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ES2321049A1 - Atcc (sincloseno) granulated non-combining for improved storage and transportation and its manufacturing process (Machine-translation by Google Translate, not legally binding) - Google Patents

Atcc (sincloseno) granulated non-combining for improved storage and transportation and its manufacturing process (Machine-translation by Google Translate, not legally binding) Download PDF

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Publication number
ES2321049A1
ES2321049A1 ES200702666A ES200702666A ES2321049A1 ES 2321049 A1 ES2321049 A1 ES 2321049A1 ES 200702666 A ES200702666 A ES 200702666A ES 200702666 A ES200702666 A ES 200702666A ES 2321049 A1 ES2321049 A1 ES 2321049A1
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Prior art keywords
atcc
synclosen
boric acid
granulated
storage
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ES2321049B1 (en
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Jordi Junyent Llado
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Inquide SA
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Inquide SA
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Atcc (sinclosene) non-combustive granulate for improved storage and transportation and its manufacturing process. The atcc (sinclosin) powder mixed with at least one additive such as boric acid, forming a preparation, in which the boric acid acts as a lubricant to facilitate the compaction of the atcc (synclosin) in the form of chlorine tablets and as flame retardant of the atcc (synclosin), to which other substances such as sodium carbonate and sodium bicarbonate are added, which constitute a non-hazardous product for storage and rapid dissolution transport, such as dccna (troclosin). The atcc (sinclosin) is obtained in conventional form until the dryer exit in the form of powder and before being granulated, according to the manufacturing process is conducted to a mixing hopper in which boric acid is added, the mixture is mixed other substances are added such as carbonate and sodium bicarbonate. (Machine-translation by Google Translate, not legally binding)

Description

ATCC (sincloseno) granulado no comburente para su almacenaje y transporte mejorados y su proceso de fabricación.ATCC (synclosen) non-oxidized granulate for its improved storage and transportation and its process of manufacturing.

Objeto de la invenciónObject of the invention

La presente invención tiene por objeto ATCC (sincloseno) granulado no comburente para su almacenaje y transporte mejorados y su proceso de fabricación.The present invention aims at ATCC (synclosen) non-oxidized granulate for storage and Improved transportation and its manufacturing process.

Campo de la invenciónField of the Invention

La presente invención tiene por objeto unos productos especialmente destinados a la desinfección y acondicionamiento del agua de piscinas, spas y otros.The present invention aims at products specially intended for disinfection and water conditioning of swimming pools, spas and others.

Antecedentes de la invenciónBackground of the invention

Entre los productos utilizados se encuentra el ATCC, denominado químicamente sincloseno o ácido tricloroisocianurico, pero presenta unos inconvenientes.Among the products used is the ATCC, chemically called synclosen or acid trichloroisocyanuric, but has some drawbacks.

El ATCC (Sincloseno) es una sustancia que una vez fabricada y debido a sus características físico- químicas atendiendo a su peligrosidad es clasificada como comburente para ser almacenada y para ser transportada estando sujeta esta sustancia al cumplimiento de normativas APQ y ADR.ATCC (Sinclosen) is a substance that a once manufactured and due to its physicochemical characteristics attending to its danger is classified as oxidizing for be stored and to be transported while holding this Substance to compliance with APQ and ADR regulations.

Se entiende que una sustancia es comburente, cuando expuesta a un foco de calor de determinada intensidad se descompone propagándose esta descomposición de partícula a partícula en un tiempo determinado.It is understood that a substance is oxidizing, when exposed to a heat source of certain intensity it decomposes spreading this particle decomposition to particle in a certain time.

Hasta ahora, el ATCC (sincloseno) se utiliza en forma granulada después de salir del secadero en polvo, y pasar al sistema de granulado.Until now, ATCC (synclosen) is used in granulated form after leaving the powder dryer, and move on to granulate system

Se ha intentado añadir al ATCC en polvo alguna sustancia que elimine la característica comburente del ATCC (sincloseno) en polvo, para hacer más fácil su manipulación.An attempt has been made to add any powder to the ATCC substance that eliminates the oxidizing characteristic of ATCC (synclosen) powder, to make handling easier.

Así, si se consigue añadir otra sustancia (aditivo de características ignífugas) pasaría de ser una sustancia a ser un preparado (más de una sustancia) y si este aditivo se añadiera en la cantidad justa y se mezclara correctamente con el ATCC (sincloseno) en polvo se obtendría un preparado que podría ser granulado.So, if you can add another substance (flame retardant additive) would go from being a substance to be a preparation (more than one substance) and if this additive is add in the right amount and mix correctly with the ATCC (synclosen) powder would obtain a preparation that could be granulated.

Si este preparado se somete al ensayo de comburencia se obtendría como resultado el No Comburente para almacenaje y transporte.If this preparation is subjected to the test of Combustion would result in the Non-Oxidizer for storage and transportation

Si este aditivo además de esas características ignífugas tuviera también propiedades lubricantes se tendría un producto que se podría compactar sin más.If this additive in addition to those characteristics flame retardants also had lubricating properties would have a product that could be compacted without more.

Sumario de la invenciónSummary of the invention

Los inconvenientes del ATCC (sincloseno o ácido tricloroisocianúrico) en polvo han sido eliminados mediante la presente invención.The disadvantages of ATCC (synclosen or acid trichloroisocyanuric) powder have been removed by present invention

En esencia, el ATCC (sincloseno) granulado no comburente para su almacenaje y transporte mejorados, que comprende ATCC (sincloseno) en polvo procedente del secadero y antes de ser granulado, caracterizado porque comprende el ATCC (sincloseno) en polvo mezclado con al menos un aditivo tal como el ácido bórico, formando un preparado, en el que el ácido bórico actúa como lubricante para facilitar la compactación y como ignífugo del ATCC (sincloseno), que constituyen un producto no peligroso para almacenaje y transporte, de disolución rápida que actúa en forma similar al DCCNa (trocloseno o dicloroisocianurato sódico)In essence, the granulated ATCC (synclosen) does not oxidizer for improved storage and transport, comprising ATCC (synclosen) powder from the dryer and before being granulated, characterized in that it comprises the ATCC (synclosen) in powder mixed with at least one additive such as boric acid, forming a preparation, in which boric acid acts as lubricant to facilitate compaction and as an ATCC flame retardant (synclosen), which constitute a non-hazardous product for storage and transport, fast dissolving that acts in the form similar to DCCNa (troclosen or sodium dichloroisocyanurate)

La composición del preparado es ATCC (Sincloseno) 61%, Acido bórico 16%, Carbonato Sódico 13% y Bicarbonato Sódico 10%.The composition of the preparation is ATCC (Sinclosen) 61%, Boric acid 16%, Sodium Carbonate 13% and 10% sodium bicarbonate.

El ATCC (sincloseno)granulado no comburente para su almacenaje, transporte y multiacción se caracteriza porque sobre el ATCC se añaden otros aditivos con características algicidas, floculantes, anticalcáreos de multiplica-
ción.
The non-oxidizing granulated ATCC (synclosen) for storage, transport and multiaction is characterized by the addition of other additives with algicidal, flocculating, anti-chalking characteristics multiplied to the ATCC.
tion.

El proceso de fabricación del ATCC (sincloseno o ácido tricloroisocianúrico) granulado no comburente para su almacenaje y transporte mejorados, para llevar a cabo la obtención del ATCC (sincloseno) granulado no comburente para su almacenaje y transporte, en el que el ATCC (sincloseno) se obtiene en forma convencional hasta la salida del secadero en el que se encuentra en polvo, se caracteriza porque el ATCC (sincloseno) en polvo a la salida del secadero y antes de ser granulado, se conduce a una tolva mezcladora o equipo de características similares en la que se añade el ácido bórico que actúa como lubricante para facilitar la compactación y como ignífugo del ATCC (sincloseno), después de lo cual a la mezcla de ATCC (sincloseno) y ácido bórico se añaden otras sustancias como el carbonato sódico y el bicarbonato sódico.The manufacturing process of ATCC (synclosen or  trichloroisocyanuric acid) non-oxidized granulate for improved storage and transport, to carry out the procurement of the non-oxidizing granulated ATCC (synclosen) for storage and transport, in which the ATCC (synclosen) is obtained in the form conventional until the exit of the dryer in which it is located in powder, is characterized in that the ATCC (synclosen) powder to the exit from the dryer and before being granulated, it leads to a mixer hopper or equipment with similar characteristics in which add boric acid that acts as a lubricant to facilitate compaction and as a flame retardant of the ATCC (synclosen), after which to the mixture of ATCC (synclosen) and boric acid are added other substances such as sodium carbonate and bicarbonate sodium

Descripción detallada de una forma de realización preferidaDetailed description of a preferred embodiment

La invención utiliza como aditivo para fabricar el ATCC (sincloseno o ácido tricloroisocianúrico) granulado no comburente para almacenaje y transporte mejorados, el ácido bórico, que ya se está utilizando en la fabricación de tabletas de cloro como aditivo que actúa como lubricante para facilitar la compactación y como ignífugo del ATCC (sincloseno), logrando tabletas de cloro no comburentes para almacenaje (según método CE A. 17).The invention uses as an additive to manufacture ATCC (synclosen or trichloroisocyanuric acid) granulated no oxidizer for improved storage and transport, boric acid, which is already being used in the manufacture of chlorine tablets as an additive that acts as a lubricant to facilitate compaction and as a flame retardant of the ATCC (synclosen), achieving non-oxidizing chlorine tablets for storage (according to CE method A. 17).

El ácido bórico es un compuesto químico levemente ácido. Es usado como antiséptico, insecticida, agente tampón o buffer, ignífugo, etc.Boric acid is a chemical compound slightly acidic. It is used as an antiseptic, insecticide, agent buffer or buffer, fire retardant, etc.

1one

La composición del ATCC (sincloseno) granulado no comburente para almacenaje es:The composition of the granulated ATCC (synclosen) Non-oxidizer for storage is:

22

El ácido bórico atendiendo a la peligrosidad, se ha catalogado como Categoría 2, proponiendo su limitación a un 5,5% como máximo, en composiciones de productos para el agua de piscinas.Boric acid according to the danger, is  has been cataloged as Category 2, proposing its limitation to a 5.5% maximum, in water product compositions of swimming pools.

Diferencia entre el ATCC (sincloseno) granulado identificado como (300/GR) y el ATCC (sincloseno) + BO_{3}H_{3} granulado identificado como (303/GR).Difference between granulated ATCC (synclosen) identified as (300 / GR) and ATCC (synclosen) + BO_ {3} H_ {3} granulate identified as (303 / GR).

33

Ventajas que presenta el 303/GRAdvantages of the 303 / GR

- Innovación- Innovation

- Exclusiva- Exclusive

- Producto no peligroso para almacenaje y transporte.- Non-hazardous product for storage and transport.

       \vskip1.000000\baselineskip\ vskip1.000000 \ baselineskip
    

La empresa no debe darse de alta como almacén de productos peligrosos, por lo tantoThe company must not register as a warehouse for  dangerous products therefore

Un menor coste en la póliza de segurosA lower cost in the insurance policy

Un menor coste en las medidas de seguridad.A lower cost in security measures.

       \vskip1.000000\baselineskip\ vskip1.000000 \ baselineskip
    

Para la fabricación de tabletasFor the manufacture of tablets

No hace falta añadir ni mezclar ninguna sustancia para compactar.No need to add or mix any substance to compact.

No se tiene que comprar aditivos para compactarYou don't have to buy additives to compact

Se evita la rotura del grano al no tener que mezclarThe breakage of the grain is avoided by not having to Mix

Menos maquinaria (basculas, mezcladoras)Less machinery (scales, mixers)

Menos personalLess personal

Menos mantenimientoLess maintenance

       \vskip1.000000\baselineskip\ vskip1.000000 \ baselineskip
    

Para fabricar el 303/GR se necesita que cuando el ATCC (sincloseno) en polvo sale del filtro secadero se debe conducir a una tolva mezcladora o equipo de características similares donde se añade el ácido bórico en cantidad suficiente para que a continuación se mezcle en un tiempo suficiente, y por último se conduce esta mezcla al sistema de granulación.To make the 303 / GR you need when the ATCC (synclosen) powder leaves the filter drier must lead to a mixing hopper or equipment features similar where boric acid is added in sufficient quantity so that it is then mixed in a sufficient time, and by Finally, this mixture is conducted to the granulation system.

Para llevar a cabo el proceso de fabricación se requiere material básico.To carry out the manufacturing process, Requires basic material.

El aditivo, ácido bórico, se añade al proceso continuo de fabricación del ATCC (sincloseno).The additive, boric acid, is added to the process continuous manufacturing of the ATCC (synclosen).

Transporte del ATCC (sincloseno) desde el filtro secadero a la tolva mezcladora o equipo de características similares.Transport of the ATCC (synclosen) from the filter  dryer to mixer hopper or equipment features Similar.

Tolva mezcladora (2 instaladas en paralelo, capacidad 1 TM/u).Mixing hopper (2 installed in parallel, capacity 1 MT / u).

Sistema dosificador de ácido bórico.Boric acid dosing system.

Transporte de la mezcla desde la tolva mezcladora al sistema de granulación.Transport of the mixture from the hopper mixer to the granulation system.

AutomatizaciónAutomation

La forma descrita es una forma de fabricar el 303/GR, se pueden estudiar otras.The manner described is a way of manufacturing the 303 / GR, others can be studied.

La presente invención prevé seguir añadiendo mas sustancias al preparado mencionado para conseguir un ATCC (sincloseno) granulado no comburente para su almacenaje y transporte mejorados.The present invention intends to continue adding more  substances to the preparation mentioned to get an ATCC (synclosen) non-oxidized granulate for storage and Improved transportation

En primer lugar, se intenta conseguir un preparado de disolución rápida, similar a la del denominado DCCNa (trocloseno o dicloroisocianurato sódico). Para lo cual si a este preparado se añaden más sustancias se puede obtener un producto granulado que actúe como el DCCNa (trocloseno o dicloroisocianurato sódico).First, you try to get a rapid dissolution preparation, similar to that of the so-called DCCNa (troclosen or sodium dichloroisocyanurate). For which if this prepared add more substances you can get a product granulate that acts like DCCNa (troclosen or dichloroisocyanurate sodium)

Este producto se identifica como 302/GR.This product is identified as 302 / GR.

44

Diferencia entre el Dicloro identificado como 200/GR y el identificado como 302/GRDifference between the dichloro identified as 200 / GR and the one identified as 302 / GR

55

Ventajas del producto 302/GRProduct advantages 302 / GR

InnovaciónInnovation

ExclusivaExclusive

Menor aportación de Ácido CianúricoLower contribution of Cyanuric Acid

       \vskip1.000000\baselineskip\ vskip1.000000 \ baselineskip
    

Para la fabricación de tabletasFor the manufacture of tablets

No hace falta añadir ni mezclar ninguna sustancia para compactarNo need to add or mix any substance to compact

No se tiene que comprar aditivos para compactar Se evita la rotura del grano al no tener que mezclarYou don't have to buy additives to compact The breakage of the grain is avoided by not having to mix

Menos maquinaria (basculas, mezcladoras)Less machinery (scales, mixers)

Menos personalLess personal

Menos mantenimientoLess maintenance

       \vskip1.000000\baselineskip\ vskip1.000000 \ baselineskip
    
Desventajas del producto 302/GRDisadvantages of the product 302 / GR

Se debe realizar una inversión en fase industrialización (se debería estudiar posibilidad de subvención por reducción de la peligrosidad e innovación). Se podría utilizar la misma que para la fabricación del 303/GR.A phase investment must be made industrialization (possibility of subsidy should be studied by reduction of danger and innovation). Could be used the same as for the manufacture of 303 / GR.

Asimismo, la invención prevé añadir siempre sobre el ATCC (sincloseno) otros aditivos, con lo que se pueden fabricar otros productos multiacción de características algicidas, floculantes, anticalcáreos, etc.Also, the invention always provides on the ATCC (synclosen) other additives, so you can manufacture other multi-action products with algicidal characteristics, flocculants, anti-calcareous, etc.

La invención, dentro de su esencialidad, puede ser llevada a la práctica en otras formas de realización que difieran solo en detalle de la indicada, únicamente a título de ejemplo a las cuales alcanzará igualmente la protección que se recaba. Podrá, pues, realizarse este proceso con los medios y componentes más convenientes y con la correspondiente instalación provista de los accesorios más adecuados, pudiendo los elementos componentes ser sustituidos por otros técnicamente equivalentes, por quedar todo ello comprendido dentro de las reivindicaciones.The invention, within its essentiality, can be put into practice in other embodiments that differ only in detail from that indicated, solely by way of example to which will also reach the protection that collect. This process can therefore be carried out with the means and more convenient components and with the corresponding installation provided with the most suitable accessories, being able to the elements components be replaced by other technically equivalent ones, by All of this falls within the claims.

Claims (4)

1. ATCC (sincloseno) granulado no comburente para su almacenaje y transporte mejorados, que comprende ATCC (sincloseno) en polvo procedente del secadero y antes de ser granulado, caracterizado porque comprende el ATCC (sincloseno) en polvo mezclado con al menos un aditivo tal como el ácido bórico, formando un preparado, en el que el ácido bórico actúa como lubricante para facilitar la compactación del ATCC (sincloseno)en forma de tabletas de cloro y como ignífugo del ATCC (sincloseno), al que se añaden otras sustancias tal como carbonato sódico y bicarbonato sódico, que constituyen un producto no peligroso para almacenaje y transporte de disolución rápida que actúa en forma similar al DCCNa (Trocloseno).1. Non-oxidizing granulated ATCC (synclosen) for improved storage and transport, comprising ATCC (synclosen) powder from the dryer and before being granulated, characterized in that it comprises powdered ATCC (synclosen) mixed with at least one such additive as boric acid, forming a preparation, in which boric acid acts as a lubricant to facilitate the compaction of ATCC (synclosen) in the form of chlorine tablets and as a flame retardant of ATCC (synclosen), to which other substances such as sodium carbonate and sodium bicarbonate, which constitute a non-hazardous product for storage and transport of rapid dissolution that acts in a similar way to DCCNa (Trocloseno). 2. ATCC (sincloseno) granulado no comburente para su almacenaje y transporte, según la reivindicación 1, caracterizado porque la composición del preparado es ATCC (Sincloseno) un 61%, Acido Bórico 16%, Carbonato Sódico 13% y Bicarbonato Sódico 10%.2. Non-oxidizing granulated ATCC (synclosen) for storage and transport, according to claim 1, characterized in that the composition of the preparation is 61% ATCC (Sinclosen), 16% Boric Acid, 13% Sodium Carbonate and 10% Sodium Bicarbonate. 3. ATCC (sincloseno) granulado no comburente para su almacenaje y transporte, multiacción, según la reivindicación 1, caracterizado porque sobre el ATCC (sincloseno)en polvo se añaden otros aditivos con características algicidas, floculantes, anticalcáreos de multiplicación.3. Non-oxidizing granulated ATCC (synclosen) for storage and transport, multiaction, according to claim 1, characterized in that other additives with algicidal, flocculating, anti-scale multiplication characteristics are added to the powdered ATCC (powder). 4. Proceso de fabricación de ATCC (sincloseno) granulado no comburente para su almacenaje y transporte mejorados, para llevar a cabo la obtención del ATCC (sincloseno) granulado no comburente para su almacenaje y transporte de las reivindicaciones anteriores, en el que el ATCC (sincloseno) se obtiene en forma convencional hasta la salida del secadero en el que se encuentra en polvo, caracterizado porque el ATCC (sincloseno) en polvo a la salida del secadero y antes de ser granulado, se conduce a una tolva mezcladora (o equipo de características similares) en la que se añade el ácido bórico que actúa como lubricante para facilitar la compactación del ATCC (sincloseno) en forma de tabletas de cloro y como ignífugo del ATCC (sincloseno) después de lo cual a la mezcla de ATCC (sincloseno) y ácido bórico se añaden otras sustancias como el carbonato sódico y el bicarbonato sódico.4. Manufacturing process of ATCC (synclosen) non-oxidizing granules for improved storage and transport, to carry out obtaining the ATCC (synclosen) non-oxidizing granules for storage and transport of the preceding claims, wherein the ATCC ( synclosen) is obtained in a conventional manner until the exit of the dryer in which it is in powder, characterized in that the ATCC (synclosen) powder at the exit of the dryer and before being granulated, is conducted to a mixing hopper (or equipment of similar characteristics) in which boric acid that acts as a lubricant is added to facilitate the compaction of ATCC (synclosen) in the form of chlorine tablets and as a flame retardant of ATCC (synclosen) after which to the mixture of ATCC (synclosen) and boric acid other substances such as sodium carbonate and sodium bicarbonate are added.
ES200702666A 2007-10-10 2007-10-10 ATCC (SYNCLOSENE) GRANULATED NON-COMBURENT FOR YOUR IMPROVED STORAGE AND TRANSPORTATION AND ITS MANUFACTURING PROCESS. Expired - Fee Related ES2321049B1 (en)

Priority Applications (1)

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ES200702666A ES2321049B1 (en) 2007-10-10 2007-10-10 ATCC (SYNCLOSENE) GRANULATED NON-COMBURENT FOR YOUR IMPROVED STORAGE AND TRANSPORTATION AND ITS MANUFACTURING PROCESS.

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ES200702666A ES2321049B1 (en) 2007-10-10 2007-10-10 ATCC (SYNCLOSENE) GRANULATED NON-COMBURENT FOR YOUR IMPROVED STORAGE AND TRANSPORTATION AND ITS MANUFACTURING PROCESS.

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ES2321049A1 true ES2321049A1 (en) 2009-06-01
ES2321049B1 ES2321049B1 (en) 2010-03-11

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51139628A (en) * 1975-05-28 1976-12-02 Nissan Chem Ind Ltd Isocyanuric acid trichloride tablet composition, degradative into gran ules
US4557926A (en) * 1983-09-06 1985-12-10 Monsanto Company Method and tablet for sanitizing toilets
ES8800821A1 (en) * 1985-01-09 1987-12-01 Charbonnages Ste Chimique Chlorinated effervescent tablets, process for their production and their use
WO1999040162A1 (en) * 1998-02-09 1999-08-12 Chem Lab Products, Inc. A quickly dissolving chlorine release mixture
EP1095566A2 (en) * 1999-10-29 2001-05-02 Great Lakes Chemical Corporation Stable, high available halogen 1,3,5-triazine-2,4,6-trione compositions having rapid dissolution rates

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51139628A (en) * 1975-05-28 1976-12-02 Nissan Chem Ind Ltd Isocyanuric acid trichloride tablet composition, degradative into gran ules
US4557926A (en) * 1983-09-06 1985-12-10 Monsanto Company Method and tablet for sanitizing toilets
ES8800821A1 (en) * 1985-01-09 1987-12-01 Charbonnages Ste Chimique Chlorinated effervescent tablets, process for their production and their use
WO1999040162A1 (en) * 1998-02-09 1999-08-12 Chem Lab Products, Inc. A quickly dissolving chlorine release mixture
EP1095566A2 (en) * 1999-10-29 2001-05-02 Great Lakes Chemical Corporation Stable, high available halogen 1,3,5-triazine-2,4,6-trione compositions having rapid dissolution rates

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