FR2375142A1 - Clarification and defluorination of phosphoric acid - by simultaneously using powdered silicate(s), esp. bentonite and stirring - Google Patents
Clarification and defluorination of phosphoric acid - by simultaneously using powdered silicate(s), esp. bentonite and stirringInfo
- Publication number
- FR2375142A1 FR2375142A1 FR7605359A FR7605359A FR2375142A1 FR 2375142 A1 FR2375142 A1 FR 2375142A1 FR 7605359 A FR7605359 A FR 7605359A FR 7605359 A FR7605359 A FR 7605359A FR 2375142 A1 FR2375142 A1 FR 2375142A1
- Authority
- FR
- France
- Prior art keywords
- clarification
- defluorination
- phosphoric acid
- acid
- stirring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title abstract 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 title abstract 3
- 238000005352 clarification Methods 0.000 title abstract 3
- 238000006115 defluorination reaction Methods 0.000 title abstract 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 title abstract 2
- 238000003756 stirring Methods 0.000 title abstract 2
- 229910000278 bentonite Inorganic materials 0.000 title 1
- 239000000440 bentonite Substances 0.000 title 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 title 1
- 239000002253 acid Substances 0.000 abstract 4
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- 230000003226 decolorizating effect Effects 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- 239000005416 organic matter Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/234—Purification; Stabilisation; Concentration
- C01B25/237—Selective elimination of impurities
- C01B25/2372—Anionic impurities, e.g. silica or boron compounds
- C01B25/2375—Fluoride or fluosilicate anion
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/234—Purification; Stabilisation; Concentration
- C01B25/235—Clarification; Stabilisation to prevent post-precipitation of dissolved impurities
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
Simultaneous clarification and defluorination of phosphoric acid comprises mixing the acid with >=1 powdered decolourising earths, stirring the mixt. until the fluorine has reacted with the silicate of the earth and the organic matter has adsorbed on the acid of the earth, finally sepg. the clarified phosphoric acid. Single-stage defluorination and clarification suitable for acid contg. 30% P2O5 and more conc. acid, contg. about 50% P2O5.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7605359A FR2375142A1 (en) | 1976-02-26 | 1976-02-26 | Clarification and defluorination of phosphoric acid - by simultaneously using powdered silicate(s), esp. bentonite and stirring |
| FR8111229A FR2507170A2 (en) | 1976-02-26 | 1981-06-05 | Phosphoric acid clarification and defluorination - by treatment with pre-wetted clay |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7605359A FR2375142A1 (en) | 1976-02-26 | 1976-02-26 | Clarification and defluorination of phosphoric acid - by simultaneously using powdered silicate(s), esp. bentonite and stirring |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2375142A1 true FR2375142A1 (en) | 1978-07-21 |
| FR2375142B1 FR2375142B1 (en) | 1979-08-10 |
Family
ID=9169632
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7605359A Granted FR2375142A1 (en) | 1976-02-26 | 1976-02-26 | Clarification and defluorination of phosphoric acid - by simultaneously using powdered silicate(s), esp. bentonite and stirring |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2375142A1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0016264A1 (en) * | 1978-12-19 | 1980-10-01 | METALLURGIE HOBOKEN-OVERPELT Société anonyme dite: | Process for extracting uranium from phosphoric acid |
| EP0016531A3 (en) * | 1979-03-19 | 1980-12-10 | INTERNATIONAL MINERALS & CHEMICAL CORPORATION | Purification of phosphoric acid |
| US4341638A (en) * | 1979-10-17 | 1982-07-27 | International Minerals & Chemical Corp. | Purification of phosphoric acid |
| FR2507170A2 (en) * | 1976-02-26 | 1982-12-10 | Ind Chimiques Maghrebines | Phosphoric acid clarification and defluorination - by treatment with pre-wetted clay |
| US5002744A (en) * | 1990-05-11 | 1991-03-26 | Imc Fertilizer, Inc. | Method for defluorinating wet process phosphoric acid |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2123785A (en) * | 1936-03-02 | 1938-07-12 | Victor Chemical Works | Removal of fluorine from phosphoric acid |
| US2132349A (en) * | 1937-01-02 | 1938-10-04 | Monsanto Chemicals | Treatment of phosphoric acid to remove fluorine |
| FR1456268A (en) * | 1964-11-30 | 1966-10-21 | Argus Chem | Tin alkylation process |
-
1976
- 1976-02-26 FR FR7605359A patent/FR2375142A1/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2123785A (en) * | 1936-03-02 | 1938-07-12 | Victor Chemical Works | Removal of fluorine from phosphoric acid |
| US2132349A (en) * | 1937-01-02 | 1938-10-04 | Monsanto Chemicals | Treatment of phosphoric acid to remove fluorine |
| FR1456268A (en) * | 1964-11-30 | 1966-10-21 | Argus Chem | Tin alkylation process |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2507170A2 (en) * | 1976-02-26 | 1982-12-10 | Ind Chimiques Maghrebines | Phosphoric acid clarification and defluorination - by treatment with pre-wetted clay |
| EP0016264A1 (en) * | 1978-12-19 | 1980-10-01 | METALLURGIE HOBOKEN-OVERPELT Société anonyme dite: | Process for extracting uranium from phosphoric acid |
| EP0016531A3 (en) * | 1979-03-19 | 1980-12-10 | INTERNATIONAL MINERALS & CHEMICAL CORPORATION | Purification of phosphoric acid |
| US4256570A (en) * | 1979-03-19 | 1981-03-17 | International Minerals & Chemical Corporation | Purification of phosphoric acid |
| US4341638A (en) * | 1979-10-17 | 1982-07-27 | International Minerals & Chemical Corp. | Purification of phosphoric acid |
| US5002744A (en) * | 1990-05-11 | 1991-03-26 | Imc Fertilizer, Inc. | Method for defluorinating wet process phosphoric acid |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2375142B1 (en) | 1979-08-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |