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ES433352A1 - Piperidine carboxylic acids and their metal salts - Google Patents

Piperidine carboxylic acids and their metal salts

Info

Publication number
ES433352A1
ES433352A1 ES433352A ES433352A ES433352A1 ES 433352 A1 ES433352 A1 ES 433352A1 ES 433352 A ES433352 A ES 433352A ES 433352 A ES433352 A ES 433352A ES 433352 A1 ES433352 A1 ES 433352A1
Authority
ES
Spain
Prior art keywords
carbon atoms
alkyl
group
phenylene
stabilizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES433352A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US429232A external-priority patent/US3920661A/en
Priority claimed from US429327A external-priority patent/US3907803A/en
Priority claimed from US05/429,231 external-priority patent/US3960809A/en
Priority claimed from US05/429,237 external-priority patent/US3939163A/en
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of ES433352A1 publication Critical patent/ES433352A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings
    • C08K5/3435—Piperidines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/40—Oxygen atoms
    • C07D211/44—Oxygen atoms attached in position 4
    • C07D211/46—Oxygen atoms attached in position 4 having a hydrogen atom as the second substituent in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/56—Nitrogen atoms
    • C07D211/58—Nitrogen atoms attached in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22—Tin compounds
    • C07F7/2224—Compounds having one or more tin-oxygen linkages

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Hydrogenated Pyridines (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)

Abstract

Procedure for the preparation of a composition of material stabilized against deterioration by ultraviolet light, characterized in that in its realization a synthetic organic polymer, preferably polyolefinic and more especially polypropylene, is combined with 0.005 to 5% of a stabilizer of the general formula I **(See formula)** in which R1 and R2 independently represent straight or branched chain alkyl having 1 to 6 carbon atoms, or together with the carbon atom to which they are attached form a cyclopentyl or cyclooliexyl ring, which is unsubstituted or substituted by a methyl group, R3 is hydrogen, alkyl with 1 to 12 carbon atoms, beta-methoxyethyl, alkenyl with 3 or 4 carbon atoms, propargyl, benzyl or alkyl-substituted benzyl M is hydrogen or a metal chosen from the group consisting of barium, nickel, manganese, calcium, zinc, sodium, cobalt, tin, dialkyltin, lithium, potassium, magnesium, and aluminum, and Z has a value between 1 and 4, the value of z being equal to the available valence of M, R5 is oxy or imino, and R4 is straight or branched chain alkylene with 1 to 10 carbon atoms, phenylene or alkyl-phenylene, or the group (CH2) mY (CH2) n where Y is oxygen or sulfur and m and n independently represent an integer from 1 and 3, and, optionally, with 0.01 to 2% by weight with respect to the organic material, of a phenolic antioxidant and of a co-stabilizer, subjecting the composition to a heat treatment of greater than 125ºC and possibly under molding pressure. (Machine-translation by Google Translate, not legally binding)
ES433352A 1973-12-28 1974-12-27 Piperidine carboxylic acids and their metal salts Expired ES433352A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US429232A US3920661A (en) 1973-12-28 1973-12-28 Hindered piperidine carboxylic acids, metal salts thereof and stabilized compositions
US429327A US3907803A (en) 1973-12-28 1973-12-28 Hindered piperidine carboxamide acids and metal salts thereof
US05/429,231 US3960809A (en) 1973-12-28 1973-12-28 Compositions stabilized with hindered piperidine carboxylic acids
US05/429,237 US3939163A (en) 1973-12-28 1973-12-28 Metal salts of hindered piperidine carboxylic acids and stabilized compositions

Publications (1)

Publication Number Publication Date
ES433352A1 true ES433352A1 (en) 1977-03-01

Family

ID=27503771

Family Applications (1)

Application Number Title Priority Date Filing Date
ES433352A Expired ES433352A1 (en) 1973-12-28 1974-12-27 Piperidine carboxylic acids and their metal salts

Country Status (13)

Country Link
JP (1) JPS5813577B2 (en)
AT (1) AT335185B (en)
BR (1) BR7410901D0 (en)
CA (1) CA1051903A (en)
CH (1) CH606225A5 (en)
DE (1) DE2459381A1 (en)
ES (1) ES433352A1 (en)
FR (1) FR2256159B1 (en)
GB (1) GB1466628A (en)
IL (1) IL46354A (en)
IT (1) IT1028067B (en)
SE (1) SE7415683L (en)
SU (1) SU524529A3 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT7928324A0 (en) * 1979-12-21 1979-12-21 Chimosa Chimica Organica Spa PIPERIDINE DERIVATIVES, STABILIZERS FOR SYNTHETIC POLYMERS.
JPS56501881A (en) * 1980-01-14 1981-12-24
IT1174664B (en) * 1980-02-19 1987-07-01 Anic Spa POLYOLEFINIC COMPOSITIONS STABILIZED WITH PYROLIDINE DERIVATIVES AGAINST ULTRAVIOLET RADIATION
US4348524A (en) * 1980-03-28 1982-09-07 Ciba-Geigy Corporation Amide derivatives of polyalkylpiperidines
JPS58149774U (en) * 1982-03-31 1983-10-07 日本精機株式会社 display device
IT1264946B1 (en) * 1993-07-16 1996-10-17 Ciba Geigy Spa DERIVATIVES OF 2,2,6,6-TETRAMETHYL-4-PIPERIDINOL USEFUL AS LIGHT AND OXIDATION STABILIZERS FOR ORGANIC MATERIALS.
WO2013142239A1 (en) 2012-03-22 2013-09-26 3M Innovative Properties Company Polymethylmethacrylate based hardcoat composition and coated article

Also Published As

Publication number Publication date
BR7410901D0 (en) 1975-09-02
JPS5813577B2 (en) 1983-03-14
IT1028067B (en) 1979-01-30
IL46354A (en) 1978-08-31
AU7677774A (en) 1976-06-24
IL46354A0 (en) 1975-03-13
FR2256159A1 (en) 1975-07-25
SE7415683L (en) 1975-06-30
FR2256159B1 (en) 1982-05-14
GB1466628A (en) 1977-03-09
SU524529A3 (en) 1976-08-05
CA1051903A (en) 1979-04-03
JPS50138041A (en) 1975-11-04
DE2459381A1 (en) 1975-07-10
CH606225A5 (en) 1978-10-31
ATA1033774A (en) 1976-06-15
AT335185B (en) 1977-02-25

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