ES2550223T3 - Combinaciones de imazalil y compuestos de plata - Google Patents
Combinaciones de imazalil y compuestos de plata Download PDFInfo
- Publication number
- ES2550223T3 ES2550223T3 ES07712453.5T ES07712453T ES2550223T3 ES 2550223 T3 ES2550223 T3 ES 2550223T3 ES 07712453 T ES07712453 T ES 07712453T ES 2550223 T3 ES2550223 T3 ES 2550223T3
- Authority
- ES
- Spain
- Prior art keywords
- silver
- component
- imazalil
- combinations
- silver compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000005795 Imazalil Substances 0.000 title abstract description 3
- 229960002125 enilconazole Drugs 0.000 title abstract description 3
- PZBPKYOVPCNPJY-UHFFFAOYSA-N 1-[2-(allyloxy)-2-(2,4-dichlorophenyl)ethyl]imidazole Chemical compound ClC1=CC(Cl)=CC=C1C(OCC=C)CN1C=NC=C1 PZBPKYOVPCNPJY-UHFFFAOYSA-N 0.000 title abstract 2
- 229940100890 silver compound Drugs 0.000 title abstract 2
- 150000003379 silver compounds Chemical class 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 abstract description 3
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 abstract description 3
- RBWNDBNSJFCLBZ-UHFFFAOYSA-N 7-methyl-5,6,7,8-tetrahydro-3h-[1]benzothiolo[2,3-d]pyrimidine-4-thione Chemical compound N1=CNC(=S)C2=C1SC1=C2CCC(C)C1 RBWNDBNSJFCLBZ-UHFFFAOYSA-N 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- 229910001961 silver nitrate Inorganic materials 0.000 abstract description 2
- JPVQDTASRDGMII-UHFFFAOYSA-N 2-[1-(carboxymethyl)cyclohexyl]acetic acid;silver Chemical compound [Ag].OC(=O)CC1(CC(O)=O)CCCCC1 JPVQDTASRDGMII-UHFFFAOYSA-N 0.000 abstract 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 abstract 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 1
- 229910021607 Silver chloride Inorganic materials 0.000 abstract 1
- 229940072056 alginate Drugs 0.000 abstract 1
- 235000010443 alginic acid Nutrition 0.000 abstract 1
- 229920000615 alginic acid Polymers 0.000 abstract 1
- 230000003115 biocidal effect Effects 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 abstract 1
- 229940071536 silver acetate Drugs 0.000 abstract 1
- QBFXQJXHEPIJKW-UHFFFAOYSA-N silver azide Chemical compound [Ag+].[N-]=[N+]=[N-] QBFXQJXHEPIJKW-UHFFFAOYSA-N 0.000 abstract 1
- 229940071575 silver citrate Drugs 0.000 abstract 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 abstract 1
- 229960003600 silver sulfadiazine Drugs 0.000 abstract 1
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 abstract 1
- 229910000367 silver sulfate Inorganic materials 0.000 abstract 1
- RHUVFRWZKMEWNS-UHFFFAOYSA-M silver thiocyanate Chemical compound [Ag+].[S-]C#N RHUVFRWZKMEWNS-UHFFFAOYSA-M 0.000 abstract 1
- UEJSSZHHYBHCEL-UHFFFAOYSA-N silver(1+) sulfadiazinate Chemical compound [Ag+].C1=CC(N)=CC=C1S(=O)(=O)[N-]C1=NC=CC=N1 UEJSSZHHYBHCEL-UHFFFAOYSA-N 0.000 abstract 1
- LMEWRZSPCQHBOB-UHFFFAOYSA-M silver;2-hydroxypropanoate Chemical compound [Ag+].CC(O)C([O-])=O LMEWRZSPCQHBOB-UHFFFAOYSA-M 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- QUTYHQJYVDNJJA-UHFFFAOYSA-K trisilver;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Ag+].[Ag+].[Ag+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QUTYHQJYVDNJJA-UHFFFAOYSA-K 0.000 abstract 1
- 229910000166 zirconium phosphate Inorganic materials 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 150000003904 phospholipids Chemical class 0.000 description 4
- -1 phosphoric acid ester salts Chemical class 0.000 description 4
- IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Chemical compound CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 229920001817 Agar Polymers 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 235000010419 agar Nutrition 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VPGSXIKVUASQIY-UHFFFAOYSA-N 1,2-dibutylnaphthalene Chemical class C1=CC=CC2=C(CCCC)C(CCCC)=CC=C21 VPGSXIKVUASQIY-UHFFFAOYSA-N 0.000 description 1
