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ES2401294R1 - DISPOSITIVO Y PROCEDIMIENTO PARA LA CAPTURA DE CO2 POR CARBONATACION DE CaO - Google Patents

DISPOSITIVO Y PROCEDIMIENTO PARA LA CAPTURA DE CO2 POR CARBONATACION DE CaO

Info

Publication number
ES2401294R1
ES2401294R1 ES201131062A ES201131062A ES2401294R1 ES 2401294 R1 ES2401294 R1 ES 2401294R1 ES 201131062 A ES201131062 A ES 201131062A ES 201131062 A ES201131062 A ES 201131062A ES 2401294 R1 ES2401294 R1 ES 2401294R1
Authority
ES
Spain
Prior art keywords
capture
carbonation
cao
solids
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES201131062A
Other languages
English (en)
Other versions
ES2401294B1 (es
ES2401294A2 (es
Inventor
Garcia Juan Carlos Abanades
Rozada Borja Arias
Adiego Gemma Grasa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hulleras Del Norte S A
Consejo Superior de Investigaciones Cientificas CSIC
Endesa Generacion SA
Original Assignee
Hulleras Del Norte S A
Consejo Superior de Investigaciones Cientificas CSIC
Endesa Generacion SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to ES201131062A priority Critical patent/ES2401294B1/es
Application filed by Hulleras Del Norte S A, Consejo Superior de Investigaciones Cientificas CSIC, Endesa Generacion SA filed Critical Hulleras Del Norte S A
Priority to CA2837796A priority patent/CA2837796A1/en
Priority to EP12738146.5A priority patent/EP2724771B1/en
Priority to PCT/ES2012/070426 priority patent/WO2013021082A1/es
Priority to CN201280027643.4A priority patent/CN104168983A/zh
Priority to AU2012293563A priority patent/AU2012293563A1/en
Priority to US14/117,471 priority patent/US20140186247A1/en
Publication of ES2401294A2 publication Critical patent/ES2401294A2/es
Publication of ES2401294R1 publication Critical patent/ES2401294R1/es
Application granted granted Critical
Publication of ES2401294B1 publication Critical patent/ES2401294B1/es
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81—Solid phase processes
    • B01D53/83—Solid phase processes with moving reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/602—Oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/606—Carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
    • B01D2253/1124—Metal oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/12—Methods and means for introducing reactants
    • B01D2259/128—Solid reactants
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Gas Separation By Absorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

Dispositivo y procedimiento para la captura de CO2 por carbonatación de CaO. La presente invención se encuadra dentro del campo de obtención de energía a partir combustibles carbonosos con captura de dióxido de carbono para su uso o almacenamiento permanente y en concreto se refiere a dispositivos y procedimientos que hacen posible la captura mejorada de CO2 mediante CaO en procesos de calcinación-carbonatación debido al uso de un recarbonatador donde se pone en contacto a los sólidos parcialmente carbonatados provenientes del carbonatador con CO2 altamente concentrado; de modo que la fracción de carbonato en los sólidos aumente ligeramente por encima de la capacidad de captura efectiva de CO2 en el carbonatador y dicho aumento compense la pérdida de capacidad de captura de CO2 que experimentan dichos sólidos en el siguiente ciclo de calcinación-carbonatación, frenando así el proceso de desactivación en un valor de capacidad de captura de CO2 del sorbente más alto.
ES201131062A 2011-06-24 2011-06-24 DISPOSITIVO Y PROCEDIMIENTO PARA LA CAPTURA DE CO2 POR CARBONATACION DE CaO Expired - Fee Related ES2401294B1 (es)

Priority Applications (7)

Application Number Priority Date Filing Date Title
ES201131062A ES2401294B1 (es) 2011-06-24 2011-06-24 DISPOSITIVO Y PROCEDIMIENTO PARA LA CAPTURA DE CO2 POR CARBONATACION DE CaO
EP12738146.5A EP2724771B1 (en) 2011-06-24 2012-06-07 Device and method for the capture of co2 by cao carbonation and for maintaining sorbent activity
PCT/ES2012/070426 WO2013021082A1 (es) 2011-06-24 2012-06-07 Device and method for the capture of c02 by cao carbonation and for maintaining sorbent activity
CN201280027643.4A CN104168983A (zh) 2011-06-24 2012-06-07 用于通过CaO的碳酸化作用捕获CO2以及用于维持吸收剂活性的装置和方法
CA2837796A CA2837796A1 (en) 2011-06-24 2012-06-07 Device and method for the capture of c02 by cao carbonation and for maintaining sorbent activity
AU2012293563A AU2012293563A1 (en) 2011-06-24 2012-06-07 Device and method for the capture of CO2 by CaO carbonation and for maintaining sorbent activity
US14/117,471 US20140186247A1 (en) 2011-06-24 2012-06-07 Device and Method for the Capture of C02 by CAO Carbonation and for Maintaining Sorbent Activity

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES201131062A ES2401294B1 (es) 2011-06-24 2011-06-24 DISPOSITIVO Y PROCEDIMIENTO PARA LA CAPTURA DE CO2 POR CARBONATACION DE CaO

Publications (3)

Publication Number Publication Date
ES2401294A2 ES2401294A2 (es) 2013-04-18
ES2401294R1 true ES2401294R1 (es) 2013-07-11
ES2401294B1 ES2401294B1 (es) 2014-05-09

Family

ID=46551579

Family Applications (1)

Application Number Title Priority Date Filing Date
ES201131062A Expired - Fee Related ES2401294B1 (es) 2011-06-24 2011-06-24 DISPOSITIVO Y PROCEDIMIENTO PARA LA CAPTURA DE CO2 POR CARBONATACION DE CaO

Country Status (7)

Country Link
US (1) US20140186247A1 (es)
EP (1) EP2724771B1 (es)
CN (1) CN104168983A (es)
AU (1) AU2012293563A1 (es)
CA (1) CA2837796A1 (es)
ES (1) ES2401294B1 (es)
WO (1) WO2013021082A1 (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI516302B (zh) * 2013-12-11 2016-01-11 財團法人工業技術研究院 循環塔二氧化碳捕獲系統、碳酸化爐、煅燒爐及其使用方法
WO2018164589A1 (en) 2017-03-09 2018-09-13 Hot Lime Labs Improved method and apparatus for carbon dioxide capture and release
CN109507358B (zh) * 2018-11-14 2021-04-13 西安交通大学 一种二氧化碳气氛下碳酸盐高温煅烧反应特性的实验装置及测试方法
US11858819B2 (en) 2021-03-04 2024-01-02 Energy And Environmental Research Center Foundation Methods of producing a syngas composition
US11717802B2 (en) 2021-03-04 2023-08-08 Energy And Environmental Research Center Foundation Methods of treating metal carbonate salts
WO2024189240A2 (en) * 2024-07-01 2024-09-19 Sumitomo SHI FW Energia Oy An apparatus for capturing co 2 from gas containing co 2 and method of operating the same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2192994A1 (es) * 2002-03-22 2003-10-16 Consejo Superior Investigacion Procedimiento de combustion con separacion integrada de co2 mediante carbonatacion.
WO2005046862A1 (en) * 2003-11-14 2005-05-26 Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Natural Resources Reactivation of lime-based sorbents by co2 shocking
WO2007002882A2 (en) * 2005-06-28 2007-01-04 The Ohio State University Regeneration of calcium sulfide to mesoporous calcium carbonate using ionic dispersants and selective reclamation...

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4226839A (en) * 1978-07-21 1980-10-07 The United States Of America As Represented By The Administrator Of The U.S. Environmental Protection Agency Activation of calcium oxide as a sorbent
JP2710267B2 (ja) * 1994-07-12 1998-02-10 工業技術院長 二酸化炭素含有ガスからの二酸化炭素の分離装置と、二酸化炭素分離機能を有する燃焼装置
JP3248514B2 (ja) * 1998-10-29 2002-01-21 日本鋼管株式会社 排出炭酸ガスの削減方法
GB0625158D0 (en) * 2006-12-18 2007-01-24 Gormley Michael D Re-carbonating device
CN101249377B (zh) * 2008-04-03 2010-11-10 东南大学 钙基二氧化碳吸收剂的改性方法
EP2296786A4 (en) 2008-06-05 2012-09-19 Ind Res Ltd METHOD FOR SEPARATING GAS
WO2010059882A2 (en) * 2008-11-19 2010-05-27 The Ohio State University Research Foundation Carbonation calcination reaction process for co2 capture using a highly regenerable sorbent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2192994A1 (es) * 2002-03-22 2003-10-16 Consejo Superior Investigacion Procedimiento de combustion con separacion integrada de co2 mediante carbonatacion.
WO2005046862A1 (en) * 2003-11-14 2005-05-26 Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Natural Resources Reactivation of lime-based sorbents by co2 shocking
WO2007002882A2 (en) * 2005-06-28 2007-01-04 The Ohio State University Regeneration of calcium sulfide to mesoporous calcium carbonate using ionic dispersants and selective reclamation...

Also Published As

Publication number Publication date
AU2012293563A8 (en) 2014-03-20
ES2401294B1 (es) 2014-05-09
CA2837796A1 (en) 2013-02-14
ES2401294A2 (es) 2013-04-18
CN104168983A (zh) 2014-11-26
AU2012293563A1 (en) 2013-12-12
WO2013021082A1 (es) 2013-02-14
EP2724771B1 (en) 2015-09-09
EP2724771A1 (en) 2014-04-30
US20140186247A1 (en) 2014-07-03

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