovery from iron-contg. phosphate soln. - using conc. pyrophosphoric acid di:ester extractant phaseInfo
- Publication number
- FR2449728A2 FR2449728A2 FR7904760A FR7904760A FR2449728A2 FR 2449728 A2 FR2449728 A2 FR 2449728A2 FR 7904760 A FR7904760 A FR 7904760A FR 7904760 A FR7904760 A FR 7904760A FR 2449728 A2 FR2449728 A2 FR 2449728A2
- Authority
- FR
- France
- Prior art keywords
- organic phase
- uranium
- extn
- contg
- iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052770 Uranium Inorganic materials 0.000 title abstract 6
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 title abstract 6
- 229910019142 PO4 Inorganic materials 0.000 title abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title abstract 2
- 239000010452 phosphate Substances 0.000 title abstract 2
- 229940005657 pyrophosphoric acid Drugs 0.000 title abstract 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 title 1
- 150000002148 esters Chemical class 0.000 title 1
- 238000011084 recovery Methods 0.000 title 1
- 239000012074 organic phase Substances 0.000 abstract 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000005690 diesters Chemical class 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- -1 pyrophosphoric acid diester Chemical class 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
- C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
- C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
- C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
- C22B60/026—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries liquid-liquid extraction with or without dissolution in organic solvents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Geology (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Removal Of Specific Substances (AREA)
Abstract
Parent patent describes a method of recovering uranium from phosphate solns. which comprises solvent extn. using an organic phase contg. a pyrophosphoric acid diester (I), stripping the uranium from the organic phase using an alkaline soln., adding an uranium pptn. agent (IIe to the alkaline soln. (opt. after separating the organic phase), acidifying in the presence of the organic phase, agitating, separating the aq. and organic phases, and recycling the organic phase to the solvent extn. stage. Improvement is that the concn. of the diester in the organic phase is 0.1-0.4M. Additionally, the stabilising agent, which may be added to the organic phase is a heavy alcohol. Use of a high concn. of (I) in the organic phase favours extn. of uranium rather than iron from phospahte solns. even when a heavy alcohol is used as the stabiliser. Complete extn. of uranium from the solns. can be achieved using fewer extn. stages.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7904760A FR2449728A2 (en) | 1979-02-23 | 1979-02-23 | Uranium recovery from iron-contg. phosphate soln. - using conc. pyrophosphoric acid di:ester extractant phase |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7904760A FR2449728A2 (en) | 1979-02-23 | 1979-02-23 | Uranium recovery from iron-contg. phosphate soln. - using conc. pyrophosphoric acid di:ester extractant phase |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2449728A2 true FR2449728A2 (en) | 1980-09-19 |
| FR2449728B2 FR2449728B2 (en) | 1982-10-15 |
Family
ID=9222409
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7904760A Granted FR2449728A2 (en) | 1979-02-23 | 1979-02-23 | Uranium recovery from iron-contg. phosphate soln. - using conc. pyrophosphoric acid di:ester extractant phase |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2449728A2 (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2866680A (en) * | 1955-03-02 | 1958-12-30 | Ray S Long | Alkyl pyrophosphate metal solvent extractants and process |
| US2869979A (en) * | 1955-08-09 | 1959-01-20 | Robert R Grinstead | Slurry solvent extraction process for the recovery of metals from solid materials |
| US2882123A (en) * | 1955-04-18 | 1959-04-14 | Ray S Long | Process for the recovery of uranium from phosphatic ore |
| FR2070722A1 (en) * | 1969-11-27 | 1971-09-17 | Israel State | Uranium from the decomposition of phosphate |
-
1979
- 1979-02-23 FR FR7904760A patent/FR2449728A2/en active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2866680A (en) * | 1955-03-02 | 1958-12-30 | Ray S Long | Alkyl pyrophosphate metal solvent extractants and process |
| US2882123A (en) * | 1955-04-18 | 1959-04-14 | Ray S Long | Process for the recovery of uranium from phosphatic ore |
| US2869979A (en) * | 1955-08-09 | 1959-01-20 | Robert R Grinstead | Slurry solvent extraction process for the recovery of metals from solid materials |
| FR2070722A1 (en) * | 1969-11-27 | 1971-09-17 | Israel State | Uranium from the decomposition of phosphate |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2449728B2 (en) | 1982-10-15 |
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