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ES2633178T3 - Battery leaching method - Google Patents

Battery leaching method Download PDF

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Publication number
ES2633178T3
ES2633178T3 ES13783980.9T ES13783980T ES2633178T3 ES 2633178 T3 ES2633178 T3 ES 2633178T3 ES 13783980 T ES13783980 T ES 13783980T ES 2633178 T3 ES2633178 T3 ES 2633178T3
Authority
ES
Spain
Prior art keywords
mineral
solution
contact
treatment phase
concentration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES13783980.9T
Other languages
Spanish (es)
Inventor
Eduardo Luis PATIÑO MARTINEZ
Michael James Nicol
George Frederick Rautenbach
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BHP Chile Inc
Original Assignee
BHP Chile Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=49513971&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2633178(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by BHP Chile Inc filed Critical BHP Chile Inc
Application granted granted Critical
Publication of ES2633178T3 publication Critical patent/ES2633178T3/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00—Preliminary treatment of ores or scrap
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00—Obtaining copper
    • C22B15/0063—Hydrometallurgy
    • C22B15/0065—Leaching or slurrying
    • C22B15/0067—Leaching or slurrying with acids or salts thereof
    • C22B15/0069—Leaching or slurrying with acids or salts thereof containing halogen
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00—Preliminary treatment of ores or scrap
    • C22B1/14—Agglomerating; Briquetting; Binding; Granulating
    • C22B1/16—Sintering; Agglomerating
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00—Obtaining copper
    • C22B15/0002—Preliminary treatment
    • C22B15/0004—Preliminary treatment without modification of the copper constituent
    • C22B15/0008—Preliminary treatment without modification of the copper constituent by wet processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00—Obtaining copper
    • C22B15/0063—Hydrometallurgy
    • C22B15/0065—Leaching or slurrying
    • C22B15/0067—Leaching or slurrying with acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • C22B3/10—Hydrochloric acid, other halogenated acids or salts thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Apparatus Associated With Microorganisms And Enzymes (AREA)

Abstract

Un método de recuperación de un metal básico a partir de un mineral en el que el mineral se somete a una fase de pre-tratamiento seguido de un ciclo de lixiviación activa y en el que, en la fase de pre-tratamiento: 1. el mineral se pone en contacto con una solución durante una etapa de aglomeración o por irrigación; 2. el potencial de la solución en contacto con el mineral supera los 700 mV frente al electrodo normal de hidrógeno (ENH), en ausencia de microorganismos; 3. la concentración total de hierro de la solución en contacto con el mineral es > 0,1 g/l; 4. la adición de la solución se controla para lograr un contenido final de humedad del mineral en el intervalo del 2 al 25% en peso; 5. el pH de la solución en contacto con el mineral no supera pH 3,0; 6. la concentración de iones Cl- de la solución en contacto con el mineral está entre 130 y 230 g/l; y 7. el nivel de oxígeno disuelto en la solución en contacto con el mineral está por debajo de 1 mg/l.A method of recovering a basic metal from a mineral in which the mineral is subjected to a pre-treatment phase followed by an active leaching cycle and in which, in the pre-treatment phase: 1. the ore is contacted with a solution during an agglomeration stage or by irrigation; 2. The potential of the solution in contact with the mineral exceeds 700 mV compared to the normal hydrogen electrode (ENH), in the absence of microorganisms; 3. The total iron concentration of the solution in contact with the mineral is> 0.1 g / l; 4. The addition of the solution is controlled to achieve a final moisture content of the mineral in the range of 2 to 25% by weight; 5. The pH of the solution in contact with the mineral does not exceed pH 3.0; 6. The concentration of Cl- ions of the solution in contact with the mineral is between 130 and 230 g / l; and 7. the level of dissolved oxygen in the solution in contact with the mineral is below 1 mg / l.

Description

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Claims (1)

imagen1image 1
ES13783980.9T 2012-08-22 2013-08-21 Battery leaching method Active ES2633178T3 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ZA201206310 2012-08-22
ZA201206310 2012-08-22
PCT/IB2013/001810 WO2014030048A1 (en) 2012-08-22 2013-08-21 Heap leaching method

Publications (1)

Publication Number Publication Date
ES2633178T3 true ES2633178T3 (en) 2017-09-19

Family

ID=49513971

Family Applications (1)

Application Number Title Priority Date Filing Date
ES13783980.9T Active ES2633178T3 (en) 2012-08-22 2013-08-21 Battery leaching method

Country Status (16)

Country Link
US (1) US9816155B2 (en)
EP (1) EP2888380B1 (en)
JP (1) JP6158927B2 (en)
KR (1) KR101839194B1 (en)
CN (1) CN104838021B (en)
AP (1) AP3820A (en)
AU (1) AU2013304626B2 (en)
CA (1) CA2882384C (en)
CL (1) CL2015000395A1 (en)
EA (1) EA026211B1 (en)
ES (1) ES2633178T3 (en)
IN (1) IN2015DN01546A (en)
MX (1) MX2015002140A (en)
PE (1) PE20151168A1 (en)
WO (1) WO2014030048A1 (en)
ZA (1) ZA201501061B (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10041143B2 (en) * 2013-10-23 2018-08-07 Bhp Chile Inc. Heap leaching of copper
CN107208176B (en) * 2014-12-17 2020-04-03 Bhp比利顿奥林匹克坝有限公司 Heap leaching process
CL2016001188A1 (en) * 2016-05-18 2017-02-24 Antofagasta Minerales S A Procedure for the improvement of copper leaching processes using calcium chloride
PE20240830A1 (en) 2016-10-19 2024-04-22 Jetti Resources Llc PROCESSES TO LEACH METAL SULFIDES WITH REAGENTS THAT HAVE THIOCARBONYL FUNCTIONAL GROUPS
RU2637204C1 (en) * 2016-12-26 2017-11-30 Акционерное общество "Золотодобывающая компания "Полюс" Method of bioleaching solid gold-containing sulfide flotoconcentrates
CL2017001777A1 (en) * 2017-07-05 2018-06-29 Tecnologias Exponenciales En Minerales Spa Method of extraction of base and precious metals by means of a pretreatment leading to the solubilization of its refractory or hypexgoldest matrices.
EP3728661B1 (en) 2017-12-21 2022-01-26 Bhp Chile Inc. Acid balance in a chloride heap leach
HUE059215T2 (en) * 2017-12-21 2022-10-28 Bhp Chile Inc Water balance in a chloride heap leach
AU2021239047A1 (en) 2020-03-18 2022-09-08 Bhp Chile Inc Oxidative heap leaching of base metals
MX2023003207A (en) 2020-09-18 2023-04-27 Jetti Resources Llc Extracting base metals using a wetting agent and a thiocarbonyl functional group reagent.
US12435389B2 (en) 2023-06-14 2025-10-07 Ceibo Inc. System and process for progressive refractory ore transformation for copper leaching
WO2025129330A1 (en) * 2023-12-19 2025-06-26 Universite Laval Complexation leaching copper and nickel from low-grade sulfide mineral resources with co2 mineralization

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4384890A (en) * 1982-02-10 1983-05-24 Phelps Dodge Corporation Cupric chloride leaching of copper sulfides
CN1058056C (en) * 1997-07-28 2000-11-01 中国科学院化工冶金研究所 Process of chlorine complexing oxidation method for slective leaching nickel cobalt copper sulfurized ore
JP2003328051A (en) * 2002-05-17 2003-11-19 Sumitomo Metal Mining Co Ltd Leaching treatment method of copper sulfide ore containing chalcopyrite
US8802042B2 (en) * 2002-07-19 2014-08-12 Vale S.A. Process of recovery of base metals from oxide ores
CA2432743C (en) 2002-11-26 2010-12-14 Minera Michilla S.A. Non-biochemical method to heap leach copper concentrates
JP2006512484A (en) * 2002-12-31 2006-04-13 インテック・リミテッド Recovery of metals from sulfide-based materials
CA2475833C (en) * 2004-01-29 2011-02-01 Minera Michilla S.A. Procedure to leach copper concentrates, under pressure and at ambient temperature, by forming a colloidal mass in a sulfate - chloride medium
WO2007134344A1 (en) * 2006-05-12 2007-11-22 Bhp Billiton Sa Limited Chloride tank leaching
EP2265736A1 (en) * 2008-03-19 2010-12-29 BHP Billiton SSM Technology Pty Ltd. A process for atmospheric leaching of laterite ores using hypersaline leach solution
AU2009266418A1 (en) * 2008-07-02 2010-01-07 Bhp Billiton Ssm Development Pty Ltd A process for heap leaching of nickeliferous oxidic ores
AR082048A1 (en) * 2010-06-30 2012-11-07 Bhp Chile Inc A METHOD FOR RECOVERING COPPER FROM A MENA CONTAINING COPPER SULFIDE MINERAL

Also Published As

Publication number Publication date
CN104838021B (en) 2017-10-03
CA2882384C (en) 2018-02-20
EP2888380A1 (en) 2015-07-01
AU2013304626A1 (en) 2015-03-12
AP3820A (en) 2016-09-30
BR112015003731A2 (en) 2017-07-04
ZA201501061B (en) 2016-01-27
PE20151168A1 (en) 2015-08-19
US20150232963A1 (en) 2015-08-20
AP2015008279A0 (en) 2015-02-28
US9816155B2 (en) 2017-11-14
EA026211B1 (en) 2017-03-31
KR20150060711A (en) 2015-06-03
CN104838021A (en) 2015-08-12
KR101839194B1 (en) 2018-03-15
JP2015530481A (en) 2015-10-15
AU2013304626B2 (en) 2017-09-14
JP6158927B2 (en) 2017-07-05
EA201590245A1 (en) 2015-08-31
CA2882384A1 (en) 2014-02-27
WO2014030048A1 (en) 2014-02-27
IN2015DN01546A (en) 2015-07-03
CL2015000395A1 (en) 2015-08-21
MX2015002140A (en) 2015-10-29
EP2888380B1 (en) 2017-05-03

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