ES462577A1 - Process for preparing phthalide colourformrs and substituted 5-aminobenzoic acid derivatives - Google Patents
Process for preparing phthalide colourformrs and substituted 5-aminobenzoic acid derivativesInfo
- Publication number
- ES462577A1 ES462577A1 ES462577A ES462577A ES462577A1 ES 462577 A1 ES462577 A1 ES 462577A1 ES 462577 A ES462577 A ES 462577A ES 462577 A ES462577 A ES 462577A ES 462577 A1 ES462577 A1 ES 462577A1
- Authority
- ES
- Spain
- Prior art keywords
- colourformrs
- substituted
- acid derivatives
- aminobenzoic acid
- phthalide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 title abstract 4
- XFDUHJPVQKIXHO-UHFFFAOYSA-N 3-aminobenzoic acid Chemical class NC1=CC=CC(C(O)=O)=C1 XFDUHJPVQKIXHO-UHFFFAOYSA-N 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 4
- 150000002596 lactones Chemical class 0.000 abstract 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- NLFBCYMMUAKCPC-KQQUZDAGSA-N ethyl (e)-3-[3-amino-2-cyano-1-[(e)-3-ethoxy-3-oxoprop-1-enyl]sulfanyl-3-oxoprop-1-enyl]sulfanylprop-2-enoate Chemical compound CCOC(=O)\C=C\SC(=C(C#N)C(N)=O)S\C=C\C(=O)OCC NLFBCYMMUAKCPC-KQQUZDAGSA-N 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
- C07D207/33—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals, directly attached to ring carbon atoms
- C07D207/337—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
- B41M5/132—Chemical colour-forming components; Additives or binders therefor
- B41M5/136—Organic colour formers, e.g. leuco dyes
- B41M5/145—Organic colour formers, e.g. leuco dyes with a lactone or lactam ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/04—Indoles; Hydrogenated indoles
- C07D209/10—Indoles; Hydrogenated indoles with substituted hydrocarbon radicals attached to carbon atoms of the hetero ring
- C07D209/18—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D209/20—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals substituted additionally by nitrogen atoms, e.g. tryptophane
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/56—Ring systems containing three or more rings
- C07D209/80—[b, c]- or [b, d]-condensed
- C07D209/82—Carbazoles; Hydrogenated carbazoles
- C07D209/86—Carbazoles; Hydrogenated carbazoles with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the ring system
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/87—Benzo [c] furans; Hydrogenated benzo [c] furans
- C07D307/88—Benzo [c] furans; Hydrogenated benzo [c] furans with one oxygen atom directly attached in position 1 or 3
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
- C07D333/24—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D455/00—Heterocyclic compounds containing quinolizine ring systems, e.g. emetine alkaloids, protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine
- C07D455/03—Heterocyclic compounds containing quinolizine ring systems, e.g. emetine alkaloids, protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine containing quinolizine ring systems directly condensed with at least one six-membered carbocyclic ring, e.g. protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine
- C07D455/04—Heterocyclic compounds containing quinolizine ring systems, e.g. emetine alkaloids, protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine containing quinolizine ring systems directly condensed with at least one six-membered carbocyclic ring, e.g. protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine containing a quinolizine ring system condensed with only one six-membered carbocyclic ring, e.g. julolidine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/06—Peri-condensed systems
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Indole Compounds (AREA)
- Color Printing (AREA)
- Furan Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
- Heterocyclic Compounds Containing Sulfur Atoms (AREA)
- Pyridine Compounds (AREA)
Abstract
Compounds of formula III are prepared by condensation of the corresponding lactone (phthalide) with a compound H-Z with opening of the lactone ring. The symbols employed are explained in Claim 1. The compounds obtained can be converted by oxidation of the compound III to re-form the lactone. The compounds described are employed as colour-generating substances in a duplication system without carbon paper.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72648276A | 1976-09-24 | 1976-09-24 | |
| US79354477A | 1977-05-04 | 1977-05-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES462577A1 true ES462577A1 (en) | 1978-07-16 |
Family
ID=27111327
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES462577A Expired ES462577A1 (en) | 1976-09-24 | 1976-09-23 | Process for preparing phthalide colourformrs and substituted 5-aminobenzoic acid derivatives |
Country Status (17)
| Country | Link |
|---|---|
| JP (1) | JPS5356224A (en) |
| AR (1) | AR224099A1 (en) |
| AU (1) | AU517656B2 (en) |
| BE (1) | BE858929A (en) |
| BR (1) | BR7706358A (en) |
| CA (1) | CA1088938A (en) |
| CH (1) | CH628922A5 (en) |
| DE (1) | DE2742909A1 (en) |
| DK (1) | DK422577A (en) |
| ES (1) | ES462577A1 (en) |
| FR (3) | FR2371418A1 (en) |
| GB (3) | GB1590913A (en) |
| IE (1) | IE45772B1 (en) |
| IT (1) | IT1198303B (en) |
| LU (1) | LU78163A1 (en) |
| MX (1) | MX149663A (en) |
| NL (1) | NL7710326A (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4189171A (en) * | 1977-03-01 | 1980-02-19 | Sterling Drug Inc. | Marking systems containing 3-aryl-3-heterylphthalides and 3,3-bis(heteryl)phthalides |
| US4275206A (en) * | 1979-03-05 | 1981-06-23 | Appleton Papers Inc. | Lactone compounds containing an indolizine radical |
| US4920220A (en) * | 1987-11-12 | 1990-04-24 | Ciba-Geigy Corporation | Chromogenic 1-heterocyclic substituted 2,4-benzoxazines |
| EP2981523B1 (en) * | 2013-04-02 | 2021-05-19 | Syngenta Participations AG | Insecticidal compounds |
| TW201922942A (en) * | 2017-10-12 | 2019-06-16 | 美商美力肯及公司 | Triarylmethane leuco compounds and compositions comprising the same |
| JP2024143725A (en) * | 2023-03-30 | 2024-10-11 | 富士フイルム株式会社 | On-press development type lithographic printing plate precursor, method for producing a lithographic printing plate, and lithographic printing method |
| JP2024143724A (en) * | 2023-03-30 | 2024-10-11 | 富士フイルム株式会社 | On-press development type lithographic printing plate precursor, method for producing lithographic printing plate, lithographic printing method, and compound |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS525746A (en) * | 1975-07-03 | 1977-01-17 | Kanzaki Paper Mfg Co Ltd | Novel process for preparation of triarymethane derivatives |
-
1976
- 1976-09-23 ES ES462577A patent/ES462577A1/en not_active Expired
-
1977
- 1977-09-13 GB GB3813377A patent/GB1590913A/en not_active Expired
- 1977-09-13 IE IE188777A patent/IE45772B1/en unknown
- 1977-09-13 GB GB1677779A patent/GB1590914A/en not_active Expired
- 1977-09-13 GB GB1677879A patent/GB1590915A/en not_active Expired
- 1977-09-14 CA CA286,689A patent/CA1088938A/en not_active Expired
- 1977-09-19 MX MX17061077A patent/MX149663A/en unknown
- 1977-09-20 NL NL7710326A patent/NL7710326A/en not_active Application Discontinuation
- 1977-09-21 AU AU28994/77A patent/AU517656B2/en not_active Expired
- 1977-09-22 BE BE1008390A patent/BE858929A/en unknown
- 1977-09-22 LU LU78163A patent/LU78163A1/xx unknown
- 1977-09-22 AR AR26929677A patent/AR224099A1/en active
- 1977-09-22 FR FR7728585A patent/FR2371418A1/en not_active Withdrawn
- 1977-09-23 IT IT2790077A patent/IT1198303B/en active
- 1977-09-23 CH CH1165477A patent/CH628922A5/en not_active IP Right Cessation
- 1977-09-23 DK DK422577A patent/DK422577A/en not_active Application Discontinuation
- 1977-09-23 DE DE19772742909 patent/DE2742909A1/en not_active Withdrawn
- 1977-09-23 BR BR7706358A patent/BR7706358A/en unknown
- 1977-09-24 JP JP11505177A patent/JPS5356224A/en active Pending
-
1978
- 1978-02-07 FR FR7803370A patent/FR2368466A1/en not_active Withdrawn
- 1978-02-07 FR FR7803371A patent/FR2368486A1/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| FR2368486A1 (en) | 1978-05-19 |
| LU78163A1 (en) | 1978-06-01 |
| IE771887L (en) | 1978-03-24 |
| FR2371418A1 (en) | 1978-06-16 |
| IE45772B1 (en) | 1982-11-17 |
| FR2368466A1 (en) | 1978-05-19 |
| AU2899477A (en) | 1979-03-29 |
| IT1198303B (en) | 1988-12-21 |
| BE858929A (en) | 1978-03-22 |
| BR7706358A (en) | 1978-06-06 |
| AR224099A1 (en) | 1981-10-30 |
| GB1590915A (en) | 1981-06-10 |
| GB1590914A (en) | 1981-06-10 |
| CH628922A5 (en) | 1982-03-31 |
| MX149663A (en) | 1983-12-09 |
| NL7710326A (en) | 1978-03-29 |
| JPS5356224A (en) | 1978-05-22 |
| GB1590913A (en) | 1981-06-10 |
| AU517656B2 (en) | 1981-08-20 |
| DK422577A (en) | 1978-03-25 |
| DE2742909A1 (en) | 1978-03-30 |
| CA1088938A (en) | 1980-11-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19980401 |