FR2063197A5 - Metal sepn process by solvent extraction - Google Patents
Metal sepn process by solvent extractionInfo
- Publication number
- FR2063197A5 FR2063197A5 FR6929924A FR6929924A FR2063197A5 FR 2063197 A5 FR2063197 A5 FR 2063197A5 FR 6929924 A FR6929924 A FR 6929924A FR 6929924 A FR6929924 A FR 6929924A FR 2063197 A5 FR2063197 A5 FR 2063197A5
- Authority
- FR
- France
- Prior art keywords
- metal
- solvent
- aqueous
- pref
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052751 metal Inorganic materials 0.000 title abstract 6
- 239000002184 metal Substances 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 3
- 238000000638 solvent extraction Methods 0.000 title 1
- 239000002904 solvent Substances 0.000 abstract 7
- 239000008346 aqueous phase Substances 0.000 abstract 2
- 229910052692 Dysprosium Inorganic materials 0.000 abstract 1
- 229910052779 Neodymium Inorganic materials 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 229910052777 Praseodymium Inorganic materials 0.000 abstract 1
- 229910052772 Samarium Inorganic materials 0.000 abstract 1
- 150000003973 alkyl amines Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- -1 alkyl phosphate Chemical compound 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000005191 phase separation Methods 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 1
- 150000002910 rare earth metals Chemical class 0.000 abstract 1
- 230000000717 retained effect Effects 0.000 abstract 1
- XREXPQGDOPQPAH-QKUPJAQQSA-K trisodium;[(z)-18-[1,3-bis[[(z)-12-sulfonatooxyoctadec-9-enoyl]oxy]propan-2-yloxy]-18-oxooctadec-9-en-7-yl] sulfate Chemical compound [Na+].[Na+].[Na+].CCCCCCC(OS([O-])(=O)=O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(CCCCCC)OS([O-])(=O)=O)COC(=O)CCCCCCC\C=C/CC(CCCCCC)OS([O-])(=O)=O XREXPQGDOPQPAH-QKUPJAQQSA-K 0.000 abstract 1
- 229910052727 yttrium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B59/00—Obtaining rare earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0488—Flow sheets
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/28—Amines
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3846—Phosphoric acid, e.g. (O)P(OH)3
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/40—Mixtures
- C22B3/409—Mixtures at least one compound being an organo-metallic compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
An aqueous metal soln. is mixed with an immiscible solvent for extracting at least one metal. The solvent and aqueous phases are separated, and the aquasol is mixed with a second immiscible solvent to repeat the process for a different metal. Sequential mixing of different solvents and phase separation is repeated until the required degree of metal concentration in the solvent soln. is obtained. The metals are then isolated from their solvents. More spec., the process is for separating rare earth metals, particularly Pr, Nd and Sm from Dy and Y, whereby Gd is retained in the aqueous phase from which it is separated by evaporation. A suitable solvent is an alkyl amine, pref. a mixture of tertiary alkyl (primary) amine with 18-21 C-atoms, with an alkyl phosphate, pref. di-2-ethyl hexyl phosphoric acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR6929924A FR2063197A5 (en) | 1969-09-02 | 1969-09-02 | Metal sepn process by solvent extraction |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR6929924A FR2063197A5 (en) | 1969-09-02 | 1969-09-02 | Metal sepn process by solvent extraction |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| FR2063197A5 true FR2063197A5 (en) | 1971-07-09 |
Family
ID=9039643
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR6929924A Expired FR2063197A5 (en) | 1969-09-02 | 1969-09-02 | Metal sepn process by solvent extraction |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2063197A5 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2190510A1 (en) * | 1972-06-28 | 1974-02-01 | Inst Francais Du Petrole | Immiscible liquid/fluid contacting column - through which a single stream of one component passes counter current to 3 parallel streams of second component |
| FR2436821A1 (en) * | 1978-09-22 | 1980-04-18 | Goldschmidt Ag Th | PROCESS FOR TREATING RESIDUES FROM NON-FERROUS HEAVY METAL HYDROXIDE SLUDGES |
-
1969
- 1969-09-02 FR FR6929924A patent/FR2063197A5/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2190510A1 (en) * | 1972-06-28 | 1974-02-01 | Inst Francais Du Petrole | Immiscible liquid/fluid contacting column - through which a single stream of one component passes counter current to 3 parallel streams of second component |
| FR2436821A1 (en) * | 1978-09-22 | 1980-04-18 | Goldschmidt Ag Th | PROCESS FOR TREATING RESIDUES FROM NON-FERROUS HEAVY METAL HYDROXIDE SLUDGES |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |