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FR2388782A1 - PROCESS FOR THE PREPARATION OF HYDROCARBONS FROM A MIXTURE OF CARBON OXIDE AND HYDROGEN - Google Patents

PROCESS FOR THE PREPARATION OF HYDROCARBONS FROM A MIXTURE OF CARBON OXIDE AND HYDROGEN

Info

Publication number
FR2388782A1
FR2388782A1 FR7812392A FR7812392A FR2388782A1 FR 2388782 A1 FR2388782 A1 FR 2388782A1 FR 7812392 A FR7812392 A FR 7812392A FR 7812392 A FR7812392 A FR 7812392A FR 2388782 A1 FR2388782 A1 FR 2388782A1
Authority
FR
France
Prior art keywords
mixture
hydrocarbons
hydrogen
preparation
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7812392A
Other languages
French (fr)
Other versions
FR2388782B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Publication of FR2388782A1 publication Critical patent/FR2388782A1/en
Application granted granted Critical
Publication of FR2388782B1 publication Critical patent/FR2388782B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0455—Reaction conditions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/48—Silver or gold
    • C07C2523/50—Silver
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

Procédé pour la préparation d'hydrocarbures. Un mélange d'oxyde de carbone et d'hydrogène, dont le rapport molaire H2 /CO est inférieur à 1,0, est mis en contact à température et pression élevées avec une combinaison de deux catalyseurs. Un catalyseur est capable de transformer au moins 30 moles % du mélange H2 /CO avec une sélectivité d'au moins 70 % en poids pour les hydrocarbures en C3 **+. L'autre catalyseur est capable de transformer au moins 80 moles % de l'eau présente dans un mélange d'oxyde de carbone et d'eau ayant un rapport molaire CO/H 2 O de 10,0 en hydrogène. Au moins 10 % en volume de chaque catalyseur est présent dans la combinaison de catalyseurs. On obtient une conversion accrue.Process for the preparation of hydrocarbons. A mixture of carbon monoxide and hydrogen, the H 2 / CO molar ratio of which is less than 1.0, is contacted at elevated temperature and pressure with a combination of two catalysts. A catalyst is capable of transforming at least 30 mole% of the H2 / CO mixture with a selectivity of at least 70% by weight for the C3 ** + hydrocarbons. The other catalyst is capable of converting at least 80 mole% of the water present in a mixture of carbon monoxide and water having a CO / H 2 O molar ratio of 10.0 into hydrogen. At least 10% by volume of each catalyst is present in the catalyst combination. An increased conversion is obtained.

FR7812392A 1977-04-28 1978-04-26 PROCESS FOR THE PREPARATION OF HYDROCARBONS FROM A MIXTURE OF CARBON OXIDE AND HYDROGEN Granted FR2388782A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7704656A NL7704656A (en) 1977-04-28 1977-04-28 PROCESS FOR THE PREPARATION OF HYDROCARBONS.

Publications (2)

Publication Number Publication Date
FR2388782A1 true FR2388782A1 (en) 1978-11-24
FR2388782B1 FR2388782B1 (en) 1982-04-23

Family

ID=19828450

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7812392A Granted FR2388782A1 (en) 1977-04-28 1978-04-26 PROCESS FOR THE PREPARATION OF HYDROCARBONS FROM A MIXTURE OF CARBON OXIDE AND HYDROGEN

Country Status (11)

Country Link
JP (1) JPS53135907A (en)
AU (1) AU515593B2 (en)
BE (1) BE866073A (en)
CA (1) CA1095535A (en)
DE (1) DE2818307A1 (en)
FR (1) FR2388782A1 (en)
GB (1) GB1553958A (en)
IN (1) IN147831B (en)
IT (1) IT1094563B (en)
NL (1) NL7704656A (en)
ZA (1) ZA782398B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0068603A3 (en) * 1981-06-19 1983-07-20 Coal Industry (Patents) Limited Amorphous silica-based catalyst and process for its production
EP0339923A1 (en) * 1988-04-25 1989-11-02 Exxon Research And Engineering Company Process for hydrocarbon synthesis catalyzed by cobalt on titania, enhanced by water addition
US5227407A (en) * 1985-12-30 1993-07-13 Exxon Research And Engineering Company Water addition for increased CO/H2 hydrocarbon synthesis activity over catalysts comprising cobalt, ruthenium and mixtures thereof which may include a promoter metal

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7704658A (en) * 1977-04-28 1978-10-31 Shell Int Research PROCESS FOR THE PREPARATION OF HYDROCARBONS.
NL179576C (en) * 1979-06-06 1986-10-01 Shell Int Research CRYSTALLINE SILICATES; PROCESS FOR PREPARING CRYSTALLINE SILICATES; PROCESS FOR PREPARING AROMATIC HYDROCARBONS.
ZA814841B (en) * 1980-07-23 1983-02-23 British Petroleum Co Process for the production of lower hydrocarbons and oxygenated derivatives thereof by the catalytic conversion of carbon monoxide and hydrogen
NL8400609A (en) * 1984-02-28 1985-09-16 Shell Int Research PROCESS FOR PREPARING HYDROCARBONS.
US4579830A (en) * 1984-06-27 1986-04-01 Union Carbide Corporation Enhanced catalyst for converting synthesis gas to liquid motor fuels
GB2169614A (en) * 1984-12-31 1986-07-16 Mobil Oil Corp Producing alpha-olefins and their conversion into lubricants
GB2204055B (en) * 1987-04-29 1992-01-02 Shell Int Research Process for the preparation of hydrocarbons
JPH01172949U (en) * 1988-05-25 1989-12-07

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2486895A (en) * 1945-12-07 1949-11-01 Texas Co Process for catalytic conversion of carbon oxides
US4017274A (en) * 1974-07-30 1977-04-12 Bechtel Associates Professional Corporation Process for the methanation of gases containing high concentration of carbon monoxide

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7704658A (en) * 1977-04-28 1978-10-31 Shell Int Research PROCESS FOR THE PREPARATION OF HYDROCARBONS.

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2486895A (en) * 1945-12-07 1949-11-01 Texas Co Process for catalytic conversion of carbon oxides
US4017274A (en) * 1974-07-30 1977-04-12 Bechtel Associates Professional Corporation Process for the methanation of gases containing high concentration of carbon monoxide

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0068603A3 (en) * 1981-06-19 1983-07-20 Coal Industry (Patents) Limited Amorphous silica-based catalyst and process for its production
US5227407A (en) * 1985-12-30 1993-07-13 Exxon Research And Engineering Company Water addition for increased CO/H2 hydrocarbon synthesis activity over catalysts comprising cobalt, ruthenium and mixtures thereof which may include a promoter metal
EP0339923A1 (en) * 1988-04-25 1989-11-02 Exxon Research And Engineering Company Process for hydrocarbon synthesis catalyzed by cobalt on titania, enhanced by water addition

Also Published As

Publication number Publication date
ZA782398B (en) 1979-04-25
BE866073A (en) 1978-10-18
DE2818307A1 (en) 1978-11-02
JPS631297B2 (en) 1988-01-12
DE2818307C2 (en) 1988-09-01
AU3538078A (en) 1979-11-01
IT7822722A0 (en) 1978-04-26
NL7704656A (en) 1978-10-31
JPS53135907A (en) 1978-11-28
CA1095535A (en) 1981-02-10
FR2388782B1 (en) 1982-04-23
IT1094563B (en) 1985-08-02
AU515593B2 (en) 1981-04-09
GB1553958A (en) 1979-10-17
IN147831B (en) 1980-07-19

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