[go: up one dir, main page]

FR2335475A1 - Selective hydrogenolysis of alkanes to ethane - using rhodium or iridium catalyst mounted on low sulphate refactory oxide carrier - Google Patents

Selective hydrogenolysis of alkanes to ethane - using rhodium or iridium catalyst mounted on low sulphate refactory oxide carrier

Info

Publication number
FR2335475A1
FR2335475A1 FR7538531A FR7538531A FR2335475A1 FR 2335475 A1 FR2335475 A1 FR 2335475A1 FR 7538531 A FR7538531 A FR 7538531A FR 7538531 A FR7538531 A FR 7538531A FR 2335475 A1 FR2335475 A1 FR 2335475A1
Authority
FR
France
Prior art keywords
ethane
alkanes
oxide carrier
hydrogenolysis
rhodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7538531A
Other languages
French (fr)
Other versions
FR2335475B1 (en
Inventor
Jacques Bousquet
Pierre Turlier
Jean-Rene Bernard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe National Elf Aquitaine
Original Assignee
Societe National Elf Aquitaine
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Societe National Elf Aquitaine filed Critical Societe National Elf Aquitaine
Priority to FR7538531A priority Critical patent/FR2335475A1/en
Priority to GB26040/76A priority patent/GB1499622A/en
Priority to SE7607277A priority patent/SE411340B/en
Priority to NO762227A priority patent/NO147597C/en
Priority to CA255,721A priority patent/CA1070337A/en
Priority to DE2628958A priority patent/DE2628958C3/en
Priority to DK291576A priority patent/DK291576A/en
Priority to BE168414A priority patent/BE843532A/en
Priority to JP51077702A priority patent/JPS527902A/en
Priority to NL7607232A priority patent/NL7607232A/en
Publication of FR2335475A1 publication Critical patent/FR2335475A1/en
Priority to US05/840,732 priority patent/US4166077A/en
Application granted granted Critical
Publication of FR2335475B1 publication Critical patent/FR2335475B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/04—Benzene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
    • C07C4/10—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from acyclic hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/26—Fuel gas
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Ethane is made by selective hydrogenolysis of alkanes by introducing a mixt. of H2 and alkanes under a total pressure P into a reactor at a space rate V, and contg. a catalyst contg. at least one metal chosen from Ir and Rh on a refractory oxide carrier low in sulphate ions SO4--, at a temp. T. The hydrogenolysis proceeds selectively to give high yields of ethane, which can be thermally cracked to give ethylene and hydrogen which is recycled to the hydrogenolysis stage.
FR7538531A 1975-06-30 1975-12-16 Selective hydrogenolysis of alkanes to ethane - using rhodium or iridium catalyst mounted on low sulphate refactory oxide carrier Granted FR2335475A1 (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
FR7538531A FR2335475A1 (en) 1975-12-16 1975-12-16 Selective hydrogenolysis of alkanes to ethane - using rhodium or iridium catalyst mounted on low sulphate refactory oxide carrier
GB26040/76A GB1499622A (en) 1975-06-30 1976-06-23 Method of production of ethane by selective hydrogenolysis of alkanes
SE7607277A SE411340B (en) 1975-06-30 1976-06-24 PROCEDURE FOR THE PRODUCTION OF ETHANE BY SELECTIVE HYDROGENOLYSIS OF ALKANES OVER A CATALYST CONTAINING CERTAIN METALS ON A CARRIER OF AN INERT FIREFUL OXIDE CONTAINING UNDER 0.5 WEIGHT% SO4 - (SULPHATIONS)
NO762227A NO147597C (en) 1975-06-30 1976-06-25 PROCEDURE FOR THE PREPARATION OF ETHANE BY SELECTIVE HYDROGENOLYSE OF ALKANES OVER AN IRIDUM OR RHODIUM-CONTAINING CATALYST
CA255,721A CA1070337A (en) 1975-06-30 1976-06-25 Method of production of ethane by selective hydrogenolysis of alkanes
DE2628958A DE2628958C3 (en) 1975-06-30 1976-06-28 Process for the production of ethane by selective, catalytic hydrogenolysis of alkanes
DK291576A DK291576A (en) 1975-06-30 1976-06-29 PROCEDURE FOR PREPARING ETHANE BY SELECTIVE HYDROGENOLYSIS OF ALKANES
BE168414A BE843532A (en) 1975-06-30 1976-06-29 ETHANE MANUFACTURING PROCESS BY SELECTIVE HYDROGENOLYSIS OF ALKANES
JP51077702A JPS527902A (en) 1975-06-30 1976-06-30 Process for preparing ethane by selective hydrogenation decomposition of alkanes
NL7607232A NL7607232A (en) 1975-06-30 1976-06-30 PROCESS FOR THE PREPARATION OF ETHANE BY SELECTIVE HYDROGENOLYSIS OF ALKANES.
US05/840,732 US4166077A (en) 1975-06-30 1977-10-11 Method of production of ethane by selective hydrogenolysis of alkane

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7538531A FR2335475A1 (en) 1975-12-16 1975-12-16 Selective hydrogenolysis of alkanes to ethane - using rhodium or iridium catalyst mounted on low sulphate refactory oxide carrier

Publications (2)

Publication Number Publication Date
FR2335475A1 true FR2335475A1 (en) 1977-07-15
FR2335475B1 FR2335475B1 (en) 1978-06-23

Family

ID=9163805

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7538531A Granted FR2335475A1 (en) 1975-06-30 1975-12-16 Selective hydrogenolysis of alkanes to ethane - using rhodium or iridium catalyst mounted on low sulphate refactory oxide carrier

Country Status (1)

Country Link
FR (1) FR2335475A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2281316C1 (en) * 2005-05-05 2006-08-10 Вадим Алексеевич Меньщиков Ethylene production process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2281316C1 (en) * 2005-05-05 2006-08-10 Вадим Алексеевич Меньщиков Ethylene production process

Also Published As

Publication number Publication date
FR2335475B1 (en) 1978-06-23

Similar Documents

Publication Publication Date Title
GB1152009A (en) Process for Preparing Methane-Containing Gases
GB1525017A (en) Steam reforming and methanation catalysts methods of making them and processes for the production of fuel gases
US2183145A (en) Process for producing hydrocarbons
FR2223449A1 (en) Reduction gas for metallurgical processes - made by passing recycle gas with carbon and/or hydrocarbons through a gas plasma to raise temp.
GB1222037A (en) Catalytic hydrogenation of di(4-aminophenyl)methane
GB1058758A (en) Process for reforming hydrocarbons, catalyst for such reforming process and method for preparing the catalyst
GB1512743A (en) Process for the manufacture of unsaturated hydrocarbons
GB8518214D0 (en) Catalyst activation
ES416286A1 (en) Process for the preparation of a nickel magnesium aluminum catalyst
GB1491499A (en) Process and catalyst for conversion of carbon monoxide and steam to hydrogen and carbon dioxide
ES2006674A6 (en) Non-cylindrical reactor for carbon black production.
GB1179120A (en) Catalysts for Use in the Production of Hydroxylammonium Salts.
FR2335475A1 (en) Selective hydrogenolysis of alkanes to ethane - using rhodium or iridium catalyst mounted on low sulphate refactory oxide carrier
FR2346309A1 (en) Selective hydrogenolysis of alkanes to ethane - using rhodium or iridium catalyst mounted on low sulphate refactory oxide carrier
GB1145032A (en) Process for the removal of oxygen and carbon oxysulphide from gases
GB1390911A (en) Production of benzene
IT1061425B (en) Selective hydrogenolysis of alkanes to ethane - using rhodium or iridium catalyst mounted on low sulphate refactory oxide carrier
FR2316206A1 (en) Selective hydrogenolysis of alkanes to ethane - using rhodium or iridium catalyst mounted on low sulphate refactory oxide carrier
GB1357502A (en) Process for producing a reducing gas
GB802100A (en) Selective hydrogenation of acetylene in ethylene
GB1342027A (en) Production of reducing gas
ES342944A1 (en) Start-up method for an lpg-reforming process
GB1523979A (en) Process for reducing chlorate content of aqueous alkali metal hydroxide solution which contains chlorate
GB1033765A (en) Process for the production of methane-containing gases
GB811820A (en) Catalytic hydrogenation of acetylene

Legal Events

Date Code Title Description
ST Notification of lapse