ES2491367B1 - Diurethane compounds, manufacturing processes of watermarks by flexography and corresponding compositions and uses - Google Patents
Diurethane compounds, manufacturing processes of watermarks by flexography and corresponding compositions and uses Download PDFInfo
- Publication number
- ES2491367B1 ES2491367B1 ES201330304A ES201330304A ES2491367B1 ES 2491367 B1 ES2491367 B1 ES 2491367B1 ES 201330304 A ES201330304 A ES 201330304A ES 201330304 A ES201330304 A ES 201330304A ES 2491367 B1 ES2491367 B1 ES 2491367B1
- Authority
- ES
- Spain
- Prior art keywords
- flexography
- watermarks
- manufacturing processes
- compounds
- corresponding compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- 150000001875 compounds Chemical class 0.000 title abstract 5
- 238000007647 flexography Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 abstract 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 3
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 abstract 2
- 239000002202 Polyethylene glycol Substances 0.000 abstract 2
- 229920001223 polyethylene glycol Polymers 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 1
- 238000007639 printing Methods 0.000 abstract 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 abstract 1
- 235000013772 propylene glycol Nutrition 0.000 abstract 1
- -1 trimethylhexamethylene Chemical group 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
- C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C271/12—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/282—Alkanols, cycloalkanols or arylalkanols including terpenealcohols
- C08G18/2825—Alkanols, cycloalkanols or arylalkanols including terpenealcohols having at least 6 carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/10—Watermarks
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Printing Plates And Materials Therefor (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paper (AREA)
Abstract
Compuestos diuretanos, procedimientos de fabricación de marcas al agua por flexografía y composiciones y usos correspondientes. Compuesto de fórmula#**IMAGEN**#donde#R1 y R2 son, independientemente, 2-etilhexanol, polietilenglicol de peso molecular comprendido entre 200 y 600 ó monometiléter de polietilenglicol de peso molecular comprendido entre 400 y 700, y#X es trimetilhexametilen.#La composición comprende un compuesto de fórmula (I) y un solvente del grupo formado por propilencarbonato, 1,2-propanodiol, etilenglicol, dietilenglicol, dimetilsulfóxido (DMSO), agua y mezclas de los anteriores, donde el solvente está en una proporción inferior o igual al 40% en peso respecto del total de dicha composición. Estos compuestos y composiciones son particularmente adecuados para la realización de marcas al agua sobre materiales celulósicos mediante la técnica de imprenta denominada flexografía.Diurethane compounds, manufacturing processes of watermarks by flexography and corresponding compositions and uses. Compound of formula # ** PICTURE ** # where # R1 and R2 are, independently, 2-ethylhexanol, polyethylene glycol of molecular weight between 200 and 600 or polyethylene glycol monomethyl ether of molecular weight between 400 and 700, and # X is trimethylhexamethylene The composition comprises a compound of formula (I) and a solvent of the group consisting of propylene carbonate, 1,2-propanediol, ethylene glycol, diethylene glycol, dimethyl sulfoxide (DMSO), water and mixtures of the foregoing, where the solvent is in a proportion less than or equal to 40% by weight with respect to the total of said composition. These compounds and compositions are particularly suitable for making watermarks on cellulosic materials by means of the printing technique called flexography.
Description
Claims (1)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES201330304A ES2491367B1 (en) | 2013-03-04 | 2013-03-04 | Diurethane compounds, manufacturing processes of watermarks by flexography and corresponding compositions and uses |
| PCT/ES2014/070157 WO2014135728A1 (en) | 2013-03-04 | 2014-03-03 | Diurethane compounds, water mark production methods using flexography and corresponding compositions and uses |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES201330304A ES2491367B1 (en) | 2013-03-04 | 2013-03-04 | Diurethane compounds, manufacturing processes of watermarks by flexography and corresponding compositions and uses |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2491367A1 ES2491367A1 (en) | 2014-09-05 |
| ES2491367B1 true ES2491367B1 (en) | 2015-06-24 |
Family
ID=50434214
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES201330304A Expired - Fee Related ES2491367B1 (en) | 2013-03-04 | 2013-03-04 | Diurethane compounds, manufacturing processes of watermarks by flexography and corresponding compositions and uses |
Country Status (2)
| Country | Link |
|---|---|
| ES (1) | ES2491367B1 (en) |
| WO (1) | WO2014135728A1 (en) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6384130B1 (en) * | 1999-12-03 | 2002-05-07 | Bayer Corporation | Liquid, hydrophobic, non-migrating, non-functional polyurethane plasticizers |
| ES2265300B1 (en) | 2006-07-17 | 2008-02-01 | Antonio Oliva Gurgui | "DERIVATIVES OF POLYURETHANS AND CORRESPONDING USES AND PROCEDURES OF MANUFACTURE OF BRANDS TO WATER". |
| ES2294965B1 (en) | 2007-05-07 | 2009-04-16 | Antonio Oliva Gurgui | "DERIVATIVES OF URETANS AND OLIGOURETHANS AND CORRESPONDING USES AND PROCEDURES OF MANUFACTURING BRANDS TO WATER THROUGH THE OFFSET PRINTING TECHNIQUE". |
| ES2386179B1 (en) * | 2012-06-13 | 2013-05-08 | Antonio Oliva Gurgui | COMPOUNDS DERIVED FROM URETANS AND OLIGOURETHANS AND MANUFACTURING PROCEDURES OF BRANDS TO WATER THROUGH OFFSET PRINTING TECHNIQUE AND CORRESPONDING USES |
-
2013
- 2013-03-04 ES ES201330304A patent/ES2491367B1/en not_active Expired - Fee Related
-
2014
- 2014-03-03 WO PCT/ES2014/070157 patent/WO2014135728A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2014135728A1 (en) | 2014-09-12 |
| ES2491367A1 (en) | 2014-09-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
Ref document number: 2491367 Country of ref document: ES Kind code of ref document: B1 Effective date: 20150624 |
|
| PC2A | Transfer of patent |
Owner name: PURINTO MARK, S.L. Effective date: 20160504 |
|
| FD2A | Announcement of lapse in spain |
Effective date: 20230726 |