ES2527542T3 - Agent for machine washing of dishes with improved protection against glass corrosion - Google Patents
Agent for machine washing of dishes with improved protection against glass corrosion Download PDFInfo
- Publication number
- ES2527542T3 ES2527542T3 ES03735481.8T ES03735481T ES2527542T3 ES 2527542 T3 ES2527542 T3 ES 2527542T3 ES 03735481 T ES03735481 T ES 03735481T ES 2527542 T3 ES2527542 T3 ES 2527542T3
- Authority
- ES
- Spain
- Prior art keywords
- agent according
- powder
- agent
- granulate
- compacted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000007797 corrosion Effects 0.000 title 1
- 238000005260 corrosion Methods 0.000 title 1
- 239000011521 glass Substances 0.000 title 1
- 238000005406 washing Methods 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 74
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 9
- -1 zinc salt Chemical class 0.000 abstract description 3
- 238000004851 dishwashing Methods 0.000 abstract 2
- 150000004760 silicates Chemical class 0.000 abstract 2
- 150000003751 zinc Chemical class 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Chemical group 0.000 abstract 1
- 239000001257 hydrogen Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 21
- 239000008187 granular material Substances 0.000 description 18
- 239000006185 dispersion Substances 0.000 description 14
- 239000000499 gel Substances 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- 239000000155 melt Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 230000004308 accommodation Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000004482 other powder Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- UUUDMEBRZTWNAO-UHFFFAOYSA-N carbonic acid;2-hydroxypropane-1,2,3-tricarboxylic acid Chemical compound OC(O)=O.OC(=O)CC(O)(C(O)=O)CC(O)=O UUUDMEBRZTWNAO-UHFFFAOYSA-N 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000011970 polystyrene sulfonate Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229920006029 tetra-polymer Polymers 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1273—Crystalline layered silicates of type NaMeSixO2x+1YH2O
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
Landscapes
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Emergency Medicine (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Detergent Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
Agente para el lavado a máquina de la vajilla o coadyuvante para el lavado a máquina de la vajilla que contiene al menos una sal de cinc soluble así como, en relación con el peso total de este agente, del 0,1 al 20 % en peso de silicato o silicatos estratificados cristalinos de Fórmula general (Ia) NaMSixO2x+1 · y H2O (Ia), en la que M representa sodio o hidrógeno, x es un número de 1,9 a 22, preferentemente de 1,9 a 4 e y se refiere a un número de 0 a 33, caracterizado por que contiene la/las sales de cinc así como el/los silicatos estratificados cristalinos de Fórmula general (Ia) en proporción 3:1 a 1:10 y habiéndose de entender por una "sal de cinc soluble" una sal de cinc con una solubilidad en agua por encima de 100 mg/l (solubilidad a 20 ºC de temperatura de agua).Machine dishwashing agent or machine dishwashing aid containing at least one soluble zinc salt as well as, relative to the total weight of this agent, from 0.1 to 20% by weight of crystalline layered silicate or silicates of general Formula (Ia) NaMSixO2x+1 y H2O (Ia), in which M represents sodium or hydrogen, x is a number from 1.9 to 22, preferably from 1.9 to 4 and y refers to a number from 0 to 33, characterized in that it contains the zinc salt(s) as well as the crystalline layered silicates of general Formula (Ia) in a proportion of 3:1 to 1:10 and having to be understood by a " soluble zinc salt" a zinc salt with a solubility in water above 100 mg/l (solubility at 20 °C water temperature).