- KILNVBDSWZSGLL-KXQOOQHDSA-N 1,2-dihexadecanoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCCCCCCCCCC KILNVBDSWZSGLL-KXQOOQHDSA-N 0.000 description 1
- TZCPCKNHXULUIY-RGULYWFUSA-N 1,2-distearoyl-sn-glycero-3-phosphoserine Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@H](COP(O)(=O)OC[C@H](N)C(O)=O)OC(=O)CCCCCCCCCCCCCCCCC TZCPCKNHXULUIY-RGULYWFUSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical group CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 description 1
- CFWRDBDJAOHXSH-SECBINFHSA-N 2-azaniumylethyl [(2r)-2,3-diacetyloxypropyl] phosphate Chemical compound CC(=O)OC[C@@H](OC(C)=O)COP(O)(=O)OCCN CFWRDBDJAOHXSH-SECBINFHSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical class CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical class CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 241000206672 Gelidium Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- JZNWSCPGTDBMEW-UHFFFAOYSA-N Glycerophosphorylethanolamin Natural products NCCOP(O)(=O)OCC(O)CO JZNWSCPGTDBMEW-UHFFFAOYSA-N 0.000 description 1
- ZWZWYGMENQVNFU-UHFFFAOYSA-N Glycerophosphorylserin Natural products OC(=O)C(N)COP(O)(=O)OCC(O)CO ZWZWYGMENQVNFU-UHFFFAOYSA-N 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 239000004147 Sorbitan trioleate Substances 0.000 description 1
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- ATBOMIWRCZXYSZ-XZBBILGWSA-N [1-[2,3-dihydroxypropoxy(hydroxy)phosphoryl]oxy-3-hexadecanoyloxypropan-2-yl] (9e,12e)-octadeca-9,12-dienoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(COP(O)(=O)OCC(O)CO)OC(=O)CCCCCCC\C=C\C\C=C\CCCCC ATBOMIWRCZXYSZ-XZBBILGWSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- AWUCVROLDVIAJX-UHFFFAOYSA-N alpha-glycerophosphate Natural products OCC(O)COP(O)(O)=O AWUCVROLDVIAJX-UHFFFAOYSA-N 0.000 description 1
- 125000003785 benzimidazolyl group Chemical class N1=C(NC2=C1C=CC=C2)* 0.000 description 1
- 210000005013 brain tissue Anatomy 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000008121 dextrose Substances 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical group OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 235000013345 egg yolk Nutrition 0.000 description 1
- 210000002969 egg yolk Anatomy 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 210000005003 heart tissue Anatomy 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 210000005228 liver tissue Anatomy 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- UYDLBVPAAFVANX-UHFFFAOYSA-N octylphenoxy polyethoxyethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCOCCO)C=C1 UYDLBVPAAFVANX-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- WTJKGGKOPKCXLL-RRHRGVEJSA-N phosphatidylcholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCCC=CCCCCCCCC WTJKGGKOPKCXLL-RRHRGVEJSA-N 0.000 description 1
- 150000008104 phosphatidylethanolamines Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Cosmetics (AREA)
- Medicinal Preparation (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Una composición que comprende una combinación de imazalil o una sal del mismo, como componente (I), y como componente (II) un compuesto de plata seleccionado de acetato de plata, alginato de plata, azida de plata, citrato de plata, lactato de plata, nitrato de plata, perclorato de plata, sulfato de plata, cloruro de plata, tiocianato de plata, plata-sodio-hidrógeno-fosfato de zirconio, sulfadiazina de plata, plata-ácido ciclohexanodiacético y diplata-2,5- dicloro-3,6-dihidroxi-2,5-ciclohexadieno-1,4-diona; en donde la relación ponderal de componente (I) a componente (II) oscila entre 4:1 y 1:4, para proporcionar un efecto biocida sinérgico.
Description
E07712453
15-10-2015
sulfato de dodecilo o de una mezcla de sulfatos de alcoholes grasos obtenidos a partir de ácidos grasos naturales. Estos compuestos también comprenden las sales de ésteres de ácido sulfúrico y ácidos sulfónicos de aductos de alcohol/óxido de etileno grasos. Los derivados de bencimidazol sulfonados contienen preferiblemente 2 grupos ácido sulfónico y un radical ácido graso que contiene 8 a 22 átomos de carbono. Ejemplos de alquilarilsulfonatos son las sales de sodio, calcio o trietanolamina de ácido dodecilbencenosulfónico, ácido dibutilnaftaleno-sulfónico o de un producto de condensación de ácido naftalenosulfónico/formaldehído. También son adecuados los correspondientes fosfatos, p. ej., sales del éster de ácido fosfórico de un aducto de p-nonilfenol con 4 a 14 moles de óxido de etileno, o fosfolípidos.
Los tensioactivos no iónicos son preferiblemente derivados de poliglicol-éter de alcoholes alifáticos o cicloalifáticos, o ácidos grasos y alquilfenoles saturados o insaturados, conteniendo dichos derivados de 3 a 10 grupos glicol-éter y de 8 a 20 átomos de carbono en el resto hidrocarbonado (alifático) y de 6 a 18 átomos de carbono en el resto alquilo de los alquilfenoles.
Tensioactivos no iónicos adecuados adicionales son los aductos solubles en agua de poli(óxido de etileno) con polipropilenglicol, etilendiamino-polipropilenglicol que contiene 1 a 10 átomos de carbono en la cadena alquilo, aductos que contienen 20 a 250 grupos etilenglicol-éter y 10 a 100 grupos propilenglicol-éter. Estos compuestos normalmente contienen 1 a 5 unidades de etilenglicol por unidad de propilenglicol.
Ejemplos representativos de tensioactivos no iónicos son nonilfenolpolietoxi-etanoles, poliglicoléteres de aceite de ricino, aductos de óxido de polipropileno/polietileno, tributilfenoxipolietoxietanol, polietilenglicol y octilfenoxipolietoxietanol. Ésteres de ácidos grasos de polietilensorbitán tales como trioleato de polioxietilensorbitán, son también tensioactivos no iónicos adecuados.
Aditivos particularmente ventajosos, útiles para mejorar la aplicación y reducir la dosis de los ingredientes activos, son los fosfolípidos naturales (animales o vegetales) o sintéticos del tipo de cefalina o de lecitina tales como, por ejemplo, fosfatidiletanolamina, fosfatidilserina, fosfatidilglicerol, lisolecitina o cardiolipina. Fosfolípidos de este tipo pueden obtenerse a partir de células animales o vegetales, en particular de tejido encefálico, de corazón o de hígado, yemas de huevo o habas de soja. Fosfolípidos apropiados de este tipo son, por ejemplo, mezclas de fosfatidilcolina. Fosfolípidos sintéticos son, por ejemplo, dioctanilfosfatidilcolina y dipalmitoilfosfatidilcolina.
Parte experimental
Experimento 1: Ensayo de placas de veneno Nombre del compuesto principal: -imazalil (I)
Nombre de la sal de plata: -nitrato de plata o perclorato de plata
Disolución patrón: 1000 ppm en DMSO
Combinaciones de ensayo: % producto A + % producto B
80+ 20
66+ 33
50+ 50
33+ 66
20+ 80
Concentraciones de ingrediente activo total en las combinaciones: una primera serie de concentraciones crecientes con pasos de 1/3: 2,11-2,82 -3,75 -5,01 -6,67 -8,90 -11,87 15,82 -21,09 -28,13 -37,50 -50,00 ppm una segunda serie de concentraciones con pasos de 1/3: 21,12 -28,16 -37,54 -50,06 -66,74 -88,99 -118,65 158,20 -210,94 -281,25 -375,00 -500,00 ppm
Medio de cultivo: Bacterias: Agar Triptosa (TA): 20 g de bacto triptosa, 5 g de
cloruro de sodio, 1 g de bacto dextrosa y 15 g de bacto agar en
1 litro de agua desionizada
8
Claims (1)
-
imagen1 imagen2
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06110745 | 2006-03-07 | ||
| EP06110745 | 2006-03-07 | ||
| PCT/EP2007/052081 WO2007101848A1 (en) | 2006-03-07 | 2007-03-06 | Combinations of imazalil and silver compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2550223T3 true ES2550223T3 (es) | 2015-11-05 |
Family
ID=36218342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES07712453.5T Active ES2550223T3 (es) | 2006-03-07 | 2007-03-06 | Combinaciones de imazalil y compuestos de plata |
Country Status (14)
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|---|---|
| US (1) | US9000017B2 (es) |
| EP (1) | EP1993361B1 (es) |
| JP (1) | JP5199891B2 (es) |
| KR (1) | KR20080099266A (es) |
| CN (1) | CN101394741B (es) |
| AU (1) | AU2007222361B2 (es) |
| BR (1) | BRPI0708577A2 (es) |
| CA (1) | CA2640426A1 (es) |
| ES (1) | ES2550223T3 (es) |
| NO (1) | NO20083632L (es) |
| PL (1) | PL1993361T3 (es) |
| PT (1) | PT1993361E (es) |
| RU (1) | RU2434382C2 (es) |
| WO (1) | WO2007101848A1 (es) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| EP1856977A3 (en) | 2004-02-04 | 2008-02-13 | Janssen Pharmaceutica N.V. | Synergistic antifungal DDAC compostions |
| US9511040B2 (en) | 2007-06-20 | 2016-12-06 | The Trustees Of Columbia University In The City Of New York | Skin and surface disinfectant compositions containing botanicals |
| US9687429B2 (en) | 2007-06-20 | 2017-06-27 | The Trustees Of Columbia University In The City Of New York | Antimicrobial compositions containing low concentrations of botanicals |
| US9981069B2 (en) | 2007-06-20 | 2018-05-29 | The Trustees Of Columbia University In The City Of New York | Bio-film resistant surfaces |
| EP2166840B1 (en) | 2007-06-20 | 2017-01-11 | The Trustees of Columbia University in the City of New York | Bio-film resistant surfaces |
| MX2009002351A (es) | 2008-03-07 | 2009-09-25 | Plant Protectants Llc | Metodos para proteger cultivos de la descomposicion microbiana de post cosecha. |
| WO2009114116A2 (en) * | 2008-03-11 | 2009-09-17 | Gowan Co. | Plant treatment compositions and methods for their use |
| BRPI0802626A2 (pt) * | 2008-06-06 | 2011-08-30 | Pure Bioscience | aplicações agrìcolas de di-hidrogênio citrato de prata |
| US9675080B2 (en) | 2009-03-20 | 2017-06-13 | Verdesian Life Sciences U.S., Llc | Methods for delaying maturity of crops |
| US20140086970A1 (en) * | 2011-03-24 | 2014-03-27 | Silver Anti-Bac, Llc | Silver chloride compositions for deodorization and disinfection |
| CN102310452A (zh) * | 2011-09-01 | 2012-01-11 | 徐忠杰 | 一种烟草秸秆人造板及其制备方法 |
| US9968101B2 (en) | 2011-11-03 | 2018-05-15 | The Trustees Of Columbia University In The City Of New York | Botanical antimicrobial compositions |
| EP2773334B1 (en) | 2011-11-03 | 2019-08-28 | The Trustees of Columbia University in the City of New York | Composition with sustained antimicrobial activity |
| TW201330856A (zh) | 2011-12-06 | 2013-08-01 | Univ Columbia | 廣效性的天然防腐組成物 |
| CN103046313A (zh) * | 2012-12-25 | 2013-04-17 | 苏州铭晋纺织有限公司 | 一种布料整理液 |
| RU2588984C2 (ru) * | 2014-07-04 | 2016-07-10 | Михаил Вячеславович Новиков | Способ выделки меховых шкурок |
| CN104441123A (zh) * | 2014-09-25 | 2015-03-25 | 阜南县永兴工艺品有限公司 | 一种柳编用藤条的处理方法 |
| CN104400857B (zh) * | 2014-10-29 | 2016-02-10 | 阜南县宏泰工艺品有限公司 | 一种柳编用柳枝的处理工艺 |
| CN105666614A (zh) * | 2016-01-22 | 2016-06-15 | 蚌埠海上明珠农业科技发展有限公司 | 一种用于活体藤条防裂护色药液的制备方法 |
| CN106003332A (zh) * | 2016-05-23 | 2016-10-12 | 阜南县方柳工艺品有限公司 | 一种蔺草草席成型用表面增润浸泡液 |
| CN106078982A (zh) * | 2016-06-03 | 2016-11-09 | 阜南县黄岗利达工艺品有限公司 | 一种蒯草保色浸泡处理液 |
| CN106078995A (zh) * | 2016-06-03 | 2016-11-09 | 阜南县黄岗利达工艺品有限公司 | 一种柳编制品用柽柳枝的干燥处理工艺 |
| CN106182275A (zh) * | 2016-07-28 | 2016-12-07 | 安徽信达家居有限公司 | 一种橡胶木板材防霉防变色的处理方法 |
| CN106239665A (zh) * | 2016-08-28 | 2016-12-21 | 桐乡市美意家具有限公司 | 一种木制家具的驱蚊驱虫处理方法 |
| CN106217548A (zh) * | 2016-08-28 | 2016-12-14 | 桐乡市美意家具有限公司 | 一种木材的表面孔径填补工艺 |
| CN106272776A (zh) * | 2016-08-28 | 2017-01-04 | 桐乡市美意家具有限公司 | 一种保健木材的加工处理方法 |
| CN106346577A (zh) * | 2016-08-31 | 2017-01-25 | 安徽阜南县万家和工艺品有限公司 | 一种便于玉米秸秆编织品染色的处理剂 |
| CN107160508B (zh) * | 2017-06-06 | 2019-07-02 | 东阳市天齐科技有限公司 | 一种针对碱性木材的霉菌消除剂 |
| CN108659597A (zh) * | 2018-04-04 | 2018-10-16 | 福建皓尔宝新材料科技有限公司 | 一种用于净化空气内墙涂料的霉菌抑制组合物及其制备方法 |
| CN108582352A (zh) * | 2018-05-23 | 2018-09-28 | 安徽省高雅家居有限公司 | 一种用于木材的杀菌防腐处理剂 |
| CN108714948A (zh) * | 2018-06-06 | 2018-10-30 | 阜南县柳祥工艺品有限公司 | 一种提升藤条防蛀性能的方法 |
| US11186493B2 (en) | 2019-09-05 | 2021-11-30 | Imam Abdulrahman Bin Faisal University | Green synthesis of noble metal/transition metal oxide nanocomposite |
| CN111109294A (zh) * | 2020-01-16 | 2020-05-08 | 陕西麦可罗生物科技有限公司 | 一种纳米银水分散粒剂及其制备方法和应用 |
| GB2596076B (en) * | 2020-06-15 | 2024-09-18 | Louver Lite Ltd | Coating composition |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
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| EP0336489B1 (en) * | 1988-04-08 | 1995-08-23 | Janssen Pharmaceutica N.V. | Imazalil containing synergistic compositions |
| WO1995007913A1 (en) * | 1993-09-17 | 1995-03-23 | Meiji Milk Products Co., Ltd. | Antibacterial and antifungal agent |
| GB9602623D0 (en) * | 1996-02-09 | 1996-04-10 | Zeneca Ltd | Fungicides |
| US6482839B1 (en) * | 1997-06-02 | 2002-11-19 | Cellegy Pharmaceuticals, Inc. | Pyridine-thiols for treatment of a follicular dermatosis |
| UA62978C2 (en) * | 1997-09-08 | 2004-01-15 | Janssen Pharmaceutica Nv | Synergistic compositions comprising imazalil and epoxiconazole |
| WO2003011029A1 (en) * | 2001-07-30 | 2003-02-13 | Ishihara Sangyo Kaisha, Ltd. | Composition for controlling plant pathogenic bacterium and method of controlling plant pathogenic bacterium |
| US20030096545A1 (en) * | 2001-11-21 | 2003-05-22 | Payne Stephen A. | Antimicrobial, sporicidal composition and treated products thereof |
| US8747908B2 (en) * | 2003-04-09 | 2014-06-10 | Osmose, Inc. | Micronized wood preservative formulations |
| US20050112339A1 (en) * | 2003-11-26 | 2005-05-26 | Sandel Bonnie B. | Antimicrobial protection for plastic structures |
| JP2005170976A (ja) * | 2003-12-08 | 2005-06-30 | Shinto Paint Co Ltd | 印刷ワニス組成物 |
| JP2005255792A (ja) * | 2004-03-10 | 2005-09-22 | Shinto Paint Co Ltd | 塗料組成物 |
| KR101105182B1 (ko) | 2004-07-13 | 2012-01-12 | 이데미쓰 테크노파인 가부시키가이샤 | 항균성 조성물, 항균성 성형체, 항균성 조성물 함유 용액, 세정제, 다다미 표면 및 다다미 |
| US20060086283A1 (en) * | 2004-10-21 | 2006-04-27 | Premier Wood Treating, L.L.C. | Water repellent cellulose preservative |
| US20060276468A1 (en) * | 2005-05-12 | 2006-12-07 | Blow Derek P | Wood preservative formulations comprising Imazalil |
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- 2007-03-06 US US12/281,874 patent/US9000017B2/en active Active
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- 2007-03-06 WO PCT/EP2007/052081 patent/WO2007101848A1/en not_active Ceased
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- 2007-03-06 BR BRPI0708577-0A patent/BRPI0708577A2/pt not_active IP Right Cessation
- 2007-03-06 EP EP07712453.5A patent/EP1993361B1/en active Active
- 2007-03-06 JP JP2008557745A patent/JP5199891B2/ja active Active
- 2007-03-06 CA CA002640426A patent/CA2640426A1/en not_active Abandoned
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Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0708577A2 (pt) | 2011-05-31 |
| EP1993361A1 (en) | 2008-11-26 |
| CA2640426A1 (en) | 2007-09-13 |
| PT1993361E (pt) | 2015-11-02 |
| PL1993361T3 (pl) | 2015-12-31 |
| AU2007222361A1 (en) | 2007-09-13 |
| EP1993361B1 (en) | 2015-07-22 |
| JP5199891B2 (ja) | 2013-05-15 |
| WO2007101848A1 (en) | 2007-09-13 |
| CN101394741A (zh) | 2009-03-25 |
| AU2007222361B2 (en) | 2011-12-22 |
| US9000017B2 (en) | 2015-04-07 |
| KR20080099266A (ko) | 2008-11-12 |
| JP2009534296A (ja) | 2009-09-24 |
| RU2008139617A (ru) | 2010-04-20 |
| US20090061021A1 (en) | 2009-03-05 |
| CN101394741B (zh) | 2012-05-23 |
| NO20083632L (no) | 2008-08-25 |
| RU2434382C2 (ru) | 2011-11-27 |
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