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FI3580388T3 - System and method for silica removal in a pulping process - Google Patents

System and method for silica removal in a pulping process Download PDF

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Publication number
FI3580388T3
FI3580388T3 FIEP18750677.9T FI18750677T FI3580388T3 FI 3580388 T3 FI3580388 T3 FI 3580388T3 FI 18750677 T FI18750677 T FI 18750677T FI 3580388 T3 FI3580388 T3 FI 3580388T3
Authority
FI
Finland
Prior art keywords
liquid
chip slurry
chip
silica
temperature
Prior art date
Application number
FIEP18750677.9T
Other languages
Finnish (fi)
Inventor
Fredrik Wilgotson
Stefan Antonsson
Lars Eriksson
Östberg Bengt Wernersson
Krister Olsson
Original Assignee
Valmet Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Valmet Oy filed Critical Valmet Oy
Application granted granted Critical
Publication of FI3580388T3 publication Critical patent/FI3580388T3/en

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C1/00Pretreatment of the finely-divided materials before digesting
    • D21C1/02Pretreatment of the finely-divided materials before digesting with water or steam
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C1/00Pretreatment of the finely-divided materials before digesting
    • D21C1/04Pretreatment of the finely-divided materials before digesting with acid reacting compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21BFIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00Fibrous raw materials or their mechanical treatment
    • D21B1/02Pretreatment of the raw materials by chemical or physical means
    • D21B1/023Cleaning wood chips or other raw materials
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/08Removal of fats, resins, pitch or waxes; Chemical or physical purification, i.e. refining, of crude cellulose by removing non-cellulosic contaminants, optionally combined with bleaching
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00Regeneration of pulp liquors or effluent waste waters
    • D21C11/0007Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00Regeneration of pulp liquors or effluent waste waters
    • D21C11/0021Introduction of various effluents, e.g. waste waters, into the pulping, recovery and regeneration cycle (closed-cycle)

Landscapes

  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Mechanical Engineering (AREA)
  • Paper (AREA)
  • Silicon Compounds (AREA)

Claims (8)

PatenttivaatimuksetPatent Claims 1. Järjestelmä (1) piidioksidin — poistamiseen — sulfaattisellutuotannon prehydrolyysiprosessissa, joka järjestelmä (1) käsittää vähintään: säiliön (2), jolla on yläosa (3) ja pohjaosa (4); yläosaan (3) järjestetyn lastun syöttöaukon (5) puulastujen tuomiseksi säiliöön (2); yläosaan (3) järjestetyn höyryn syöttöaukon (6) höyryn tuomiseksi säiliöön (2; säiliöön (2) järjestetyn ensimmäisen nesteen syöttöaukon (7) nesteiden tuomiseksi säiliöön (2), tuottamaan hakelietelämpötilassa olevaa hakelietettä yläosan (3) alle sijoitetulle liotusalueelle (8), liotusalueen (8) ollessa alue, jossa puulastut on upotettu nesteeseen määritellyksi liotusajaksi; hakelietteen ulostulon (9) järjestettynä pohjaosaan (4) ja liitettynä hakelietteen kuljetusputkeen (10) hakelietteen kuljettamiseksi; toisen nesteen syöttöaukon (11) järjestettynä pohjaosaan (4) ja/tai hakelietteen kuljetusputkeen (10) hakelietteen laimentamisseksi hakelietteen kuljetusputkessa (10) neste-puu -suhteeseen, joka on vähintään 10:1 laimennusnesteen lämpötilan ollessa korkeampi kuin hakelietteen lämpötila; hakelietteen kuljetusputkeen (10) liitetyn vedenpoistolaitteen (12) hakelietteen veden poistamiseksi ja ensimmäisen virtauksen (13), joka sisältää hakelietettä alle 3:1 neste-puu —-suhteella, sekä piidioksidi-sisältöisen nesteen toisen virtauksen (14) luomiseksi; ja paluuputken (15), joka on liitetty vedenpoistolaitteeseen (12) piidioksidi-sisältöisen nesteen toisen virtauksen kuljettamiseksi, ja joka on liitetty ensimmäiseen nesteen syöttöaukkoon (7) ja/tai toiseen nesteen syöttöaukkoon (11), missä vähintään yksi piidioksidi-erotin (16) on järjestetty paluuputkeen (15), ja että liotusaika on 30 minuutin ja 120 minuutin välillä, että hakelietteen lämpötila on 95-105 °C, ja että laimennusnesteen lämpötila on 110-130 °C.1. A system (1) for — removing — silica in the prehydrolysis process of sulfate pulp production, which system (1) comprises at least: a container (2) with an upper part (3) and a lower part (4); a chip feed hole (5) arranged in the upper part (3) for bringing wood chips into the container (2); the steam supply opening (6) arranged in the upper part (3) for bringing steam to the tank (2; the first liquid supply opening (7) arranged in the tank (2) for bringing liquids into the tank (2), to produce chip slurry at the temperature of the chip slurry to the soaking area (8) placed under the upper part (3), the soaking area (8) being the area where the wood chips are immersed in the liquid for a specified soaking time; the chip slurry outlet (9) arranged in the bottom part (4) and connected to the chip slurry transport pipe (10) for transporting the chip slurry; the second liquid supply opening (11) arranged in the bottom part (4) and/or the chip slurry transport pipe (10) to dilute the chip slurry in the chip slurry transport pipe (10) to a liquid-to-wood ratio of at least 10:1 when the temperature of the dilution liquid is higher than the temperature of the chip slurry; to remove the water of the chip slurry from the dewatering device (12) connected to the chip slurry transport pipe (10) and the first flow (13), containing chip slurry with a liquid-to-wood ratio of less than 3:1, and a silica-containing liquid to create a second stream (14); and a return pipe (15) connected to a dewatering device (12) for conveying a second flow of silica-containing liquid, and connected to the first liquid inlet (7) and/or the second liquid inlet (11), where at least one silica separator (16) is arranged in the return pipe (15), and that the soaking time is between 30 minutes and 120 minutes, that the temperature of the chip slurry is 95-105 °C, and that the temperature of the dilution liquid is 110-130 °C. 2. Patenttivaatimuksen 1 mukainen järjestelmä (1), tunnettu siitä, että prosessi sellun tuotantoon on prosessi liukoselluloosan tuotantoon.2. System (1) according to claim 1, characterized in that the process for the production of pulp is a process for the production of soluble cellulose. 3. Patenttivaatimuksen 1 tai patenttivaatimuksen 2 mukainen järjestelmä (1) tunnettu siitä, että sekoitin (20) on järjestetty hakelietteen kuljetusputkeen (10).3. The system (1) according to claim 1 or claim 2, characterized in that the mixer (20) is arranged in the chip slurry transport pipe (10). 4. Jonkin aiemman patenttivaatimuksen mukainen järjestelmä (1) tunnettu siitä, että paluuputkeen (15) on järjestetty ennen piidioksidi-erotinta (16) syöttöaukko agglomerointiaineen lisäykseen.4. The system (1) according to one of the previous claims, characterized in that the return pipe (15) is arranged before the silica separator (16) with a feed opening for the addition of agglomerating agent. 5. Menetelmä piidioksidin poistamiseen sulfaattisellutuotannon prehydrolyysiprosessissa, joka menetelmä käsittää vähintään seuraavat vaiheet: tuodaan puulastuja säiliöön (2) säiliön (2) yläosaan (3) järjestetyn lastun syöttöaukon (5) kautta, mainitun säiliön käsittäessä mainitun yläosan (3) ja pohjaosan (4); tuodaan höyryä säiliöön (2) yläosaan (3) järjestetyn höyryn syöttöaukon (6) kautta; tuodaan nestettä säiliöön (2) säiliöön (2) järjestetyn ensimmäisen nesteen syöttöaukon (7) kautta hakelämpötilassa olevan hakelietteen tarjoamiseksi yläosan (3) alle sijoitetulle liotusalueelle (8), lastuliotusalueen (8) ollessa alue, jossa puulastut on upotettu nesteeseen määritellyksi liotusajaksi; kuljetetaan hakeliete ulos säiliöstä (2) pohjaosaan (4) järjestetyn ja hakelietteen kuljetusputkeen (10) liitetyn hakelietteen ulostulon (9) kautta; laimennetaan hakeliete hakelietteen kuljetusputkessa (10) vähintään 10:1 neste-puu -osuudeksi laimennusnesteellä, jonka lämpötila on korkeampi kuin hakelietteen lämpötila, pohjaosaan (4) ja/tai hakelietteen kuljetusputkeen (10) järjestetyn toisen nesteen syöttöaukon (11) kautta; poistetaan hakelietteen vesi hakelietteen kuljetusputkeen (10) liitetyllä vedenpoistolaitteella (12) ja luodaan hakelietteen ensimmäinen virtaus (13) alle 3:1 neste-puu —-suhteella ja piidioksidi-sisältöisen nesteen toinen virtaus (14); ja kuljetetaan piidioksidi-sisältöisen nesteen toinen virtaus (14) paluuputken (15) kautta, joka on liitetty nesteenpoistolaitteeseen (12), ja joka on liitetty ensimmäiseen nestesyöttöön (7) ja/tai toiseen nestesyöttöön (11), missä piidioksidi poistetaan piidioksidi- sisältöisestä nesteestä paluuputkeen (15) järjestetyllä vähintään yhdellä piidioksidi-erottimella (16), ja että liotusaika on 30 minuutin ja 120 minuutin välillä, että hakelietteen lämpötila on 95-105 °C, ja että laimennusnesteen lämpötila on 110-130 °C.5. A method for removing silicon dioxide in the prehydrolysis process of sulfate pulp production, which method comprises at least the following steps: introducing wood chips into the container (2) through the chip feed opening (5) arranged in the upper part (3) of the container (2), said container comprising said upper part (3) and bottom part (4) ; introducing steam into the container (2) through the steam supply opening (6) arranged in the upper part (3); liquid is introduced into the tank (2) through the first liquid supply opening (7) arranged in the tank (2) to provide the chip slurry at chip temperature to the soaking area (8) located under the upper part (3), the chip soaking area (8) being the area where the wood chips are immersed in the liquid for a specified soaking time; the chip slurry is transported out of the tank (2) through the chip slurry outlet (9) arranged in the bottom part (4) and connected to the chip slurry transport pipe (10); the chip slurry is diluted in the chip slurry transport pipe (10) to at least a 10:1 liquid-to-wood ratio with a dilution liquid whose temperature is higher than the temperature of the chip slurry, via the second liquid supply opening (11) arranged in the bottom part (4) and/or the chip slurry transport pipe (10); the water in the chip slurry is removed with the dewatering device (12) connected to the chip slurry transport pipe (10) and the first flow (13) of the chip slurry is created with a ratio of less than 3:1 liquid to wood and the second flow (14) of liquid containing silicon dioxide; and conveying the second flow (14) of the silica-containing liquid through the return pipe (15) connected to the liquid removal device (12) and connected to the first liquid supply (7) and/or the second liquid supply (11) where the silica is removed from the silica-containing liquid with at least one silica separator (16) arranged in the return pipe (15), and that the soaking time is between 30 minutes and 120 minutes, that the temperature of the chip slurry is 95-105 °C, and that the temperature of the dilution liquid is 110-130 °C. 6. Patenttivaatimuksen 5 mukainen menetelmä tunnettu siitä, että prosessi sellun tuotantoon on prosessi liukoselluloosan tuotantoon.6. The method according to claim 5 characterized in that the process for the production of pulp is a process for the production of soluble cellulose. 7. Patenttivaatimuksen 5 tai patenttivaatimuksen 6 mukainen menetelmä, tunnettu siitä, että sekoitin (20) on järjestetty hakelietteen kuljetusputkeen (10).7. The method according to claim 5 or claim 6, characterized in that the mixer (20) is arranged in the chip slurry transport pipe (10). 8. Jonkin aiemman patenttivaatimuksen 5-7 mukainen menetelmä tunnettu siitä , että paluuputkeen (15) on järjestetty ennen piidioksidi-erotinta (16) syöttöaukko agglomerointiaineen lisäykselle.8. The method according to one of the previous claims 5-7, characterized in that the return pipe (15) is arranged before the silica separator (16) with a feed opening for the addition of agglomerating agent.
FIEP18750677.9T 2017-02-07 2018-01-31 System and method for silica removal in a pulping process FI3580388T3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE1750106A SE1750106A1 (en) 2017-02-07 2017-02-07 System and method for silica removal in a pulping process
PCT/SE2018/050072 WO2018147784A1 (en) 2017-02-07 2018-01-31 System and method for silica removal in a pulping process