Description
E03735481 E03735481
23-12-2014 12-23-2014
cuatro o más cámaras de alojamiento. El experto conoce procedimientos para la producción de tales envases. A estos procedimientos pertenecen, por ejemplo, procedimientos de embutición profunda, moldeo por inyección o colada. Por consiguiente, mediante envases de una y dos cámaras están descritas algunas combinaciones preferentes de acuerdo con la invención de agentes confeccionados de forma diferente: Four or more accommodation cameras. The expert knows procedures for the production of such containers. To these procedures belong, for example, deep drawing, injection molding or casting procedures. Accordingly, some preferred combinations according to the invention of differently made agents are described by means of one and two chamber packages:
Envase soluble en agua o dispersable en agua con una cámara de alojamiento: Water soluble or water dispersible container with a housing chamber:
- Cámara de alojamiento 1 Chamber of accommodation 1
- Agente de acuerdo con la invención en un polvo y líquido Agent according to the invention in a powder and liquid
- Agente de acuerdo con la invención en un polvo y otro polvo Agent according to the invention in a powder and other powder
- Agente de acuerdo con la invención en un polvo y granulado Agent according to the invention in a powder and granulate
- Agente de acuerdo con la invención en un polvo y compactado Agent according to the invention in a powder and compacted
- Agente de acuerdo con la invención en un polvo y extruído Agent according to the invention in a powder and extruded
- Agente de acuerdo con la invención en un polvo y cuerpo colado Agent according to the invention in a powder and cast body
- Agente de acuerdo con la invención en un polvo y gel con estabilidad dimensional Agent according to the invention in a powder and gel with dimensional stability
- Agente de acuerdo con la invención en una masa fundida y líquido Agent according to the invention in a melt and liquid
- Agente de acuerdo con la invención en una masa fundida y otro polvo Agent according to the invention in a melt and other powder
- Agente de acuerdo con la invención en una masa fundida y granulado Agent according to the invention in a melt and granulate
- Agente de acuerdo con la invención en una masa fundida y compactado Agent according to the invention in a melt and compacted mass
- Agente de acuerdo con la invención en una masa fundida y extruído Agent according to the invention in a molten and extruded mass
- Agente de acuerdo con la invención en una masa fundida y cuerpo colado Agent according to the invention in a melt and cast body
- Agente de acuerdo con la invención en una masa fundida y gel con estabilidad dimensional Agent according to the invention in a melt and gel with dimensional stability
- Agente de acuerdo con la invención en un granulado y líquido Agent according to the invention in a granulate and liquid
- Agente de acuerdo con la invención en un granulado y otro polvo Agent according to the invention in a granulate and other powder
- Agente de acuerdo con la invención en un granulado y granulado Agent according to the invention in a granulate and granulate
- Agente de acuerdo con la invención en un granulado y compactado Agent according to the invention in a granulate and compacted
- Agente de acuerdo con la invención en un granulado y extruído Agent according to the invention in a granulate and extruded
- Agente de acuerdo con la invención en un granulado y cuerpo colado Agent according to the invention in a granulate and cast body
- Agente de acuerdo con la invención en un granulado y gel con estabilidad dimensional Agent according to the invention in a granulate and gel with dimensional stability
Envase soluble en agua o dispersable en agua con dos cámaras de alojamiento Water soluble or water dispersible container with two housing chambers
- Cámara de alojamiento 1 Chamber of accommodation 1
- Cámara de alojamiento 2 Housing chamber 2
- Agente de acuerdo con la invención en una dispersión Agent according to the invention in a dispersion
- Líquido Liquid
- Agente de acuerdo con la invención en una dispersión Agent according to the invention in a dispersion
- Polvo Powder
- Agente de acuerdo con la invención en una dispersión Agent according to the invention in a dispersion
- Granulado Granulated
- Agente de acuerdo con la invención en una dispersión Agent according to the invention in a dispersion
- Compactado Compacted
- Agente de acuerdo con la invención en una dispersión Agent according to the invention in a dispersion
- Extruído Extruded
- Agente de acuerdo con la invención en una dispersión Agent according to the invention in a dispersion
- Cuerpo colado Cast body
- Agente de acuerdo con la invención en una dispersión Agent according to the invention in a dispersion
- Gel con estabilidad dimensional Gel with dimensional stability
- Agente de acuerdo con la invención en una dispersión Agent according to the invention in a dispersion
- Dispersión Dispersion
- Agente de acuerdo con la invención en un polvo Agent according to the invention in a powder
- Líquido Liquid
- Agente de acuerdo con la invención en un polvo Agent according to the invention in a powder
- Polvo Powder
- Agente de acuerdo con la invención en un polvo Agent according to the invention in a powder
- Granulado Granulated
- Agente de acuerdo con la invención en un polvo Agent according to the invention in a powder
- Compactado Compacted
- Agente de acuerdo con la invención en un polvo Agent according to the invention in a powder
- Extruído Extruded
- Agente de acuerdo con la invención en un polvo Agent according to the invention in a powder
- Cuerpo colado Cast body
- Agente de acuerdo con la invención en un polvo Agent according to the invention in a powder
- Gel con estabilidad dimensional Gel with dimensional stability
- Agente de acuerdo con la invención en un polvo Agent according to the invention in a powder
- Dispersión Dispersion
- Agente de acuerdo con la invención en un granulado Agent according to the invention in a granulate
- Líquido Liquid
- Agente de acuerdo con la invención en un granulado Agent according to the invention in a granulate
- Polvo Powder
5 5
E03735481 E03735481
23-12-2014 12-23-2014
- Cámara de alojamiento 1 Chamber of accommodation 1
- Cámara de alojamiento 2 Housing chamber 2
- Agente de acuerdo con la invención en un granulado Agent according to the invention in a granulate
- Granulado Granulated
- Agente de acuerdo con la invención en un granulado Agent according to the invention in a granulate
- Compactado Compacted
- Agente de acuerdo con la invención en un granulado Agent according to the invention in a granulate
- Extruído Extruded
- Agente de acuerdo con la invención en un granulado Agent according to the invention in a granulate
- Cuerpo colado Cast body
- Agente de acuerdo con la invención en un granulado Agent according to the invention in a granulate
- Gel con estabilidad dimensional Gel with dimensional stability
- Agente de acuerdo con la invención en un granulado Agent according to the invention in a granulate
- Dispersión Dispersion
- Agente de acuerdo con la invención en un compactado Agent according to the invention in a compacted
- Líquido Liquid
- Agente de acuerdo con la invención en un compactado Agent according to the invention in a compacted
- Polvo Powder
- Agente de acuerdo con la invención en un compactado Agent according to the invention in a compacted
- Granulado Granulated
- Agente de acuerdo con la invención en un compactado Agent according to the invention in a compacted
- Compactado Compacted
- Agente de acuerdo con la invención en un compactado Agent according to the invention in a compacted
- Extruído Extruded
- Agente de acuerdo con la invención en un compactado Agent according to the invention in a compacted
- Cuerpo colado Cast body
- Agente de acuerdo con la invención en un compactado Agent according to the invention in a compacted
- Gel con estabilidad dimensional Gel with dimensional stability
- Agente de acuerdo con la invención en un compactado Agent according to the invention in a compacted
- Dispersión Dispersion
- Agente de acuerdo con la invención en un extruído Agent according to the invention in an extrudate
- Líquido Liquid
- Agente de acuerdo con la invención en un extruído Agent according to the invention in an extrudate
- Polvo Powder
- Agente de acuerdo con la invención en un extruído Agent according to the invention in an extrudate
- Granulado Granulated
- Agente de acuerdo con la invención en un extruído Agent according to the invention in an extrudate
- Compactado Compacted
- Agente de acuerdo con la invención en un extruído Agent according to the invention in an extrudate
- Extruído Extruded
- Agente de acuerdo con la invención en un extruído Agent according to the invention in an extrudate
- Cuerpo colado Cast body
- Agente de acuerdo con la invención en un extruído Agent according to the invention in an extrudate
- Gel con estabilidad dimensional Gel with dimensional stability
- Agente de acuerdo con la invención en un extruído Agent according to the invention in an extrudate
- Dispersión Dispersion
- Agente de acuerdo con la invención en un cuerpo colado Agent according to the invention in a cast body
- Líquido Liquid
- Agente de acuerdo con la invención en un cuerpo colado Agent according to the invention in a cast body
- Polvo Powder
- Agente de acuerdo con la invención en un cuerpo colado Agent according to the invention in a cast body
- Granulado Granulated
- Agente de acuerdo con la invención en un cuerpo colado Agent according to the invention in a cast body
- Compactado Compacted
- Agente de acuerdo con la invención en un cuerpo colado Agent according to the invention in a cast body
- Extruído Extruded
- Agente de acuerdo con la invención en un cuerpo colado Agent according to the invention in a cast body
- Cuerpo colado Cast body
- Agente de acuerdo con la invención en un cuerpo colado Agent according to the invention in a cast body
- Gel con estabilidad dimensional Gel with dimensional stability
- Agente de acuerdo con la invención en un cuerpo colado Agent according to the invention in a cast body
- Dispersión Dispersion
Para la producción de la lámina soluble en agua y/o dispersable en agua en principio son adecuadas todas las sustancias o mezclas de sustancias que se pueden confeccionar en forma de una lámina. Sin embargo, es particularmente preferente un procedimiento en el que la lámina soluble en agua y/o dispersable en agua está For the production of the water-soluble and / or water-dispersible sheet in principle all substances or mixtures of substances that can be made in the form of a sheet are suitable. However, a process is particularly preferred in which the water soluble and / or water dispersible sheet is
5 compuesta de polivinilalcohol (acetalizado), polivinilpirrolidona, óxido de polietileno, gelatina, almidón y derivado o derivados de almidón, celulosa y derivado o derivados de celulosa, en particular metilcelulosa y/o mezclas de estas sustancias, habiéndose de valorar esta enumeración como ilustrativa y no limitante de la invención. 5 composed of polyvinyl alcohol (acetalized), polyvinyl pyrrolidone, polyethylene oxide, gelatin, starch and derivative or derivatives of starch, cellulose and derivative or cellulose derivatives, in particular methyl cellulose and / or mixtures of these substances, this enumeration being assessed as illustrative and not limiting the invention.
En otra forma de realización asimismo preferente, de acuerdo con la invención es ventajoso que la lámina o las In another equally preferred embodiment, according to the invention it is advantageous that the sheet or the
10 láminas comprenda/comprendan uno o varios materiales del grupo de polímeros que contienen ácido acrílico, poliacrilamidas, polímeros de oxazolina, poliestirenosulfonatos, poliuretanos, poliésteres y poliéteres y sus mezclas. 10 sheets comprise / comprise one or more materials from the group of polymers containing acrylic acid, polyacrylamides, oxazoline polymers, polystyrene sulfonates, polyurethanes, polyesters and polyethers and mixtures thereof.
De forma particularmente ventajosa se puede mencionar uno o varios materiales de la siguiente enumeración ilustrativa, sin embargo no limitante: Particularly advantageously, one or more materials of the following illustrative enumeration may be mentioned, however not limiting:
15 fifteen
- Mezclas del 50 al 100 % de polinivilalcohol o poli(vinilalcohol - co - vinilacetato) con pesos moleculares en el intervalo de 10.000 a 200.000 g/mol y contenidos de acetato del 0 al 30 % en moles; estos pueden contener aditivos de procesamiento tales como plastificantes (glicerol, sorbitol, agua, PEG, etc.), lubricantes (ácido esteárico y otros ácidos mono-, di- y tricarboxílicos), los denominados "agentes deslizantes" (por ejemplo, - Mixtures of 50 to 100% polyvinyl alcohol or poly (vinyl alcohol-co-vinyl acetate) with molecular weights in the range of 10,000 to 200,000 g / mol and acetate contents of 0 to 30 mol%; these may contain processing additives such as plasticizers (glycerol, sorbitol, water, PEG, etc.), lubricants (stearic acid and other mono-, di- and tricarboxylic acids), the so-called "sliding agents" (for example,
20 "Aerosil"), pigmentos orgánicos e inorgánicos, sales, agentes de moldeado por soplado (mezclas de ácido cítricobicarbonato sódico); 20 "Aerosil"), organic and inorganic pigments, salts, blow molding agents (mixtures of citric acid bicarbonate);
- Polímeros que contienen ácido acrílico tales como, por ejemplo, copolímeros, terpolímeros o tetrapolímeros que contienen al menos el 20 % de ácido acrílico y que poseen un peso molecular de 5.000 a 500.000 g/mol; como comonómeros se prefieren en particular ésteres de ácido acrílico tales como etilacrilato, metilacrilato, hidroxi- Polymers containing acrylic acid such as, for example, copolymers, terpolymers or tetrapolymers containing at least 20% acrylic acid and having a molecular weight of 5,000 to 500,000 g / mol; as comonomers, acrylic acid esters, such as ethyl acrylate, methylacrylate, hydroxy, are particularly preferred.
6 6
Claims (1)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10225116A DE10225116A1 (en) | 2002-06-06 | 2002-06-06 | Automatic dishwashing detergent with improved glass corrosion protection II |
| DE10225116 | 2002-06-06 | ||
| PCT/EP2003/005602 WO2003104370A1 (en) | 2002-06-06 | 2003-05-28 | Automatic dishwashing detergent with improved glass anti-corrosion properties |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2527542T3 true ES2527542T3 (en) | 2015-01-26 |
Family
ID=29594300
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES05027033T Expired - Lifetime ES2298919T3 (en) | 2002-06-06 | 2003-05-28 | COMPOSITION CONTAINING A ZINC SALT AND A LAMINATED CRYSTAL SILICATE. |
| ES03735481.8T Expired - Lifetime ES2527542T3 (en) | 2002-06-06 | 2003-05-28 | Agent for machine washing of dishes with improved protection against glass corrosion |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES05027033T Expired - Lifetime ES2298919T3 (en) | 2002-06-06 | 2003-05-28 | COMPOSITION CONTAINING A ZINC SALT AND A LAMINATED CRYSTAL SILICATE. |
Country Status (7)
| Country | Link |
|---|---|
| EP (2) | EP1509589B1 (en) |
| JP (1) | JP2005534728A (en) |
| AT (1) | ATE381608T1 (en) |
| AU (1) | AU2003237704A1 (en) |
| DE (2) | DE10225116A1 (en) |
| ES (2) | ES2298919T3 (en) |
| WO (1) | WO2003104370A1 (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10334047A1 (en) * | 2003-07-25 | 2005-02-24 | Clariant Gmbh | Adsorbate from phyllosilicate and its use |
| US7241726B2 (en) | 2003-10-16 | 2007-07-10 | The Procter & Gamble Company | Complete-cycle methods for protecting glassware from surface corrosion in automatic dishwashing appliances |
| US7271138B2 (en) * | 2003-10-16 | 2007-09-18 | The Procter & Gamble Company | Compositions for protecting glassware from surface corrosion in automatic dishwashing appliances |
| US7094740B2 (en) | 2003-10-16 | 2006-08-22 | The Procter & Gamble Company | Zinc corrosion protection agents for treating glassware surfaces |
| US20050119154A1 (en) * | 2003-10-16 | 2005-06-02 | The Procter & Gamble Company | Methods for protecting glassware from surface corrosion in automatic dishwashing appliances |
| US7101833B2 (en) | 2004-10-12 | 2006-09-05 | The Procter & Gamble Company | Methods for treating glassware surfaces using zinc corrosion protection agents |
| DE102005025332A1 (en) * | 2005-05-31 | 2006-12-07 | Henkel Kgaa | surfactant compound |
| DE102008017796A1 (en) * | 2008-04-08 | 2009-10-15 | Süd-Chemie AG | Phyllosilicate odor adsorbers based on zinc ricinoleates and related compounds |
| DE102008020275A1 (en) | 2008-04-22 | 2009-10-29 | Henkel Ag & Co. Kgaa | Cleaning agent shaped body from pressed particulate material, useful e.g. for cleaning utensils in a household dishwasher, comprises zinc-containing cogranulate comprising zinc compounds and carrier material from group of builders |
| DE102008020274A1 (en) | 2008-04-22 | 2009-10-29 | Henkel Ag & Co. Kgaa | Preparing a cleaning agent tablet, useful for cleaning or washing e.g. moldings, comprises compressing a particulate premix containing zinc-containing granulates and other ingredients |
| EP2216393B1 (en) * | 2009-02-09 | 2024-04-24 | The Procter & Gamble Company | Detergent composition |
| DE102011077865A1 (en) * | 2011-06-21 | 2012-12-27 | Henkel Ag & Co. Kgaa | Dishwashing detergent with improved decor protection |
| MX2014002014A (en) | 2011-10-19 | 2014-03-27 | Basf Se | Formulations, use thereof as or to produce dishwashing detergents, and production thereof. |
| ES2672303T3 (en) | 2013-04-02 | 2018-06-13 | Basf Se | Formulations, their use as a dishwashing agent and their production |
| JP5801941B1 (en) * | 2014-11-21 | 2015-10-28 | 株式会社ニイタカ | Cleaning composition, dishwashing method, liquid cleaning composition kit and cartridge cleaning |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3255117A (en) * | 1963-10-08 | 1966-06-07 | Fmc Corp | Low-foaming dishwashing composition |
| DE2539531A1 (en) * | 1975-09-05 | 1977-03-17 | Henkel & Cie Gmbh | Dishwashing compsn. - contains a divalent or trivalent cation additive to reduce corrosion |
| US4670617A (en) * | 1985-12-30 | 1987-06-02 | Amoco Corporation | Propylation of toluene with a high surface area, zinc-modified, crystalline silica molecular sieve |
| US4933101A (en) * | 1989-02-13 | 1990-06-12 | The Procter & Gamble Company | Liquid automatic dishwashing compositions compounds providing glassware protection |
| US4917812A (en) * | 1989-02-13 | 1990-04-17 | The Procter & Gamble Company | Granular automatic dishwasher detergent composition providing glassware protection containing insoluble zinc compound |
| US6391839B1 (en) * | 1992-08-01 | 2002-05-21 | The Procter & Gamble Company | Detergent bleach compositions containing layered silicate builder and percarbonate stabilized by EDDS |
| DE4437486A1 (en) | 1994-10-20 | 1996-04-25 | Henkel Kgaa | Crystalline layered silicates in automatic dishwashing detergents |
| CA2177317A1 (en) * | 1995-05-25 | 1996-11-26 | Tsuneo Asai | Iodo-complex and its use |
| DE19819187A1 (en) * | 1998-04-30 | 1999-11-11 | Henkel Kgaa | Solid dishwasher detergent with phosphate and crystalline layered silicates |
| DE19943470A1 (en) * | 1999-09-11 | 2001-03-15 | Clariant Gmbh | Crystalline alkali layer silicate |
| DE10039100A1 (en) * | 2000-08-07 | 2002-02-28 | Henkel Kgaa | Deodorant textile treatment agent |
| DE10140535B4 (en) * | 2001-08-17 | 2006-05-04 | Henkel Kgaa | Machine dishwashing detergent with improved glass corrosion protection |
| EP1417291B1 (en) * | 2001-08-17 | 2010-04-07 | Henkel AG & Co. KGaA | Dishwasher detergent with improved protection against glass corrosion n |
-
2002
- 2002-06-06 DE DE10225116A patent/DE10225116A1/en not_active Ceased
-
2003
- 2003-05-28 AU AU2003237704A patent/AU2003237704A1/en not_active Abandoned
- 2003-05-28 EP EP03735481.8A patent/EP1509589B1/en not_active Expired - Lifetime
- 2003-05-28 DE DE50308871T patent/DE50308871D1/en not_active Expired - Lifetime
- 2003-05-28 JP JP2004511431A patent/JP2005534728A/en active Pending
- 2003-05-28 ES ES05027033T patent/ES2298919T3/en not_active Expired - Lifetime
- 2003-05-28 WO PCT/EP2003/005602 patent/WO2003104370A1/en not_active Ceased
- 2003-05-28 EP EP05027033A patent/EP1657295B1/en not_active Expired - Lifetime
- 2003-05-28 AT AT05027033T patent/ATE381608T1/en not_active IP Right Cessation
- 2003-05-28 ES ES03735481.8T patent/ES2527542T3/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ATE381608T1 (en) | 2008-01-15 |
| DE10225116A1 (en) | 2003-12-24 |
| EP1657295B1 (en) | 2007-12-19 |
| EP1657295A1 (en) | 2006-05-17 |
| ES2298919T3 (en) | 2008-05-16 |
| JP2005534728A (en) | 2005-11-17 |
| DE50308871D1 (en) | 2008-01-31 |
| EP1509589B1 (en) | 2014-10-22 |
| WO2003104370A1 (en) | 2003-12-18 |
| EP1509589A1 (en) | 2005-03-02 |
| AU2003237704A1 (en) | 2003-12-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2527542T3 (en) | Agent for machine washing of dishes with improved protection against glass corrosion | |
| ATE489945T1 (en) | ACRYLIC COMPOSITIONS FOR ENTERIC COATING | |
| ES2886644T3 (en) | water soluble packaging film | |
| ES2610481T3 (en) | Recreational Water Treatment | |
| NO2021008I1 (en) | fedratinib or a pharmaceutically acceptable salt thereof | |
| ES2663788T3 (en) | Sulfoximin-substituted quinazolines and their use as inhibitors of MNK1 and / or MNK2 kinases | |
| ES2635262T3 (en) | Sulfoximin substituted quinazolines for pharmaceutical compositions | |
| ES2555149T3 (en) | Composition for use in a dishwasher | |
| CN109153640A (en) | Hepatitis type B virus is eliminated with antivirotic | |
| CA2502219A1 (en) | A process for producing an amorphous isomer of lansoprazole | |
| KR20140114391A (en) | Alpha-amino boronic acid derivatives, selective immunoproteasome inhibitors | |
| PT87329A (en) | PROCESS FOR PREPARING A STABILIZED HYDROGEN PEROXIDE SOLUTION FOR DISINFECTING CONTACT LENS | |
| ES2363132T3 (en) | IMPROVEMENTS IN, OR RELATED TO, RECIPIENTS. | |
| ES2238941T1 (en) | ZOLPIDEM HEMITARTRATE SOLVATE. | |
| ES2959269T3 (en) | Plasticizer blend for chlorine stability of water-soluble films | |
| ES2324612T3 (en) | DETERGENT OR CLEANING PRODUCT. | |
| RU2006118689A (en) | CONTAINING PHARMACEUTICAL AGENT COMPOSITION COATED | |
| RU2000101021A (en) | Tramadol-containing compositions of prolonged action, capable of preserving during storage the specified characteristics of the release of the active substance, and the method of their manufacture | |
| EP0009008A3 (en) | Cephalosporin derivatives, process for their preparation and pharmaceutical compositions containing them | |
| ES2795061T3 (en) | Using polyvinyl alcohol with a low content of sodium acetate in a 3D printing procedure | |
| IE35964L (en) | Cephalosporin complexes | |
| ES2250405T3 (en) | COMPOSITIONS FOR MECHANICAL WASHING OF OBJECTS, CONTAINING INHIBITION POLYMERS OF INCRUSTATION. | |
| RU2008130892A (en) | SOLID MEDICINE WITH CONTROLLED RELEASE | |
| US3852213A (en) | Chelating compositions and detergent compositions pertaining to same | |
| US10047329B2 (en) | Water dispersible films for packaging high water containing formulations |