FR2114954A5 - Paper binder - by reacting polyaminoamide from long chain (un)satd (cycloaliphatic acids and excess polyamine with epihalohydri - Google Patents
Paper binder - by reacting polyaminoamide from long chain (un)satd (cycloaliphatic acids and excess polyamine with epihalohydriInfo
- Publication number
- FR2114954A5 FR2114954A5 FR7142386A FR7142386A FR2114954A5 FR 2114954 A5 FR2114954 A5 FR 2114954A5 FR 7142386 A FR7142386 A FR 7142386A FR 7142386 A FR7142386 A FR 7142386A FR 2114954 A5 FR2114954 A5 FR 2114954A5
- Authority
- FR
- France
- Prior art keywords
- aliphatic
- pref
- cycloaliphatic
- reaction
- pdt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title abstract 3
- 229920000768 polyamine Polymers 0.000 title abstract 3
- 150000007513 acids Chemical class 0.000 title 1
- 239000011230 binding agent Substances 0.000 title 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 3
- 125000003277 amino group Chemical group 0.000 abstract 2
- 125000004429 atom Chemical group 0.000 abstract 2
- 230000005494 condensation Effects 0.000 abstract 2
- 238000009833 condensation Methods 0.000 abstract 2
- 229920001131 Pulp (paper) Polymers 0.000 abstract 1
- 230000032683 aging Effects 0.000 abstract 1
- 125000003368 amide group Chemical group 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 230000014759 maintenance of location Effects 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/48—Polymers modified by chemical after-treatment
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
- D21H17/55—Polyamides; Polyaminoamides; Polyester-amides
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
Abstract
Paper binding is effected in the mass by adding to the paper pulp an aqs. soln. or dispersion of a cationic condensation pdt. with amide groups obtained by reacting one equivalent of active H atoms bonded to the N of the amino groups of a polyaminoamide (I) with 0.5-2.0, pref. 0.8-1.5 mole of an epihalohydrin of formula (II) (where R is H or CH3; and X is Cl or Br) adding to the reaction mixt, before or after the reaction of (I) with (II), a solvent which is at least partly aqueous, and adjusting the pH of the reaction mixt. towards the end of the reaction to 6.0-8.0, pref. 7. (I) is obtained by condensing (a) a polyunsatd. (cyclo)aliphatic, or cycloaliphatic-aliphatic monocarboxylic acid having at least 16 pref. 18-24C atoms; or a(n) (un)satd. (cyclo)aliphatic or cycloaliphatic-aliphatic polycarboxylic acid having at least 16, pref. 18-24C atoms; and (b) a (cyclo)aliphatic, cycloaliphatic-aliphatic or heterocyclic-aliphatic polyamine contg. at least two primary amino groups, pref. a polyalkylene-polyamine, using an excess of amino groups of (b) relative to the carboxyl groups of (a). The condensation pdt. has excellent binding properties and gives paper with a permanent high wet strength, and assists in the retention of fillers. Only small amounts of the pdt. are required and they operate effectively under acid or alkaline conditions. The pdts. have a good resistance to ageing.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1776770 | 1970-12-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| FR2114954A5 true FR2114954A5 (en) | 1972-06-30 |
Family
ID=4427952
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7142386A Expired FR2114954A5 (en) | 1970-12-01 | 1971-11-26 | Paper binder - by reacting polyaminoamide from long chain (un)satd (cycloaliphatic acids and excess polyamine with epihalohydri |
Country Status (8)
| Country | Link |
|---|---|
| AU (1) | AU3582571A (en) |
| BE (1) | BE776009A (en) |
| BR (1) | BR7107953D0 (en) |
| DE (1) | DE2157932A1 (en) |
| FR (1) | FR2114954A5 (en) |
| IT (1) | IT945097B (en) |
| NL (1) | NL7116300A (en) |
| ZA (1) | ZA717720B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0678620A3 (en) * | 1994-04-18 | 1996-07-17 | Hercules Inc | Oligoamide-epichlorohydrin resins used as draining agents. |
| EP1865013A1 (en) * | 2006-06-09 | 2007-12-12 | Air Products and Chemicals, Inc. | Polyamide curing agent compositions |
| US7655736B2 (en) | 2006-06-09 | 2010-02-02 | Air Products And Chemicals, Inc. | Polyamide curative from substituted amine mixture and dimer fatty acid or ester |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070287808A1 (en) * | 2006-06-09 | 2007-12-13 | Gamini Ananda Vedage | Polyamide curing agent compositions |
-
1971
- 1971-11-16 ZA ZA717720A patent/ZA717720B/en unknown
- 1971-11-17 AU AU35825/71A patent/AU3582571A/en not_active Expired
- 1971-11-23 DE DE19712157932 patent/DE2157932A1/en active Pending
- 1971-11-26 NL NL7116300A patent/NL7116300A/xx unknown
- 1971-11-26 FR FR7142386A patent/FR2114954A5/en not_active Expired
- 1971-11-30 IT IT54421/71A patent/IT945097B/en active
- 1971-11-30 BR BR7953/71A patent/BR7107953D0/en unknown
- 1971-11-30 BE BE776009A patent/BE776009A/en unknown
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0678620A3 (en) * | 1994-04-18 | 1996-07-17 | Hercules Inc | Oligoamide-epichlorohydrin resins used as draining agents. |
| US5656699A (en) * | 1994-04-18 | 1997-08-12 | Hercules Incorporated | Oligoamide-epichlorohydrin resins as drainage aids |
| EP1865013A1 (en) * | 2006-06-09 | 2007-12-12 | Air Products and Chemicals, Inc. | Polyamide curing agent compositions |
| US7655736B2 (en) | 2006-06-09 | 2010-02-02 | Air Products And Chemicals, Inc. | Polyamide curative from substituted amine mixture and dimer fatty acid or ester |
| US8293863B2 (en) | 2006-06-09 | 2012-10-23 | Air Products And Chemicals, Inc. | Polyamide curative from substituted amine and dimer fatty acid or ester |
Also Published As
| Publication number | Publication date |
|---|---|
| AU3582571A (en) | 1973-05-24 |
| NL7116300A (en) | 1972-06-05 |
| BR7107953D0 (en) | 1973-06-07 |
| DE2157932A1 (en) | 1972-06-15 |
| BE776009A (en) | 1972-05-30 |
| ZA717720B (en) | 1972-08-30 |
| IT945097B (en) | 1973-05-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |