FR2317365A1 - PROCESS FOR SEPARATING MANGANESE FROM SOLUTIONS CONTAINING METALS, IN PARTICULAR ZINC SULPHATE SOLUTIONS - Google Patents
PROCESS FOR SEPARATING MANGANESE FROM SOLUTIONS CONTAINING METALS, IN PARTICULAR ZINC SULPHATE SOLUTIONSInfo
- Publication number
- FR2317365A1 FR2317365A1 FR7617888A FR7617888A FR2317365A1 FR 2317365 A1 FR2317365 A1 FR 2317365A1 FR 7617888 A FR7617888 A FR 7617888A FR 7617888 A FR7617888 A FR 7617888A FR 2317365 A1 FR2317365 A1 FR 2317365A1
- Authority
- FR
- France
- Prior art keywords
- zinc
- solutions
- soln
- zinc sulphate
- containing metals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011572 manganese Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 5
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 title abstract 3
- 235000009529 zinc sulphate Nutrition 0.000 title abstract 3
- 239000011686 zinc sulphate Substances 0.000 title abstract 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title abstract 2
- 229910052748 manganese Inorganic materials 0.000 title abstract 2
- 229910052751 metal Inorganic materials 0.000 title abstract 2
- 239000002184 metal Substances 0.000 title abstract 2
- 150000002739 metals Chemical class 0.000 title 1
- 239000011701 zinc Substances 0.000 abstract 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 4
- 229910052725 zinc Inorganic materials 0.000 abstract 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 239000012141 concentrate Substances 0.000 abstract 2
- 150000002500 ions Chemical class 0.000 abstract 2
- 239000007800 oxidant agent Substances 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 239000012266 salt solution Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229910003144 α-MnO2 Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/20—Obtaining zinc otherwise than by distilling
- C22B19/26—Refining solutions containing zinc values, e.g. obtained by leaching zinc ores
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/02—Oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/06—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Method of removing soluble manganous ions from a soln. contg. zinc sulphate comprises treatment of (part of) the soln. with an oxidant which can oxidise the manganous ions to insoluble filterable alpha-MnO2, the oxidant being in amount 130-150% of that theoretically required to remove all the Mn ++, and separating off the ppte. The process is effected at between 90 degrees C and the b.pt. of the soln. in 1/2-2 hrs. Used in the recovery of zinc from a concentrate of Zn contg. Mn, the concentrate having been roasted and leached to dissolve the zinc and treated to remove iron. Process may also be used in removing manganese from other metal salt solutions. In the subsequent process of electrolysing the zinc sulphate to extract the zinc, improved yields are obtained of zinc uncontaminated with Mn, having improved physical and chemical properties.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US59427875A | 1975-07-09 | 1975-07-09 | |
| US05/682,442 US4067789A (en) | 1975-07-09 | 1976-05-03 | Process for manganese removal from zinc metal bearing solutions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2317365A1 true FR2317365A1 (en) | 1977-02-04 |
| FR2317365B1 FR2317365B1 (en) | 1980-10-24 |
Family
ID=27081922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7617888A Granted FR2317365A1 (en) | 1975-07-09 | 1976-06-11 | PROCESS FOR SEPARATING MANGANESE FROM SOLUTIONS CONTAINING METALS, IN PARTICULAR ZINC SULPHATE SOLUTIONS |
Country Status (8)
| Country | Link |
|---|---|
| AR (1) | AR214399A1 (en) |
| AU (1) | AU498352B2 (en) |
| CA (1) | CA1070122A (en) |
| DE (1) | DE2626679A1 (en) |
| ES (2) | ES448693A1 (en) |
| FI (1) | FI65815C (en) |
| FR (1) | FR2317365A1 (en) |
| NL (1) | NL7606394A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0001680A1 (en) * | 1977-09-17 | 1979-05-02 | Interox Chemicals Limited | Process for the recovery of manganese from aqueous acidic solutions |
