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FR2391978A1 - Light olefin cpds. prodn. from carbon mon:oxide and hydrogen - using organo-metallic iron, cobalt or nickel on inorganic support as catalyst - Google Patents

Light olefin cpds. prodn. from carbon mon:oxide and hydrogen - using organo-metallic iron, cobalt or nickel on inorganic support as catalyst

Info

Publication number
FR2391978A1
FR2391978A1 FR7716450A FR7716450A FR2391978A1 FR 2391978 A1 FR2391978 A1 FR 2391978A1 FR 7716450 A FR7716450 A FR 7716450A FR 7716450 A FR7716450 A FR 7716450A FR 2391978 A1 FR2391978 A1 FR 2391978A1
Authority
FR
France
Prior art keywords
catalyst
prodn
inorganic support
cpds
organo
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7716450A
Other languages
French (fr)
Other versions
FR2391978B1 (en
Inventor
Jean Basset
Yves Chauvin
Dominique Commereuc
Anthony Smith
Albert Theolier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7716450A priority Critical patent/FR2391978A1/en
Priority to DE19782822656 priority patent/DE2822656A1/en
Priority to ZA00783017A priority patent/ZA783017B/en
Publication of FR2391978A1 publication Critical patent/FR2391978A1/en
Application granted granted Critical
Publication of FR2391978B1 publication Critical patent/FR2391978B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/0445—Preparation; Activation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
    • C07C1/063—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons the organic compound being the catalyst or a part of the catalyst system
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/20—Carbonyls

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Process is effected using catalyst produced by depositing an organometallic Fe, Co and/or Ni cluster on an inorganic support, (substd.) metal carbonyl clusters being pref. Used for the prodn. of 2-4C olefins. The selectivity is good and only traces of condensn. prods. with >=5C are formed. In an example, a catalyst was prepd. by impregnating Al2O3 with a reaction prod. of Fe(CO)5 and pyridine of the formula Fe(C5H5N)6 Fe4(CO)13 . In the reaction of H2 and CO at 10 bar and 360 degrees C, this gave a gas contg. 16 vol.% hydrocarbons, comprising 72.4 wt.% 1-4C paraffins and 27.5 wt.% 2-4C olefins. Little water and no liquid hydrocarbons were formed.
FR7716450A 1977-05-26 1977-05-26 Light olefin cpds. prodn. from carbon mon:oxide and hydrogen - using organo-metallic iron, cobalt or nickel on inorganic support as catalyst Granted FR2391978A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
FR7716450A FR2391978A1 (en) 1977-05-26 1977-05-26 Light olefin cpds. prodn. from carbon mon:oxide and hydrogen - using organo-metallic iron, cobalt or nickel on inorganic support as catalyst
DE19782822656 DE2822656A1 (en) 1977-05-26 1978-05-24 METHOD FOR PRODUCING LIGHT OLEFINIC HYDROCARBONS BY CONVERSING HYDROGEN WITH CARBON MONOXIDE IN THE PRESENCE OF A CATALYST
ZA00783017A ZA783017B (en) 1977-05-26 1978-05-25 New catalyst process for the synthesis of light olefinic hydrocarbons by reaction of hydrogen with carbon monoxide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7716450A FR2391978A1 (en) 1977-05-26 1977-05-26 Light olefin cpds. prodn. from carbon mon:oxide and hydrogen - using organo-metallic iron, cobalt or nickel on inorganic support as catalyst

Publications (2)

Publication Number Publication Date
FR2391978A1 true FR2391978A1 (en) 1978-12-22
FR2391978B1 FR2391978B1 (en) 1980-05-16

Family

ID=9191411

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7716450A Granted FR2391978A1 (en) 1977-05-26 1977-05-26 Light olefin cpds. prodn. from carbon mon:oxide and hydrogen - using organo-metallic iron, cobalt or nickel on inorganic support as catalyst

Country Status (3)

