FI81613B - Katoder laempliga foer vaetealstrande elektrokemiska processer. - Google Patents
Katoder laempliga foer vaetealstrande elektrokemiska processer. Download PDFInfo
- Publication number
- FI81613B FI81613B FI873122A FI873122A FI81613B FI 81613 B FI81613 B FI 81613B FI 873122 A FI873122 A FI 873122A FI 873122 A FI873122 A FI 873122A FI 81613 B FI81613 B FI 81613B
- Authority
- FI
- Finland
- Prior art keywords
- cathode
- platinum
- gold
- ruthenium
- silver
- Prior art date
Links
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 69
- 229910052737 gold Inorganic materials 0.000 claims description 43
- 239000010931 gold Substances 0.000 claims description 43
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 42
- 238000000576 coating method Methods 0.000 claims description 38
- 239000000758 substrate Substances 0.000 claims description 38
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 36
- 239000011248 coating agent Substances 0.000 claims description 36
- 229910052697 platinum Inorganic materials 0.000 claims description 33
- 229910052707 ruthenium Inorganic materials 0.000 claims description 26
- 229910052709 silver Inorganic materials 0.000 claims description 25
- 239000004332 silver Substances 0.000 claims description 25
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 24
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 24
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 23
- 239000010411 electrocatalyst Substances 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 21
- 229910052742 iron Inorganic materials 0.000 claims description 20
- 229910052751 metal Inorganic materials 0.000 claims description 19
- 239000002184 metal Substances 0.000 claims description 19
- 239000002245 particle Substances 0.000 claims description 16
- -1 polytetrafluoroethylene Polymers 0.000 claims description 15
- 229910052759 nickel Inorganic materials 0.000 claims description 12
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 10
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 10
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 10
- 231100000572 poisoning Toxicity 0.000 claims description 9
- 230000000607 poisoning effect Effects 0.000 claims description 9
- 229920000620 organic polymer Polymers 0.000 claims description 8
- 239000002243 precursor Substances 0.000 claims description 8
- 238000001556 precipitation Methods 0.000 claims description 7
- 230000001427 coherent effect Effects 0.000 claims description 5
- 230000008021 deposition Effects 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims 1
- 239000000243 solution Substances 0.000 description 16
- 239000002244 precipitate Substances 0.000 description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 13
- 229910052739 hydrogen Inorganic materials 0.000 description 13
- 239000001257 hydrogen Substances 0.000 description 13
- CFQCIHVMOFOCGH-UHFFFAOYSA-N platinum ruthenium Chemical compound [Ru].[Pt] CFQCIHVMOFOCGH-UHFFFAOYSA-N 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 239000003513 alkali Substances 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 238000003843 chloralkali process Methods 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 2
- 229940106681 chloroacetic acid Drugs 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000007788 roughening Methods 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical group [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- 229910001111 Fine metal Inorganic materials 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- AOGYCOYQMAVAFD-UHFFFAOYSA-N chlorocarbonic acid Chemical compound OC(Cl)=O AOGYCOYQMAVAFD-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910003446 platinum oxide Inorganic materials 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 1
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
- C25B11/095—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds at least one of the compounds being organic
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/42—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/462—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
- C25B11/097—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds comprising two or more noble metals or noble metal alloys
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inert Electrodes (AREA)
- Cell Electrode Carriers And Collectors (AREA)
Claims (9)
1. Katod lämplig för användning vid en vätgasutvecklande elektrokemisk process, omfattande ett elektriskt ledande substrat av icke-järnmetall eller uppvisande en koherent, icke-porös beläggning av icke-järnmetall, en elektrokataly-sator omfattande en avsättning av platina och rutenium eller prekursorer därav pä det ledande substratet, och en avsättning för öka katodens förgiftningsresistans gentemot järn jäm-fört med en liknande katod utan nämnda avsättning, kännetecknad av att avsättningen omfattar guld-och/eller silvermetall.
2. Katod enligt patentkrav 1, kännetecknad av att mängden guld och silver som avsätts uppgär tili mellan 0,1 och 11 vikt-% av den totala vikten av platinagruppens metall (inkluderande metallmängden av nägon prekursor).
3. Katod enligt patentkrav 1 eller 2, kännetecknad av att substratet innehäller nickel.
4. Katod enligt nSgot av patentkraven 1-3, kännetecknad av att elektrokatalysatorn även omfattar partiklar av en organisk polymer.
5. Katod enligt patentkrav 4, kännetecknad av att den organiska polymeren är polytetrafluoreten.
6. Förfarande för framställnig av en katod enligt patentkrav 1, kännetecknad av att platina och rutenium eller prekursorer därav avsätts pä ett elektriskt ledande substrat av en icke-järnmetall eller uppvisande en koherent, icke-porös beläggning av icke-järnmetall, och av guld- och/eller silvermetall bildas en avsättning.
7. Förfarande enligt patentkrav 6, kännetecknat av att platinat och ruteniet avsätts genom bytesutfällning.
8. Förfarande enligt patentkrav 6 eller 7, kännetecknat av att guldet och/eller silvret avsätts genom bytesutfällning. 15 81613
9. Förfarande enligt nägot av patentkraven 6-8, kännetecknat av att platinat och ruteniet av-sätts först och dSrefter avsätts guldet och/eller silvret.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB868617325A GB8617325D0 (en) | 1986-07-16 | 1986-07-16 | Poison-resistant cathodes |
| GB8617325 | 1986-07-16 |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI873122A0 FI873122A0 (fi) | 1987-07-15 |
| FI873122L FI873122L (fi) | 1988-01-17 |
| FI81613B true FI81613B (fi) | 1990-07-31 |
| FI81613C FI81613C (sv) | 1990-11-12 |
Family
ID=10601136
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI873122A FI81613C (sv) | 1986-07-16 | 1987-07-15 | Katoder lämpliga för vätealstrande elektrokemiska processer |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4784730A (sv) |
| EP (1) | EP0256673B1 (sv) |
| JP (1) | JP2584778B2 (sv) |
| KR (1) | KR950000644B1 (sv) |
| AU (1) | AU606604B2 (sv) |
| CA (1) | CA1311720C (sv) |
| DE (1) | DE3776458D1 (sv) |
| ES (1) | ES2028084T3 (sv) |
| FI (1) | FI81613C (sv) |
| GB (1) | GB8617325D0 (sv) |
| HK (1) | HK179895A (sv) |
| NO (1) | NO167047C (sv) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU7780291A (en) * | 1990-03-13 | 1991-10-10 | Boris M. Khudenko | Method and apparatus for nuclear fusion |
| US5759944A (en) * | 1993-04-20 | 1998-06-02 | Johnson Matthey Public Limited Company | Catalyst material |
| US5968325A (en) * | 1997-01-07 | 1999-10-19 | A.T.S. Electro-Lube Holdings Ltd. | Auto-electrolytic hydrogen generator |
| CA2243219A1 (en) * | 1998-07-14 | 2000-01-14 | A.T.S. Electro-Lube Holdings Ltd. | Electrolytic generation of nitrogen |
| WO2005103337A1 (ja) | 2004-04-23 | 2005-11-03 | Tosoh Corporation | 水素発生用電極およびその製造方法並びにこれを用いた電解方法 |
| JP4341838B2 (ja) * | 2004-10-01 | 2009-10-14 | ペルメレック電極株式会社 | 電解用陰極 |
| JP4771467B2 (ja) * | 2005-11-17 | 2011-09-14 | 東亞合成株式会社 | 高純度水酸化アルカリ金属の製造方法 |
| ITMI20091621A1 (it) * | 2009-09-23 | 2011-03-24 | Industrie De Nora Spa | Elettrodo per processi elettrolitici con struttura cristallina controllata |
| EP3440241A1 (de) * | 2016-04-07 | 2019-02-13 | Covestro Deutschland AG | Bifunktionelle elektrode und elektrolysevorrichtung für die chlor-alkali-elektrolyse |
| JP6743483B2 (ja) * | 2016-05-24 | 2020-08-19 | 東洋インキＳｃホールディングス株式会社 | 水電解装置に用いられる触媒層形成用組成物、触媒層及び水電解装置 |
| CN111293303B (zh) * | 2018-12-06 | 2021-06-29 | 中国科学院大连化学物理研究所 | 一种镁水电池阴极及其制备方法与应用 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH340810A (de) * | 1955-04-01 | 1959-09-15 | Lonza Ag | Verfahren zum Aktivieren der Kathodenflächen von elektrolytischen Wasserstofferzeugern |
| DE1567718A1 (de) * | 1966-12-23 | 1970-07-02 | Barthel Dipl Ing Dipl Chem Gue | Elektrode fuer die elektrolytische Zerlegung von Salzsaeure und Verfahren zu ihrer Herstellung |
| JPS5128057A (ja) * | 1974-08-31 | 1976-03-09 | Matsushita Electric Works Ltd | Denkikamisori |
| US4191618A (en) * | 1977-12-23 | 1980-03-04 | General Electric Company | Production of halogens in an electrolysis cell with catalytic electrodes bonded to an ion transporting membrane and an oxygen depolarized cathode |
| IT1122699B (it) * | 1979-08-03 | 1986-04-23 | Oronzio De Nora Impianti | Collettore elettrico resiliente e cella elettrochimica ad elettrolita solido comprendente lo stesso |
| US4293396A (en) * | 1979-09-27 | 1981-10-06 | Prototech Company | Thin carbon-cloth-based electrocatalytic gas diffusion electrodes, and electrochemical cells comprising the same |
| GB2074190B (en) * | 1980-04-22 | 1984-03-14 | Johnson Matthey Co Ltd | Electrode |
| JPS57143482A (en) * | 1981-02-27 | 1982-09-04 | Asahi Glass Co Ltd | Cathode body, its manufacture and electrolyzing method |
| JPS58133387A (ja) * | 1982-02-02 | 1983-08-09 | Asahi Glass Co Ltd | 低水素過電圧陰極及びその製法 |
| GB8501479D0 (en) * | 1985-01-21 | 1985-02-20 | Johnson Matthey Plc | Making polymer-modified electrode |
-
1986
- 1986-07-16 GB GB868617325A patent/GB8617325D0/en active Pending
-
1987
- 1987-07-15 NO NO872952A patent/NO167047C/no not_active IP Right Cessation
- 1987-07-15 FI FI873122A patent/FI81613C/sv not_active IP Right Cessation
- 1987-07-15 CA CA000542169A patent/CA1311720C/en not_active Expired - Lifetime
- 1987-07-16 ES ES198787306296T patent/ES2028084T3/es not_active Expired - Lifetime
- 1987-07-16 AU AU75732/87A patent/AU606604B2/en not_active Ceased
- 1987-07-16 DE DE8787306296T patent/DE3776458D1/de not_active Expired - Lifetime
- 1987-07-16 EP EP87306296A patent/EP0256673B1/en not_active Expired - Lifetime
- 1987-07-16 US US07/074,217 patent/US4784730A/en not_active Expired - Lifetime
- 1987-07-16 KR KR1019870007764A patent/KR950000644B1/ko not_active Expired - Fee Related
- 1987-07-16 JP JP62176058A patent/JP2584778B2/ja not_active Expired - Fee Related
-
1995
- 1995-11-23 HK HK179895A patent/HK179895A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NO167047C (no) | 1991-09-25 |
| JP2584778B2 (ja) | 1997-02-26 |
| DE3776458D1 (de) | 1992-03-12 |
| HK179895A (en) | 1995-12-01 |
| AU7573287A (en) | 1988-01-21 |
| AU606604B2 (en) | 1991-02-14 |
| NO872952D0 (no) | 1987-07-15 |
| CA1311720C (en) | 1992-12-22 |
| NO872952L (no) | 1988-01-18 |
| KR950000644B1 (ko) | 1995-01-26 |
| FI873122L (fi) | 1988-01-17 |
| FI81613C (sv) | 1990-11-12 |
| EP0256673B1 (en) | 1992-01-29 |
| GB8617325D0 (en) | 1986-08-20 |
| JPS6372897A (ja) | 1988-04-02 |
| US4784730A (en) | 1988-11-15 |
| NO167047B (no) | 1991-06-17 |
| KR880001847A (ko) | 1988-04-27 |
| FI873122A0 (fi) | 1987-07-15 |
| ES2028084T3 (es) | 1992-07-01 |
| EP0256673A1 (en) | 1988-02-24 |
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Owner name: JOHNSON MATTHEY PUBLIC LIMITED COMPANY |
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