| EP0013098A1 (en) * | 1978-12-20 | 1980-07-09 | Sherritt Gordon Mines Limited | Removal of manganese ions from zinc and manganese containing solutions |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4100911A1 (en) * | 1991-01-15 | 1992-07-16 | Bayer Ag | Sepg. zinc from pyrolusite by washing with dil. mineral acid - also giving manganese di:oxide useful in pigment, oxidant and ferrite mfr. and e.g. zinc sulphate |
| WO2020031178A1 (en) * | 2018-08-09 | 2020-02-13 | Bromine Compounds Ltd. | A process for recovering metals from recycled rechargeable batteries |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE154085C (en) * | ||||
| DE303802C (en) * | ||||
| GB100171A (en) * | 1915-03-16 | 1900-01-01 | Bonastre Llopart Ramon | Process of Preparing and Inalternate White Product for Painting and other Purposes. |
| FR464038A (en) * | 1913-09-02 | 1914-03-11 | Shunjiro Araki | Process for preparing a solution of pure zinc sulphate using zinc ores |
| GB138946A (en) * | 1918-05-22 | 1920-02-26 | Samuel Field | Improvements in or relating to the purification of zinc solutions |
| US1395811A (en) * | 1919-11-07 | 1921-11-01 | Electrolytic Zinc Company | Treatment of zinc-bearing ores |
| US1937633A (en) * | 1931-03-18 | 1933-12-05 | Niels C Christensen | Process of treating zinc ores |
| US3436177A (en) * | 1968-02-28 | 1969-04-01 | Kennecott Copper Corp | Continuous process for removing multivalent impurities from copper-bearing leach solutions |
| FR2025077A1 (en) * | 1968-12-03 | 1970-09-04 | Norddeutsche Affinerie | |
| US3691038A (en) * | 1969-09-25 | 1972-09-12 | Det Norske Zenkkompani As | Process for the recovery of zinc from zinc- and iron-containing materials |
-
1976
- 1976-05-21 CA CA253,081A patent/CA1070122A/en not_active Expired
- 1976-05-26 AU AU14295/76A patent/AU498352B2/en not_active Expired
- 1976-06-09 FI FI761659A patent/FI65815C/en not_active IP Right Cessation
- 1976-06-09 ES ES448693A patent/ES448693A1/en not_active Expired
- 1976-06-11 FR FR7617888A patent/FR2317365A1/en active Granted
- 1976-06-14 NL NL7606394A patent/NL7606394A/en not_active Application Discontinuation
- 1976-06-15 DE DE19762626679 patent/DE2626679A1/en not_active Withdrawn
- 1976-06-18 AR AR263673A patent/AR214399A1/en active
-
1977
- 1977-05-05 ES ES458525A patent/ES458525A1/en not_active Expired
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE154085C (en) * | ||||
| DE303802C (en) * | ||||
| FR464038A (en) * | 1913-09-02 | 1914-03-11 | Shunjiro Araki | Process for preparing a solution of pure zinc sulphate using zinc ores |
| GB100171A (en) * | 1915-03-16 | 1900-01-01 | Bonastre Llopart Ramon | Process of Preparing and Inalternate White Product for Painting and other Purposes. |
| GB138946A (en) * | 1918-05-22 | 1920-02-26 | Samuel Field | Improvements in or relating to the purification of zinc solutions |
| US1395811A (en) * | 1919-11-07 | 1921-11-01 | Electrolytic Zinc Company | Treatment of zinc-bearing ores |
| US1937633A (en) * | 1931-03-18 | 1933-12-05 | Niels C Christensen | Process of treating zinc ores |
| US3436177A (en) * | 1968-02-28 | 1969-04-01 | Kennecott Copper Corp | Continuous process for removing multivalent impurities from copper-bearing leach solutions |
| FR2025077A1 (en) * | 1968-12-03 | 1970-09-04 | Norddeutsche Affinerie | |
| US3691038A (en) * | 1969-09-25 | 1972-09-12 | Det Norske Zenkkompani As | Process for the recovery of zinc from zinc- and iron-containing materials |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0001680A1 (en) * | 1977-09-17 | 1979-05-02 | Interox Chemicals Limited | Process for the recovery of manganese from aqueous acidic solutions |
| EP0013098A1 (en) * | 1978-12-20 | 1980-07-09 | Sherritt Gordon Mines Limited | Removal of manganese ions from zinc and manganese containing solutions |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1070122A (en) | 1980-01-22 |
| ES448693A1 (en) | 1977-11-16 |
| ES458525A1 (en) | 1978-04-01 |
| AU498352B2 (en) | 1979-03-08 |
| FI65815B (en) | 1984-03-30 |
| AU1429576A (en) | 1977-12-01 |
| DE2626679A1 (en) | 1977-01-27 |
| FR2317365B1 (en) | 1980-10-24 |
| FI761659A7 (en) | 1977-01-10 |
| NL7606394A (en) | 1977-01-11 |
| FI65815C (en) | 1984-07-10 |
| AR214399A1 (en) | 1979-06-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |