ES8202776A1 - Process for reducing the water content of alcohol-water mixtures - Google Patents
Process for reducing the water content of alcohol-water mixturesInfo
- Publication number
- ES8202776A1 ES8202776A1 ES501396A ES501396A ES8202776A1 ES 8202776 A1 ES8202776 A1 ES 8202776A1 ES 501396 A ES501396 A ES 501396A ES 501396 A ES501396 A ES 501396A ES 8202776 A1 ES8202776 A1 ES 8202776A1
- Authority
- ES
- Spain
- Prior art keywords
- water
- alcohols
- alcohol
- reducing
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title 2
- 239000003054 catalyst Substances 0.000 abstract 3
- 230000002378 acidificating effect Effects 0.000 abstract 2
- 150000001298 alcohols Chemical class 0.000 abstract 2
- 229910006069 SO3H Inorganic materials 0.000 abstract 1
- 150000001336 alkenes Chemical group 0.000 abstract 1
- 239000003456 ion exchange resin Substances 0.000 abstract 1
- 229920003303 ion-exchange polymer Polymers 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 230000003071 parasitic effect Effects 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
- C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/88—Separation; Purification; Use of additives, e.g. for stabilisation by treatment giving rise to a chemical modification of at least one compound
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C11/00—Fermentation processes for beer
- C12C11/02—Pitching yeast
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Food Science & Technology (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- Mycology (AREA)
- Health & Medical Sciences (AREA)
- Microbiology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
An improved process is disclosed for producing petrol-grade C2-C4 alcohols from aqueous mixtures which contain these alcohols. The improvement is that the aqueous mixture is reacted with a tertiary olefin in the presence of a catalyst having an acidic character, preferably at a temperature of from 40 to 90 DEG C and at a space velocity of from 5 to 25 litres of reactants per litre of catalyst per hour. Preferred catalysts are acidic ion-exchange resins, especially those having -SO3H groups. The temperature and space velocity ranges are critical in order to minimize the parasitic ether- forming reaction.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT21068/80A IT1140794B (en) | 1980-03-31 | 1980-03-31 | PROCEDURE FOR THE PRODUCTION OF C2-C4 "GASOLINE" ALCOHOLS FROM AQUEOUS MIXTURES CONTAINING THEM |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES501396A0 ES501396A0 (en) | 1982-02-16 |
| ES8202776A1 true ES8202776A1 (en) | 1982-02-16 |
Family
ID=11176255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES501396A Expired ES8202776A1 (en) | 1980-03-31 | 1981-03-31 | Process for reducing the water content of alcohol-water mixtures |
Country Status (25)
| Country | Link |
|---|---|
| JP (1) | JPS56151790A (en) |
| AU (1) | AU550088B2 (en) |
| BE (1) | BE888150A (en) |
| BR (1) | BR8101872A (en) |
| CA (1) | CA1160252A (en) |
| CH (1) | CH648340A5 (en) |
| CS (1) | CS221292B2 (en) |
| DD (1) | DD157700A5 (en) |
| DE (1) | DE3112277C2 (en) |
| DK (1) | DK137281A (en) |
| ES (1) | ES8202776A1 (en) |
| FR (1) | FR2479186A1 (en) |
| GB (1) | GB2072668B (en) |
| HU (1) | HU192065B (en) |
| IE (1) | IE51127B1 (en) |
| IT (1) | IT1140794B (en) |
| LU (1) | LU83265A1 (en) |
| NL (1) | NL8101594A (en) |
| NO (1) | NO811022L (en) |
| NZ (1) | NZ196606A (en) |
| PL (1) | PL230427A1 (en) |
| RO (1) | RO84498B (en) |
| SE (1) | SE8101977L (en) |
| SU (1) | SU1034610A3 (en) |
| YU (1) | YU41038B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0723331B2 (en) * | 1985-03-12 | 1995-03-15 | 旭化成工業株式会社 | Method for producing tertiary butanol |
| US7007764B2 (en) | 2002-12-06 | 2006-03-07 | Manitowoc Crane Companies, Inc. | Carbody to crawler connection |
| JP2007021643A (en) * | 2005-07-15 | 2007-02-01 | Amada Co Ltd | Work attracting device using permanent magnet |
| US10570071B1 (en) | 2018-12-12 | 2020-02-25 | Saudi Arabian Oil Company | Membrane-based process for butanols production from mixed butenes |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL299568A (en) * | 1900-01-01 | |||
| FR1314120A (en) * | 1962-01-08 | 1963-01-04 | Bayer Ag | Process for the preparation of tert-butyl and alkyl ethers |
| DE1249844B (en) * | 1962-03-21 | 1967-09-14 | GuIf Research &. Development Company, Pittsburgh, Pa (V St A) | Process for the production of alcohols by the addition of water to the corresponding olefins in the liquid phase |
| US3822119A (en) * | 1970-11-19 | 1974-07-02 | Goodyear Tire & Rubber | Anti-pollution anti-knock gasoline |
| DE2629769C3 (en) * | 1976-07-02 | 1989-03-16 | Hüls AG, 4370 Marl | Process for the preparation of pure methyl tertiary butyl ether |
| US4087471A (en) * | 1977-05-20 | 1978-05-02 | Petro-Tex Chemical Corporation | Fixed bed process for the production of t-butanol |
-
1980
- 1980-03-31 IT IT21068/80A patent/IT1140794B/en active
-
1981
- 1981-03-18 IE IE602/81A patent/IE51127B1/en unknown
- 1981-03-19 GB GB8108640A patent/GB2072668B/en not_active Expired
- 1981-03-24 NZ NZ196606A patent/NZ196606A/en unknown
- 1981-03-26 DK DK137281A patent/DK137281A/en not_active Application Discontinuation
- 1981-03-26 FR FR8106118A patent/FR2479186A1/en active Granted
- 1981-03-26 NO NO811022A patent/NO811022L/en unknown
- 1981-03-26 BR BR8101872A patent/BR8101872A/en unknown
- 1981-03-27 SE SE8101977A patent/SE8101977L/en not_active Application Discontinuation
- 1981-03-27 BE BE0/204278A patent/BE888150A/en not_active IP Right Cessation
- 1981-03-27 DE DE3112277A patent/DE3112277C2/en not_active Expired
- 1981-03-30 AU AU68903/81A patent/AU550088B2/en not_active Ceased
- 1981-03-30 CA CA000374128A patent/CA1160252A/en not_active Expired
- 1981-03-30 SU SU813266251A patent/SU1034610A3/en active
- 1981-03-30 PL PL23042781A patent/PL230427A1/xx unknown
- 1981-03-30 HU HU81810A patent/HU192065B/en unknown
- 1981-03-30 CH CH2146/81A patent/CH648340A5/en not_active IP Right Cessation
- 1981-03-30 YU YU828/81A patent/YU41038B/en unknown
- 1981-03-30 LU LU83265A patent/LU83265A1/en unknown
- 1981-03-30 RO RO103858A patent/RO84498B/en unknown
- 1981-03-30 JP JP4566881A patent/JPS56151790A/en active Pending
- 1981-03-31 CS CS812393A patent/CS221292B2/en unknown
- 1981-03-31 DD DD81228774A patent/DD157700A5/en unknown
- 1981-03-31 ES ES501396A patent/ES8202776A1/en not_active Expired
- 1981-03-31 NL NL8101594A patent/NL8101594A/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DK137281A (en) | 1981-10-01 |
| FR2479186B1 (en) | 1982-11-26 |
| CH648340A5 (en) | 1985-03-15 |
| RO84498B (en) | 1984-08-30 |
| PL230427A1 (en) | 1981-11-13 |
| ES501396A0 (en) | 1982-02-16 |
| FR2479186A1 (en) | 1981-10-02 |
| IT8021068A0 (en) | 1980-03-31 |
| DE3112277A1 (en) | 1982-03-18 |
| HU192065B (en) | 1987-05-28 |
| IT1140794B (en) | 1986-10-10 |
| GB2072668B (en) | 1984-03-28 |
| NZ196606A (en) | 1984-03-16 |
| DD157700A5 (en) | 1982-12-01 |
| CA1160252A (en) | 1984-01-10 |
| IE810602L (en) | 1981-09-30 |
| JPS56151790A (en) | 1981-11-24 |
| YU41038B (en) | 1986-10-31 |
| SE8101977L (en) | 1981-10-01 |
| BR8101872A (en) | 1981-10-06 |
| RO84498A (en) | 1984-06-21 |
| SU1034610A3 (en) | 1983-08-07 |
| NL8101594A (en) | 1981-10-16 |
| AU6890381A (en) | 1981-10-08 |
| LU83265A1 (en) | 1981-10-29 |
| YU82881A (en) | 1983-02-28 |
| AU550088B2 (en) | 1986-03-06 |
| DE3112277C2 (en) | 1985-05-02 |
| BE888150A (en) | 1981-09-28 |
| IE51127B1 (en) | 1986-10-15 |
| NO811022L (en) | 1981-10-01 |
| GB2072668A (en) | 1981-10-07 |
| CS221292B2 (en) | 1983-04-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CS26486A2 (en) | Method of aldehydes production by means of olefins' hydroformylation | |
| NO852001L (en) | PROCEDURE FOR CONTINUOUS PREPARATION OF ALCOHOLS. | |
| ES2003683A6 (en) | Process for producing gasoline | |
| FR2523121B1 (en) | PROCESS FOR THE PREPARATION OF ALKYLIC TERTIO-BUTYL ETHERS IN THE PRESENCE OF BUTADIENE | |
| JPS5610124A (en) | Preparation of tert-butyl alcohol | |
| ES2038353T3 (en) | METHOD FOR SYNTHESIS IN A STAGE OF METHYL T-BUTIL ETER. | |
| IT1275413B (en) | PROCEDURE FOR THE JOINT PRODUCTION OF ETHERS AND HIGH-OCTANIC HYDROCARBONS | |
| ES8607895A1 (en) | Purification of ethylene glycol derived from ethylene carbonate. | |
| ES2001465A6 (en) | Process for preparation of secondary amine | |
| ES8202776A1 (en) | Process for reducing the water content of alcohol-water mixtures | |
| JPS565424A (en) | Preparation of tertiary alcohol | |
| KR860001041A (en) | Process for preparing orthoalkyl phenol | |
| BE888531A (en) | PROCESS FOR PRODUCING ETHERS BY REACTION OF OLEFINS WITH ALCOHOLS, | |
| JPS6434933A (en) | Condensation of alcohol | |
| JPS55143919A (en) | Preparation of tertiary alcohol | |
| JPS56139588A (en) | Production of component for being compounded in motor spirit | |
| JPS5785323A (en) | Preparation of tertiary olefin | |
| FR2627182B1 (en) | IMPROVEMENT IN SYNTHESIS OF SECONDARY MERCAPTANS FROM LINEAR OLEFINS | |
| DE3665590D1 (en) | Method for the preparation of 4'-0-tetrahydropyranyladriamycin b | |
| FI102744B (en) | A process for preparing a mixture of tertiary alkyl ethers | |
| KR890010166A (en) | Improved production process of gasoline mixture | |
| KR830001839A (en) | Method for producing methyl t-butyl ether | |
| JPS5742637A (en) | Production of hydrocarbon | |
| TW256827B (en) | Preparation process for tertiary amine |