FI69106C - Framstaellning av bly ur sulfidiska blyraomaterial - Google Patents
Framstaellning av bly ur sulfidiska blyraomaterial Download PDFInfo
- Publication number
- FI69106C FI69106C FI813810A FI813810A FI69106C FI 69106 C FI69106 C FI 69106C FI 813810 A FI813810 A FI 813810A FI 813810 A FI813810 A FI 813810A FI 69106 C FI69106 C FI 69106C
- Authority
- FI
- Finland
- Prior art keywords
- lead
- sulphide
- flame
- melt
- smelting
- Prior art date
Links
- 238000000034 method Methods 0.000 claims abstract description 45
- 238000003723 Smelting Methods 0.000 claims abstract description 29
- 230000008569 process Effects 0.000 claims abstract description 25
- 239000012535 impurity Substances 0.000 claims abstract description 22
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 21
- 239000001301 oxygen Substances 0.000 claims abstract description 21
- 239000007789 gas Substances 0.000 claims abstract description 20
- 239000000155 melt Substances 0.000 claims abstract description 11
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 9
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 9
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 9
- XCAUINMIESBTBL-UHFFFAOYSA-N lead(ii) sulfide Chemical compound [Pb]=S XCAUINMIESBTBL-UHFFFAOYSA-N 0.000 claims abstract description 8
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 7
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims abstract description 7
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 229910052718 tin Inorganic materials 0.000 claims abstract description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 5
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 17
- 239000012141 concentrate Substances 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 12
- 238000002844 melting Methods 0.000 claims description 11
- 230000008018 melting Effects 0.000 claims description 11
- 229910052717 sulfur Inorganic materials 0.000 claims description 8
- 239000011593 sulfur Substances 0.000 claims description 8
- 239000012159 carrier gas Substances 0.000 claims description 4
- 230000004907 flux Effects 0.000 claims description 2
- 230000002950 deficient Effects 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 4
- 238000000926 separation method Methods 0.000 abstract description 4
- 230000001590 oxidative effect Effects 0.000 abstract description 2
- 239000005864 Sulphur Substances 0.000 abstract 2
- 239000011133 lead Substances 0.000 description 63
- 239000002893 slag Substances 0.000 description 17
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- 229910000464 lead oxide Inorganic materials 0.000 description 10
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 8
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 229910044991 metal oxide Inorganic materials 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 239000000571 coke Substances 0.000 description 6
- 150000004706 metal oxides Chemical class 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 239000003238 silicate melt Substances 0.000 description 6
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 229910001882 dioxygen Inorganic materials 0.000 description 4
- 229940056932 lead sulfide Drugs 0.000 description 4
- 229910052981 lead sulfide Inorganic materials 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 238000005245 sintering Methods 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000010970 precious metal Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- KEQXNNJHMWSZHK-UHFFFAOYSA-L 1,3,2,4$l^{2}-dioxathiaplumbetane 2,2-dioxide Chemical compound [Pb+2].[O-]S([O-])(=O)=O KEQXNNJHMWSZHK-UHFFFAOYSA-L 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910000805 Pig iron Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002801 charged material Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- -1 metal oxide silicate Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B13/00—Obtaining lead
- C22B13/02—Obtaining lead by dry processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/12—Dry methods smelting of sulfides or formation of mattes by gases
- C22B5/14—Dry methods smelting of sulfides or formation of mattes by gases fluidised material
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Glass Compositions (AREA)
- Liquid Developers In Electrophotography (AREA)
- Diaphragms For Electromechanical Transducers (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Claims (6)
1. FÖrfarande för utvinning av bly ur sulfidiska bly-rämaterial innehällande föroreningar av typ vismut, arsenik, antimon och tenn genom flamsmältning med syre innehällande gas, kännetecknat av att syrepotentialen och temperaturen vid f1amsmältningen avpassas sä, att den därvid bildade produkten kommer att väsentligen utgöras av en frän flyktiga, sulfidiska och metalliska föroreningar av nämnda typ väsentligen befriad blysulfidsmälta, att blysulfidsmä1tan bringas i kontakt med frän föroreningar av nämnda typ väsentligen fritt oxidiskt blymaterial under oxidering av dess sul-fidsvavelinnehäll och bildning av en frän svavel väsentligen fri smälta, ur vilken bly utvinnes genom separation, even-tuellt efter reducerande behandling av denna smälta eller del av dens amma.
2. FÖrfarande enligt krav 1, kännetecknat av att det oxidiska blymateriai et utgöres av en produkt er-hällen genom f1amsmältning med syre av en frän föroreningar av den nämnda typen väsentligen fri blysulfids 1ig.
3. FÖrfarande enligt krav 1 och 2, varvid f1amsmältning genomföres med hjälp av minst en första och minst en andra . lans, kännetecknat av att den första lansen mätäs med den väsentligen föroreningsfria blysulfidsligen samt överskott av syre, varvid denna första lans mynnar under ytan i det smältbad som bildas vid f1amsmältningen, och att den andra lansen mätäs med det sulfidiska, förorenings-haltiga blyrämaterialet och en bärgas med underskott av syre, varvid denna andra lans riktas mot och mynnar ovanför smält-badets yta.
4. FÖrfarande enligt krav 1 och 2, känneteck-* n a t av att f1amsmältningen genomföres i en med tvä separata f1amsmältschakt försedd ugn.
5. FÖrfarande enligt krav 1 och 2, känneteck-n.a t av att f1amsmältningen genomföres i ett motströms-förfarande i ett schakt indelat i tvä zoner, varvid det sulfidiska^ föroreningshaltiga blyrämäteria 1 et tillföres en Övre zon i schaktet tillsammans med en förhä11andevis syrefattig bärgas, li
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE8008425 | 1980-12-01 | ||
| SE8008425A SE444184B (sv) | 1980-12-01 | 1980-12-01 | Forfarande for utvinning av bly ur sulfidiska material blyramaterial innehallande fororeningar av vismut, arsenik, antimon eller tenn |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI813810L FI813810L (fi) | 1982-06-02 |
| FI69106B FI69106B (fi) | 1985-08-30 |
| FI69106C true FI69106C (fi) | 1985-12-10 |
Family
ID=20342372
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI813810A FI69106C (fi) | 1980-12-01 | 1981-11-27 | Framstaellning av bly ur sulfidiska blyraomaterial |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4396426A (sv) |
| EP (1) | EP0053594B1 (sv) |
| AT (1) | ATE11933T1 (sv) |
| CA (1) | CA1181244A (sv) |
| DE (1) | DE3169115D1 (sv) |
| FI (1) | FI69106C (sv) |
| SE (1) | SE444184B (sv) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4514222A (en) * | 1981-11-26 | 1985-04-30 | Mount Isa Mines Limited | High intensity lead smelting process |
| EP0196800B1 (en) * | 1985-03-07 | 1990-07-18 | Mount Isa Mines Limited | Secondary lead production |
| AU573965B2 (en) * | 1985-03-07 | 1988-06-23 | Mount Isa Mines Ltd. | Lead from used lead-acid batteries by submerged lance smelting |
| US4654077A (en) * | 1985-11-19 | 1987-03-31 | St. Joe Minerals Corporation | Method for the pyrometallurgical treatment of finely divided materials |
| AU2007281012B2 (en) * | 2006-08-01 | 2010-12-16 | Metso Metals Oy | Lead slag reduction |
| CN112239812A (zh) * | 2020-09-18 | 2021-01-19 | 中国恩菲工程技术有限公司 | 连续炼铅装置和连续炼铅工艺 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE641244A (sv) | 1962-12-14 | |||
| US3365185A (en) * | 1963-01-31 | 1968-01-23 | Boliden Ab | Production of metals from pulverulent materials by flash smelting in an electrically heated furnace |
| US3326671A (en) * | 1963-02-21 | 1967-06-20 | Howard K Worner | Direct smelting of metallic ores |
| GB1002495A (en) * | 1963-06-06 | 1965-08-25 | Imp Smelting Corp N S Co Ltd | Improvements in or relating to sulphur infusers |
| US3542352A (en) | 1965-01-04 | 1970-11-24 | Noranda Mines Ltd | Apparatus for the continuous smelting and converting of copper concentrates to metallic copper |
| FI41464B (sv) * | 1965-12-10 | 1969-07-31 | Outokumpu Oy | |
| US3462265A (en) * | 1966-03-30 | 1969-08-19 | Polaroid Corp | Photographic products and processes employing aluminum in the photosensitive element |
| US3555164A (en) | 1967-02-17 | 1971-01-12 | Vladimir Nikolaevich Kostin | Method of processing ores and concentrates containing rare metals and a unit for effecting said method |
| AT301193B (de) * | 1969-04-25 | 1972-08-25 | Metallgesellschaft Ag | Verfahren und Vorrichtung zur pyrometallurgischen Behandlung kleinteiliger Erze oder Erzkonzentrate |
| CA893624A (en) * | 1969-10-27 | 1972-02-22 | J. Themelis Nickolas | Direct process for smelting of lead sulphide concentrates to lead |
| US3847595A (en) * | 1970-06-29 | 1974-11-12 | Cominco Ltd | Lead smelting process |
| AT306389B (de) * | 1970-07-30 | 1973-04-10 | Vni Gornometallurgichesky I Ts | Verfahren zum Verarbeiten von Nichteisenmetalle enthaltenden Erzen oder Konzentraten |
| JPS5143015B2 (sv) | 1972-05-04 | 1976-11-19 | ||
| US3941587A (en) * | 1973-05-03 | 1976-03-02 | Q-S Oxygen Processes, Inc. | Metallurgical process using oxygen |
| US4087274A (en) * | 1975-07-04 | 1978-05-02 | Boliden Aktiebolag | Method of producing a partially reduced product from finely-divided metal sulphides |
| US4080197A (en) * | 1977-03-18 | 1978-03-21 | Institute Of Gas Technology | Process for producing lead |
-
1980
- 1980-12-01 SE SE8008425A patent/SE444184B/sv unknown
-
1981
- 1981-11-18 US US06/322,686 patent/US4396426A/en not_active Expired - Fee Related
- 1981-11-23 CA CA000390718A patent/CA1181244A/en not_active Expired
- 1981-11-27 FI FI813810A patent/FI69106C/fi not_active IP Right Cessation
- 1981-11-27 AT AT81850227T patent/ATE11933T1/de not_active IP Right Cessation
- 1981-11-27 DE DE8181850227T patent/DE3169115D1/de not_active Expired
- 1981-11-27 EP EP81850227A patent/EP0053594B1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CA1181244A (en) | 1985-01-22 |
| EP0053594B1 (en) | 1985-02-20 |
| EP0053594A1 (en) | 1982-06-09 |
| ATE11933T1 (de) | 1985-03-15 |
| SE8008425L (sv) | 1982-06-02 |
| DE3169115D1 (en) | 1985-03-28 |
| US4396426A (en) | 1983-08-02 |
| FI69106B (fi) | 1985-08-30 |
| SE444184B (sv) | 1986-03-24 |
| FI813810L (fi) | 1982-06-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed |
Owner name: BOLIDEN AKTIEBOLAG |