FR2298367A1 - Dual-purpose catalysts for exhaust gas purifcn - by simultaneous oxidn and reduction in a single-bed process - Google Patents
Dual-purpose catalysts for exhaust gas purifcn - by simultaneous oxidn and reduction in a single-bed processInfo
- Publication number
- FR2298367A1 FR2298367A1 FR7601884A FR7601884A FR2298367A1 FR 2298367 A1 FR2298367 A1 FR 2298367A1 FR 7601884 A FR7601884 A FR 7601884A FR 7601884 A FR7601884 A FR 7601884A FR 2298367 A1 FR2298367 A1 FR 2298367A1
- Authority
- FR
- France
- Prior art keywords
- oxidn
- simultaneous
- silica
- purifcn
- dual
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract 3
- 239000000377 silicon dioxide Substances 0.000 abstract 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- 239000000969 carrier Substances 0.000 abstract 1
- 229910000420 cerium oxide Inorganic materials 0.000 abstract 1
- 229910052878 cordierite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 abstract 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 229910052863 mullite Inorganic materials 0.000 abstract 1
- 229910000480 nickel oxide Inorganic materials 0.000 abstract 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 abstract 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 abstract 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 239000000741 silica gel Substances 0.000 abstract 1
- 229910002027 silica gel Inorganic materials 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 229910052596 spinel Inorganic materials 0.000 abstract 1
- 239000011029 spinel Substances 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 229910001928 zirconium oxide Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
- B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/894—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Combustion & Propulsion (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
Catalyst for simultaneous oxidn. of CO and hydrocarbons and redn. of nitrogen oxides in exhaust gases from i.c. engines, contains (a) 0.01-2 wt.% Pd and/or Pt, (b) 0.1-10% cerium oxide and/or zirconium oxide, (c) 3-60% nickel oxide, and (d) silica and/or alumina carrier as the remainder. Impurities are efficiently removed by a single bed instead of two catalyst beds of different compsn. Suitable carriers are alumina, silica gel, silica/zirconia, silica/alumina cordierite, MgO/Al2O3 spinel or mullite, pref. with surface area 50-400 m2/g and sufficient porosity to take up 0.3-2 ml. soln. per g. solid carrier.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US54402575A | 1975-01-24 | 1975-01-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2298367A1 true FR2298367A1 (en) | 1976-08-20 |
| FR2298367B3 FR2298367B3 (en) | 1978-10-13 |
Family
ID=24170475
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7601884A Granted FR2298367A1 (en) | 1975-01-24 | 1976-01-23 | Dual-purpose catalysts for exhaust gas purifcn - by simultaneous oxidn and reduction in a single-bed process |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS5187490A (en) |
| DE (1) | DE2602286A1 (en) |
| FR (1) | FR2298367A1 (en) |
| IT (1) | IT1054981B (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2403824A1 (en) * | 1977-09-23 | 1979-04-20 | Engelhard Min & Chem | CATALYTIC COMPOSITIONS, PREPARATION AND USE |
| FR2403825A1 (en) * | 1977-09-23 | 1979-04-20 | Engelhard Min & Chem | CATALYTIC COMPOSITIONS, PREPARATION AND APPLICATION |
| EP0125565A3 (en) * | 1983-05-12 | 1986-12-30 | Nippon Shokubai Kagaku Kogyo Co., Ltd | Process for producing honeycomb catalyst for exhaust gas conversion |
| FR2595265A1 (en) * | 1986-03-07 | 1987-09-11 | Pro Catalyse | Catalyst and process for the treatment of exhaust gases of internal combustion engines |
| EP0221598A3 (en) * | 1985-11-08 | 1987-10-28 | Shell Internationale Research Maatschappij B.V. | Supported metal catalysts and use thereof |
| EP0244127A1 (en) * | 1986-04-16 | 1987-11-04 | Johnson Matthey, Inc., | Method for catalytically controlling exhaust gaz from automobiles |
| EP0272136A3 (en) * | 1986-12-18 | 1989-02-22 | Nippon Shokubai Kagaku Kogyo Co., Ltd | Catalyst for purifying exhaust gas and method for its production |
| US4895824A (en) * | 1987-09-08 | 1990-01-23 | W. R. Grace & Co.-Conn. | Add-on hydrogen sulfide trap |
| WO1999037397A1 (en) * | 1998-01-21 | 1999-07-29 | Dytech Corporation Ltd. | Catalyst carrier carrying nickel, aluminium, lanthanum and a precious metal element |
| WO2000043121A1 (en) * | 1999-01-21 | 2000-07-27 | Imperial Chemical Industries Plc | Catalyst carrier carrying nickel ruthenium and lanthanum |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022022813A1 (en) * | 2020-07-28 | 2022-02-03 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method of forming dielectric films, new precursors and their use in the semi-conductor manufacturing |
-
1975
- 1975-09-12 JP JP50110137A patent/JPS5187490A/ja active Pending
-
1976
- 1976-01-22 DE DE19762602286 patent/DE2602286A1/en active Pending
- 1976-01-23 IT IT19553/76A patent/IT1054981B/en active
- 1976-01-23 FR FR7601884A patent/FR2298367A1/en active Granted
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2403824A1 (en) * | 1977-09-23 | 1979-04-20 | Engelhard Min & Chem | CATALYTIC COMPOSITIONS, PREPARATION AND USE |
| FR2403825A1 (en) * | 1977-09-23 | 1979-04-20 | Engelhard Min & Chem | CATALYTIC COMPOSITIONS, PREPARATION AND APPLICATION |
| EP0125565A3 (en) * | 1983-05-12 | 1986-12-30 | Nippon Shokubai Kagaku Kogyo Co., Ltd | Process for producing honeycomb catalyst for exhaust gas conversion |
| EP0221598A3 (en) * | 1985-11-08 | 1987-10-28 | Shell Internationale Research Maatschappij B.V. | Supported metal catalysts and use thereof |
| FR2595265A1 (en) * | 1986-03-07 | 1987-09-11 | Pro Catalyse | Catalyst and process for the treatment of exhaust gases of internal combustion engines |
| EP0244127A1 (en) * | 1986-04-16 | 1987-11-04 | Johnson Matthey, Inc., | Method for catalytically controlling exhaust gaz from automobiles |
| EP0272136A3 (en) * | 1986-12-18 | 1989-02-22 | Nippon Shokubai Kagaku Kogyo Co., Ltd | Catalyst for purifying exhaust gas and method for its production |
| US4895824A (en) * | 1987-09-08 | 1990-01-23 | W. R. Grace & Co.-Conn. | Add-on hydrogen sulfide trap |
| WO1999037397A1 (en) * | 1998-01-21 | 1999-07-29 | Dytech Corporation Ltd. | Catalyst carrier carrying nickel, aluminium, lanthanum and a precious metal element |
| WO2000043121A1 (en) * | 1999-01-21 | 2000-07-27 | Imperial Chemical Industries Plc | Catalyst carrier carrying nickel ruthenium and lanthanum |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2602286A1 (en) | 1976-07-29 |
| IT1054981B (en) | 1981-11-30 |
| FR2298367B3 (en) | 1978-10-13 |
| JPS5187490A (en) | 1976-07-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |