ES355257A1 - Process for polymerizing vinyl monomers - Google Patents
Process for polymerizing vinyl monomersInfo
- Publication number
- ES355257A1 ES355257A1 ES355257A ES355257A ES355257A1 ES 355257 A1 ES355257 A1 ES 355257A1 ES 355257 A ES355257 A ES 355257A ES 355257 A ES355257 A ES 355257A ES 355257 A1 ES355257 A1 ES 355257A1
- Authority
- ES
- Spain
- Prior art keywords
- monomer
- mercaptan
- stage
- peroxide
- ter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000178 monomer Substances 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 2
- 230000000379 polymerizing effect Effects 0.000 title 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title 1
- 229920002554 vinyl polymer Polymers 0.000 title 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 abstract 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 2
- 239000006188 syrup Substances 0.000 abstract 2
- 235000020357 syrup Nutrition 0.000 abstract 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- NEHDRDVHPTWWFG-UHFFFAOYSA-N Dioctyl hexanedioate Chemical compound CCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCC NEHDRDVHPTWWFG-UHFFFAOYSA-N 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- 239000005062 Polybutadiene Substances 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 1
- 150000002825 nitriles Chemical group 0.000 abstract 1
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 abstract 1
- 235000019271 petrolatum Nutrition 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 229920002857 polybutadiene Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000005060 rubber Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/02—Polymerisation in bulk
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Monomers of formula where R is H or CH 3 and R1 is nitrile, phenyl or esterified carboxyl are continuously bulk polymerized by preparing a prepolymer syrup containing monomer and polymer in a two-stage process, the first stage being carried out at 50-120 C. followed by cooling the product to a temperature not below 25 C. and carrying out the second stage at 60-150 C., removing the monomer in part from the syrup and completing the polymerization by heating. The monomer may be styrene containing di-terbutyl-peroxide or dicumyl peroxide, ter-dodecyl - mercaptan or isopropyl - xantogendisulphide, petroleum jelly and rubber methyl methacrylate containing lauroyl peroxide, octyl mercaptan and optionally methyl acrylate or styrene and acrylonitrile containing lauroyl peroxide, di-ter-dodecyl mercaptan, a phosphitic anti-oxidant and di-octyl adipate and optionally polybutadiene. The monomer may be removed from the prepolymer by applying a vacuum to an extruder.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1746567 | 1967-06-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES355257A1 true ES355257A1 (en) | 1969-11-16 |
Family
ID=11150369
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES355257A Expired ES355257A1 (en) | 1967-06-21 | 1968-06-20 | Process for polymerizing vinyl monomers |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3806556A (en) |
| DE (1) | DE1770664C3 (en) |
| ES (1) | ES355257A1 (en) |
| GB (1) | GB1233079A (en) |
| NL (1) | NL6808669A (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5442035B2 (en) * | 1974-02-04 | 1979-12-12 | ||
| FR2405269A1 (en) * | 1977-10-06 | 1979-05-04 | Sumitomo Chemical Co | PROCESS FOR THE CONTINUOUS PRODUCTION OF SYRUP OF METHYL METHACRYLATE PREPOLYMERS AND NEW PRODUCTS THUS OBTAINED |
| DE2839563A1 (en) * | 1978-09-12 | 1980-03-27 | Hoechst Ag | METHOD FOR CONTINUOUS MASS POLYMERIZATION OF ALKENYL FLAVORS |
| ZA803162B (en) * | 1979-06-01 | 1981-05-27 | Mobil Oil Corp | A continuous process for the preparation of rubber modified polymers |
| US4940754A (en) * | 1988-05-17 | 1990-07-10 | The Dow Chemical Company | Easily colored thermoplastic molding composition |
| JPH0236243A (en) * | 1988-07-27 | 1990-02-06 | Tonen Sekiyukagaku Kk | Thermoplastic elastomer composition |
| DE4235980A1 (en) * | 1992-10-24 | 1994-04-28 | Basf Ag | Process for the preparation of a vinyl aromatic compound |
| KR101711257B1 (en) * | 2013-09-30 | 2017-03-02 | 주식회사 엘지화학 | Mass PVC composition, method and apparatus for mass polymerization PVC |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2496653A (en) * | 1943-10-12 | 1950-02-07 | Union Carbide & Carbon Corp | Continuous bulk polymerization of styrene |
| DE1074264B (en) * | 1952-11-26 | 1960-01-28 | ||
| GB875853A (en) * | 1959-07-03 | 1961-08-23 | Ici Ltd | Improved process for the production of polymeric material |
| DE1112631B (en) * | 1959-08-26 | 1961-08-10 | Basf Ag | Process for the continuous bulk polymerization of styrene |
-
1968
- 1968-06-20 GB GB1233079D patent/GB1233079A/en not_active Expired
- 1968-06-20 NL NL6808669A patent/NL6808669A/xx unknown
- 1968-06-20 ES ES355257A patent/ES355257A1/en not_active Expired
- 1968-06-20 DE DE1770664A patent/DE1770664C3/en not_active Expired
-
1971
- 1971-06-16 US US00153802A patent/US3806556A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US3806556A (en) | 1974-04-23 |
| DE1770664C3 (en) | 1982-03-18 |
| GB1233079A (en) | 1971-05-26 |
| NL6808669A (en) | 1968-12-23 |
| DE1770664A1 (en) | 1972-03-02 |
| DE1770664B2 (en) | 1981-06-04 |
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