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ES8104979A1 - Procedimiento para la reaccion de un gas de sintesis conte- niendo monoxido de carbono e hidrogeno en presencia de un catalizador de hidrogenacion. esta patente se ha depositado en: australia, canada, israel, japon, noruega y patent - Google Patents

Procedimiento para la reaccion de un gas de sintesis conte- niendo monoxido de carbono e hidrogeno en presencia de un catalizador de hidrogenacion. esta patente se ha depositado en: australia, canada, israel, japon, noruega y patent

Info

Publication number
ES8104979A1
ES8104979A1 ES492883A ES492883A ES8104979A1 ES 8104979 A1 ES8104979 A1 ES 8104979A1 ES 492883 A ES492883 A ES 492883A ES 492883 A ES492883 A ES 492883A ES 8104979 A1 ES8104979 A1 ES 8104979A1
Authority
ES
Spain
Prior art keywords
carbon atom
methane
producing
synthesis gas
oxygenated compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES492883A
Other languages
English (en)
Other versions
ES492883A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of ES492883A0 publication Critical patent/ES492883A0/es
Publication of ES8104979A1 publication Critical patent/ES8104979A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6562—Manganese
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C07C29/158—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof containing rhodium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)

Abstract

METODO PARA OBTENER HIDROCARBUROS OXIGENADOS DE DOS ATOMOS DE CARBONO A PARTIR DE UN GAS DE SINTESIS QUE CONTIENE MONOXIDO DE CARBONO E HIDROGENO, EN PRESENCIA DE UN CATALIZADOR DE HIDROGENACION. CONSISTE EN PONER EN CONTACTO CONTINUO DICHO GAS DE SINTESIS CON UN CATALIZADOR HETEROGENEO QUE COMPRENDE RODIO EN COMBINACION CON SODIO BAJO CONDICIONES DE REACCION ADECUADAS PARA PRODUCIR SELECTIVAMENTE ACIDO ACETICO, ETANOL Y ACETALDEHIDO, EN CANTIDADES SUPERIORES AL 50 POR 100 EN PESO DE LOS COMPONENTES DE DOS O MAS ATOMOS DE CARBONO PRODUCIDOS POR LA REACCION. LA CONCENTRACION DE SODIO EN EL CATALIZADOR NO HA DE SER INFERIOR AL 0,1 POR 100 EN PESO. AL CATALIZADOR SE LE PUEDE AÑADIR MANGANESO PARA AUMENTAR LA VELOCIDAD DEL PROCESO. LA REACCION TIENE LUGAR A UNA TEMPERATURA COMPRENDIDA ENTRE 150 Y 450G Y A UNA PRESION DEL ORDEN DE 1,05 A 700 KG./CM. CUADRADOS. LA RELACION MOLAR DE HIDROENO A MONOXIDO DE CARBONO VARIA ENTRE 20:1 A 1:200. DE USO EN LA OBTENCION DE ACIDO ACETICO, ETANOL Y ACETALDEHIDO.
ES492883A 1979-06-28 1980-06-27 Procedimiento para la reaccion de un gas de sintesis conte- niendo monoxido de carbono e hidrogeno en presencia de un catalizador de hidrogenacion. esta patente se ha depositado en: australia, canada, israel, japon, noruega y patent Expired ES8104979A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US5286979A 1979-06-28 1979-06-28
US12198580A 1980-02-15 1980-02-15

Publications (2)

Publication Number Publication Date
ES492883A0 ES492883A0 (es) 1981-06-01
ES8104979A1 true ES8104979A1 (es) 1981-06-01

Family

ID=26731190

Family Applications (1)

Application Number Title Priority Date Filing Date
ES492883A Expired ES8104979A1 (es) 1979-06-28 1980-06-27 Procedimiento para la reaccion de un gas de sintesis conte- niendo monoxido de carbono e hidrogeno en presencia de un catalizador de hidrogenacion. esta patente se ha depositado en: australia, canada, israel, japon, noruega y patent

Country Status (7)

Country Link
EP (1) EP0021443B1 (es)
AU (1) AU541662B2 (es)
CA (1) CA1146592A (es)
DE (1) DE3062016D1 (es)
ES (1) ES8104979A1 (es)
IL (1) IL60385A (es)
NO (1) NO801919L (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2845587A1 (en) 2011-08-31 2013-03-07 Sekisui Chemical Co., Ltd. Catalyst for oxygenate synthesis and method for manufacturing same, device for manufacturing oxygenate, and method for manufacturing oxygenate
CA2847233A1 (en) 2012-02-28 2013-09-06 Sekisui Chemical Co., Ltd. Catalyst for c2 oxygenate synthesis, device for manufacturing c2 oxygenate, and method for manufacturing c2 oxygenate
US9333491B2 (en) 2012-03-07 2016-05-10 Sekisui Chemical Co., Ltd. Catalyst for oxygenate synthesis, oxygenate production apparatus, and method of producing oxygenate
CA2879840A1 (en) 2012-07-23 2014-01-30 Sekisui Chemical Co., Ltd. System for producing oxygenate and method for producing oxygenate
JP6093780B2 (ja) 2012-12-20 2017-03-08 積水化学工業株式会社 アルコール合成用の触媒、アルコールの製造装置及びアルコールの製造方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB712686A (en) * 1950-06-26 1954-07-28 Ruhrchemie Ag Process for the catalytic hydrogenation of carbon monoxide
FR2259077B1 (es) * 1974-01-28 1978-07-13 Union Carbide Corp
US3952039A (en) * 1974-07-12 1976-04-20 Union Carbide Corporation Catalytic process for polyhydric alcohols and derivatives
US4014913A (en) * 1975-06-26 1977-03-29 Union Carbide Corporation Process for producing oxygenated two carbon compounds
DE2825598A1 (de) * 1978-06-10 1979-12-20 Hoechst Ag Verfahren zur herstellung sauerstoffhaltiger kohlenstoffverbindungen aus synthesegas

Also Published As

Publication number Publication date
ES492883A0 (es) 1981-06-01
NO801919L (no) 1980-12-29
DE3062016D1 (en) 1983-03-24
CA1146592A (en) 1983-05-17
IL60385A (en) 1984-02-29
EP0021443A1 (en) 1981-01-07
EP0021443B1 (en) 1983-02-16
AU541662B2 (en) 1985-01-17
IL60385A0 (en) 1980-09-16
AU5972780A (en) 1981-01-08

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