Publications (1)

Publication Number Publication Date
FI3580388T3 true FI3580388T3 (en) 2023-07-10

Family

ID=62244602

Family Applications (1)

Application Number Title Priority Date Filing Date
FIEP18750677.9T FI3580388T3 (en) 2017-02-07 2018-01-31 System and method for silica removal in a pulping process

Country Status (9)

Country Link
EP (1) EP3580388B1 (en)
CN (1) CN110249092A (en)
CL (1) CL2019002201A1 (en)
ES (1) ES2947013T3 (en)
FI (1) FI3580388T3 (en)
PL (1) PL3580388T3 (en)
PT (1) PT3580388T (en)
SE (1) SE1750106A1 (en)
WO (1) WO2018147784A1 (en)

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US4199399A (en) * 1976-04-19 1980-04-22 Process Evaluation & Development Corp. Method for preparing bagasse dissolving pulps and producing rayon having a degree of polymerization of at least 800 therefrom
IN154386B (en) * 1979-12-10 1984-10-20 Dorr Oliver Inc
US4436586A (en) * 1982-01-22 1984-03-13 Kamyr, Inc. Method of producing kraft pulp using an acid prehydrolysis and pre-extraction
US4668340A (en) * 1984-03-20 1987-05-26 Kamyr, Inc. Method of countercurrent acid hydrolysis of comminuted cellulosic fibrous material
FI103418B (en) * 1996-01-31 1999-06-30 Sunds Defibrator Woodhandling Method and apparatus for the pre-treatment of fibrous material for the production of cellulose pulp
ZA974836B (en) * 1997-06-02 1998-06-24 Bountiful Applied Res Corp Process for treating spent, waste, alkaline digestion liquor from paper pulping operations and product.
WO1998059107A1 (en) * 1997-06-25 1998-12-30 Kvaerner Pulping Ab Method in connection with the pretreatment of comminuted fibrous material
RU2383675C1 (en) * 2005-12-07 2010-03-10 Келли Энтони О`ФЛИНН Process of industrial cellulose pulp, native lignin and unicellular protein production, which is carried out in catalytic reactor
CN101255664B (en) * 2008-02-02 2010-10-20 山东太阳纸业股份有限公司 Method for pulping of non-lumber fibre
FI123100B (en) * 2010-03-11 2012-11-15 Metso Paper Inc Procedure for the collection of by-products
WO2013149913A1 (en) * 2012-04-03 2013-10-10 Ovivo Luxembourg S.a.r.l. Process for removal of solid non-fibrous material from pulp
US9333468B2 (en) * 2012-09-24 2016-05-10 Abengoa Bioenergy New Technologies, Llc Soak vessels and methods for impregnating biomass with liquid
JP6522274B2 (en) * 2013-08-06 2019-05-29 日本製紙株式会社 Method of making dissolved kraft pulp.
CN203429499U (en) * 2013-09-11 2014-02-12 江苏飞翔纸业有限公司 Anti-blocking pulping waste water recycling system
US10179971B2 (en) * 2014-03-21 2019-01-15 Iogen Energy Corporation Method for processing a cellulosic feedstock at high consistency
SE539706C2 (en) * 2014-11-07 2017-11-07 Valmet Oy Method for recovering hydrolysate

Also Published As

Publication number Publication date
SE540305C2 (en) 2018-06-05
PL3580388T3 (en) 2023-09-11
EP3580388B1 (en) 2023-05-10
SE1750106A1 (en) 2018-06-05
ES2947013T3 (en) 2023-07-31
WO2018147784A1 (en) 2018-08-16
EP3580388A4 (en) 2020-12-23
CN110249092A (en) 2019-09-17
BR112019014396A2 (en) 2020-02-11
CL2019002201A1 (en) 2019-11-08
EP3580388A1 (en) 2019-12-18
PT3580388T (en) 2023-06-05

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