ES8504874A1 - Phenolic foams - Google Patents
Phenolic foamsInfo
- Publication number
- ES8504874A1 ES8504874A1 ES523967A ES523967A ES8504874A1 ES 8504874 A1 ES8504874 A1 ES 8504874A1 ES 523967 A ES523967 A ES 523967A ES 523967 A ES523967 A ES 523967A ES 8504874 A1 ES8504874 A1 ES 8504874A1
- Authority
- ES
- Spain
- Prior art keywords
- phenolic
- resole
- average molecular
- resoles
- phenolic foams
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title abstract 7
- 239000006260 foam Substances 0.000 title abstract 4
- 229920003987 resole Polymers 0.000 abstract 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229920001568 phenolic resin Polymers 0.000 abstract 2
- 238000009413 insulation Methods 0.000 abstract 1
- 239000012774 insulation material Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/147—Halogen containing compounds containing carbon and halogen atoms only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
- C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
- C08G8/10—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fats And Perfumes (AREA)
Abstract
An aqueous phenol formaldehyde resole, suitable for use in the manufacture of phenolic foam insulation, has a molar ratio of formaldehyde to phenol in the range of from about 1.7:1 to about 2.3:1, and a weight average molecular weight greater than 800. Preferably, the resole also has a number average molecular weight greater than 350 and a dispersivity greater than about 1.7. Phenol formaldehyde resoles having these characteristics are processable into phenolic foams having these characteristics which make them especially useful as an insulation material. There is also disclosed foamable phenolic resole compositions prepared from the phenolic resoles, and phenolic foams prepared from the compositions.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US39650082A | 1982-07-09 | 1982-07-09 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES523967A0 ES523967A0 (en) | 1985-05-01 |
| ES8504874A1 true ES8504874A1 (en) | 1985-05-01 |
Family
ID=23567441
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES523967A Expired ES8504874A1 (en) | 1982-07-09 | 1983-07-08 | Phenolic foams |
Country Status (20)
| Country | Link |
|---|---|
| JP (2) | JPS5962615A (en) |
| AT (1) | AT385279B (en) |
| AU (1) | AU540472B2 (en) |
| BE (1) | BE897254A (en) |
| CA (1) | CA1209748A (en) |
| CH (1) | CH662577A5 (en) |
| DE (1) | DE3324431A1 (en) |
| DK (1) | DK317783A (en) |
| ES (1) | ES8504874A1 (en) |
| FI (1) | FI73445C (en) |
| FR (1) | FR2529897B1 (en) |
| GB (1) | GB2125055B (en) |
| IT (1) | IT1172292B (en) |
| LU (1) | LU84906A1 (en) |
| MX (2) | MX9100674A (en) |
| NL (1) | NL8302441A (en) |
| NO (1) | NO159938C (en) |
| NZ (1) | NZ204804A (en) |
| PT (1) | PT77004B (en) |
| SE (1) | SE457262B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4478958A (en) * | 1981-07-10 | 1984-10-23 | Kopper Company, Inc. | Method for preparing phenolic foams using anhydrous aryl sulfonic acid catalysts |
| FI73445C (en) * | 1982-07-09 | 1987-10-09 | Koppers Co Inc | FENOLFORMALDEHYDRESOLER FOER FRAMSTAELLNING AV FENOLSKUM. |
| US4720510A (en) * | 1984-05-25 | 1988-01-19 | Bp Chemicals Limited | Process for producing phenolic foams |
| FI852712A7 (en) * | 1984-07-12 | 1986-01-13 | Insulboard Pty Ltd | Foam mixture and its use. |
| US4882364A (en) * | 1987-08-28 | 1989-11-21 | Fiberglas Canada Inc. | Process for manufacturing closed cell phenolic foams |
| AU4396099A (en) | 1998-07-03 | 2000-01-24 | Asahi Kasei Kogyo Kabushiki Kaisha | Phenolic foam |
| US12091521B2 (en) | 2018-10-01 | 2024-09-17 | Bakelite Gmbh | Compositions for producing foamed materials |
| KR102529929B1 (en) * | 2021-10-26 | 2023-05-08 | 현대제철 주식회사 | System and method for manufacturing composite material |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3271331A (en) * | 1963-10-10 | 1966-09-06 | Union Carbide Corp | Phenolic foams stabilized by siloxane-oxyalkylene copolymers |
| US3389094A (en) * | 1963-10-10 | 1968-06-18 | Union Carbide Corp | Foaming phenol-formaldehyde resins with fluorocarbons |
| FR1462228A (en) * | 1965-07-08 | 1966-04-15 | Saint Gobain | Process for obtaining foams of phenolic resins |
| US3385010A (en) * | 1966-03-25 | 1968-05-28 | Norton Co | Abrasive disc |
| US3823103A (en) * | 1971-07-21 | 1974-07-09 | Union Carbide Corp | Aqueous dispersions based on heathardenable phenolic resins containing a gum mixture stabilizing agent |
| US3876620A (en) * | 1973-04-26 | 1975-04-08 | Celotex Corp | Process of preparing phenolic-aldehyde polymer using o-cresol |
| US3821337A (en) * | 1973-05-07 | 1974-06-28 | Exxon Research Engineering Co | Process for controlled curing of foams |
| FR2292733A1 (en) * | 1974-11-27 | 1976-06-25 | Rhone Poulenc Ind | PERFECTION OF THE PROCESS FOR MANUFACTURING FORMO-PHENOLIC FOAMS |
| US3968300A (en) * | 1975-02-24 | 1976-07-06 | The Celotex Corporation | Phenolic polymer, related products and processes thereof |
| US4033910A (en) * | 1975-09-26 | 1977-07-05 | Union Carbide Corporation | Methyl formate as an adjuvant in phenolic foam formation |
| US4133931A (en) * | 1976-05-19 | 1979-01-09 | The Celotex Corporation | Closed cell phenolic foam |
| US4122045A (en) * | 1976-05-24 | 1978-10-24 | Armstrong Cork Company | Non-punking non-corrosive phenolic foam containing sodium tetraborate |
| US4303758A (en) * | 1976-06-07 | 1981-12-01 | Gusmer Frederick E | Method of preparing closed cell phenol-aldehyde foam and the closed cell foam thus prepared |
| US4018725A (en) * | 1976-08-09 | 1977-04-19 | H. H. Robertson Company | Phenolic foam products and method of making the same |
| US4075139A (en) * | 1977-02-22 | 1978-02-21 | The Upjohn Company | Process of making a cured resole foam and product produced therefrom |
| US4219623A (en) * | 1977-07-26 | 1980-08-26 | Reichhold Limited | Phenol formaldehyde resin foams |
| US4176106A (en) * | 1977-07-28 | 1979-11-27 | Union Carbide Corporation | Phenol/formaldehyde resoles and cellular products derived therefrom |
| US4207400A (en) * | 1977-11-16 | 1980-06-10 | Monsanto Company | Foamable resole resin composition |
| US4202945A (en) * | 1979-04-03 | 1980-05-13 | Leinhardt Franklyn J | Phenolic foam materials and method of making same |
| GB2078228B (en) * | 1980-06-24 | 1984-02-22 | Coal Industry Patents Ltd | Phenol-formaldehyde foams |
| US4423163A (en) * | 1980-10-09 | 1983-12-27 | Koppers Company, Inc. | Method of producing phenolic foam using pressure and foam produced by the method |
| CA1160389A (en) * | 1980-11-17 | 1984-01-10 | Shui-Tung Chiu | Liquid phenolic resin composition and method for waferboard manufacture |
| JPS58125371A (en) * | 1982-01-22 | 1983-07-26 | Matsushita Electric Ind Co Ltd | Control device for weaving welding machine |
| FI73445C (en) * | 1982-07-09 | 1987-10-09 | Koppers Co Inc | FENOLFORMALDEHYDRESOLER FOER FRAMSTAELLNING AV FENOLSKUM. |
-
1983
- 1983-06-21 FI FI832256A patent/FI73445C/en not_active IP Right Cessation
- 1983-06-30 AU AU16420/83A patent/AU540472B2/en not_active Ceased
- 1983-07-04 NZ NZ204804A patent/NZ204804A/en unknown
- 1983-07-05 NO NO832444A patent/NO159938C/en unknown
- 1983-07-06 SE SE8303858A patent/SE457262B/en not_active IP Right Cessation
- 1983-07-07 DE DE19833324431 patent/DE3324431A1/en active Granted
- 1983-07-08 JP JP58125371A patent/JPS5962615A/en active Granted
- 1983-07-08 AT AT0252283A patent/AT385279B/en active
- 1983-07-08 IT IT48658/83A patent/IT1172292B/en active
- 1983-07-08 NL NL8302441A patent/NL8302441A/en not_active Application Discontinuation
- 1983-07-08 ES ES523967A patent/ES8504874A1/en not_active Expired
- 1983-07-08 BE BE0/211146A patent/BE897254A/en not_active IP Right Cessation
- 1983-07-08 PT PT77004A patent/PT77004B/en unknown
- 1983-07-08 CH CH3777/83A patent/CH662577A5/en not_active IP Right Cessation
- 1983-07-08 CA CA000432126A patent/CA1209748A/en not_active Expired
- 1983-07-08 DK DK317783A patent/DK317783A/en not_active Application Discontinuation
- 1983-07-08 GB GB08318584A patent/GB2125055B/en not_active Expired
- 1983-07-11 FR FR8311549A patent/FR2529897B1/en not_active Expired
- 1983-07-11 LU LU84906A patent/LU84906A1/en unknown
-
1990
- 1990-06-06 JP JP2148432A patent/JPH03255153A/en active Pending
-
1991
- 1991-08-15 MX MX9100674A patent/MX9100674A/en unknown
- 1991-08-15 MX MX9100672A patent/MX9100672A/en unknown
Also Published As
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19970401 |