Country Link
DE (1) DE2822656A1 (en)
FR (1) FR2391978A1 (en)
ZA (1) ZA783017B (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2456718A1 (en) * 1979-05-17 1980-12-12 Vielstich Wolf PROCESS FOR THE PREPARATION OF GASEOUS OLEFINS FROM CARBON MONOXIDE AND HYDROGEN, AND CATALYSTS FOR THIS PROCESS
FR2471961A1 (en) * 1979-12-18 1981-06-26 Haldor Topsoe As PROCESS AND CATALYST FOR THE PREPARATION OF A GASEOUS MIXTURE COMPRISING A HIGH CONTENT OF C2 HYDROCARBONS
FR2564748A1 (en) * 1984-05-24 1985-11-29 Charbonnages Ste Chimique Catalyst for hydrocondensation of carbon monoxide, process for its preparation and its application to the manufacture of hydrocarbons and aliphatic oxygen compounds
EP0170534A1 (en) * 1984-05-04 1986-02-05 Elf Atochem S.A. Process for the hydrocondensation of carbon monoxide
WO2009013174A3 (en) * 2007-07-20 2009-09-24 Basf Se Method for producing olefins through reaction of carbon monoxide with hydrogen
WO2010028995A1 (en) * 2008-09-10 2010-03-18 Basf Se Integrated method for producing carbonyl iron powder and hydrocarbons
WO2014174372A3 (en) * 2013-04-24 2015-03-26 Saudi Basic Industries Corporation Production of products from natural resources

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA814841B (en) * 1980-07-23 1983-02-23 British Petroleum Co Process for the production of lower hydrocarbons and oxygenated derivatives thereof by the catalytic conversion of carbon monoxide and hydrogen
EP2314557A1 (en) * 2009-10-23 2011-04-27 Netherlands Organisation for Scientific Research (Advanced Chemical Technologies for Sustainability) Production of lower olefins from synthesis gas
CN102711991B (en) 2009-11-06 2015-01-21 巴斯夫欧洲公司 Heterogeneous catalysts containing iron and manganese and process for the preparation of olefins by reaction of carbon monoxide with hydrogen
WO2011054738A1 (en) 2009-11-06 2011-05-12 Basf Se Ferrous heterogeneous catalyst and method for producing olefins by converting carbon monoxide with hydrogen
EP2496346A1 (en) 2009-11-06 2012-09-12 Basf Se Heterogeneous catalyst containing iron and copper and method for producing olefins by converting carbon monoxide with hydrogen

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2456718A1 (en) * 1979-05-17 1980-12-12 Vielstich Wolf PROCESS FOR THE PREPARATION OF GASEOUS OLEFINS FROM CARBON MONOXIDE AND HYDROGEN, AND CATALYSTS FOR THIS PROCESS
FR2471961A1 (en) * 1979-12-18 1981-06-26 Haldor Topsoe As PROCESS AND CATALYST FOR THE PREPARATION OF A GASEOUS MIXTURE COMPRISING A HIGH CONTENT OF C2 HYDROCARBONS
EP0170534A1 (en) * 1984-05-04 1986-02-05 Elf Atochem S.A. Process for the hydrocondensation of carbon monoxide
FR2564748A1 (en) * 1984-05-24 1985-11-29 Charbonnages Ste Chimique Catalyst for hydrocondensation of carbon monoxide, process for its preparation and its application to the manufacture of hydrocarbons and aliphatic oxygen compounds
WO2009013174A3 (en) * 2007-07-20 2009-09-24 Basf Se Method for producing olefins through reaction of carbon monoxide with hydrogen
WO2010028995A1 (en) * 2008-09-10 2010-03-18 Basf Se Integrated method for producing carbonyl iron powder and hydrocarbons
US8608824B2 (en) 2008-09-10 2013-12-17 Basf Se Integrated method for producing carbonyl iron powder and hydrocarbons
WO2014174372A3 (en) * 2013-04-24 2015-03-26 Saudi Basic Industries Corporation Production of products from natural resources
US10112883B2 (en) 2013-04-24 2018-10-30 Saudi Basic Industries Corporation Production of products from natural resources
US10676419B2 (en) 2013-04-24 2020-06-09 Saudi Basic Industries Corporation Production of products from natural resources

Also Published As

Publication number Publication date
ZA783017B (en) 1979-06-27
FR2391978B1 (en) 1980-05-16
DE2822656A1 (en) 1978-12-07

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